The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus ar...The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.展开更多
The surrounding rock of underground space is always affected by external dynamic disturbance from the side position,such as blasting vibration from a stope at the same level or seismic waves from adjacent strata.A ser...The surrounding rock of underground space is always affected by external dynamic disturbance from the side position,such as blasting vibration from a stope at the same level or seismic waves from adjacent strata.A series of laboratory tests,numerical simulations and theoretical analyses were carried out in this study to disclose the sliding mechanism of roof rock blocks under lateral disturbance.Firstly,the experiments on trapezoidal key block under various clamping loads and disturbance were conducted,followed by numerical simulations using the fast Lagrangian analysis of continua(FLAC3D).Then,based on the conventional wave propagation model and the classical shear-slip constitutive model,a theoretical model was proposed to capture the relative displacement between blocks and the sliding displacement of the key block.The results indicate that the sliding displacement of the key block increased linearly with the disturbance energy and decreased exponentially with the clamping load when the key block was disturbed to slide(without instability).Meanwhile,when the key block was disturbed to fall,two types of instability process may appear as immediate type or delayed type.In addition,the propagation of stress waves in the block system exhibited obvious low-velocity and lowfrequency characteristics,resulting in the friction reduction effect appearing at the contact interface,which is the essential reason for the sliding of rock blocks.The results can be applied to practical underground engineering and provide valuable guidance for the early detection and prevention of rockfalling disasters.展开更多
The seepage evolution characteristic of brittle rock materials is very significant for the stability and safety of rock engineering. In this research, a series of conventional triaxial compression and gas seepage test...The seepage evolution characteristic of brittle rock materials is very significant for the stability and safety of rock engineering. In this research, a series of conventional triaxial compression and gas seepage tests were carried out on sandstone specimens with a rock mechanics servo-controlled testing system. Based on the experimental results, the relationship between permeability and deformation is firstly analyzed in detail. The results show that the permeability–axial strain curve can be divided into the following five phases: the phase of micro-defects closure, the phase of linear elastic deformation, the phase of nonlinear deformation, the phase of post-peak stress softening and the phase of residual strength. The seepage evolution characteristic is also closely correlated with the volumetric deformation according to the relationship between permeability and volumetric strain. It is found that the gas seepage pressure has a great effect on the permeability evolution, i.e. permeability coefficients increase with increasing gas seepage pressures. Finally, the influence of gas seepage pressures on the failure behavior of brittle sandstone specimens is discussed.展开更多
Functionalized ionic liquids(FILs)as extractants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time.The effects of initial pH,extractant concentration,metal concentr...Functionalized ionic liquids(FILs)as extractants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time.The effects of initial pH,extractant concentration,metal concentrations in the feed were comprehensively investigated.The results showed that tricaprylmethylammonium bis(2,4,4-trimethylpentyl)phosphinate([A336][Cyanex272])could selectively extract W over Mo at an initial pH value of 5.5;the best separation factorβ_(W/Mo) of 25.61 was obtained for a solution with low metal concentrations(WO3:2.49 g/L,Mo:1.04 g/L).The[A336][Cyanex272]system performed effectively for solutions of different W/Mo molar ratios and different metal ion concentrations in the feed.The chemical reaction between[A336][Cyanex272]and W followed the ion association mechanism,which was further proved by the Fourier-transform infrared(FTIR)spectra of loaded[A336][Cyanex272]and the free extractant.The stripping experiments indicated that 95.48%W and 100.00%Mo were stripped using a 0.20 mol/L sodium hydroxide solution.Finally,the selective extractions of W and Mo from two synthetic solutions of different high metal concentrations were obtained;the separation factorβW/Mo reached 23.24 and 17.59 for the first and second solutions,respectively.The results suggest the feasibility of[A336][Cyanex272]as an extractant for the separation of tungsten and molybdenum.展开更多
