Cu_2ZnSnS_4 thin films prepared by sulfurization of ion beam sputtered precursor and their electrical and optical properties

Cu2ZnSnS4 (CZTS) thin films were successfully prepared by sulfurization of ion bean sputtered precursors on soda-lime glass substrate. The single phase of stannite-type structure CZTS films were obtained as revealed in EDS and XRD analysis when the ratios of the constituents of CZTS thin films are close to stoichiometric by optimizing the conditions of precursor preparation and sulfurization. A low sheet resistivity as about 0.156 Ω·cm and a high absorption coefficient as 1×104 cm-1 were achieved in this method by Hall effect measurements and UV-VIS spectrophotometer. The optical band-gap energy of the CZTS sample is about 1.51 eV, which is very close to the optimum value for a solar-cell absorber.

Technological conditions and kinetics of leaching copper from complex copper oxide ore

The kinetic behavior of leaching copper from low grade copper oxide ore was investigated. The effects of leaching temperature, H2SO4 concentration, particle size of crude ore and agitation rate on the leaching efficiency of copper were also evaluated. And the kinetic equations of the leaching process were obtained. The results show that the leaching process can be described with a reaction model of shrinking core. The reaction can be divided into three stages. The first stage is the dissolution of free copper oxide and copper oxide wrapped by hematite-limonite ore. At this stage, the leaching efficiency is very fast （leaching efficiency is larger than 60%）. The second stage is the leaching of diffiuent copper oxides, whose apparent activation energy is 43.26 kJ/mol. During this process, the chemical reaction is the control step, and the reaction order of H2SO4 is 0.433 84. The third stage is the leaching of copper oxide wrapped by hematite-limonite and silicate ore with apparent activation energy of 16.08 kJ/mol, which belongs to the mixed control.

Functional Imaging of Breast Tissue and Clinical Application

A novel approach to image hemoglobin concentration（△Dhb） and oxygen saturation （△Doxy） of breast tissue is presented. The scenograph of dual-wavelength （760 and 850 nm） near infrared lights through breast tissue is acquired by high sensitive charge coupled device （CCD） camera. The evaluation criterion of the difference of △Dhh and △Doxy between detected and referenced breast tissue can be obtained by a calculation formula without complicate caculation. This approach is applied to clinic detection in breast tissue. The ongoing clinical experiments indicate that malignant tumor usually exhibits characterize of ＂higher △Dhb and lower △Doxy＂, while benign lesion often shows ＂lower △Dhb and higher △Doxy＂ or other characters. So it is useful to assist the diagnosis of breast disease.

Effect of Sc and Zr on the in-plane anisotropy of Al-Mg-Mn alloy sheets

The Al-Mg-Mn alloy sheets with and without trace Sc and Zr were investigated by means of tensile test,X-ray diffraction,optical microscope,and transmission electron microscope.The indexes of in-plane anisotropy(IIPA)of their tensile mechanical properties were calculated and their inverse pole figures were obtained by Harris method.The two alloy sheets have the same law of in-plane anisotropy and remarkable in-plane anisotropy of mechanical properties,and the IIPA of the alloy sheet with Sc and Zr is bigger than that of the alloy sheet without Sc and Zr.The relationships of the in-plane anisotropy and the anisotropy of the crystallographic texture were analyzed based on the model of monocrystal.It is the common action of the anisotropy of crystallography and microstructures that causes the in-plane anisotropy of their mechanical properties,but the major cause is the{110}〈112〉crystallographic texture.The trace Sc and Zr can promote the formation and stabilization of the{110}〈112〉texture,inhibit the formation of the{100}〈001〉texture,and increase the in-plane anisotropy of the alloy sheet containing trace Sc and Zr.

Influence of Coloured Correlated Noises on Probability Distribution and Mean of Tumour Cell Number in the Logistic Growth Model

An approximate Fokker-Planck equation for the logistic growth model which is driven by coloured correlated noises is derived by applying the Novikov theorem and the Fox approximation. The steady-state probability distribution （SPD） and the mean of the tumour cell number are analysed. It is found that the SPD is the single extremum configuration when the degree of correlation between the multiplicative and additive noises, λ is in -1 〈λ≤0 and can be the double extrema in 0〈λ〈1. A configuration transition occurs because of the variation of noise parameters. A minimum appears in the curve of the mean of the steady-state tumour cell number, （x）, versus λ The position and the value of the minimum are controlled by the noise-correlated times.

