Identifying the Hydrochemical Characteristics,Genetic Mechanisms and Potential Human Health Risks of Fluoride and Nitrate Enriched Groundwater in the Tongzhou District,Beijing,North China

Fluoride and nitrate enriched groundwater are potential threats to the safety of the groundwater supply that may cause significant effects on human health and public safety,especially in aggregated population areas and economic hubs.This study focuses on the high F^(−)and NO_(3)^(−)concentration groundwater in Tongzhou District,Beijing,North China.A total of 36 groundwater samples were collected to analyze the hydrochemical characteristics,elucidate genetic mechanisms and evaluate the potential human health risks.The results of the analysis indicate:Firstly,most of the groundwater samples are characterized by Mg-HCO_(3) and Na-HCO_(3) with the pH ranging from 7.19 to 8.28 and TDS with a large variation across the range 471-2337 mg/L.The NO_(3)^(−)concentration in 38.89%groundwater samples and the F^(−)concentration in 66.67%groundwater samples exceed the permissible limited value.Secondly,F^(−)in groundwater originates predominantly from water-rock interactions and the fluorite dissolution,which is also regulated by cation exchange,competitive adsorption of HCO_(3)−and an alkaline environment.Thirdly,the effect of sewage disposal and agricultural activities have a significant effect on high NO3-concentration,while the high F^(−)concentration is less influenced by anthropogenic activity.The alkaline environment favors nitrification,thus being conducive to the production of NO_(3)^(−).Finally,the health risk assessment is evaluated for different population groups.The results indicate that high NO_(3)^(−)and F^(−)concentration in groundwater would have the largest threat to children’s health.The findings of this study could contribute to the provision of a scientific basis for groundwater supply policy formulation relating to public health in Tongzhou District.

Geochemical and Isotopic Techniques Constraints on the Origin,Evolution,and Residence Time of Low-enthalpy Geothermal Water in Western Wugongshan,SE China

Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate change.The Wugongshan area,situated in the southeast coast geothermal belt of China,is a typical geothermal anomaly and contains abundant medium-and low-temperature geothermal resources.This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region,encompassing the recharge origin,water-rock interaction mechanisms,and residence time.The results show that the geothermal water in the western region of Wugongshan is weakly alkaline,with low enthalpy and mineralization levels.The hydrochemistry of geothermal waters is dominated by Na-HCO_(3)and Na-SO_(4),while the hydrochemistry types of cold springs are all Na-HCO_(3).The hydrochemistry types of surface waters and rain waters are NaHCO_(3)or Ca-HCO_(3).The δD and δ^(18)O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m.Molar ratios of maj or solutes and isotopic compositions of^(87)Sr/^(86)Sr underscore the significant role of silicate weathering,dissolution,and cation exchange in controlling geothermal water chemistry.Additionally,geothermal waters experienced varying degrees of mixing with cold water during their ascent.Theδ^(13)C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic.Theδ^(34)S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock.Age dating using 3H and^(14)C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.

Fiber optic monitoring of an anti-slide pile in a retrogressive landslide

Anti-slide piles are one of the most important reinforcement structures against landslides,and evalu-ating the working conditions is of great significance for landslide mitigation.The widely adopted analytical methods of pile internal forces include cantilever beam method and elastic foundation beam method.However,due to many assumptions involved in calculation,the analytical models cannot be fully applicable to complex site situations,e.g.landslides with multi-sliding surfaces and pile-soil interface separation as discussed herein.In view of this,the combination of distributed fiber optic sensing(DFOS)and strain-internal force conversion methods was proposed to evaluate the working conditions of an anti-sliding pile in a typical retrogressive landslide in the Three Gorges reservoir area,China.Brillouin optical time domain reflectometry(BOTDR)was utilized to monitor the strain distri-bution along the pile.Next,by analyzing the relative deformation between the pile and its adjacent inclinometer,the pile-soil interface separation was profiled.Finally,the internal forces of the anti-slide pile were derived based on the strain-internal force conversion method.According to the ratio of calculated internal forces to the design values,the working conditions of the anti-slide pile could be evaluated.The results demonstrated that the proposed method could reveal the deformation pattern of the anti-slide pile system,and can quantitatively evaluate its working conditions.