The axial loading in rockbolts changes due to stress redistribution and rheology in the country rock mass.Such a change may lead to debonding at rockbolt to grout interface or rupture of the rockbolt.In this study,bas...The axial loading in rockbolts changes due to stress redistribution and rheology in the country rock mass.Such a change may lead to debonding at rockbolt to grout interface or rupture of the rockbolt.In this study,based on laboratory experiments,ultrasonic guided wave propagation in fully grouted rockbolt under different pull-out loads was investigated in order to examine the resultant debonding of rockbolt.The signals obtained from the ultrasonic monitoring during the pull-out test were processed using wavelet multi-scale analysis and frequency spectrum analysis,the signal amplitude and the amplitude ratio(Q)of low frequency to high frequency were defined to quantify the debonding of rockbolt.In addition to the laboratory test,numerical simulation on the effect of the embedment lengths on ultrasonic guided wave propagation in rockbolt was conducted by using a damage-based model,and the debonding between rockbolt and cement mortar was numerically examined.It was confirmed that the ultrasonic guided wave propagation in rockbolt was very sensitive to the debonding because of pull-out load,therefore,the critical bond length could be calculated based on the propagation of guided wave in the grouted rockbolt.In time domain,the signal amplitude in rockbolt increased with pull-out load from 0 to 100 kN until the completely debonding,thus quantifying the debonding under the different pull-out loads.In the frequency domain,as the Q value increased,the debonding length of rockbolt decreased exponentially.The numerical results confirmed that the guided wave propagation in the fully grouted rockbolt was effective in detecting and quantifying the debonding of rockbolt under pull-out load.展开更多
Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experim...Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.展开更多
The shear behavior is regarded as the dominant property of rock joints and is dramatically affected by the joint surface roughness.To date,the effect of surface roughness on the shear behavior of rock joints under sta...The shear behavior is regarded as the dominant property of rock joints and is dramatically affected by the joint surface roughness.To date,the effect of surface roughness on the shear behavior of rock joints under static or cyclic loading conditions has been extensively studied,but such effect under impact loading conditions keeps unclear.To address this issue,a series of impact shear tests was performed using a novel-designed dynamic experimental system combined with the digital image correlation(DIC)technique.The dynamic shear strength,deformability and failure mode of the jointed specimens with various joint roughness coefficients(JRC)are comprehensively analyzed.Results show that the shear strength and shear displacement characteristics of the rock joint under the impact loading keep consistent with those under static loading conditions.However,the temporal variations of shear stress,slip displacement and normal displacement under the impact loading conditions show obviously different behaviors.An elastic rebound of the slip displacement occurs during the impact shearing and its value increases with increasing joint roughness.Two identifiable stages(i.e.compression and dilation)are observed in the normal displacement curves for the rougher rock joints,whereas the joints with small roughness only manifest normal compression displacement.Besides,as the roughness increases,the maximum compression tends to decrease,while the maximum dilation gradually increases.More-over,the microstructural analysis based on scanning electron microscope(SEM)suggests that the roughness significantly affects the characteristics of the shear fractured zone enclosing the joint surface.展开更多
The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated.Starch can depress hematite effectively in a wide pH range,but cannot depress siderite efficiently in neu...The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated.Starch can depress hematite effectively in a wide pH range,but cannot depress siderite efficiently in neutral conditions.The flotation recovery of pure hematite,siderite,and quartz in the oleate-starch-CaCl2 system is significantly different when the slurry pH varies from 4 to 12.A novel two-step flotation process was developed for the separation of iron concentrate from Donganshan carbonaceous iron ore through which the siderite concentrate is first recovered and the high quality hematite concentrates with relative high iron recovery can be obtained in the second step flotation.The siderite concentrate may be utilized directly or undergo further concentration steps to increase iron grade.展开更多
The oxidation behavior of artificial magnetite pellets was investigated through measurements of the oxidation degree and mineralogical analysis. The results show that artificial magnetite pellets are much easier to ox...The oxidation behavior of artificial magnetite pellets was investigated through measurements of the oxidation degree and mineralogical analysis. The results show that artificial magnetite pellets are much easier to oxidize than natural magnetite. The oxidation is controlled through two different reaction mechanisms. The oxidation of artificial magnetite is dominated by internal diffusion, with an activation energy of 8.40 kJ/mol, at temperatures less than 800°C, whereas it is controlled by chemical reaction, with a reaction activation energy of 67.79 kJ/mol, at temperatures greater than 800°C. In addition, factors such as the oxygen volume fraction and the pellet diameter strongly influence the oxidation of artificial magnetite: a larger oxygen volume fraction and a smaller pellet diameter result in a much faster oxidation process.展开更多
