The development and vigor of soil microorganisms in terrestrial ecosystems are frequently constrained by the limited availability of essential elements such as carbon(C),nitrogen(N),and phosphorus(P).In this study,we ...The development and vigor of soil microorganisms in terrestrial ecosystems are frequently constrained by the limited availability of essential elements such as carbon(C),nitrogen(N),and phosphorus(P).In this study,we investigated the impact of long-term application of varying levels of organic manure,low(7.5 Mg ha^(−1)yr^(−1)),moderate(15.0 Mg ha^(−1)yr^(−1)),and high(22.5 Mg ha^(−1)yr^(−1)),on the stoichiometry of enzymes and the structures of the microbial communities in soybean rhizospheric and bulk soils.The main goal of this research was to examine how soil microbial resource limitations in the rhizosphere respond to different long-term fertilization strategies.The soil enzymatic activities were quantified,and the structure of the microbial community was assessed by analyzing phospholipid fatty acid profiles.When compared to the bulk soil,the rhizospheric soil had significant increases in microbial biomass carbon(MBC),nitrogen(MBN),and phosphorus(MBP),with MBC increasing by 54.19 to 72.86%,MBN by 47.30 to 48.17%,and MBP by 17.37 to 208.47%.Compared with the unfertilized control(CK),the total microbial biomasses of the rhizospheric(increased by 22.80 to 90.82%)and bulk soils(increased by 10.57 to 60.54%)both exhibited increases with the application of organic manure,and the rhizospheric biomass was higher than that of bulk soil.Compared with bulk soil,the activities of C-,N-and P-acquiring enzymes of rhizospheric soil increased by 22.49,14.88,and 29.45%under high levels of organic manure,respectively.Analyses of vector length,vector angle,and scatter plots revealed that both rhizospheric and bulk soils exhibited limitations in terms of both carbon(C)and phosphorus(P)availability.The results of partial least-squares path modelling indicated that the rhizospheric soil exhibited a more pronounced response to the rate of manure application than the bulk soil.The varying reactions of rhizospheric and bulk soils to the extended application of organic manure underscore the crucial function of the rhizosphere in mitigating limitations related to microbial resources,particularly in the context of different organic manure application rates.展开更多
Investigation of rarely studied gravel layers found in the loess in Shandong Province,eastern China,reveals the fabric characteristics of two gravel layers(G1,G2)and the sedimentary characteristics of loess at the typ...Investigation of rarely studied gravel layers found in the loess in Shandong Province,eastern China,reveals the fabric characteristics of two gravel layers(G1,G2)and the sedimentary characteristics of loess at the typical and well-preserved Heiyu section(HY),where,to determine the paleoclimatic changes during Marine Isotope Stage 3a.Optically stimulated luminescence dates of the HY formation range from 0.26±0.02 ka to 39.00±2.00 ka.In addition,the ages of G1 and G2 were estimated using the Bayesian model to be 39.60-40.50 and 29.00-29.50 ka.G1 and G2 are mainly composed of fine and medium gravel,both of which were subangular to subrounded limestone,with gravel directions to NE and E.The average flow velocity,average depth,and flood peak flow of G1 are 1.10 m/s,0.49 m,and 37.04 m^(3)/s,respectively,calculated using the flow energy method,whereas those of G2 are 0.98 m/s,0.38 m,and 18.38 m^(3)/s,respectively.Analysis of climate proxy indices show that the sedimentary environment of the gravel and loess in HY might be a regional response to global change.展开更多
Currently,cigarette smoke(CS)remains a major contributor to disease morbidity and mortality.CS can be divided into cigarette mainstream smoke(CMS)and side-stream smoke,depending on where it is produced by burning toba...Currently,cigarette smoke(CS)remains a major contributor to disease morbidity and mortality.CS can be divided into cigarette mainstream smoke(CMS)and side-stream smoke,depending on where it is produced by burning tobacco^([1]).CMS is inhaled by smokers from the filter end during cigarette combustion and is strongly associated with the development of several diseases^([2-4]).展开更多
[Objectives]This study was conducted to explore the characteristics of plant diversity of Jiangxia Wetland in Lhasa River basin.[Methods]Based on the survey data of 37 plant community in three types of sample plots of...[Objectives]This study was conducted to explore the characteristics of plant diversity of Jiangxia Wetland in Lhasa River basin.[Methods]Based on the survey data of 37 plant community in three types of sample plots of Jiangxia Wetland in the Lhasa River basin,this study analyzed the diversity of plant community in different habitats of Jiangxia Wetland from Pielou evenness,Margalef richness,Simpson and Shannon Wiener diversity indexes of different types and levels.[Results]The Pielou index,Shannon-Wiener index and Simpson diversity index of dry land was higher than those of other plots,while the Margalef species richness index of the ecotone of seasonally flooded and dry land was higher than that of other plots.The Pielou index,Shannon-Wiener index,Simpson diversity index and Margalef species richness index of composite plants were higher than those of other herbaceous plants.The Shannon-Wiener index,Simpson diversity index and Margalef species richness index of hygrophytes were higher than those of other plants,while the Pielou index evenness index of aquatic plants was higher than that of other plants.Annual or perennial herbaceous plants occupied the primary position in the study area,and shrub plants occupied a secondary position,and floating plants took the lowest position.[Conclusions]The results of this study can provide theoretical support or reference basis for the scientific management of comprehensive wetland systems such as wetland ecosystem restoration and plant diversity protection in Jiangxia Wetland.展开更多
Land use/cover change(LUCC)plays a key role in altering surface hydrology and water balance,finally affect-ing the security and availability of water resources.However,mechanisms underlying LUCC determination of water...Land use/cover change(LUCC)plays a key role in altering surface hydrology and water balance,finally affect-ing the security and availability of water resources.However,mechanisms underlying LUCC determination of water-balance processes at the basin scale remain unclear.In this study,the Soil and Water Assessment Tool(SWAT)model and partial least squares regression were used to detect the effects of LUCC on hydrology and water components in the Zuli River Basin(ZRB),a typical watershed of the Yellow River Basin.In general,three recommended coefficients(R^(2)and E ns greater than 0.5,and P bias less than 20%)indicated that the output results of the SWAT model were reliable and that the model was effective for the ZRB.Then,several key findings were obtained.First,LUCC in the ZRB was characterized by a significant increase in forest(21.61%)and settlement(23.52%)and a slight reduction in cropland(-1.35%),resulting in a 4.93%increase in evapotranspiration and a clear decline in surface runoffand water yield by 15.68%and 2.95%at the whole basin scale,respectively.Second,at the sub-basin scale,surface runoffand water yield increased by 14.26%-36.15%and 5.13%-15.55%,respectively,mainly due to settlement increases.Last,partial least squares regression indicated that urbanization was the most significant contributor to runoffchange,and evapotranspiration change was mainly driven by forest expansion.These conclusions are significant for understanding the relationship between LUCC and water balance,which can provide meaningful information for managing water resources and the long-term sustainability of such watersheds.展开更多