Preparation of the four-qubit cluster states in cavity QED and the trapped-ion system

This paper proposes a simple scheme to generate a four-atom entangled cluster state in cavity quantum electrodynamics. With the assistantce of a strong classical field the cavity is only virtually excited and no quantum information will be transferred from the atoms to the cavity during the preparation for a four-atom entangled cluster state, and thus the scheme is insensitive to the cavity field states and cavity decay. Assuming that deviation of laser intensity is 0.01 and that of simultaneity for the interaction is 0.01, it shows that the fidelity of the resulting four-atom entangled cluster state is about 0.9886. The scheme can also be used to generate a four-ion entangled cluster state in a hot trapped-ion system. Assuming that deviation of laser intensity is 0.01, it shows that the fidelity of the resulting four-ion entangled cluster state is about 0.9990. Experimental feasibility for achieving this scheme is also discussed.

Effect of sputtering pressure and rapid thermal annealing on optical properties of Ta_2O_5 thin films

Ta2O5 thin films were deposited by DC reactive magnetron sputtering followed by rapid thermal annealing(RTA). Influence of sputtering pressure and annealing temperature on surface characteristics,microstructure and optical property of Ta2O5 thin films were investigated. As-deposited Ta2O5 thin films are amorphous. It takes hexagonal structure(δ-Ta2O5) after being annealed at 800 ℃. A transition from δ-Ta2O5 to orthorhombic structure(L-Ta2O5) occurs at 900-1 000 ℃. Surface roughness is decreased after annealing at low temperature. Refractive index and extinction coefficient are decreased when annealing temperature is increased.

Effect of F- and CH-Doped on Dielectric Properties of SiCOH Films Deposited by Decamethylcyclopentasiloxane Electron Cyclotron Resonance Plasma

We investigate the effect of CH-doped and F-doped on dielectric properties of SiCOH films deposited by de- camethylcyclopentasiloxane （DMCPS） electron cyclotron resonance plasma. The dielectric constant k is closely related to the configurations of films. For the films deposited only using DMCPS, the minimum k is as low as 2.88. By adding CH4 in the precursor, the k value can be reduced to 2.45 due to the film density decreasing by incorporating large size CHx groups. By adding CHF3 in the precursor, the k value can also be reduced to 2.48 due to the incorporation of the weak-polarization F atom. Thus the dielectric constant for SiCOH films depends on not only the film density but also the polarization of atoms. By increasing the film density or by reducing the polarization of atoms under the condition of a lower film density, the low dielectric constant SiCOH films can be obtained.

Structure and electronic properties of SiC thin-films deposited by RF magnetron sputtering

SiC thin-films were prepared by RF-magnetron sputtering technique(RMS) with the target of single crystalline SiC and then annealed. The surface morphology of thin-films was characterized by AFM. The result shows that the surface of the thin-films is smooth and compact; XRD analysis reveals that the thin-films are amorphous. The thickness, square-resistance and curves of resistance—temperature were measured. The results show that the curves of lnR versus 1/kT both before and after annealing satisfy the expression of lnR∝△W/kT, where ?W is electron excitation energy in the range of 0.014 2-0.018 5 eV, and it has a trend of increasing when the temperature is increased. After synthetical analysis we get the conclusion that the electronic mechanism of the thin-films is short distance transition between the localized states in the temperature range of 25-250 ℃. The resistivity is in the range of 2.4×10-3-4.4×10-3 Ω·cm and it has the same trend as electron excitation energy when annealing temperature is increased, which further confirms the electronic mechanism of thin-films and the trend of electron excitation energy versus annealing temperature.

Hyperchaos behaviors and chaos synchronization of two unidirectional coupled simplified Lorenz systems

To design a hyperchaotic generator and apply chaos into secure communication, a linear unidirectional coupling control is applied to two identical simplified Lorenz systems. The dynamical evolution process of the coupled system is investigated with variations of the system parameter and coupling coefficients. Particularly, the influence of coupling strength on dynamics of the coupled system is analyzed in detail. The range of the coupling strength in which the coupled system can generate hyperchaos or realize synchronization is determined, including phase portraits, Lyapunov exponents, and Poincare section. And the critical value of the system parameter between hyperchaos and synchronization is also found with fixed coupled strength. In addition, abundant dynamical behaviors such as four-wing hyperchaotic, two-wing chaotic, single-wing coexisting attractors and periodic orbits are observed and chaos synchronization error curves are also drawn by varying system parameter c. Numerical simulations are implemented to verify the results of these investigations.