A packing-flotation column was proposed to optimize the flotation environment A research system was es- tablished using a 100 mm diameter cyclonic micro-bubble flotation column to study fluid properties. Dry-plate and...A packing-flotation column was proposed to optimize the flotation environment A research system was es- tablished using a 100 mm diameter cyclonic micro-bubble flotation column to study fluid properties. Dry-plate and wet- plate pressure drops were studied and the corresponding pressure drop equations developed. The results show that the dry-plate pressure drop of the packing cyclonic micro-bubble flotation column is 10–15 times less than that of the chemical tower, which is principally shown in its relatively small resistance coefficient, ξ ≈0.0207. The wet-plate pressure drop is 2–3 times higher than that of the chemical tower, which is largely caused by the separation materials and characteristics of the equipment. With flotation, the greater the pressure drop, the better the flotation environment.展开更多
A new type of device,a dissolved-air flotation column,was developed for separation of oily wastewater. The unique design idea of the dissolved-air flotation column is the combined use of dissolved-air flotation and co...A new type of device,a dissolved-air flotation column,was developed for separation of oily wastewater. The unique design idea of the dissolved-air flotation column is the combined use of dissolved-air flotation and column flotation. The dissolved air release occurred within the column separation system. As a potential application the column was investigated for its performance in separating emulsified oil droplets in oily wastewater. A high separation efficiency was obtained in a series of tests. The aeration performance of the bubble generator used in the dissolved-air flotation column was also studied in particular.展开更多
The pre-treatment of zinc oxide bearing ores with high slime content is important to ensure that resources are utilized optimally. This paper reports an improved process using hydrocyclone de-sliming, dispersion reage...The pre-treatment of zinc oxide bearing ores with high slime content is important to ensure that resources are utilized optimally. This paper reports an improved process using hydrocyclone de-sliming, dispersion reagents, and magnetic removal of iron minerals for the pre-treatment of zinc oxide ore with a high slime and iron content, and the benefits compared to traditional technologies are shown. In addition, this paper investigates the damage related to fine slime and iron during zinc oxide flotation, the necessity of using hydrocyclone de-sliming together with dispersion reagents to alleviate the influence of slime, and interactions among hydrocyclone de-sliming, reagent dispersion, and magnetic iron removal. Results show that under optimized operating conditions the entire beneficiation technology results in a flotation concentrate with a Zn grade of 34.66% and a recovery of 73.41%.展开更多
The adsorption of bacteria on sulfide minerals surface was studied,and the selective adsorption mechanism of cells on the sulfide minerals was investigated by means of FTIR,UVS and XPS.The results show that the three ...The adsorption of bacteria on sulfide minerals surface was studied,and the selective adsorption mechanism of cells on the sulfide minerals was investigated by means of FTIR,UVS and XPS.The results show that the three strains of bacteria adsorbed more preferentially on pyrite than on other two sulfide minerals surface at neutral and alkaline pH conditions.FTIR and UVS of three strains of bacteria indicate that there are more functional groups on their surface,such as O-H,C=O,N-H,C-O,and the content of saccharide is more than that of protein.The state of every element on sulfide minerals surface was analyzed by XPS.The empty orbital number of electronic shell of metal ions on minerals surface is important in selective adsorption process,and some stable constants of metal coordinates can be used to explain the contribution of some groups in saccharide of cell wall to the selective adsorption.展开更多
The feasibility of using sodium sulfide as the sole modifier for the flotation of Xinhua molybdenite ore was examined.The potential mechanisms involved in the different flotation systems were discussed.The comparative...The feasibility of using sodium sulfide as the sole modifier for the flotation of Xinhua molybdenite ore was examined.The potential mechanisms involved in the different flotation systems were discussed.The comparative flotation results reveal that in the kerosene-sodium silicate flotation system,better recovery and grade of the molybdenum are obtained using sodium sulfide as the slurry pH adjustment agent than using CaO.Under the optimal conditions(64 g/t kerosene and 6 kg/t Na2S),satisfied recovery and grade of molybdenite concentrate can be achieved(84%and 8.2%,respectively),indicating that sodium sulfide is a potential substitute modifier of sodium silicate.The open-circuit flotation test results further confirm the effectiveness of sodium sulfide which may render recycling the tailing water possible and make the flotation process more environmental acceptable and more economical due to the less use of kerosene and scavengers.展开更多