Comparison of debris flow susceptibility assessment methods:support vector machine,particle swarm optimization,and feature selection techniques

The selection of important factors in machine learning-based susceptibility assessments is crucial to obtain reliable susceptibility results.In this study,metaheuristic optimization and feature selection techniques were applied to identify the most important input parameters for mapping debris flow susceptibility in the southern mountain area of Chengde City in Hebei Province,China,by using machine learning algorithms.In total,133 historical debris flow records and 16 related factors were selected.The support vector machine(SVM)was first used as the base classifier,and then a hybrid model was introduced by a two-step process.First,the particle swarm optimization(PSO)algorithm was employed to select the SVM model hyperparameters.Second,two feature selection algorithms,namely principal component analysis(PCA)and PSO,were integrated into the PSO-based SVM model,which generated the PCA-PSO-SVM and FS-PSO-SVM models,respectively.Three statistical metrics(accuracy,recall,and specificity)and the area under the receiver operating characteristic curve(AUC)were employed to evaluate and validate the performance of the models.The results indicated that the feature selection-based models exhibited the best performance,followed by the PSO-based SVM and SVM models.Moreover,the performance of the FS-PSO-SVM model was better than that of the PCA-PSO-SVM model,showing the highest AUC,accuracy,recall,and specificity values in both the training and testing processes.It was found that the selection of optimal features is crucial to improving the reliability of debris flow susceptibility assessment results.Moreover,the PSO algorithm was found to be not only an effective tool for hyperparameter optimization,but also a useful feature selection algorithm to improve prediction accuracies of debris flow susceptibility by using machine learning algorithms.The high and very high debris flow susceptibility zone appropriately covers 38.01%of the study area,where debris flow may occur under intensive human activities and heavy rainfall events.

Reactive Transport Process of Earthquake-induced Hydrochemical Changes in Guanding Thermal Spring,Western Sichuan,China

Earthquake-related hydrochemical changes in thermal springs have been widely observed;however,quantitative modeling of the reactive transport process is absent.In the present study,we apply reactive transport simulation to capture the hydrochemical responses in a thermal spring following the Wenchuan Ms 8.0 and Lushan Ms 7.0 earthquakes.We first constrain deep reservoir geothermal fluid compositions and temperature by multicomponent geothermometry,and then a reactive geochemical transport model is constructed to reproduce the hydrochemical evolution process.The results show that the recharge from the shallow aquifer increases gradually until it reaches a peak because of the permeability enhancement caused by the Lushan earthquake,which may be the mechanism to explain the earthquake-related hydrochemical responses.In contrast to the postseismic effect of the Wenchuan earthquake,the chemical evolution can be considered as hydrochemical anomalies related to the Lushan earthquake.This study proves that the efficient simulation of reactive transport processes is useful for investigating earthquake-related signals in hydrochemical time series.

Source,migration,distribution,toxicological effects and remediation technologies of arsenic in groundwater in China

Groundwater with high arsenic(As) content seriously threatens human life and health. Drinking high-As groundwater for a long time will lead to various pathological changes such as skin cancer, liver cancer,and kidney cancer. High-As groundwater has become one of the most serious environmental geological problems in China and even internationally. This paper aims to systematically summarize the sources,migration, distribution, toxicological effects, and treatment techniques of As in natural groundwater in China based on a large number of literature surveys. High-As groundwater in China is mainly distributed in the inland basins in arid and semi-arid environments and the alluvial and lacustrine aquifers in river deltas in humid environments, which are in neutral to weakly alkaline and strongly reducing environments.The content of As in groundwater varies widely, and As(Ⅲ) is the main form. The main mechanism of the formation of high-As groundwater in China is the reduced dissolution of Fe and Mn oxides under the action of organic matter and primary microorganisms, alkaline environment, intense evaporation and concentration, long-term water-rock interaction, and slow groundwater velocity, which promote the continuous migration and enrichment of As in groundwater. There are obvious differences in the toxicity of different forms of As. The toxic of As(Ⅲ) is far more than As(V), which is considered to be more toxic than methyl arsenate(MMA) and dimethyl arsenate(DMA). Inorganic As entering the body is metabolized through a combination of methylation(detoxification) and reduction(activation) and catalyzed by a series of methyltransferases and reductases. At present, remediation methods for high-As groundwater mainly include ion exchange technology, membrane filtration technology, biological treatment technology, nanocomposite adsorption technology, electrochemical technology, and so on. All the above remediation methods still have certain limitations, and it is urgent to develop treatment materials and technical means with stronger As removal performance and sustainability. With the joint efforts of scientists and governments of various countries in the future, this worldwide problem of drinking-water As poisoning will be solved as soon as possible. This paper systematically summarizes and discusses the hot research results of natural high-As groundwater, which could provide a reference for the related research of high-As groundwater in China and even the world.