Effect of flank angle and friction coefficient on contact stress of turbine rotor

In order to simulate the stress of turbine rotor in aeroengine, based on the ANSYS, the simplification model of the turbine rotor was built up. By applying the simplification model, the contact stress of turbine rotor was computed. The maximum contact stress appears at the chamfer below the flank, which agrees with experiment result. At the same time, the contact stress changing with the flank angle and friction coefficient was calculated, The results show that the contact stress in the flank increases slowly with the increase of flank angle; with the friction coefficient increasing, the contact stress in flank length decreases; the contact stress will not change when the friction coefficient is over 0.25.

Observation of Periodic Multiplication and Chaotic Phenomena in Atmospheric Cold Plasma Jets

We investigate the temporal evolution of the current pulses from an ac Fie cold plasma jet at atmospheric pressure and with driving frequency in the range 14.76-15.30 kHz. The driving frequency is used as the plasma system＇s bifurcation parameter in analogy with the evolution in which the current pulses undergoes multiplication and chaos. Such time-domain nonlineaxity is important for controlling instabilities in atmospheric glow discharges. In addition, the observation can provide some data to support the simulation results reported previously [Appl. Phys. Lett. 90 （2007） 071501].

Magnetocrystalline anisotropy and spin reorientation transition of DyMn_6Sn_6 compound

The spin-reorientation transition of intermetallic compound DyMn6Sn6 was investigated by applying the molecular field theory. The temperature dependence of easy magnetization direction of compound and the magnetic moment directions of Dy and Mn ions were theoretically calculated and they have good agreement with the experimental data. In the framework of single ion model, the temperature dependence of magnetocrystalline anisotropic constants K1R and K2R of Dy ion were also calculated. The results show that the fourth-order crystal field parameter, B 40, and the corresponding second-order magnetocrystalline anisotropic constant, K2R, of Dy ion must be taken into account in order to explain the spin-reorientation transition satisfactorily. The competition between K2R and K1R plays a key role in the spin-reorientation transition of DyMn6Sn6.

Mechanism of toughening and strengthening of Si_3N_4/SiC/ZrO_2 nanocomposites

The Si3N4-based nanocomposites reinforced with micro ZrO2 and nano SiC particles were prepared by polarity dispersant and vacuum-sintering technology. The mechanical properties and microstructures were tested. The results show that appropriate amount of micro ZrO2 and nano SiC particles, not only enhance the microhardness, but also block the excessively growth of β-Si3N4 and β-Si3N4 grains, so they finally all grow up to uniformly pole-shaped grains. This process is similar to the strengthening and toughening mechanism of grain whiskers and makes a remarkable improvement on the toughness. Compared with Si3N4 ceramic, the toughness of Si3N4/SiC/ZrO2 nanocomposites are increased from 6.2 MPa·m1/2 to 11 MPa·m1/2.

Hydrothermal Preparation and White-Light-Controlled Resistive Switching Behavior of BaWO_4 Nanospheres

In this work, BaWO4 nanospheres were successfully prepared by hydrothermal process. The bipolar resistive switching behavior of Ag/BaWO4/FTO device is observed. Moreover, this resistive switching behavior can be modulated by white light. The device can maintain superior stability in the dark and under white-light illumination. This study is useful for developing the light-controlled nonvolatile memory devices.

Effect of Low-frequency Power on F, CF_2 Relative Density and F/CF_2 Ratio in Fluorocarbon Dual-Frequency Plasmas

Effect of low-frequency power on F, CF2 relative density and F/CF2 ratio, in C2F6, C4F8 and CHF3 dual-frequency capacitively couple discharge driven by the power of 13.56 MHz/2 MHz, was investigated by using optical emission spectroscopy. High F, CF2 relative density and high F/CF2 ratio were obtained in a CHF3 plasma. But for C2F6 and C4Fs plasmas, the F, CF2 relative density and F/CF2 ratio all decreased significantly due to the difference in both reactive paths and reactive energy. The increase of LF power caused simultaneous increase of F and CF2 radical relative densities in C4Fs and CHF3 plasmas, but led to increase of F with the decrease in CF2 relative densities in C2F6 plasma due to the increase of lower energy electrons and the decrease of higher energy electrons in electron energy distribution function （EEDF）.