The performance-based passive control analysis of the Maxwell dampers between one 10-story and one 6-story adjacent RC frames is conducted in this work.Not only the optimal parameters but also the optimal arrangements...The performance-based passive control analysis of the Maxwell dampers between one 10-story and one 6-story adjacent RC frames is conducted in this work.Not only the optimal parameters but also the optimal arrangements of the Maxwell dampers are proposed based on the optimal target of making the total exceeding probability of the adjacent structures to be minimal.The applicability of the analytical expressions of the Maxwell damper damping parameters under different seismic performance targets are firstly examined and then the preferable damping parameters of the Maxwell dampers are proposed through the extensive parametric studies.Furthermore,the optimal arranging positions and optimal arranging numbers of the Maxwell dampers between the adjacent buildings are derived based on a large number of seismic fragility analyses,as well.The general arranging laws of the Maxwell dampers between the adjacent buildings are generated based on the discussion of the theoretical method through the simplified plane model.The optimal parameters and optimal arrangement of the Maxwell dampers presented make both the adjacent structures have preferable controlled effects under each seismic performance target which can satisfy the requirements of multi-performance seismic resistance of the modern seismic codes.展开更多
The coupled three-components liquid diffusion within a porous pellet was investigated. The coupled diffusion model was given according to irreversible thermodynamics, and the rigorous solutions of the model subject to...The coupled three-components liquid diffusion within a porous pellet was investigated. The coupled diffusion model was given according to irreversible thermodynamics, and the rigorous solutions of the model subject to the homogeneous boundary conditions of the first kind are derived by employing Hankel transform technique and the standard technique resolving ordinary differential system. The method can also be used to solve the other coupled diffusion problems within a pellet with different kinds of boundary conditions. Then the case computations were conducted. The calculation results show that the effect of interdiffussion on the concentration of components depends upon the diffusion time strongly, after a long diffusion period, a very small cross diffusion coefficient will induce the observable change of concentration profile, and that, when the cross coefficients are close to 5%7% of the main coefficients, the significant effect of coupled diffusion on the concentration profiles of components is observed. The case computations also show that interdiffussion can induce non-monotonous concentration profiles. So, for the diffusion taking place within ternary system, the concentration profiles obtained by the analysis of interdiffussion can be very different from that obtained by the equivalent binary system analysis method.展开更多
The purpose of this study is to apply process mineralogy as a practical tool to further understand and analyze the reasons for low leaching rates in the curing-leaching process of vanadium-bearing stone coal and to fi...The purpose of this study is to apply process mineralogy as a practical tool to further understand and analyze the reasons for low leaching rates in the curing-leaching process of vanadium-bearing stone coal and to find a solution or improvement to optimize the leaching index.Using vanadium-bearing stone coal with the V2O5 mass fraction of 0.88%as the research object,the effects of particle size,mineral composition,and sulfuric acid curing on the feed,intermediate,and final products of curing-leaching were analyzed.The main vanadium-bearing minerals in the feed samples included sericite/illite,montmorillonite,kaolinite,limonite,and schreyerite.Through the penetration depth analysis of sulfuric acid,the reason for the high vanadium content in the coarse leaching residue(0.205%V2O5)was found,mainly due to the poor curing effect and incomplete washing after screening.Therefore,thorough washing after sieving and further optimizing the curing process are necessary.The vanadium content of the fine leaching residue(0.078%)was low and the curing-leaching effect was good.However,the vanadium content in the thickened residue(0.296%)exceeded that in the fine leaching residue,which was attributed to the neutralization reaction in the#1 thickener.To solve this problem,the neutralization and thickening processes should be performed in separate equipment.The analysis and detection of key products is helpful for identifying problems and improving the curing-leaching circuit process.展开更多
基金supported by the National Natural Science Foundation of China(Nos.41472065 and 42073059).
文摘The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.
基金This work was financially supported by National Key Research and Development Program of China(Grant No.2022YFC2903903)National Natural Science Foundation of China(Grant No.52304132)Yunnan Major Scientific and Technological Projects(Grant No.202202AG050014).These support is gratefully acknowledged.