Urban-rural integration (URI) is a global challenge that is highly related to inequalities, poverty, economic growth, and other Sustainable Development Goals (SDGs). Existing research has evaluated the extent of URI a...Urban-rural integration (URI) is a global challenge that is highly related to inequalities, poverty, economic growth, and other Sustainable Development Goals (SDGs). Existing research has evaluated the extent of URI and explored its influencing factors, but urban-rural linkages are seldom incorporated in evaluation systems, and geographical factors are rarely recognized as the influencing factors. We construct a URI framework including regional economy, rural development, urban-rural linkage, and urban-rural gap. Based on a dataset consisting of 1,669 counties in China in 2020, we reveal the spatial pattern of URI and find a high correlation between the spatial pattern of URI and the relief degree of land surface (RDLS). Using structural equation modeling, we discover that topography has direct ( − 0.18, p < 0.001) and indirect ( − 0.17, p < 0.001) effects on URI. The indirect negative effects are mediated through the infrastructure, and the combination of localized advantages and modern technical conditions could mitigate the negative impact of topography. Finally, we identify 742 counties as lagging regions in URI, which can be clustered into eight types. Our findings could facilitate policy designing for those countries striving for integrated and sustainable development of urban and rural areas.展开更多
Since China’s reform and opening up in 1978,the acceleration of industrialization and urbanization in China had led to dramatic changes in the pattern of urban-rural land use.In this paper,we focused on the rural ind...Since China’s reform and opening up in 1978,the acceleration of industrialization and urbanization in China had led to dramatic changes in the pattern of urban-rural land use.In this paper,we focused on the rural industrialized areas in central China(Xinxiang County and Changyuan City of Henan Province).We used the average nearest neighbor index,spatial statistical analysis,and a structural equation model to analyze the spatiotemporal evolution and influencing factors of urban-rural construction land based on multisource spatial data and survey data.The results showed that:1)from 1975 to 2019,the spatial distribution of urban-rural construction land in rural industrialized areas had evolved from homogeneous distribution to local agglomeration.In terms of comparative analysis of cases,the spatial distribution of urban-rural construction land in Changyuan City had shown a trend from diffusion to agglomeration,and Xinxiang County had overall shown a spatial change from homogenization to agglomeration and then to regional integration development.2)The hot spots with increased urban-rural construction land significantly expanded,and they had a high degree of spatial overlap with industrial development.Among them,Xinxiang County was concentrated in central and marginal areas,and Changyuan was mainly concentrated in central urban areas.3)From the evolution of spatial proximity of urban-rural construction land,rural industrialized areas generally decline,showing the characteristics of internal differentiation in the rate of change.4)Industrial development,social economy,the policy environment,and urban development played a positive role in promoting the expansion of urban-rural construction land in rural industrialized areas.To promote the optimal use of regional land and the integrated development of urban-rural areas,we should combine the advantages of regional endowment,formulate development strategies according to local conditions,and adjust the way that land is used in a timely manner.展开更多
Karst environmental issues have become one of the hot spots in contemporary international geological research. The same problem of water shortage is one of the hot spots of global concern. The peak-cluster depression ...Karst environmental issues have become one of the hot spots in contemporary international geological research. The same problem of water shortage is one of the hot spots of global concern. The peak-cluster depression basins in southwest of Guangxi is an important water connotation and ecological barrier areas in the Pearl River Basin of China. Thus, studying the spatial and temporal variations and the influencing factors of its water yield services is critical to achieve the sustainable development of water resources and ecological environmental protection in this region. As such, this paper uses the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST) model to assess the spatial and temporal variabilities of water yield services and its trends in the peak-cluster depression basins in southwest of Guangxi from 2000 to 2020. This work also integrates precipitation(Pre), reference evapotranspiration(ET), temperature(Tem), digital elevation model(DEM), slope, normalized difference vegetation index(NDVI), land use/land cover(LULC) and soil type to reveal the main factors that influence water yield services with the help of Geodetector. Results show that: 1) in time scale,the total annual water yield in the study area show a fluctuating and increasing trend from 2000 to 2020, with a growth rate of 7.3753 × 10^(8)m^(3)/yr, and its multi-year average water yield was 538.07 mm;2) in spatial pattern, with high yield areas mainly distributed in the south of the study area(mainly including Shangsi County, Pingxiang City, Ningming County, Longzhou County and Jingxi County), and low yield areas mainly distributed in Baise City and Nanning City;3) the dominant factor of water yield within karst and non-karst landforms is not necessarily controlled by precipitation, and the explanation degree of DEM factors in karst areas is significantly higher than that in non-karst areas;4) amongst the climatic factors, Pre, ET and Tem are dominant in the spatial pattern of region water yield capacity. among which Pre has the highest explanatory power for the spatial heterogeneity of annual water production, with q values above0.8, and each driver showed a significant interaction on the spatial distribution of water yield, with Pre exhibiting the strongest interaction with LULC.展开更多
At present,knowledge embedding methods are widely used in the field of knowledge graph(KG)reasoning,and have been successfully applied to those with large entities and relationships.However,in research and production ...At present,knowledge embedding methods are widely used in the field of knowledge graph(KG)reasoning,and have been successfully applied to those with large entities and relationships.However,in research and production environments,there are a large number of KGs with a small number of entities and relations,which are called sparse KGs.Limited by the performance of knowledge extraction methods or some other reasons(some common-sense information does not appear in the natural corpus),the relation between entities is often incomplete.To solve this problem,a method of the graph neural network and information enhancement is proposed.The improved method increases the mean reciprocal rank(MRR)and Hit@3 by 1.6%and 1.7%,respectively,when the sparsity of the FB15K-237 dataset is 10%.When the sparsity is 50%,the evaluation indexes MRR and Hit@10 are increased by 0.8%and 1.8%,respectively.展开更多
In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distanc...In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.展开更多
The interest in curtailing environmental pollution issues through physical separation processes has inspired an extensive search for novel nanoporous materials with exceptional adsorption capabilities.Covalent triazin...The interest in curtailing environmental pollution issues through physical separation processes has inspired an extensive search for novel nanoporous materials with exceptional adsorption capabilities.Covalent triazine frameworks(CTFs),emerged as a class of crystalline covalent organic frameworks(COFs),have been widely examined for various separation applications,owing to their large porosity,high stability,and rich nitrogen(N)doping.The development of CTFs for efficient adsorption of mercury(Ⅱ)(Hg^(2+))is of great importance for the field,whereas it is rarely attempted,on account of limited synthetic strategies and unknown structural-property relations of conventional CTFs derived from ionothermal approaches.Herein,we report rational synthesis of a crystalline CTF with methylthio pendant arms for efficient removal of Hg^(2+)with an exceptional capacity of 751 mg·g^(-1),ranking at the top among previously-reported adsorbents.This work may open up new possibility in the synthesis of COFs for various separations.展开更多
