Vulnerability of Large City and Its Implication in Urban Planning: A Perspective of Intra-urban Structure

Vulnerability is a new field and analytical tool in the study of urban safety. Analysis and assessment of vulnerability provide a new basis for urban planning. This study constructed a quantitative index system for assessing vulnerability, based on the city′s sensitivity and emergency response capacity. City size, density, and spatial form influence a city′s sensitivity to crises and risks, to which vulnerability is positively related. Levels of socio-economic development, infrastructures, and emergency management contribute to a city′s emergency response capacity, with which vulnerability is inversely associated. Vulnerability of 19 large Chinese cities was assessed. Harbin and Shenzhen demonstrated the highest and lowest vulnerability among 19 cities, while Beijing, Shanghai and Guangzhou ranked the 5th, the 9th and the 12th. Spatially, northern cities tended to be more vulnerable than southern cities. And the differences in vulnerability among cities were explored based on cities′ physical geography conditions, level of socioeconomic development, infrastructures, regional status, history of disaster, history of urban planning and development, government policies, etc.

Analysis of Urban Expansion and Driving Forces in Xuzhou City Based on Remote Sensing

Based on satellite remote sensing TM/ETM+ images of Xuzhou city,land use forms of the city in 1987,1994 and 2000 were extracted by using a neural network classification method. The expansion contribution rate and annual expansion intensity index of each administrative district have been calculated and the contribution rate matrices and spatial distribution maps of land use changes were obtained. Based on the above analysis,the characteristics of urban expansion from 1987 to 2000 have been explored. From 1987 to 1994,the expansion contribution rate of Quanshan dis-trict reached 46.80%,the highest in all administrative districts of Xuzhou city; Tongshan town was in a high-speed ex-pansion period; both Quanshan and Yunlong districts were experiencing fast-speed expansion periods while the entire city was expanding at a medium-speed with an annual expansion intensity index of 0.98; the city spread eastwards and southwards. From 1994 to 2000,the expansion contribution rate of Quanshan district reached 43.67%,the highest in Xuzhou; the entire city was in a medium-speed expansion period with an annual expansion intensity index of 1.04; the city has rapidly been extended towards the southeast. According to the contribution rate matrices of land use changes,urban expansion mainly usurps cropland and woodland. A quantitative analysis found that population growth,indus-trialization and economic development are the primary driving forces behind urban expansion.

The Impact of the Cognition of Landscape Experience on Tourist Environmental Conservation Behaviors

This article explores the relationship between the tourist's cognition of the landscape experience and the environmental conservation efforts at three distinct tourist sites in mountains of southwestern China. A total of 1500 on-site questionnaire surveys were distributed and 1142 valid questionnaires were used for statistical analysis. Results from multi-group path analysis showed that both cognition of the cultural landscape experience and cognition of the natural landscape experience had positive impacts on environmental conservation behaviors and behavior intentions of tourists. Results from comparative analysis among the three tourist sites indicated that cognition of the cultural landscape experience had a stronger power to predict senior environmental conservation behaviors and behavior intentions than cognition of the natural landscape experience, whereas cognition of the natural landscape experience had more power to predict general environmental conservation behaviors and behavior intentions than cognition of the cultural landscape experience. Furthermore, our findings benefit environmental management and sustainabilityat tourist sites.

Contribution of Root and Microbial Respiration to Soil CO_2 Efflux and Their Environmental Controls in a Humid Temperate Grassland of Japan