文摘The surrounding rock of underground space is always affected by external dynamic disturbance from the side position,such as blasting vibration from a stope at the same level or seismic waves from adjacent strata.A series of laboratory tests,numerical simulations and theoretical analyses were carried out in this study to disclose the sliding mechanism of roof rock blocks under lateral disturbance.Firstly,the experiments on trapezoidal key block under various clamping loads and disturbance were conducted,followed by numerical simulations using the fast Lagrangian analysis of continua(FLAC3D).Then,based on the conventional wave propagation model and the classical shear-slip constitutive model,a theoretical model was proposed to capture the relative displacement between blocks and the sliding displacement of the key block.The results indicate that the sliding displacement of the key block increased linearly with the disturbance energy and decreased exponentially with the clamping load when the key block was disturbed to slide(without instability).Meanwhile,when the key block was disturbed to fall,two types of instability process may appear as immediate type or delayed type.In addition,the propagation of stress waves in the block system exhibited obvious low-velocity and lowfrequency characteristics,resulting in the friction reduction effect appearing at the contact interface,which is the essential reason for the sliding of rock blocks.The results can be applied to practical underground engineering and provide valuable guidance for the early detection and prevention of rockfalling disasters.
基金supported by the National Natural Science Foundation of China (Grant 41272344)the National Basic Research Program (973) of China (Grant 2014CB046905)+3 种基金the Natural Science Foundation of Jiangsu Province of China (Grant BK2012568)the Team Project Funded by 2014 Jiangsu Innovation and Entrepreneurship Programthe Fundamental Research Funds for the Central Universities (China University of Mining and Technology) (Grants 2014YC10 and 2014XT03)Outstanding Innovation Team Project in China University of Mining and Technology (Grant 2014QN002)
文摘The seepage evolution characteristic of brittle rock materials is very significant for the stability and safety of rock engineering. In this research, a series of conventional triaxial compression and gas seepage tests were carried out on sandstone specimens with a rock mechanics servo-controlled testing system. Based on the experimental results, the relationship between permeability and deformation is firstly analyzed in detail. The results show that the permeability–axial strain curve can be divided into the following five phases: the phase of micro-defects closure, the phase of linear elastic deformation, the phase of nonlinear deformation, the phase of post-peak stress softening and the phase of residual strength. The seepage evolution characteristic is also closely correlated with the volumetric deformation according to the relationship between permeability and volumetric strain. It is found that the gas seepage pressure has a great effect on the permeability evolution, i.e. permeability coefficients increase with increasing gas seepage pressures. Finally, the influence of gas seepage pressures on the failure behavior of brittle sandstone specimens is discussed.
基金financially supported by the National Natural Science Foundation of China(No.51504225).
文摘Functionalized ionic liquids(FILs)as extractants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time.The effects of initial pH,extractant concentration,metal concentrations in the feed were comprehensively investigated.The results showed that tricaprylmethylammonium bis(2,4,4-trimethylpentyl)phosphinate([A336][Cyanex272])could selectively extract W over Mo at an initial pH value of 5.5;the best separation factorβ_(W/Mo) of 25.61 was obtained for a solution with low metal concentrations(WO3:2.49 g/L,Mo:1.04 g/L).The[A336][Cyanex272]system performed effectively for solutions of different W/Mo molar ratios and different metal ion concentrations in the feed.The chemical reaction between[A336][Cyanex272]and W followed the ion association mechanism,which was further proved by the Fourier-transform infrared(FTIR)spectra of loaded[A336][Cyanex272]and the free extractant.The stripping experiments indicated that 95.48%W and 100.00%Mo were stripped using a 0.20 mol/L sodium hydroxide solution.Finally,the selective extractions of W and Mo from two synthetic solutions of different high metal concentrations were obtained;the separation factorβW/Mo reached 23.24 and 17.59 for the first and second solutions,respectively.The results suggest the feasibility of[A336][Cyanex272]as an extractant for the separation of tungsten and molybdenum.
基金This work is funded by the National Science Foundation of China(Grant Nos.U1906208,52104157,51904056 and 51874069)and the Fundamental Research Funds for the Central Universities of China(Grant Nos.N2101028 and N2101015).