Achieving high maize yields and efficient phosphorus(P)use with limited environmental impacts is one of the greatest challenges in sustainable maize production.Increasing plant density is considered an effective appro...Achieving high maize yields and efficient phosphorus(P)use with limited environmental impacts is one of the greatest challenges in sustainable maize production.Increasing plant density is considered an effective approach for achieving high maize yields.However,the low mobility of P in soils and the scarcity of natural P resources have hindered the development of methods that can simultaneously optimize P use and mitigate the P-related environmental footprint at high plant densities.In this study,meta-analysis and substance flow analysis were conducted to evaluate the effects of different types of mineral P fertilizer on maize yield at varying plant densities and assess the flow of P from rock phosphate mining to P fertilizer use for maize production in China.A significantly higher yield was obtained at higher plant densities than at lower plant densities.The application of single superphosphate,triple super-phosphate,and calcium magnesium phosphate at high plant densities resulted in higher yields and a smaller environmental footprint than the application of diammonium phosphate and monoammonium phosphate.Our scenario analyses suggest that combining the optimal P type and application rate with a high plant density could increase maize yield by 22%.Further,the P resource use efficiency throughout the P supply chain increased by 39%,whereas the P-related environmental footprint decreased by 33%.Thus,simultaneously optimizing the P type and application rate at high plant densities achieved multiple objectives during maize production,indicating that combining P management with cropping techniques is a practical approach to sustainable maize production.These findings offer strategic,synergistic options for achieving sustainable agricultural development.展开更多
Electrochemical biosensors have emerged as a promising technology for cancer detection due to their high sensitivity,rapid response,low cost,and capability for non-invasive detection.Recent advances in nanomaterials l...Electrochemical biosensors have emerged as a promising technology for cancer detection due to their high sensitivity,rapid response,low cost,and capability for non-invasive detection.Recent advances in nanomaterials like nanoparticles,graphene,and nanowires have enhanced sensor performance to allow for cancer biomarker detection,like circulating tumor cells,nucleic acids,proteins and metabolites,at ultra-low concentrations.However,several challenges need to be addressed before electrochemical biosensors can be clinically implemented.These include improving sensor selectivity in complex biological media,device miniaturization for implantable applications,integration with data analytics,handling biomarker variability,and navigating regulatory approval.This editorial critically examines the prospects of electrochemical biosensors for efficient,low-cost and minimally invasive cancer screening.We discuss recent developments in nanotechnology,microfabrication,electronics integration,multiplexing,and machine learning that can help realize the potential of these sensors.However,significant interdisciplinary efforts among researchers,clinicians,regulators and the healthcare industry are still needed to tackle limitations in selectivity,size constraints,data interpretation,biomarker validation,toxicity and commercial translation.With committed resources and pragmatic strategies,electrochemical biosensors could enable routine early cancer detection and dramatically reduce the global cancer burden.展开更多
Retrieval of oxalate from snow and ice provides information on past environmental changes. In recent years, records of organic acids in middle-and low-latitude glaciers have attracted the attention of researchers glob...Retrieval of oxalate from snow and ice provides information on past environmental changes. In recent years, records of organic acids in middle-and low-latitude glaciers have attracted the attention of researchers globally. In this study, we analyzed oxalates in an ice core from Laohugou Glacier No. 12 on the Qilian Mountains at an elevation of 5,040 m a.s.l. in2006. Average oxalate concentration was 18.5±2.4 ng/g over the prior 46 years. Oxalate values showed a significantly increasing trend since 1985. From 1985 to 1995, oxalate concentrations had large fluctuations, peaking in about 1987 and exhibiting a slightly decreasing trend since 1995. The result shows that the abrupt increase of oxalate concentration in the ice core since the mid-1980 s reflects atmospheric environmental pollution by human and industrial activities.展开更多
The North Branch, separated by the Chongming Island, was once the main channel in the estuary of the Changjiang River. Reclamation and a decrease in runoffto the North Branch had led to the narrowing and shallowing of...The North Branch, separated by the Chongming Island, was once the main channel in the estuary of the Changjiang River. Reclamation and a decrease in runoffto the North Branch had led to the narrowing and shallowing of the channel. The Yuantuojiao Point is located at the intersecting point connecting the North Branch of the Changjiang River and the Jiangsu coastline. Erosion cliffs are developed between the typical silty-muddy tidal flat and the salt marsh occupied by Spartina alterniflorea, and this has changed rapidly over the past few years. The sediment grain size analysis results of the surficial and two core samples indi- cate that the Yuantuoiiao Point tidal fiat experienced continuous accretional processes. Based upon 137Cs analysis results of the YT and YY Cores sampled from the tidal flat at the Yuantuojiao Point, the average sed- imentation rate of the YT Core was 2.30 cm/a from 1963 to 2007, and 2.38 cm/a from 1954 to 2007 for the YY Core. The sedimentation rates of both core locations have declined since the 1960s corresponding to the seaward reclamation at the Yuantuojiao Point. The average sedimentation rates at the Yuantnojiao Point were similar to that of the silty-muddy tidal flat at the northern ]iangsu coast, but lower than that of the south of the Changjiang River Estuary. According to field morphological investigations from 2006 to 2008 on the salt marsh at the Yuantuojiao Point, cliffs retreated markedly by storm surges and disappeared gradu- ally because of the rapid sedimentation on the silty-muddy tidal flat. The maximum annual retreat reached 10 m. The recent sedimentation and morphological changes of the Yuantuojiao Point tidal flat not only displayed the retreat of the salt marsh and the disappearance of cliffs, but also was accompanied by rapid sedimentation of the silty-muddy tidal flat and the salt marsh, indicating the responses to the tidal currents, storm surges, Spartina alterniflorea trapping sediments and large-scale reclamation. The sediment grain size and their trends, southward coastal flow, and sandspits of the longshore bars suggest that the main sediment source at the Yuantuoijao Point, estuary of the North Branch was possibly from the Changjiang River before 1958, since then, it has been from the south of the submarine radial sand ridges of the southern Huanghai Sea (Yellow Sea).展开更多