Investigation of soil and groundwater environment in urban area during post-industrial era: A case study of brownfield in Zhenjiang, Jiangsu Province, China

With the adjustment of industrial structure,many high pollution enterprises will gradually shut down.This process will produce a large number of high-risk pollution plots and cause a series of environmental problems.In this study,geophysical detection and direct push technology were applied to investigate soil and groundwater pollution in a typical brownfield in Zhenjiang,Jiangsu province,China.The results showed that Chlorotoluene and its ramification were the main pollutants for the brownfield.Pollution decreased with depth and was quite uneven in the brownfield.Production and wastewater treatment areas were heavily polluted,where volatile organic compounds contaminated and semi-volatile organic compounds were found 12 m and 15 m below the land surface,respectively.About 18880 m3 groundwater was contaminated.This study is significant to develop a geological survey work mode for the postindustrial era.

Evaluation of groundwater potential and eco-geological environment quality in Sanjiang Plain of Heilongjiang Province

Sanjiang Plain of Heilongjiang Province has become an important commodity grain base in our country after the construction of more than a century. Groundwater is the main water source for industrial and agricultural production and daily life in the area. With the large-scale development and construction in this area, there are a series of ecological and environmental geological problems, such as the reduction of groundwater resources, which seriously restricts the sustainable development of local agriculture and society as well as economy. Based on the characteristics of three-dimensional flowof groundwater in Sanjiang Plain, this paper adopts the simulation software Visual MODFLOW to evaluate groundwater exploitation potential. The results show that overall there is a certain exploitation potential of Sanjiang Plain groundwater but it is unevenly distributed, and overdraft phenomenon exists in seven farms such as Baoquanling and Chuangye. Based on analytic hierarchy process, the evaluation result of eco-geological environment quality in Sanjiang Plain shows that 94.5% of the region features good geological environment quality, medium stability and medium bearing capacity. The study can provide geological evidence for optimal allocation of water resources, land planning and regulation, and the high and stable yield of the commodity grain base in Sanjiang Plain.

Hydrochemistry and H-O-C-S Isotopic Geochemistry Characteristics of Geothermal Water in Nyemo-Nagqu,Tibet

Nyemo-Nagqu, Tibet, is rich in high-temperature geothermal resources. The geothermal fields in Yangbajain and Yangyi as well as 11 unexplored geothermal fields along the geothermal belt from Nyemo to Nagqu were systematically investigated and the hydrochemistry data were collected from the whole field. Meanwhile, H-O-C-S isotope data were obtained for the new fields, and H-O isotope data for the Yangbajain and Yangyi fields. A comparison of the Nyemo-Nagqu geothermal fields with those in the Yangbajain area shows that the types of high-temperature geothermal water are dominated by Cl-Na and Cl·HCO3-Na, while the types of medium-high-temperature geothermal water are dominated by HCO3-Na. The concentrations of Li, F, SiO2, and HBO2 in the geothermal water are positively correlated with Cl content, indicating possible mixing with magma water. The reservoir temperatures range from 90 to 270°C by geothermometers. Slight drifting of 18O was recorded at the Dongweng and Nyingzhong high-temperature geothermal fields, while more significant drifting was recorded at Gulu. The geothermal water is mainly replenished by atmospheric precipitation. The low tritium contents（〈1 TU） of the geothermal water from Nyingzhong, Gulu, and Luoma indicate that it is mainly replenished by sub-modern（prior to 1952） water, while the high tritium content（8.4 TU） in Yuela implies modern water replenishment. Other geothermal fields are replenished by a mix of sub-modern fresher water. The isotopic data in this study show that the carbon and sulfur in the geothermal water originates mainly from sediment leaching, with some of the carbon and sulfur having a deep origin.