文摘The axial loading in rockbolts changes due to stress redistribution and rheology in the country rock mass.Such a change may lead to debonding at rockbolt to grout interface or rupture of the rockbolt.In this study,based on laboratory experiments,ultrasonic guided wave propagation in fully grouted rockbolt under different pull-out loads was investigated in order to examine the resultant debonding of rockbolt.The signals obtained from the ultrasonic monitoring during the pull-out test were processed using wavelet multi-scale analysis and frequency spectrum analysis,the signal amplitude and the amplitude ratio(Q)of low frequency to high frequency were defined to quantify the debonding of rockbolt.In addition to the laboratory test,numerical simulation on the effect of the embedment lengths on ultrasonic guided wave propagation in rockbolt was conducted by using a damage-based model,and the debonding between rockbolt and cement mortar was numerically examined.It was confirmed that the ultrasonic guided wave propagation in rockbolt was very sensitive to the debonding because of pull-out load,therefore,the critical bond length could be calculated based on the propagation of guided wave in the grouted rockbolt.In time domain,the signal amplitude in rockbolt increased with pull-out load from 0 to 100 kN until the completely debonding,thus quantifying the debonding under the different pull-out loads.In the frequency domain,as the Q value increased,the debonding length of rockbolt decreased exponentially.The numerical results confirmed that the guided wave propagation in the fully grouted rockbolt was effective in detecting and quantifying the debonding of rockbolt under pull-out load.
基金Natural Science Foundations of China(Grant Nos.41502057 and 41472065)Foundations of Suzhou University(Nos.2019ZD46,2015jb01 and 2015jb07).
文摘Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.
基金We acknowledge the funding support from the National Natural Science Foundation of China(Grant Nos.51879135 and 51879184)the Natural Sciences and Engineering Research Council of Canada(NSERC)through the Discovery Grant No.72031326.
文摘The shear behavior is regarded as the dominant property of rock joints and is dramatically affected by the joint surface roughness.To date,the effect of surface roughness on the shear behavior of rock joints under static or cyclic loading conditions has been extensively studied,but such effect under impact loading conditions keeps unclear.To address this issue,a series of impact shear tests was performed using a novel-designed dynamic experimental system combined with the digital image correlation(DIC)technique.The dynamic shear strength,deformability and failure mode of the jointed specimens with various joint roughness coefficients(JRC)are comprehensively analyzed.Results show that the shear strength and shear displacement characteristics of the rock joint under the impact loading keep consistent with those under static loading conditions.However,the temporal variations of shear stress,slip displacement and normal displacement under the impact loading conditions show obviously different behaviors.An elastic rebound of the slip displacement occurs during the impact shearing and its value increases with increasing joint roughness.Two identifiable stages(i.e.compression and dilation)are observed in the normal displacement curves for the rougher rock joints,whereas the joints with small roughness only manifest normal compression displacement.Besides,as the roughness increases,the maximum compression tends to decrease,while the maximum dilation gradually increases.More-over,the microstructural analysis based on scanning electron microscope(SEM)suggests that the roughness significantly affects the characteristics of the shear fractured zone enclosing the joint surface.
基金Project(2006DFB72570) supported by the Grand Project of International Cooperation of Ministry of Science and Technology of China
文摘The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated.Starch can depress hematite effectively in a wide pH range,but cannot depress siderite efficiently in neutral conditions.The flotation recovery of pure hematite,siderite,and quartz in the oleate-starch-CaCl2 system is significantly different when the slurry pH varies from 4 to 12.A novel two-step flotation process was developed for the separation of iron concentrate from Donganshan carbonaceous iron ore through which the siderite concentrate is first recovered and the high quality hematite concentrates with relative high iron recovery can be obtained in the second step flotation.The siderite concentrate may be utilized directly or undergo further concentration steps to increase iron grade.