A long-term field experiment was carried out with a wheat-maize rotation system to investigate the accumulation and bioavailability of heavy metals in a calcareous soil at different rates of sewage sludge amendment. T...A long-term field experiment was carried out with a wheat-maize rotation system to investigate the accumulation and bioavailability of heavy metals in a calcareous soil at different rates of sewage sludge amendment. There are significant linear correlations between the contents of Hg, Zn, Cu, Pb, and Cd in soil and sewage sludge amendment rates. By increasing 1 ton of applied sludge per hectare per year in soil, the contents of Hg, Zn, Cu, Pb, and Cd in soil increased by 6.20, 619, 92.9, 49.2, and 0.500 μg kg–1, respectively. For Hg, sewage sludge could be safely applied to the soil for 18 years at an application rate of 7.5 t ha–1 before content exceeded the soil environmental quality standards in China(1 mg kg–1). The safe application period for Zn is 51 years and is even longer for other heavy metals(112 years for Cu, 224 years for Cd, and 902 years for Pb) at an application rate of 7.5 t ha–1 sewage sludge. The contents of Zn and Ni in wheat grains and Zn, Cu, and Cr in maize grains increased linearly with increasing sewage sludge amendment rates. The contents of Zn, Cr, and Ni in wheat straws and Zn, Cu, and As in maize straws were positively correlated with sewage sludge amendment rates, while the content of Cu in wheat straws and Cr in maize straws showed the opposite trend. The bioconcentration factors of the heavy metals in wheat and maize grains were found to be in the order of Zn>Cu>Cd>Hg>Cr=Ni>Pb>As. Furthermore, the bioconcentration factors of heavy metals in wheat were greater than those in maize, indicating that wheat is more sensitive than maize as an indicator plant. These results will be helpful in developing the critical loads for sewage sludge amendment in calcareous soils.展开更多
Based on the classical static theory and static numerical simulation,the static method could not accurately reflect the stability of goaf where the rocks on the pillar and roof are influenced by Theological and blasti...Based on the classical static theory and static numerical simulation,the static method could not accurately reflect the stability of goaf where the rocks on the pillar and roof are influenced by Theological and blasting disturbance for a long time.According to the test from the site,an experimental study was made in Theological and dynamic disturbance.After that,on the basis of variable rock mechanics parameters from the experimental data,numerical simulation was used to analyze the vertical stress distribution of goaf,vertical displacement and plastic area of roof in the "deterioration" caused by Theological and blasting,which shows that the mechanics properties of the rock were greatly influenced by Theological,and dynamic disturbance.The results of the experimental study and numerical simulation show that the mechanics properties of rock are greatly influenced by Theological and dynamic disturbance.As a result,the stability of goaf is greatly reduced.Finally,by comparing golf monitoring results with the analysis of theoretical calculation,it was found that the results were approximately the same,which testifies the reliability of the method.This method provides a new way of studying the stability of goaf as well as laying a basic foundation for future safety management.展开更多
It is of great significance for safety reason to obtain the triaxial compressive properties of cemented tailings backfill(CTB).The influence of cement content,curing age and confining pressure on strength and deformat...It is of great significance for safety reason to obtain the triaxial compressive properties of cemented tailings backfill(CTB).The influence of cement content,curing age and confining pressure on strength and deformation properties of CTB was examined and discussed.Results indicate that the triaxial compressive and deformation behavior of CTB is strongly affected by the cement content,curing age and confining pressure.The increase in cement content,curing age and confining pressure leads to a change in stress−strain behavior and an increase in the axial strain at failure and post-peak strength loss.The cohesion of CTB rises as the curing age and cement content increase.However,the enhancement in internal friction angle is trivial and negligible.It should be noted that the failure pattern of CTB samples in triaxial compression is mainly along a shear plane,the confining pressure restrains the lateral expansion and the bulging failure pattern is dominantly detected in CTB samples as curing age length and cement content increase.The results will help to better understand the triaxial mechanical and deformation behavior of CTB.展开更多
The source and sink landscape patterns refer to landscape types or units that can either promote positive evolvement of non-point source(NPS) pollution process, or can prevent/defer the ecological process, respectivel...The source and sink landscape patterns refer to landscape types or units that can either promote positive evolvement of non-point source(NPS) pollution process, or can prevent/defer the ecological process, respectively. Therefore, the role of a catchment landscape pattern in nutrient losses can be identified based on the spatial arrangement of source and sink landscapes. To reveal the relations between landscape spatial characteristics and NPS pollution in small catchment, a case study was carried out in a Wangjiagou small catchment of the Three Gorges Reservoir Region(TGRR), China. Google earth imagery for 2015 were processed and used to differentiate source and sink landscape types, and six subcatchments were selected as sample regions for monitoring nitrogen and phosphorus nutrients.Relative elevation, slope gradient and relative flow length was used to construct the Lorenz curves of different source and sink landscape types in the catchment, in order to assess the source and sink landscape spatial characteristics. By calculating the location-weighted landscape indices of each subcatchment and total catchment, the landscape spatial load characteristics affecting the NPS pollution was identified, with a further Pearson correlation analysis for location-weighted landscape indices and nitrogen-phosphorus monitoring indicators. The analysis of Lorenz curve has revealed that the obtained distribution trend of Lorenz curve and curve area quantified well the spatial characteristics of source and sink landscape pattern related to the relative elevation, slope gradient and relative flow length in small catchment. Results of Pearson correction analysis indicated that location-weighted landscape index(LWLI) combining of terrain and landscape type factor did better in reflecting the status of nitrogen and phosphorus loss than the indices related to relative elevation, slope gradient and relative flow length.展开更多
In order to predict long-term flooding under extreme weather conditions in central Asia, an energy balance-based distributed snowmelt runoff model was developed and coupled with the Soil and Water Assessment Tool(SWAT...In order to predict long-term flooding under extreme weather conditions in central Asia, an energy balance-based distributed snowmelt runoff model was developed and coupled with the Soil and Water Assessment Tool(SWAT) model. The model was tested at the Juntanghu watershed on the northern slope of the Tian Shan Mountains, Xinjiang,China. We compared the performances of temperature-index method and energy balanced method in SWAT model by taking Juntanghu river basin as an application example(as the simulation experiment was conducted in Juntanghu River, we call the energy balanced method as SWAT-JTH). The results suggest that the SWAT snowmelt model had overall Nash-Sutcliffe efficiency(NSE) coefficients ranging from 0.61 to 0.85 while the physical based approach had NSE coefficients ranging from 0.58 to0.69. Overall, on monthly scale, the SWAT model provides better results than that from the SWAT-JTH model. However, results generated from both methods seem to be fairly close at a daily scale. Thestructure of the temperature-index method is simple and produces reasonable simulation results if the parameters are well within empirical ranges. Although the data requirement for the energy balance method in current observation is difficult to meet and the existence of uncertainty is associated with the experimental approaches of physical processes, the SWAT-JTH model still produced a reasonably high NSE. We conclude that using temperature-index methods to simulate the snowmelt process is sufficient, but the energy balance-based model is still a good choice to simulate extreme weather conditions especially when the required data input for the model is acquired.展开更多
基金the National Key R&D Program of China(2022YFD1500100)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA28070100)+1 种基金the Young Scholars Program in Regional Development,Chinese Academy of Sciences(2022-027)the China Agriculture Research System(CARS-04).