Differences in major ions as well as hydrogen and oxygen isotopes of sediment pore water and lake water

Isotopic and chemical compositions of pore water(PW) are highly relevant to environmental and forensic study. Five lake water(LW)samples and five sediment samples were collected to investigate the effects of pore sizes of sediments on PW chemistry and stable isotopes and determine mechanisms controlling their variations. Six pore water fractions were extracted from different-sized pores in each sediment sample at six sequential centrifugal speeds for chemical and isotopic analysis. The sediments consisted mainly of quartz, feldspar, and clay minerals. The hydrogen and oxygen isotopic compositions of PW are mainly controlled by the overlying LW, although the lag effect of exchange between overlying LW and PW results in isotopic differences when recharge of LW is quicker than isotopic exchange in PW. Identical isotopic compositions of PW from sediments with different pore sizes indicate that isotopic exchange of water molecules with different pore sizes is a quick process. The ratio of average total dissolved solid(TDS) concentration of PW to TDS concentration of LW shows a strong relationship with adsorption capacity of sediments, demonstrating that remobilization of ions bound to sediments mainly causes a chemical shift from LW to PW.Concentrations of Ca^(2+), Mg^(2+),and Cl^-in PW remain unchanged,while concentrations of Na^+,K^+,and SO_4^(2-) slightly increase with decreasing pore size. Chemical differences of PW from sediments with different pore sizes are governed by ion adsorption properties and surface characteristics of different-si zed particles.

Hydrogeochemical characterization and quality assessment of groundwater using self-organizing maps in the Hangjinqi gasfield area,Ordos Basin,NW China

Water resources are scarce in arid or semiarid areas,which not only limits economic development,but also threatens the survival of mankind.The local communities around the Hangjinqi gasfield depend on groundwater sources for water supply.A clear understanding of the groundwater hydrogeochemical characteristics and the groundwater quality and its seasonal cycle is invaluable and indispensable for groundwater protection and management.In this study,self-organizing maps were used in combination with the quantization and topographic errors and K-means clustering method to investigate groundwater chemistry datasets.The Piper and Gibbs diagrams and saturation index were systematically applied to investigate the hydrogeochemical characteristics of groundwater from both rainy and dry seasons.Further,the entropy-weighted theory was used to characterize groundwater quality and assess its seasonal variability and suitability for drinking purposes.Our hydrochemical groundwater dataset,consisting of 10 parameters measured during both dry and rainy seasons,was classified into 6 clusters,and the Piper diagram revealed three hydrochemical facies:Cl-Na type(clusters 1,2 and 3),mixed type(clusters 4 and 5),and HCO3-Ca type(cluster 6).The Gibbs diagram and saturation index suggested thatweathering of rock-forming mineralswere the primary process controlling groundwater chemical composition and validated the credibility and practicality of the clustering results.Two-thirds of 45 groundwater samples were categorized as excellent-or good-quality and were suitable as drinking water.Cluster changes within the same and different clusters from the dry season to the rainy season were detected in approximately 78%of the collected samples.The main factors affecting the groundwater quality were hydrogeochemical characteristics,and dry season groundwater quality was better than rainy season groundwater quality.Based on this work,such results can be used to investigate the seasonal variation of hydrogeochemical characteristics and assess water quality accurately in the others similar area.

Characteristics of groundwater in Northeast Qinghai-Tibet Plateau and its response to climate change and human activities:A case study of Delingha,Qaidam Basin

Delingha is located in the northeast margin of Qaidam Basin.Bayin River alluvial proluvial fan is the main aquifer of Delingha,in which groundwater generally flows from north to south.The hydrochemistry results showed that two different hydrochemical evolution paths formed along southeast and southwest directions,respectively.Cl-Na type groundwater was formed in front of Gahai Lake,and SO_(4)·HCO_(3)-Na·Ca type groundwater was formed in front of Keluke Lake.The results of deuterium(D)and 18O revealed that the groundwater mainly originated from the continuous accumulation of precipitation during geological history under cold and humid climate conditions.In addition,results of ^(14)C indicated that the groundwater age was more than 1140 years,implying relatively poor renewal capability of regional groundwater.Moreover,our numerical modeling results showed that the regional groundwater level will continue to rise under the warm and humid climate conditions.

Hydrochemical and isotope characteristics of spring water discharging from Qiushe Loess Section in Lingtai, northwestern China and their implication to groundwater recharge

The loess plateau in northwestern China with an area of 640 000km^2, which has developed the loess deposits with a thickness up to 200m in typical areas, is regarded as a huge carbon stock like the karst area in southwestern China, and plays an important role in regional(even global) carbon cycle. But the spring discharging from loess is poorly known compared with karst spring so far. The objective of this study is to ascertain the characteristics and origin of spring at Qiushe Village, Lingtai County, Gansu Province by hydro-chemical and isotopic methods. The results show that the springs including LGQ, HMQ, YYQ and CZQ are the depression spring and belong to the same shallow aquifer with the well water JZJ. There are not distinct seasonal/diurnal-scale variations on the hydro-chemical characteristics of the spring water(LGQ, HMQ, YYQ, CZQ) and groundwater(JZJ). The hydro-chemical type of groundwater is Ca·Mg-HCO_3. The D and O isotope ratios indicate that the precipitation is the main recharge source of groundwater in study area. And the results of tritium(TU) and Cl concentration suggest that the recharge cycle of groundwater may be more than 60 yrs. Our study shows that the water cycle in loess plateau including rainfall, infiltration, recharge and discharge exerts a continuous impact on carbon stock in loess, which should be paid more attention to in future research on the quantitative reconstruction of paleoclimate.

