A high-performance adaptive radiative cooler comprising a multilayer-filter VO_(2)-based Fabry-Pérot(FP)cavity is proposed.The bottom FP cavity has four layers,VO_(2)/NaCl/PVC/Ag.Based on the phase transition of ...A high-performance adaptive radiative cooler comprising a multilayer-filter VO_(2)-based Fabry-Pérot(FP)cavity is proposed.The bottom FP cavity has four layers,VO_(2)/NaCl/PVC/Ag.Based on the phase transition of VO_(2),the average emissivity in the transparent window can be switched from 3.7%to 96.3%.Additionally,the average emissivity can also be adjusted with external strain to the PVC layer,providing another way to attain the desired cooling effect.An upper filter is included to block most of the solar radiation and provide a transmittance of 96.7% in the atmospheric window.At high temperature,the adaptive emitter automatically activates radiative cooling.The net cooling power is up to 156.4 W·m^(-2)at an ambient temperature of 303 K.Our adaptive emitter still exhibits stable selective emissivity at different incident angles and heat transfer coefficients.At low temperature,the radiative cooling automatically deactivates,and the average emissivity decreases to only 3.8%.Therefore,our work not only provides new insights into the design of high-performance adaptive radiative coolers but also advances the development of intelligent thermal management.展开更多
The presence of interstitial electrons in electrides endows them with interesting attributes,such as low work function,high carrier concentration,and unique magnetic properties.Thorough knowledge and understanding of ...The presence of interstitial electrons in electrides endows them with interesting attributes,such as low work function,high carrier concentration,and unique magnetic properties.Thorough knowledge and understanding of electrides are thus of both scientific and technological significance.Here,we employ first-principles calculations to investigate Mott-insulating Ae_(5)X_(3)(Ae=Ca,Sr,and Ba;X=As and Sb)electrides with Mn_(5)Si_(3)-type structure,in which half-filled interstitial electrons serve as ions and are spin-polarized.The Mott-insulating property is induced by strong electron correlation between the nearest interstitial electrons,resulting in spin splitting and a separation between occupied and unoccupied states.The half-filled antiferromagnetic configuration and localization of the interstitial electrons are critical for the Mott-insulating properties of these materials.Compared with that in intermetallic electrides,the orbital hybridization between the half-filled interstitial electrons and the surrounding atoms is weak,leading to highly localized magnetic centers and pronounced correlation effects.Therefore,the Mott-insulating electrides Ae_(5)X_(3)have very large indirect bandgaps(0.30 eV).In addition,high pressure is found to strengthen the strong correlation effects and enlarge the bandgap.The present results provide a deeper understanding of the formation mechanism of Mott-insulating electrides and provide guidance for the search for new strongly correlated electrides.展开更多
基金supported by the Natural Science Foundation of Henan Province(Grant No.232102231023)。
文摘A high-performance adaptive radiative cooler comprising a multilayer-filter VO_(2)-based Fabry-Pérot(FP)cavity is proposed.The bottom FP cavity has four layers,VO_(2)/NaCl/PVC/Ag.Based on the phase transition of VO_(2),the average emissivity in the transparent window can be switched from 3.7%to 96.3%.Additionally,the average emissivity can also be adjusted with external strain to the PVC layer,providing another way to attain the desired cooling effect.An upper filter is included to block most of the solar radiation and provide a transmittance of 96.7% in the atmospheric window.At high temperature,the adaptive emitter automatically activates radiative cooling.The net cooling power is up to 156.4 W·m^(-2)at an ambient temperature of 303 K.Our adaptive emitter still exhibits stable selective emissivity at different incident angles and heat transfer coefficients.At low temperature,the radiative cooling automatically deactivates,and the average emissivity decreases to only 3.8%.Therefore,our work not only provides new insights into the design of high-performance adaptive radiative coolers but also advances the development of intelligent thermal management.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.12204419 and 12074013)。
文摘The presence of interstitial electrons in electrides endows them with interesting attributes,such as low work function,high carrier concentration,and unique magnetic properties.Thorough knowledge and understanding of electrides are thus of both scientific and technological significance.Here,we employ first-principles calculations to investigate Mott-insulating Ae_(5)X_(3)(Ae=Ca,Sr,and Ba;X=As and Sb)electrides with Mn_(5)Si_(3)-type structure,in which half-filled interstitial electrons serve as ions and are spin-polarized.The Mott-insulating property is induced by strong electron correlation between the nearest interstitial electrons,resulting in spin splitting and a separation between occupied and unoccupied states.The half-filled antiferromagnetic configuration and localization of the interstitial electrons are critical for the Mott-insulating properties of these materials.Compared with that in intermetallic electrides,the orbital hybridization between the half-filled interstitial electrons and the surrounding atoms is weak,leading to highly localized magnetic centers and pronounced correlation effects.Therefore,the Mott-insulating electrides Ae_(5)X_(3)have very large indirect bandgaps(0.30 eV).In addition,high pressure is found to strengthen the strong correlation effects and enlarge the bandgap.The present results provide a deeper understanding of the formation mechanism of Mott-insulating electrides and provide guidance for the search for new strongly correlated electrides.
