Antimony-doped tin hydroxide colloid precipitates have been synthesized by hydrolysis of SnCl4 and SbCl3 using： （1） an ion-exchange hydrolysis to remove chlorine ions, and （2） isoamyl acetate as an azeotropic sol...Antimony-doped tin hydroxide colloid precipitates have been synthesized by hydrolysis of SnCl4 and SbCl3 using： （1） an ion-exchange hydrolysis to remove chlorine ions, and （2） isoamyl acetate as an azeotropic solvent to obviate water. The obtained dried powder is of high dispersivity without any need for further grinding. The size and dispersivity of the final particles are investigated with the aid of TG-DTA, BET, XRD and TEM. After having calcined, the antimony-doped tin oxide nanopowder possesses a tetragonal rutile structure with high dispersivity, uniform particles and low hard agglomeration.展开更多
A novel current feed style, alternating pulse current, was proposed in electrocoagulation aiming at preventing the passivation of electrode materials. The open circuit potential （OCP） measurements after anodic and c...A novel current feed style, alternating pulse current, was proposed in electrocoagulation aiming at preventing the passivation of electrode materials. The open circuit potential （OCP） measurements after anodic and cathodic potentiodynamic polarization showed that cathodic polarization could activate Al electrode. The surface of Al electrode after alternating pulse current electrocoagulation was investigated by scanning electron microscope （SEM） and X-ray photoelectron spectroscopy （XPS）, and the results indicate that passivation of Al is not observed. Furthermore, the simulated wastewater treatment tests show that alternating pulse current electrocoagulation has a visible energy saving effect and is worthy of generalization.展开更多
基金National Natural Science Foundation of China (50533060)
文摘Antimony-doped tin hydroxide colloid precipitates have been synthesized by hydrolysis of SnCl4 and SbCl3 using： （1） an ion-exchange hydrolysis to remove chlorine ions, and （2） isoamyl acetate as an azeotropic solvent to obviate water. The obtained dried powder is of high dispersivity without any need for further grinding. The size and dispersivity of the final particles are investigated with the aid of TG-DTA, BET, XRD and TEM. After having calcined, the antimony-doped tin oxide nanopowder possesses a tetragonal rutile structure with high dispersivity, uniform particles and low hard agglomeration.
基金National 863 Plan(No.2005AA601010-02-2)Water Environment Research & Data Sharing Platform in the Middle Reaches of the Yangtse River(Wuhan University)(No.WERDSPMYR-0602)
文摘A novel current feed style, alternating pulse current, was proposed in electrocoagulation aiming at preventing the passivation of electrode materials. The open circuit potential （OCP） measurements after anodic and cathodic potentiodynamic polarization showed that cathodic polarization could activate Al electrode. The surface of Al electrode after alternating pulse current electrocoagulation was investigated by scanning electron microscope （SEM） and X-ray photoelectron spectroscopy （XPS）, and the results indicate that passivation of Al is not observed. Furthermore, the simulated wastewater treatment tests show that alternating pulse current electrocoagulation has a visible energy saving effect and is worthy of generalization.