基金financially supported by the National Natural Science Foundation of China (No. 51474161)
文摘The oxidation behavior of artificial magnetite pellets was investigated through measurements of the oxidation degree and mineralogical analysis. The results show that artificial magnetite pellets are much easier to oxidize than natural magnetite. The oxidation is controlled through two different reaction mechanisms. The oxidation of artificial magnetite is dominated by internal diffusion, with an activation energy of 8.40 kJ/mol, at temperatures less than 800°C, whereas it is controlled by chemical reaction, with a reaction activation energy of 67.79 kJ/mol, at temperatures greater than 800°C. In addition, factors such as the oxygen volume fraction and the pellet diameter strongly influence the oxidation of artificial magnetite: a larger oxygen volume fraction and a smaller pellet diameter result in a much faster oxidation process.
基金Project 50425414 supported by the National Outstanding Youth Science Foundation of China
文摘A packing-flotation column was proposed to optimize the flotation environment A research system was es- tablished using a 100 mm diameter cyclonic micro-bubble flotation column to study fluid properties. Dry-plate and wet- plate pressure drops were studied and the corresponding pressure drop equations developed. The results show that the dry-plate pressure drop of the packing cyclonic micro-bubble flotation column is 10–15 times less than that of the chemical tower, which is principally shown in its relatively small resistance coefficient, ξ ≈0.0207. The wet-plate pressure drop is 2–3 times higher than that of the chemical tower, which is largely caused by the separation materials and characteristics of the equipment. With flotation, the greater the pressure drop, the better the flotation environment.
基金Projects 50425414 supported by thte National Fund for Distinguished Young Scholars2006A019 by the Science and Technology Fund of China University of Mining &Technology
文摘A new type of device,a dissolved-air flotation column,was developed for separation of oily wastewater. The unique design idea of the dissolved-air flotation column is the combined use of dissolved-air flotation and column flotation. The dissolved air release occurred within the column separation system. As a potential application the column was investigated for its performance in separating emulsified oil droplets in oily wastewater. A high separation efficiency was obtained in a series of tests. The aeration performance of the bubble generator used in the dissolved-air flotation column was also studied in particular.
基金financially supported by the Natural Science Foundation of Hubei Province,China(No.2014CFB794)the Young Fund of Wuhan Institute of Technology(No.Q201405)the Natural Science Foundation of Hunan Province for International Cooperation and Innovation(Nos.2017JJ4035 and 2016WK2049)
文摘The pre-treatment of zinc oxide bearing ores with high slime content is important to ensure that resources are utilized optimally. This paper reports an improved process using hydrocyclone de-sliming, dispersion reagents, and magnetic removal of iron minerals for the pre-treatment of zinc oxide ore with a high slime and iron content, and the benefits compared to traditional technologies are shown. In addition, this paper investigates the damage related to fine slime and iron during zinc oxide flotation, the necessity of using hydrocyclone de-sliming together with dispersion reagents to alleviate the influence of slime, and interactions among hydrocyclone de-sliming, reagent dispersion, and magnetic iron removal. Results show that under optimized operating conditions the entire beneficiation technology results in a flotation concentrate with a Zn grade of 34.66% and a recovery of 73.41%.
基金Project(50174014) supported by the National Natural Science Foundation of ChinaProject(2006223002) supported by the High-Tech Program of Liaoning Province, China
文摘The adsorption of bacteria on sulfide minerals surface was studied,and the selective adsorption mechanism of cells on the sulfide minerals was investigated by means of FTIR,UVS and XPS.The results show that the three strains of bacteria adsorbed more preferentially on pyrite than on other two sulfide minerals surface at neutral and alkaline pH conditions.FTIR and UVS of three strains of bacteria indicate that there are more functional groups on their surface,such as O-H,C=O,N-H,C-O,and the content of saccharide is more than that of protein.The state of every element on sulfide minerals surface was analyzed by XPS.The empty orbital number of electronic shell of metal ions on minerals surface is important in selective adsorption process,and some stable constants of metal coordinates can be used to explain the contribution of some groups in saccharide of cell wall to the selective adsorption.
基金Project(NCET-05-0291)supported by Program for University Talents in the New Century of China
文摘The feasibility of using sodium sulfide as the sole modifier for the flotation of Xinhua molybdenite ore was examined.The potential mechanisms involved in the different flotation systems were discussed.The comparative flotation results reveal that in the kerosene-sodium silicate flotation system,better recovery and grade of the molybdenum are obtained using sodium sulfide as the slurry pH adjustment agent than using CaO.Under the optimal conditions(64 g/t kerosene and 6 kg/t Na2S),satisfied recovery and grade of molybdenite concentrate can be achieved(84%and 8.2%,respectively),indicating that sodium sulfide is a potential substitute modifier of sodium silicate.The open-circuit flotation test results further confirm the effectiveness of sodium sulfide which may render recycling the tailing water possible and make the flotation process more environmental acceptable and more economical due to the less use of kerosene and scavengers.