文摘The development and vigor of soil microorganisms in terrestrial ecosystems are frequently constrained by the limited availability of essential elements such as carbon(C),nitrogen(N),and phosphorus(P).In this study,we investigated the impact of long-term application of varying levels of organic manure,low(7.5 Mg ha^(−1)yr^(−1)),moderate(15.0 Mg ha^(−1)yr^(−1)),and high(22.5 Mg ha^(−1)yr^(−1)),on the stoichiometry of enzymes and the structures of the microbial communities in soybean rhizospheric and bulk soils.The main goal of this research was to examine how soil microbial resource limitations in the rhizosphere respond to different long-term fertilization strategies.The soil enzymatic activities were quantified,and the structure of the microbial community was assessed by analyzing phospholipid fatty acid profiles.When compared to the bulk soil,the rhizospheric soil had significant increases in microbial biomass carbon(MBC),nitrogen(MBN),and phosphorus(MBP),with MBC increasing by 54.19 to 72.86%,MBN by 47.30 to 48.17%,and MBP by 17.37 to 208.47%.Compared with the unfertilized control(CK),the total microbial biomasses of the rhizospheric(increased by 22.80 to 90.82%)and bulk soils(increased by 10.57 to 60.54%)both exhibited increases with the application of organic manure,and the rhizospheric biomass was higher than that of bulk soil.Compared with bulk soil,the activities of C-,N-and P-acquiring enzymes of rhizospheric soil increased by 22.49,14.88,and 29.45%under high levels of organic manure,respectively.Analyses of vector length,vector angle,and scatter plots revealed that both rhizospheric and bulk soils exhibited limitations in terms of both carbon(C)and phosphorus(P)availability.The results of partial least-squares path modelling indicated that the rhizospheric soil exhibited a more pronounced response to the rate of manure application than the bulk soil.The varying reactions of rhizospheric and bulk soils to the extended application of organic manure underscore the crucial function of the rhizosphere in mitigating limitations related to microbial resources,particularly in the context of different organic manure application rates.
基金the National Natural Science Foundation of China(Grant Nos.41472159,41172160,41371537).
文摘Investigation of rarely studied gravel layers found in the loess in Shandong Province,eastern China,reveals the fabric characteristics of two gravel layers(G1,G2)and the sedimentary characteristics of loess at the typical and well-preserved Heiyu section(HY),where,to determine the paleoclimatic changes during Marine Isotope Stage 3a.Optically stimulated luminescence dates of the HY formation range from 0.26±0.02 ka to 39.00±2.00 ka.In addition,the ages of G1 and G2 were estimated using the Bayesian model to be 39.60-40.50 and 29.00-29.50 ka.G1 and G2 are mainly composed of fine and medium gravel,both of which were subangular to subrounded limestone,with gravel directions to NE and E.The average flow velocity,average depth,and flood peak flow of G1 are 1.10 m/s,0.49 m,and 37.04 m^(3)/s,respectively,calculated using the flow energy method,whereas those of G2 are 0.98 m/s,0.38 m,and 18.38 m^(3)/s,respectively.Analysis of climate proxy indices show that the sedimentary environment of the gravel and loess in HY might be a regional response to global change.
基金supported by the National Natural Science Foundation of China(Grant No.82060638)Academic and Technical Leaders of Major Disciplines in Jiangxi Province(Grant No.20194BCJ22032)
文摘Currently,cigarette smoke(CS)remains a major contributor to disease morbidity and mortality.CS can be divided into cigarette mainstream smoke(CMS)and side-stream smoke,depending on where it is produced by burning tobacco^([1]).CMS is inhaled by smokers from the filter end during cigarette combustion and is strongly associated with the development of several diseases^([2-4]).
基金Supported by Prefecture-level Science and Technology Program of Hetian Prefecture(202439).
文摘[Objectives]This study was conducted to explore the characteristics of plant diversity of Jiangxia Wetland in Lhasa River basin.[Methods]Based on the survey data of 37 plant community in three types of sample plots of Jiangxia Wetland in the Lhasa River basin,this study analyzed the diversity of plant community in different habitats of Jiangxia Wetland from Pielou evenness,Margalef richness,Simpson and Shannon Wiener diversity indexes of different types and levels.[Results]The Pielou index,Shannon-Wiener index and Simpson diversity index of dry land was higher than those of other plots,while the Margalef species richness index of the ecotone of seasonally flooded and dry land was higher than that of other plots.The Pielou index,Shannon-Wiener index,Simpson diversity index and Margalef species richness index of composite plants were higher than those of other herbaceous plants.The Shannon-Wiener index,Simpson diversity index and Margalef species richness index of hygrophytes were higher than those of other plants,while the Pielou index evenness index of aquatic plants was higher than that of other plants.Annual or perennial herbaceous plants occupied the primary position in the study area,and shrub plants occupied a secondary position,and floating plants took the lowest position.[Conclusions]The results of this study can provide theoretical support or reference basis for the scientific management of comprehensive wetland systems such as wetland ecosystem restoration and plant diversity protection in Jiangxia Wetland.
基金This research was jointly supported by the National Natural Science Foundation of China(Grants No.U21A2011,41991233 and 41971129)the National Key Research and Development Program of China(Grant No.SQ2022YFF1300053)the Distinguished Membership Project of the Youth Innovation Promotion Association of Chinese Academy of Sci-ences(Grant No.Y201812).
文摘Land use/cover change(LUCC)plays a key role in altering surface hydrology and water balance,finally affect-ing the security and availability of water resources.However,mechanisms underlying LUCC determination of water-balance processes at the basin scale remain unclear.In this study,the Soil and Water Assessment Tool(SWAT)model and partial least squares regression were used to detect the effects of LUCC on hydrology and water components in the Zuli River Basin(ZRB),a typical watershed of the Yellow River Basin.In general,three recommended coefficients(R^(2)and E ns greater than 0.5,and P bias less than 20%)indicated that the output results of the SWAT model were reliable and that the model was effective for the ZRB.Then,several key findings were obtained.First,LUCC in the ZRB was characterized by a significant increase in forest(21.61%)and settlement(23.52%)and a slight reduction in cropland(-1.35%),resulting in a 4.93%increase in evapotranspiration and a clear decline in surface runoffand water yield by 15.68%and 2.95%at the whole basin scale,respectively.Second,at the sub-basin scale,surface runoffand water yield increased by 14.26%-36.15%and 5.13%-15.55%,respectively,mainly due to settlement increases.Last,partial least squares regression indicated that urbanization was the most significant contributor to runoffchange,and evapotranspiration change was mainly driven by forest expansion.These conclusions are significant for understanding the relationship between LUCC and water balance,which can provide meaningful information for managing water resources and the long-term sustainability of such watersheds.
基金the National Natural Science Foundation of China(Grants No.T2261129477 and 41971220)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA23070300).