Soil CO2 efflux, root mass, and root production were investigated in a humid temperate grassland of Japan over a growing season （Apr. to Sep.） of 2005 to reveal seasonal changes of soil CO2 efflux, to separate the respective contributions of root and microbial respiration to the total soil CO2 efttux, and to determine the environmental factors that control soil respiration. Minimal microbial respiration rate was estimated based on the linear regression equations between soil CO2 effiux and root mass at different experimental sites. Soil CO2 efflux, ranging from 4.99 to 16.29 μmol CO2 m^-2 s^-1, depended on the seasonal changes in soil temperature. The root mass at 0-10 cm soil depth was 0.82 and 1.27 kg m^-2 in Apr. and Sep., respectively. The root mass at 0-10 cm soil depth comprised 60% of the total root mass at 0-50 cm soil depth. The root productivity at 0-30 cm depth varied from 8 to 180 g m^-2 month^-1. Microbial and root respiration rates ranged from 1.35 to 5.51 and 2.72 to 12.06μmol CO2 m^-2 s^-1, respectively. The contribution of root respiration to the total soil CO2 efflux averaged 53%, ranging from 33% to 72%. The microbial respiration rate was exponentially related to soil temperature at 10 cm depth （R^2 = 0.9400, P = 0.002, n = 6）, and the root respiration rate was linearly related to the root production at 0-30 cm depth （R2 = 0.6561, P = 0.042, n = 6）.

Geological Environmental Adaptability of Qingdao Rural Urbanization Based on Fuzzy Mathematical Method

Fuzzy mathematics comprehensive evaluation method is used to evaluate the geological environment suitability of rural urbanization in Qingdao City,China.A total of 5 first-level evaluation factors are selected,including environmental geological condition,geological resources,engineering geological condition,geological disaster and environmental geological problem,and human engineering activity.And there are 27 second-level evaluation factors,such as topography,land type and vegetation,nature reserve,water source protection area,groundwater quality division,and major engineering project.Qingdao City is divided into four districts of suitable area,relatively suitable area,moderately suitable area and relatively unsuitable area of ecological environment.And their characteristics are introduced.Suggestions for the developing direction of urban construction are put forward.Region of Laoshan District lying to the west of the Shilaoren is suitable to set up high-rise building;west Hongshiya may establish a waste landfill site;Jiaozhou Bay,the downstream of Dagu River,and Jihongtan Reservoir should be built as the key geological environment protection area and water source protection area.And the north Hongdao should be strictly monitored in order to control the expansion of urban construction to Jihongtan Reservoir.Mocheng District and the area north of it,Jiaozhou District and the area east of it are the ideal urban construction development areas in Qingdao City in the future.

Dynamic Changes in the Wetland Landscape Pattern of the Yellow River Delta from 1976 to 2016 Based on Satellite Data

The Yellow River Delta wetland is the youngest wetland ecosystem in China's warm temperate zone. To better understand how its landscape pattern has changed over time and the underlying factors responsible, this study analyzed the dynamic changes of wetlands using five Landsat series of images, namely MSS(Mulri Spectral Scanner), TM(Thematic Mapper), and OLI(Operational Land Imager) sensors in 1976, 1986, 1996, 2006, and 2016. Object-oriented classification and the combination of spatial and spectral features and both the Normalized Difference Vegetation Index(NDVI) and Normalized Difference Water Index(NDWI), as well as brightness characteristic indices, were used to classify the images in eCognition software. Landscape pattern changes in the Yellow River Delta over the past 40 years were then delineated using transition matrix and landscape index methods. Results show that: 1) from1976 to 2016, the total area of wetlands in the study area decreased from 2594.76 to 2491.79 km^2, while that of natural wetlands decreased by 954.03 km^2 whereas human-made wetlands increased by 851.06 km^2. 2) The transformation of natural wetlands was extensive: 31.34% of those covered by Suaeda heteropteras were transformed into reservoirs and ponds, and 24.71% with Phragmites australis coverage were transformed into dry farmland. Some human-made wetlands were transformed into non-wetlands types: 1.55% of reservoirs and ponds became construction land, and likewise 21.27% were transformed into dry farmland. 3) From 1976 to 2016, as the intensity of human activities increased, the number of landscape types in the study area continuously increased. Patches were scattered and more fragmented. The whole landscape became more complex. In short, over the past 40 years, the wetlands of the Yellow River Delta have been degraded, with the area of natural wetlands substantially reduced. Human activities were the dominant forces driving these changes in the Yellow River Delta.