Exchange interactions and magnetic properties of intermetallic compounds

The temperature dependence of lattice parameters a and c of intermetallic compounds RMn 2Ge 2(R=La, Sm and Gd)were measured in the temperature range of 10800 K by using the X-ray diffractometer . It is found that the high temperature magnetic transitions of Mn-subsystem in light rare earth compounds from paramagnetic to antiferromagnetic state accompany the negative magnetoelastic anomalies of lattice parameters c, where a does not change. This indicates that the antiferromagnetic component of intralayer Mn-Mn exchange coupling is correlated with lattice constant c. The low temperature first order ferromagnetism→antiferromagnetism transitions(or antiferromagnetism→ferromagnetism transition) of Mn-subsystem in SmMn 2Ge 2 and GdMn 2Ge 2 accompany the abruptly decrease(or increase) of lattice parameter a, and Δa/a≈0.15%. This demonstrates that the interlayer Mn-Mn exchange interaction is very sensitive to the intralayer Mn-Mn distance. The critical value of lattice constant a k, at which the interlayer Mn-Mn coupling changes its sign, is 4.044 5×10 -10 m. Based on the molecular field model of exchange interaction the magnetic curves of GdMn 2Ge 2 single crystal at different temperatures were calculated and a good agreement with experimental data had gotten. The Gd-Gd, Gd-Mn, intralayer Mn-Mn and interlayer Mn-Mn exchange coupling parameters were estimated.

Negative Thermal Expansion and Spontaneous Magnetostriction of Nd2Fe16.5Cr0.5 Compound

The structural,thermal expansion,and magnetic properties of the Nc/2^16.5^0.5 compound are investigated by means of x-ray diffraction and magnetization measurements.The Nd2^616.560.5 compound has a rhombohedral Th2Znn-type structure.There exists a small negative thermal expansion resulting from a spontaneous magnetostriction in the magnetic state of the^2^16.5 Cr0.5 compound.The average thermal expansion coefficient is-1.06×10^6/K in a temperature range 299-394 K.The spontaneous magnetostrictive deformation and the Curie temperature are discussed.

Fabrication of nano-crystalline W-Ni-Fe alloy with Mo and rare earth element additives

Three kinds of nano-crystalline high density alloys(86W-7Ni-3Fe-4Mo, 90W-4Ni-2Fe-4Mo and 90W4Ni-2Fe-3.8Mo-0.2RE) were fabricated by a technique combining lower temperature vacuum sintering with highenergy ball milling mechanical alloying. The crystalline size and microstructures of the specimens sintered at different sintering temperatures were examined by X-ray diffraction(XRD) and scanning electron microscope(SEM). The results show that the optimal sintering temperature of 86W-7Ni-3Fe-4Mo, 90W-4Ni-2Fe-4Mo and 90W-4Ni-2Fe3.8Mo-0.2RE alloys are 1 300 - 1 350 ℃. When they are sintered at 1 300 ℃ for 75 min, the hardness of three kinds of specimens can reach above HRC30, the relative density can reach above 96%,and 90W-4Ni-2Fe-3.8Mo-0.2RE alloy possesses the best integrated properties, its hardness is HRC35 and its relative density is 98%.

Enhancement of proton collimation and acceleration by an ultra-intense laser interacting with a cone target followed by a beam collimator

A special method is proposed of a laser-induced cavity pressure acceleration scheme for collimating,accelerating and guiding protons,using a single-cone target with a beam collimator through a target normal sheath acceleration mechanism.In addition,the problems involved are studied by using two-dimensional particle-in-cell simulations.The results show that the proton beam can be collimated,accelerated and guided effectively through this type of target.Theoretically,a formula is derived for the combined electric field of accelerating protons.Compared with a proton beam without a beam collimator,the proton beam density and cut-off energy of protons in the type II are increased by 3.3 times and 10%respectively.Detailed analysis shows that the enhancement is mainly due to the compact and strong sheath electrostatic field,and that the beam collimator plays a role in focusing energy.In addition,the simulation results show that the divergence angle of the proton beam in type II is less than 1.67 times that of type I.The more prominent point is that the proton number of type II is 2.2 times higher than that of type I.This kind of target has important applications in many fields,such as fast ion ignition in inertial fusion,high energy physics and proton therapy.