文摘Urban-rural integration (URI) is a global challenge that is highly related to inequalities, poverty, economic growth, and other Sustainable Development Goals (SDGs). Existing research has evaluated the extent of URI and explored its influencing factors, but urban-rural linkages are seldom incorporated in evaluation systems, and geographical factors are rarely recognized as the influencing factors. We construct a URI framework including regional economy, rural development, urban-rural linkage, and urban-rural gap. Based on a dataset consisting of 1,669 counties in China in 2020, we reveal the spatial pattern of URI and find a high correlation between the spatial pattern of URI and the relief degree of land surface (RDLS). Using structural equation modeling, we discover that topography has direct ( − 0.18, p < 0.001) and indirect ( − 0.17, p < 0.001) effects on URI. The indirect negative effects are mediated through the infrastructure, and the combination of localized advantages and modern technical conditions could mitigate the negative impact of topography. Finally, we identify 742 counties as lagging regions in URI, which can be clustered into eight types. Our findings could facilitate policy designing for those countries striving for integrated and sustainable development of urban and rural areas.
基金Under the auspices of National Natural Science Foundation of China(No.42271225)Research Program Fund for Humanities and Social Sciences of the Ministry of Education of China(No.22YJA790050)+2 种基金Henan Provincial Planning Fund for Philosophy and Social Sciences(No.2022BJJ011)Postgraduate Cultivating Innovation Action Plan of Henan University(No.SYLYC2022014)Henan University of Economics and Law Huang Tingfang/Xinhe Young Scholars Program(No.13)。
文摘Since China’s reform and opening up in 1978,the acceleration of industrialization and urbanization in China had led to dramatic changes in the pattern of urban-rural land use.In this paper,we focused on the rural industrialized areas in central China(Xinxiang County and Changyuan City of Henan Province).We used the average nearest neighbor index,spatial statistical analysis,and a structural equation model to analyze the spatiotemporal evolution and influencing factors of urban-rural construction land based on multisource spatial data and survey data.The results showed that:1)from 1975 to 2019,the spatial distribution of urban-rural construction land in rural industrialized areas had evolved from homogeneous distribution to local agglomeration.In terms of comparative analysis of cases,the spatial distribution of urban-rural construction land in Changyuan City had shown a trend from diffusion to agglomeration,and Xinxiang County had overall shown a spatial change from homogenization to agglomeration and then to regional integration development.2)The hot spots with increased urban-rural construction land significantly expanded,and they had a high degree of spatial overlap with industrial development.Among them,Xinxiang County was concentrated in central and marginal areas,and Changyuan was mainly concentrated in central urban areas.3)From the evolution of spatial proximity of urban-rural construction land,rural industrialized areas generally decline,showing the characteristics of internal differentiation in the rate of change.4)Industrial development,social economy,the policy environment,and urban development played a positive role in promoting the expansion of urban-rural construction land in rural industrialized areas.To promote the optimal use of regional land and the integrated development of urban-rural areas,we should combine the advantages of regional endowment,formulate development strategies according to local conditions,and adjust the way that land is used in a timely manner.
基金Under the auspices of National Natural Science Foundation of China (No. 42061020)Natural Science Foundation of Guangxi Zhuang Autonomous Region (No. 2018JJA150135)+3 种基金Guangxi Key Research and Development Program (No. AA18118038)Science and Technology Department of Guangxi Zhuang Autonomous Region (No. 2019AC20088)The Program of Improving the Basic Research Ability of Young and Middle-aged Teachers in Guangxi Universities (No. 2021KY0431)High Level Talent Introduction Project of Beibu Gulf University (No. 2019KYQD28)。
文摘Karst environmental issues have become one of the hot spots in contemporary international geological research. The same problem of water shortage is one of the hot spots of global concern. The peak-cluster depression basins in southwest of Guangxi is an important water connotation and ecological barrier areas in the Pearl River Basin of China. Thus, studying the spatial and temporal variations and the influencing factors of its water yield services is critical to achieve the sustainable development of water resources and ecological environmental protection in this region. As such, this paper uses the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST) model to assess the spatial and temporal variabilities of water yield services and its trends in the peak-cluster depression basins in southwest of Guangxi from 2000 to 2020. This work also integrates precipitation(Pre), reference evapotranspiration(ET), temperature(Tem), digital elevation model(DEM), slope, normalized difference vegetation index(NDVI), land use/land cover(LULC) and soil type to reveal the main factors that influence water yield services with the help of Geodetector. Results show that: 1) in time scale,the total annual water yield in the study area show a fluctuating and increasing trend from 2000 to 2020, with a growth rate of 7.3753 × 10^(8)m^(3)/yr, and its multi-year average water yield was 538.07 mm;2) in spatial pattern, with high yield areas mainly distributed in the south of the study area(mainly including Shangsi County, Pingxiang City, Ningming County, Longzhou County and Jingxi County), and low yield areas mainly distributed in Baise City and Nanning City;3) the dominant factor of water yield within karst and non-karst landforms is not necessarily controlled by precipitation, and the explanation degree of DEM factors in karst areas is significantly higher than that in non-karst areas;4) amongst the climatic factors, Pre, ET and Tem are dominant in the spatial pattern of region water yield capacity. among which Pre has the highest explanatory power for the spatial heterogeneity of annual water production, with q values above0.8, and each driver showed a significant interaction on the spatial distribution of water yield, with Pre exhibiting the strongest interaction with LULC.
基金supported by the Sichuan Science and Technology Program under Grants No.2022YFQ0052 and No.2021YFQ0009.
文摘At present,knowledge embedding methods are widely used in the field of knowledge graph(KG)reasoning,and have been successfully applied to those with large entities and relationships.However,in research and production environments,there are a large number of KGs with a small number of entities and relations,which are called sparse KGs.Limited by the performance of knowledge extraction methods or some other reasons(some common-sense information does not appear in the natural corpus),the relation between entities is often incomplete.To solve this problem,a method of the graph neural network and information enhancement is proposed.The improved method increases the mean reciprocal rank(MRR)and Hit@3 by 1.6%and 1.7%,respectively,when the sparsity of the FB15K-237 dataset is 10%.When the sparsity is 50%,the evaluation indexes MRR and Hit@10 are increased by 0.8%and 1.8%,respectively.
基金This research was funded by the National Natural Science Foundation of China(Grant No.52174113)the Young Jinggang Scholars Award Program in Jiangxi Province,China(Grant No.QNJG2018051)the“Thousand Talents”of Jiangxi Province,China(Grant No.jxsq2019201043).
文摘In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.
基金The National Natural Science Foundation of China(22078349,22005319,52170109)Self-deployment Program from Lanzhou Institute of Chemical Physics(E30159SQ).