The Implications of Population Decline and Fiscal Austerity on Public Nature:Insights From the Evolution of Urban Park Management System in Japan

Facing challenges of population decline and fiscal austerity,Japan has implemented a series of initiatives to promote public-private partnerships(PPP)to ensure the sustainability of urban parks and revitalize urban spaces.These initiatives,while alleviating the government’s financial burdens on parks,have also raised concerns about the potential erosion of publicness and public interests resulted from the commercialization of public assets.This paper reviews the evolution of Japan’s urban park management system after World War II—including three phases of being purely public goods,initiating marketization,and diversifying management entities.The functions of parks have continuously enriched,and the construction,management,and operational modes have shifted from government-led towards multi-stakeholder participation,along with expanded funding sources.By examining the PPP types,driving forces,implementation mechanisms and challenges in urban park management,this paper points out that,in different eras and social contexts,the Japanese government has kept adjusting its role to maximize public interests.This has proactively updated the implications of publicness in infrastructure like urban parks,from a post-war opposite of publicness versus privateness on ownership,to the participation of private capital for a higher efficiency,and finally to a community for a stronger regional competitiveness.The reforms of urban park management system in Japan offer significant lessons and insights for urban infrastructure management in other countries and regions.

Case study on the extraction of land cover information from the SAR image of a coal mining area

In this study,analyses are conducted on the information features of a construction site,a cornfield and subsidence seeper land in a coal mining area with a synthetic aperture radar (SAR) image of medium resolution. Based on features of land cover of the coal mining area,on texture feature extraction and a selection method of a gray-level co-occurrence matrix (GLCM) of the SAR image,we propose in this study that the optimum window size for computing the GLCM is an appropriate sized window that can effectively distinguish different types of land cover. Next,a band combination was carried out over the text feature images and the band-filtered SAR image to secure a new multi-band image. After the transformation of the new image with principal component analysis,a classification is conducted selectively on three principal component bands with the most information. Finally,through training and experimenting with the samples,a better three-layered BP neural network was established to classify the SAR image. The results show that,assisted by texture information,the neural network classification improved the accuracy of SAR image classification by 14.6%,compared with a classification by maximum likelihood estimation without texture information.

Relationship Between Social Economic Agglomeration and Labor Productivity of Core Cities in Northeast China

Dalian, Shenyang, Changchun and Harbin are the four core cities which play an essential role in terms of promoting the economic development in Northeast China. In this paper, the impact of urban agglomeration on labor productivity is explored by making comparisons among these four cities. The model used for analysis is a classical model derived from previous studies. Some indicators, such as population density and economic density, were selected to examine the impact of urban agglomeration on the labor productivity based on the time-series data for the four cities from 1990 to 2007. The four main conclusions are： l） The promotion from the growth rate of population density on the growth rate of labor productivity is limited. 2） The negative relationship exists between the growth rate of employment density and the growth rate of labor productivity. 3） Agglomeration effect exists in the four cities, the highest one is Dalian, Shenyang takes the second place, followed by Changchun and Harbin, and the predominant promotion exerted on the labor productivity is the output density.

Decomposition Analysis on Direct Material Input and Dematerialization of Mining Cities in Northeast China

Material dematerialization is a basic approach to reduce the pressure on the resources and environment and to realize the sustainable development. The material flow analysis and decomposition method are used to calculate the direct material input (DMI) of 14 typical mining cities in Northeast China in 1995–2004 and to analyze the demateri- alization and its driving factors in the different types of mining cities oriented by coal, petroleum, metallurgy and multi-resources. The results are as follows: 1) from 1995 to 2006, the increase rates of the DMI and the material input intensity of mining cities declined following the order of multi-resources, metallurgy, coal, and petroleum cities, and the material utilizing efficiency did following the order of petroleum, coal, metallurgy, and multi-resources cities; 2) during the research period, all the kinds of mining cities were in the situation of weak sustainable development in most years; 3) the pressure on resources and environment in the multi-resources cities was the most serious; 4) the petro- leum cities showed the strong trend of sustainable development; and 5) in recent years, the driving function of eco- nomic development for material consuming has continuously strengthened and the controlling function of material utilizing efficiency for it has weakened. The key approaches to promote the development of circular economy of min- ing cities in Northeast China are put forward in the following aspects: 1) to strengthen the research and development of the technique of resources’ cycling utilization, 2) to improve the utilizing efficiency of resources, and 3) to carry out the auditing system of resources utilization.

