Enhancing the availability and reliability of dielectric ceramic energy storage devices is of great importance.In this work,(1-x)Na_(0.5)Bi_(0.5)TiO_(3)-xBi(Mg_(0.5)Hf_(0.5))O_(3)(NBT-xBMH)lead-free ceramics were crea...Enhancing the availability and reliability of dielectric ceramic energy storage devices is of great importance.In this work,(1-x)Na_(0.5)Bi_(0.5)TiO_(3)-xBi(Mg_(0.5)Hf_(0.5))O_(3)(NBT-xBMH)lead-free ceramics were created utilizing a solid-state reaction technique.All NBT-xBMH ceramics have a single perovskite structure.With increasing BMH doping,the grain size shrinks drastically,which greatly enhances the breakdown electric field(310 kV/cm at x=0.25).Additionally,the relaxation behaviors of NBT-xBMH ceramics with high BMH content are more remarkable.Among all designed components,the NBT-0.25BMH ceramic exhibits the best energy storage performance with a high Wrec of 4.63 J/cm^(3) and anηof 75.1%at 310 kV/cm.The NBT-0.25BMH ceramic has exceptional resistance to fluctuations in both frequency(5-500 Hz)and temperature(30-100°C).Charge-discharge test shows that the NBT-0.25BMH ceramic has a quick discharge rate(t0.9<110 ns).With these properties,the NBT-0.25BMH ceramic may have applications in microdevices as well as in ultra-high power electronic systems.展开更多
A series of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors were synthesized by solid-state reaction method. The crystal structure, photolu- minescence emission and excitation spectra and decay times of the phosphors were care...A series of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors were synthesized by solid-state reaction method. The crystal structure, photolu- minescence emission and excitation spectra and decay times of the phosphors were carefully investigated. The results revealed that an effi- cient energy transfer occurred from Ce3+ to Zb3+ ions in NaBaPO4 host by means of dipole-dipole interactions and the critical distance of the energy transfer was about 0.638 nm. Moreover, the phosphor emitted strong green emission under UV excitation, indicating that the phos- phors are potentially useful as a highly efficient, green-emitting phosphor.展开更多
Surface plasmonic resonance(SPR)has been a corner stone for approaching single molecular detection due to its highsensitivity capability and simple detection mechanism,and has brought major advancements in biomedicine...Surface plasmonic resonance(SPR)has been a corner stone for approaching single molecular detection due to its highsensitivity capability and simple detection mechanism,and has brought major advancements in biomedicine and life science technology.Over decades,the successful integration of SPR with versatile techniques has been demonstrated.However,several crucial limitations have hindered this technique for practical applications,such as long detection time and low overall sensitivity.This review aims to provide a comprehensive summary of existing approaches in enhancing the performance of SPR sensors based on“passive”and“active”methods.Firstly,passive enhancement is discussed from a material aspect,including signal amplification tags and modifications of conventional substrates.Then,the focus is on the most popular active enhancement methods including electrokinetic,optical,magnetic,and acoustic manipulations that are summarized with highlights on their advantageous features and ability to concentrate target molecules at the detection sites.Lastly,prospects and future development directions for developing SPR sensing towards a more practical,single molecular detection technique in the next generation are discussed.This review hopes to inspire researchers’interests in developing SPR-related technology with more innovative and influential ideas.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.51604087,11904056,and 12172093)the Guangdong Basic and Applied Basic Research Foundation(Grant No.2021A1515012607).
文摘Enhancing the availability and reliability of dielectric ceramic energy storage devices is of great importance.In this work,(1-x)Na_(0.5)Bi_(0.5)TiO_(3)-xBi(Mg_(0.5)Hf_(0.5))O_(3)(NBT-xBMH)lead-free ceramics were created utilizing a solid-state reaction technique.All NBT-xBMH ceramics have a single perovskite structure.With increasing BMH doping,the grain size shrinks drastically,which greatly enhances the breakdown electric field(310 kV/cm at x=0.25).Additionally,the relaxation behaviors of NBT-xBMH ceramics with high BMH content are more remarkable.Among all designed components,the NBT-0.25BMH ceramic exhibits the best energy storage performance with a high Wrec of 4.63 J/cm^(3) and anηof 75.1%at 310 kV/cm.The NBT-0.25BMH ceramic has exceptional resistance to fluctuations in both frequency(5-500 Hz)and temperature(30-100°C).Charge-discharge test shows that the NBT-0.25BMH ceramic has a quick discharge rate(t0.9<110 ns).With these properties,the NBT-0.25BMH ceramic may have applications in microdevices as well as in ultra-high power electronic systems.
基金Project supported by the Cooperation Project in Industry, Education and Research of Guangdong ProvinceMinistry of Education of China(2010B090400021)
文摘A series of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors were synthesized by solid-state reaction method. The crystal structure, photolu- minescence emission and excitation spectra and decay times of the phosphors were carefully investigated. The results revealed that an effi- cient energy transfer occurred from Ce3+ to Zb3+ ions in NaBaPO4 host by means of dipole-dipole interactions and the critical distance of the energy transfer was about 0.638 nm. Moreover, the phosphor emitted strong green emission under UV excitation, indicating that the phos- phors are potentially useful as a highly efficient, green-emitting phosphor.
基金the National Natural Science Foundation of China(No.61905145)Guangdong Natural Science Foundation and Province Project(No.2021A1515011916)Shenzhen Science and Technology R&D and Innovation Foundation(No.JCYJ20200109105608771).
文摘Surface plasmonic resonance(SPR)has been a corner stone for approaching single molecular detection due to its highsensitivity capability and simple detection mechanism,and has brought major advancements in biomedicine and life science technology.Over decades,the successful integration of SPR with versatile techniques has been demonstrated.However,several crucial limitations have hindered this technique for practical applications,such as long detection time and low overall sensitivity.This review aims to provide a comprehensive summary of existing approaches in enhancing the performance of SPR sensors based on“passive”and“active”methods.Firstly,passive enhancement is discussed from a material aspect,including signal amplification tags and modifications of conventional substrates.Then,the focus is on the most popular active enhancement methods including electrokinetic,optical,magnetic,and acoustic manipulations that are summarized with highlights on their advantageous features and ability to concentrate target molecules at the detection sites.Lastly,prospects and future development directions for developing SPR sensing towards a more practical,single molecular detection technique in the next generation are discussed.This review hopes to inspire researchers’interests in developing SPR-related technology with more innovative and influential ideas.