文摘The interest in curtailing environmental pollution issues through physical separation processes has inspired an extensive search for novel nanoporous materials with exceptional adsorption capabilities.Covalent triazine frameworks(CTFs),emerged as a class of crystalline covalent organic frameworks(COFs),have been widely examined for various separation applications,owing to their large porosity,high stability,and rich nitrogen(N)doping.The development of CTFs for efficient adsorption of mercury(Ⅱ)(Hg^(2+))is of great importance for the field,whereas it is rarely attempted,on account of limited synthetic strategies and unknown structural-property relations of conventional CTFs derived from ionothermal approaches.Herein,we report rational synthesis of a crystalline CTF with methylthio pendant arms for efficient removal of Hg^(2+)with an exceptional capacity of 751 mg·g^(-1),ranking at the top among previously-reported adsorbents.This work may open up new possibility in the synthesis of COFs for various separations.
基金supported by the National Natural Science Foundation of China(32301453 and 3272675)the China Postdoctoral Science Foundation(2023M730682)。
文摘Achieving high maize yields and efficient phosphorus(P)use with limited environmental impacts is one of the greatest challenges in sustainable maize production.Increasing plant density is considered an effective approach for achieving high maize yields.However,the low mobility of P in soils and the scarcity of natural P resources have hindered the development of methods that can simultaneously optimize P use and mitigate the P-related environmental footprint at high plant densities.In this study,meta-analysis and substance flow analysis were conducted to evaluate the effects of different types of mineral P fertilizer on maize yield at varying plant densities and assess the flow of P from rock phosphate mining to P fertilizer use for maize production in China.A significantly higher yield was obtained at higher plant densities than at lower plant densities.The application of single superphosphate,triple super-phosphate,and calcium magnesium phosphate at high plant densities resulted in higher yields and a smaller environmental footprint than the application of diammonium phosphate and monoammonium phosphate.Our scenario analyses suggest that combining the optimal P type and application rate with a high plant density could increase maize yield by 22%.Further,the P resource use efficiency throughout the P supply chain increased by 39%,whereas the P-related environmental footprint decreased by 33%.Thus,simultaneously optimizing the P type and application rate at high plant densities achieved multiple objectives during maize production,indicating that combining P management with cropping techniques is a practical approach to sustainable maize production.These findings offer strategic,synergistic options for achieving sustainable agricultural development.
文摘Electrochemical biosensors have emerged as a promising technology for cancer detection due to their high sensitivity,rapid response,low cost,and capability for non-invasive detection.Recent advances in nanomaterials like nanoparticles,graphene,and nanowires have enhanced sensor performance to allow for cancer biomarker detection,like circulating tumor cells,nucleic acids,proteins and metabolites,at ultra-low concentrations.However,several challenges need to be addressed before electrochemical biosensors can be clinically implemented.These include improving sensor selectivity in complex biological media,device miniaturization for implantable applications,integration with data analytics,handling biomarker variability,and navigating regulatory approval.This editorial critically examines the prospects of electrochemical biosensors for efficient,low-cost and minimally invasive cancer screening.We discuss recent developments in nanotechnology,microfabrication,electronics integration,multiplexing,and machine learning that can help realize the potential of these sensors.However,significant interdisciplinary efforts among researchers,clinicians,regulators and the healthcare industry are still needed to tackle limitations in selectivity,size constraints,data interpretation,biomarker validation,toxicity and commercial translation.With committed resources and pragmatic strategies,electrochemical biosensors could enable routine early cancer detection and dramatically reduce the global cancer burden.
基金supported by Equipment Function Development Technology Innovation Project of Chinese Academy of Science(Y429C51005)the National Natural Science Foundation of China(41301064)+1 种基金Gansu Provincial Natural Science Foundation of China(1506RJZA286)National Found for Fostering Talents of Basic Science(Y311801001)
文摘Retrieval of oxalate from snow and ice provides information on past environmental changes. In recent years, records of organic acids in middle-and low-latitude glaciers have attracted the attention of researchers globally. In this study, we analyzed oxalates in an ice core from Laohugou Glacier No. 12 on the Qilian Mountains at an elevation of 5,040 m a.s.l. in2006. Average oxalate concentration was 18.5±2.4 ng/g over the prior 46 years. Oxalate values showed a significantly increasing trend since 1985. From 1985 to 1995, oxalate concentrations had large fluctuations, peaking in about 1987 and exhibiting a slightly decreasing trend since 1995. The result shows that the abrupt increase of oxalate concentration in the ice core since the mid-1980 s reflects atmospheric environmental pollution by human and industrial activities.
基金The National Natural Science Foundation of China under contract Nos 41071006 and 40676052the Jiangsu Natural Science Foundation under contract No. BK2010050the Research Fund for the Doctoral Program of Higher Education of China under contract No.20100091110011
文摘The North Branch, separated by the Chongming Island, was once the main channel in the estuary of the Changjiang River. Reclamation and a decrease in runoffto the North Branch had led to the narrowing and shallowing of the channel. The Yuantuojiao Point is located at the intersecting point connecting the North Branch of the Changjiang River and the Jiangsu coastline. Erosion cliffs are developed between the typical silty-muddy tidal flat and the salt marsh occupied by Spartina alterniflorea, and this has changed rapidly over the past few years. The sediment grain size analysis results of the surficial and two core samples indi- cate that the Yuantuoiiao Point tidal fiat experienced continuous accretional processes. Based upon 137Cs analysis results of the YT and YY Cores sampled from the tidal flat at the Yuantuojiao Point, the average sed- imentation rate of the YT Core was 2.30 cm/a from 1963 to 2007, and 2.38 cm/a from 1954 to 2007 for the YY Core. The sedimentation rates of both core locations have declined since the 1960s corresponding to the seaward reclamation at the Yuantuojiao Point. The average sedimentation rates at the Yuantnojiao Point were similar to that of the silty-muddy tidal flat at the northern ]iangsu coast, but lower than that of the south of the Changjiang River Estuary. According to field morphological investigations from 2006 to 2008 on the salt marsh at the Yuantuojiao Point, cliffs retreated markedly by storm surges and disappeared gradu- ally because of the rapid sedimentation on the silty-muddy tidal flat. The maximum annual retreat reached 10 m. The recent sedimentation and morphological changes of the Yuantuojiao Point tidal flat not only displayed the retreat of the salt marsh and the disappearance of cliffs, but also was accompanied by rapid sedimentation of the silty-muddy tidal flat and the salt marsh, indicating the responses to the tidal currents, storm surges, Spartina alterniflorea trapping sediments and large-scale reclamation. The sediment grain size and their trends, southward coastal flow, and sandspits of the longshore bars suggest that the main sediment source at the Yuantuoijao Point, estuary of the North Branch was possibly from the Changjiang River before 1958, since then, it has been from the south of the submarine radial sand ridges of the southern Huanghai Sea (Yellow Sea).