Tourism and Land Transformation:A Case Study of the Li River Basin,Guilin,China

Land-use change is intertwined with tourism because land is used as a resource for human activities.Land-use change also provides an opportunity to evaluate the status of the ecoenvironment.Understanding the relationship between tourism and land use change would help to predict the effect of tourism on land use and encourage sustainable tourism development.Using the Li River Basin as a case study,a hybrid approach using multilevel modeling and logistic regressions was employed to analyze the distribution of land-usechange between 1989 and 2010 to examine potential driving factors.Results reveal that rapid tourism development and construction expansion expose this area to risk of deforestation and forest degradation.Construction increased by 141% between 1989 and 2000 and by 195% between 2000 and 2010.The primary driving force for construction expansion shifted from population growth between 1989 and 2000 to investment growth after 2000.New construction primarily occurred on crop and woodlands areas,with shares of 81.25% and 6.38%,respectively,between 1989 and 2000,and with shares of 57.79% and 15.29%,respectively,between 2000 and 2010.Moreover,these drastic increases in construction also led to frequent transitions between croplands,woodlands,and grasslands.Traits including distances to urban areas and roads and scenic locations exerted significant effects on land-use change.Woodland regrowth in the areas thatsurround scenic locations consisted of fluctuating woodlands,whereas stable woodland regrowth was often absent in these areas.Likewise,permanent woodland clearing tended to be closed to near scenic locations.That is,construction at scenic locations negatively affected forest conservation in the Li River Basin.

Analysis of Spatio-Temporal Changes of Land Usein Xuzhou City Based on Remote Sensing

Based on the satellite remote sensing TM/ETM images of Xuzhou city, basic data about land use of the city from 1994 to 2000 are obtained with the neural network classification module of PCI software, and the dynamic con- version matrix of land use is thus calculated. The areas of construction land and water body have increased by 1833.93 hm2 and 804.87 hm2, respectively. On the contrary, the area of cropland has decreased by 3207.24 hm2. The area of cropland converted into construction land makes up 26.84%, and that converted into water body amounts for 8.17% of the total area of cropland in 1994. The variation index of land use degree and the dynamic degree index of land use computed are 1.38 and 57.81%, respectively, which demonstrate that land use in Xuzhou is in a development period and the changes are drastic. The frequency index and importance index of the form in which cropland converted into con- struction land are 29.91% and 68.93% respectively. The results indicate that the change is not only widespread in space but a major form of spatial change of land use in the area.

Response Relationship between the Seasonal Freezing-Thawing Process of Soil and Spatial Factor Changes in the Dayekou Basin of the Qilian Mountains