基金Projects(51408443,51178203)supported by the National Natural Science Foundation of ChinaProject(K201511)supported by the Science Foundation of Wuhan Institute of Technology,China
文摘The performance-based passive control analysis of the Maxwell dampers between one 10-story and one 6-story adjacent RC frames is conducted in this work.Not only the optimal parameters but also the optimal arrangements of the Maxwell dampers are proposed based on the optimal target of making the total exceeding probability of the adjacent structures to be minimal.The applicability of the analytical expressions of the Maxwell damper damping parameters under different seismic performance targets are firstly examined and then the preferable damping parameters of the Maxwell dampers are proposed through the extensive parametric studies.Furthermore,the optimal arranging positions and optimal arranging numbers of the Maxwell dampers between the adjacent buildings are derived based on a large number of seismic fragility analyses,as well.The general arranging laws of the Maxwell dampers between the adjacent buildings are generated based on the discussion of the theoretical method through the simplified plane model.The optimal parameters and optimal arrangement of the Maxwell dampers presented make both the adjacent structures have preferable controlled effects under each seismic performance target which can satisfy the requirements of multi-performance seismic resistance of the modern seismic codes.
基金Project (50136020) supported by the National Natural Science Foundation of China Project (01056) supported by theKey Project of Education Ministry of China
文摘The coupled three-components liquid diffusion within a porous pellet was investigated. The coupled diffusion model was given according to irreversible thermodynamics, and the rigorous solutions of the model subject to the homogeneous boundary conditions of the first kind are derived by employing Hankel transform technique and the standard technique resolving ordinary differential system. The method can also be used to solve the other coupled diffusion problems within a pellet with different kinds of boundary conditions. Then the case computations were conducted. The calculation results show that the effect of interdiffussion on the concentration of components depends upon the diffusion time strongly, after a long diffusion period, a very small cross diffusion coefficient will induce the observable change of concentration profile, and that, when the cross coefficients are close to 5%7% of the main coefficients, the significant effect of coupled diffusion on the concentration profiles of components is observed. The case computations also show that interdiffussion can induce non-monotonous concentration profiles. So, for the diffusion taking place within ternary system, the concentration profiles obtained by the analysis of interdiffussion can be very different from that obtained by the equivalent binary system analysis method.
基金supported by the National Key Research and Development Program of China(No.2020YFC1909704)the National Natural Science Foundation of China(Nos.51904222 and 52074068)+1 种基金the Shaanxi Innovation Capacity Support Plan(2020KJXX-053)the Shaanxi Natural Science Basic Research Program(No.2019JQ-468).
文摘The purpose of this study is to apply process mineralogy as a practical tool to further understand and analyze the reasons for low leaching rates in the curing-leaching process of vanadium-bearing stone coal and to find a solution or improvement to optimize the leaching index.Using vanadium-bearing stone coal with the V2O5 mass fraction of 0.88%as the research object,the effects of particle size,mineral composition,and sulfuric acid curing on the feed,intermediate,and final products of curing-leaching were analyzed.The main vanadium-bearing minerals in the feed samples included sericite/illite,montmorillonite,kaolinite,limonite,and schreyerite.Through the penetration depth analysis of sulfuric acid,the reason for the high vanadium content in the coarse leaching residue(0.205%V2O5)was found,mainly due to the poor curing effect and incomplete washing after screening.Therefore,thorough washing after sieving and further optimizing the curing process are necessary.The vanadium content of the fine leaching residue(0.078%)was low and the curing-leaching effect was good.However,the vanadium content in the thickened residue(0.296%)exceeded that in the fine leaching residue,which was attributed to the neutralization reaction in the#1 thickener.To solve this problem,the neutralization and thickening processes should be performed in separate equipment.The analysis and detection of key products is helpful for identifying problems and improving the curing-leaching circuit process.