基金the National Key Research and Development Program of China (2016YFD0800406) for financial support
文摘A long-term field experiment was carried out with a wheat-maize rotation system to investigate the accumulation and bioavailability of heavy metals in a calcareous soil at different rates of sewage sludge amendment. There are significant linear correlations between the contents of Hg, Zn, Cu, Pb, and Cd in soil and sewage sludge amendment rates. By increasing 1 ton of applied sludge per hectare per year in soil, the contents of Hg, Zn, Cu, Pb, and Cd in soil increased by 6.20, 619, 92.9, 49.2, and 0.500 μg kg–1, respectively. For Hg, sewage sludge could be safely applied to the soil for 18 years at an application rate of 7.5 t ha–1 before content exceeded the soil environmental quality standards in China(1 mg kg–1). The safe application period for Zn is 51 years and is even longer for other heavy metals(112 years for Cu, 224 years for Cd, and 902 years for Pb) at an application rate of 7.5 t ha–1 sewage sludge. The contents of Zn and Ni in wheat grains and Zn, Cu, and Cr in maize grains increased linearly with increasing sewage sludge amendment rates. The contents of Zn, Cr, and Ni in wheat straws and Zn, Cu, and As in maize straws were positively correlated with sewage sludge amendment rates, while the content of Cu in wheat straws and Cr in maize straws showed the opposite trend. The bioconcentration factors of the heavy metals in wheat and maize grains were found to be in the order of Zn>Cu>Cd>Hg>Cr=Ni>Pb>As. Furthermore, the bioconcentration factors of heavy metals in wheat were greater than those in maize, indicating that wheat is more sensitive than maize as an indicator plant. These results will be helpful in developing the critical loads for sewage sludge amendment in calcareous soils.
文摘Based on the classical static theory and static numerical simulation,the static method could not accurately reflect the stability of goaf where the rocks on the pillar and roof are influenced by Theological and blasting disturbance for a long time.According to the test from the site,an experimental study was made in Theological and dynamic disturbance.After that,on the basis of variable rock mechanics parameters from the experimental data,numerical simulation was used to analyze the vertical stress distribution of goaf,vertical displacement and plastic area of roof in the "deterioration" caused by Theological and blasting,which shows that the mechanics properties of the rock were greatly influenced by Theological,and dynamic disturbance.The results of the experimental study and numerical simulation show that the mechanics properties of rock are greatly influenced by Theological and dynamic disturbance.As a result,the stability of goaf is greatly reduced.Finally,by comparing golf monitoring results with the analysis of theoretical calculation,it was found that the results were approximately the same,which testifies the reliability of the method.This method provides a new way of studying the stability of goaf as well as laying a basic foundation for future safety management.
基金Projects(2018YFC0808403,2018YFE0123000)supported by the National Key Technologies Research&Development Program of ChinaProject(800015Z1185)supported by the Yueqi Young Scholar Project,ChinaProject(2020YJSNY04)supported by the Fundamental Research Funds for the Central Universities,China。
文摘It is of great significance for safety reason to obtain the triaxial compressive properties of cemented tailings backfill(CTB).The influence of cement content,curing age and confining pressure on strength and deformation properties of CTB was examined and discussed.Results indicate that the triaxial compressive and deformation behavior of CTB is strongly affected by the cement content,curing age and confining pressure.The increase in cement content,curing age and confining pressure leads to a change in stress−strain behavior and an increase in the axial strain at failure and post-peak strength loss.The cohesion of CTB rises as the curing age and cement content increase.However,the enhancement in internal friction angle is trivial and negligible.It should be noted that the failure pattern of CTB samples in triaxial compression is mainly along a shear plane,the confining pressure restrains the lateral expansion and the bulging failure pattern is dominantly detected in CTB samples as curing age length and cement content increase.The results will help to better understand the triaxial mechanical and deformation behavior of CTB.
基金funded by the National Natural Science Foundation of China (Grant No.41671291)
文摘The source and sink landscape patterns refer to landscape types or units that can either promote positive evolvement of non-point source(NPS) pollution process, or can prevent/defer the ecological process, respectively. Therefore, the role of a catchment landscape pattern in nutrient losses can be identified based on the spatial arrangement of source and sink landscapes. To reveal the relations between landscape spatial characteristics and NPS pollution in small catchment, a case study was carried out in a Wangjiagou small catchment of the Three Gorges Reservoir Region(TGRR), China. Google earth imagery for 2015 were processed and used to differentiate source and sink landscape types, and six subcatchments were selected as sample regions for monitoring nitrogen and phosphorus nutrients.Relative elevation, slope gradient and relative flow length was used to construct the Lorenz curves of different source and sink landscape types in the catchment, in order to assess the source and sink landscape spatial characteristics. By calculating the location-weighted landscape indices of each subcatchment and total catchment, the landscape spatial load characteristics affecting the NPS pollution was identified, with a further Pearson correlation analysis for location-weighted landscape indices and nitrogen-phosphorus monitoring indicators. The analysis of Lorenz curve has revealed that the obtained distribution trend of Lorenz curve and curve area quantified well the spatial characteristics of source and sink landscape pattern related to the relative elevation, slope gradient and relative flow length in small catchment. Results of Pearson correction analysis indicated that location-weighted landscape index(LWLI) combining of terrain and landscape type factor did better in reflecting the status of nitrogen and phosphorus loss than the indices related to relative elevation, slope gradient and relative flow length.
基金financially supported by the Ministry of Water Resources (MWR) public sector research and special funds-the most stringent in arid zone water resources management key technologies (201301103)National Nature Science Foundation of China (NSFC) under Grant No. 41130641, 41201025+1 种基金Ministry of Education Key Laboratory of Eco-Oasis Open Topic-Moisture change in Central Asia and its influence on precipitation in Xinjang Province (XJDX0201-2013-07)the Tianshan Scholar Start-up Fund provided by Xinjiang University
文摘In order to predict long-term flooding under extreme weather conditions in central Asia, an energy balance-based distributed snowmelt runoff model was developed and coupled with the Soil and Water Assessment Tool(SWAT) model. The model was tested at the Juntanghu watershed on the northern slope of the Tian Shan Mountains, Xinjiang,China. We compared the performances of temperature-index method and energy balanced method in SWAT model by taking Juntanghu river basin as an application example(as the simulation experiment was conducted in Juntanghu River, we call the energy balanced method as SWAT-JTH). The results suggest that the SWAT snowmelt model had overall Nash-Sutcliffe efficiency(NSE) coefficients ranging from 0.61 to 0.85 while the physical based approach had NSE coefficients ranging from 0.58 to0.69. Overall, on monthly scale, the SWAT model provides better results than that from the SWAT-JTH model. However, results generated from both methods seem to be fairly close at a daily scale. Thestructure of the temperature-index method is simple and produces reasonable simulation results if the parameters are well within empirical ranges. Although the data requirement for the energy balance method in current observation is difficult to meet and the existence of uncertainty is associated with the experimental approaches of physical processes, the SWAT-JTH model still produced a reasonably high NSE. We conclude that using temperature-index methods to simulate the snowmelt process is sufficient, but the energy balance-based model is still a good choice to simulate extreme weather conditions especially when the required data input for the model is acquired.