Objective: In this study, the influence and response relationship between the seasonal freezing-thawing process of soil and the spatial factor changes in the management and utilization of water resource processes were explored. Methods: The monitoring equipment in this study was arranged at different altitudes, gradients, and slope directions, such as the typical forest sample area in the Dayekou Basin of the Qilian Mountains. The spatial variation characteristics of the seasonal freezing-thawing process of the soil were analyzed, and a regression model was established. Results: 1) The results of this study determined that the rate of the soil’s freezing increased with the altitude in a trend of volatility. However, the rate of the thawing of the frozen soil was found to have an opposite trend. The variation degree of the freezing-thawing process increased with the altitude in a trend of volatility. The end time of the approximate soil freezing with altitude increased in a volatility trend ahead of schedule. However, the opposite was observed in the thawing rate of the frozen soil;2) The rate of the soil’s freezing under the mosses of the spruce forest at an altitude of 3028 m was found to be the lowest. However, in the sub-alpine scrub forest at an altitude of 3300 m, a maximum in the spatial ordering was observed, with an average of 1.9 cm·d-1. The thawing rate of the frozen soil in scrub-spruce forest at an altitude of 3300 m was found to be minimal. However, in the sunny slope grassland at an altitude of 2946 m, a maximum in the spatial ordering was observed, with an average of 1.5 cm·d-1. In the spatial ordering of the variation degree of the process of freezing-thawing with an average of 1.2, the scrub-grassland at an altitude of 2518 m was found to be the lowest, and the scrub-spruce forest at an altitude of 3195 m was also low;3) The soil freezing began on approximately October 20th, and the rate of soil freezing gradually became reduced. The arrival time of the frozen soil of up to 150 cm in depth in sub-alpine scrub forest was first observed at an altitude of 3028 m. However, the scrub-spruce forest at an altitude of 3100 m did not become frozen until approximately January 12th on average. Then, the thawing rate of the frozen soil increased gradually. The end time of the thawing was earliest observed in the sunny slope grassland at an altitude of 2946 m. However, the scrub-spruce forest at an altitude of 3100 m was found to be the last to thaw, and averaged approximately July 27th. The average durations of the freezing and thawing of the soil were 77 and 121 days, respectively, and the average duration of the entire process of freezing-thawing was 199 days;4) This study’s established regression models of the duration time of frozen soil’s thaw, and the rate of frozen soil’s thaw, all passed the R test of goodness of fit, F test of variance, and t test. Conclusions: The characteristics of the seasonal freezing-thawing process of the soil with the spatial changes were seasonal. However, the characteristics under the different spatial factor influences were not the same.

Fusing multi-source data to map spatio-temporal dynamics of winter rape on the Jianghan Plain and Dongting Lake Plain, China

Mapping crop distribution with remote sensing data is of great importance for agricultural production, food security and agricultural sustainability. Winter rape is an important oil crop, which plays an important role in the cooking oil market of China. The Jianghan Plain and Dongting Lake Plain (JPDLP) are major agricultural production areas in China. Essential changes in winter rape distribution have taken place in this area during the 21st century. However, the pattern of these changes remains unknown. In this study, the spatial and temporal dynamics of winter rape from 2000 to 2017 on the JPDLP were analyzed. An artificial neural network (ANN)-based classification method was proposed to map fractional winter rape distribution by fusing moderate resolution imaging spectrometer (MODIS) data and high-resolution imagery. The results are as follows:(1) The total winter rape acreages on the JPDLP dropped significantly, especially on the Jianghan Plain with a decline of about 45% during 2000 and 2017.(2) The winter rape abundance keeps changing with about 20–30% croplands changing their abundance drastically in every two consecutive observation years.(3) The winter rape has obvious regional differentiation for the trend of its change at the county level, and the decreasing trend was observed more strongly in the traditionally dominant agricultural counties.

Walking Access Distance of Metro Passengers and Relationship with Demographic Characteristics: A Case Study of Nanjing Metro

In the metropolises of China, the metro plays an increasingly important role in commuting because of its efficiency, affordability, and cleanliness. This paper attempts to explore the relationship between walking access distance to metro stations and the demographic characteristics of passengers, such as age, monthly income, travel frequency, gender, and travel purpose, as well as the influence of the urban context. Nanjing Metro Line 2 is selected as the case study. By using different methods such as a questionnaire survey, spatial decay function, analysis of covariance(ANOVA), network analysis of routes, and K-means cluster analysis, it is suggested that demographic characteristics have a significant impact on the pedestrian walking distance, with the exception of gender. Furthermore, the paper finds a spatial decay effect in walking access distance, the decay rate of which, however, varies across stations. Terminal stations have a larger pedestrian catchment area than in regular and exchange stations. Moreover, the passengers of Nanjing Metro Line 2 can be classified into six groups according to their demographic characteristics, among which education and occupation are vital indicators in determining their willingness to walk to the stations. Middle-class passengers have a higher dependence on the metro and tend to walk longer than other groups do. This study provides an important reference for planners and transport sectors to optimize land-use and transport infrastructures.

Evaluation of SWAT Model performance on glaciated and non-glaciated subbasins of Nam Co Lake, Southern Tibetan Plateau, China

This paper presents an assessment of the Soil and Water Assessment Tool(SWAT) on a glaciated(Qugaqie) and a non-glaciated(Niyaqu) subbasin of the Nam Co Lake. The Nam Co Lake is located in the southern Tibetan Plateau, two subbasins having catchment areas of 59 km^2 and 388 km^2, respectively. The scores of examined evaluation indices(i.e., R^2, NSE, and PBIAS) established that the performance of the SWAT model was better on the monthly scale compared to the daily scale. The respective monthly values of R^2, NSE, and PBIAS were 0.94, 0.97, and 0.50 for the calibration period while 0.92, 0.88, and -8.80 for the validation period. Glacier melt contribution in the study domain was simulated by using the SWAT model in conjunction with the Degree Day Melt(DDM) approach. The conjunction of DDM with the SWAT Model ensued improved results during both calibration(R^2=0.96, NSE=0.95, and PBIAS=-13.49) and validation (R^2=0.97, NSE=0.96, and PBIAS=-2.87) periods on the monthly time scale. Average contribution(in percentage) of water balance components to the total streamflow of Niyaqu and Qugaqie subbasins was evaluated. We found that the major portion(99.45%) of the streamflow in the Niyaqu subbasin was generated by snowmelt or rainfall surface runoff(SURF_Q), followed by groundwater(GW_Q, 0.47%), and lateral(LAT_Q, 0.06%) flows. Conversely, in the Qugaqie subbasin, major contributor to the streamflow(79.63%) was glacier melt(GLC_Q), followed by SURF_Q(20.14%), GW_Q(0.13%), and LAT_Q(0.089%). The contribution of GLC_Q was the highest(86.79%) in July and lowest(69.95%) in September. This study concludes that the performance of the SWAT model in glaciated catchment is weak without considering glacier component in modeling; however, it performs reasonably well in non-glaciated catchment. Furthermore, the temperature index approach with elevation bands is viable in those catchments where streamflows are driven by snowmelt. Therefore, it is recommended to use the SWAT Model in conjunction with DDM or energy base model to simulate the glacier melt contribution to the total streamflow. This study might be helpful in quantification and better management of water resources in data scarce glaciated regions.

Retrieval of Outgoing Longwave Radiation from COMS Narrowband Infrared Imagery

Hourly outgoing longwave radiation （OLR） from the geostationary satellite Communication Oceanography Meteorological Satellite （COMS） has been retrieved since June 2010.The COMS OLR retrieval algorithms are based on regression analyses of radiative transfer simulations for spectral functions of COMS infrared channels.This study documents the accuracies of OLRs for future climate applications by making an intercomparison of four OLRs from one single-channel algorithm （OLR12.0 using the 12.0 μm channel） and three multiple-channel algorithms （OLR10.8＋12.0 using the 10.8 and 12.0 pm channels; OLR6.7＋10.8 using the 6.7 and 10.8 μm channels; and OLRAll using the 6.7,10.8,and 12.0 μm channels）.The COMS OLRs from these algorithms were validated with direct measurements of OLR from a broadband radiometer of the Clouds and Earth＇s Radiant Energy System （CERES） over the full COMS field of view [roughly （50°S-50°N,70°-170°E）] during April 2011.Validation results show that the root-mean-square errors of COMS OLRs are 5-7 W m-2,which indicates good agreement with CERES OLR over the vast domain.OLR6.7＋10.8 and OLRAll have much smaller errors （～ 6 W m-2） than OLR12.0 and OLR10.8＋12.0 （～ 8 W m-2）.Moreover,the small errors of OLR6.7＋10.8 and OLRAll are systematic and can be readily reduced through additional mean bias correction and/or radiance calibration.These results indicate a noteworthy role of the 6.7 μm water vapor absorption channel in improving the accuracy of the OLRs.The dependence of the accuracy of COMS OLRs on various surface,atmospheric,and observational conditions is also discussed.

Analysis of the Relationship Between Plant Growth and Moisture Variation in the Desert Area of Hexi Corridor

In order to analyze the relationship between desert plant growth and precipitation,soil moisture,as well as groundwater in desertification control,a comprehensive desertification prevention and control station was established in the desert area of Hexi Corridor for long-term location monitoring,and data of precipitation,soil moisture,groundwater,coverage,and biomass were obtained.Methods including characteristic parameter algorithm,correlation analysis,and stepwise multiple linear regression analysis were employed to analyze the annual and inter-annual variation characteristics of plant growth and moisture,and related regression models were analyzed.The results showed that:(1) from 2006 to 2014,the inter-annual variation of soil moisture was the most drastic,the precipitation,biomass,and coverage underwent a similarly great variation,and the variation of the groundwater was the most moderate.The coverage showed a significantly fluctuating uptrend,and the biomass increased slightly.The precipitation,soil moisture,and groundwater showed a slight decrease,but it was not obvious.(2) During the plant growing season from March to November,the change of moisture content in each layer of soil was basical y the same,and the changes in biomass and coverage were basically the same,so were the changes in precipitation and groundwater.The order of the change range from large to small within the year was precipitation > groundwater depth > biomass > average coverage > soil moisture content.(3) Both the coverage and biomass models passed the R-fitting test,the F-test,and the t-test.The models predicted the variation of 58.0% and 98.7%,and the accuracy rate reached 52.0% and 86.2%.The research results can provide scientific support and reference data for water resources management in the prevention and control of desertification,as well as the evaluation of the influence of projects such as returning farmland to forest,natural forest protection,and comprehensive management of the Heihe River Basin on water resources.

Suppression of gold nanoparticle agglomeration and its separation via nylon membranes

Use of ultraporous nylon membrane is one of the most widely employed techniques for removal of hard and soft nanoparticles in the semiconductor industry, and the accurate determination of membrane pore size is necessary in order to avoid manufacturing defects caused by contamination. The gold nanoparticle has several benefits for the evaluation of polymeric membranes; however, the nanoparticles agglomerate easily on the nylon membrane and make it difficult to evaluate the membrane precisely. The properties of 2-amino-2-hydroxymethyl-1,3-propanediol(ADP) ligand in gold nanoparticle solution were systematically investigated, and ADP was utilized for improved evaluation of the nylon membranes. Nylon membrane used in this study was prepared by phase inversion techniques. Ultrathin dense layer on top of the membrane surface and Darcy structures in the microporous membrane support were observed. The gold particle rejection was carried out at various p H values from 4 to14 and higher rejection was observed at p H 4 and 8. The suppression of gold colloid agglomeration using ADP and monodispersity of gold colloids was also analyzed by confocal laser scanning microscopy(CLSM), transmission electron microscopy(TEM), and scanning electron microscopy(SEM). van der Waals interaction energy of the particles was reduced in the addition of ADP. The presence of ADP ligand in the gold solutions prevented the agglomeration of gold nanoparticles and reduced the adsorption of the particles on the nylon membrane surface,leading to precise evaluation of membrane pore sizes.

Research on the Development of Green Building Technology in Hot Summer and Cold Winter Area under the Background of Carbon Neutrality:A Case Study of Zhuzhou City

Carbon sequestration and emission reduction in the construction industry plays an important role in China’s goal of achieving carbon neutrality.Research in Zhuzhou city scored 42 since the assessment of the green building project situation as the research object,in hot summer and cold winter areas of analysis and evaluation on the development of green building technology,and then sums up the carbon neutral background the priority areas and tasks for the development of green building techniques,optimization of the construction industry into a new era under the background of green development to provide the reference.