Study on hydrochemical characteristics and formation mechanism of shallow groundwater in eastern Songnen Plain

Under the influence of global climate changes and human activities, the Songnen Plain's groundwater environment is deteriorating, which becomes an important factor restricting the social economic development and ecological balance. As a relatively independent water system in the Songnen Plain, the groundwater system of the Songhua River provides the main water sources for industry, agriculture, life and other aspects. According to the hydrogeological investigation, groundwater sample collection and testing in the eastern Songnen Plain, descriptive statistics analysis, piper diagram, Gibbs diagram and reverse hydrogeochemical simulation were used to analyze the hydrochemical characteristics and evolution laws of regional groundwater. The results of this study show that HCO_3^- and Ca^(2+) are the main anion and cation in the groundwater; the formation of groundwater chemical components are controlled by topographic and geomorphic factors and groundwater occurrence conditions; groundwater subarea of the Lalin-Ashi River is mainly controlled by weathering-dissolution process, and evaporation and ion-exchange reactions are more obvious in groundwater subarea of the Hulan-Tongken River, whose chemical composition also affects the valley plain groundwater subarea in the discharge area; in addition, local high intensity withdrawal causes abnormal hydrochemical evolution processes. The research results can offer scientific basis for rational utilization and protection of groundwater.

Soil water movement and deep drainage through thick vadose zones on the northern slope of the Tianshan Mountain: Croplands vs.natural lands

Regional aridity is increasing under global climate change,and therefore the sustainable use of water resources has drawn attention from scientists and the public.Land-use changes can have a significant impact on groundwater recharge in arid regions,and quantitative assessment of the impact is key to sustainable groundwater resources management.In this study,the changes of groundwater recharge after the conversion of natural lands to croplands were investigated and compared in inland and arid region,i.e.,the northern slope of the Tianshan Mountain.Stable isotopes suggest that soil water in topsoil(<2 m)has experienced stronger evaporation under natural lands than croplands,and then moves downward as a piston flow.Recharge was estimated by the tracer-based mass balance method,i.e.,chloride and sulfate.Recharge rates under natural conditions estimated by the chloride mass balance(CMB)method were estimated to be 0.07 mm/a in deserts and 0.4 mm/a in oases.In contrast,the estimated groundwater recharge ranged from 61.2 mm/a to 44.8 mm/a in croplands,indicating that groundwater recharge would increase significantly after land changes from natural lands to irrigated croplands in arid regions.Recharge estimated by the sulfate mass balance method is consistent with that from the CMB method,indicating that sulfate is also a good tracer capable of estimating groundwater recharge.

Provenance analysis of surface sediments in the Holocene mud area of the southern coastal waters off Shandong Peninsula,China

The sedimentary record of mud areas is an important carrier of information on the Holocene evolution of marine environments. Based on fine interpretations of the shallow stratigraphic section data, a small mud deposit area has been found in the southern coastal waters off Shandong Peninsula. This mud area is mainly distributed in coastal waters north of Laoshantou to the vicinity of Rushan Estuary. Overall, it is parallel to the coastline and spreads in a banded pattern, gradually thinning from offshore to the sea. The isopach map of depth distribution is parallel with the shoreline, and the depocenter lies in coastal waters of the Aoshan Bay where the maximum thickness is up to 22.5 m. Accelerator mass spectrometry（AMS） ^（14）C dating shows that the mud area was formed in the Holocene. The test data of surface sediments from the mud area, including particle size, mineral characteristics, and rare earth element contents, are used in comparisons with the composition of materials from the major surrounding medium and small rivers flowing into the sea and the Huanghe（Yellow） River. In this paper, the sedimentary characteristics and provenance of the mud deposit area are discussed. The results show that the formation of this mud area resulted from the joint action of the Huanghe River and surrounding rivers flowing into the sea.

Quantification of groundwater recharge and evapotranspiration along a semi-arid wetland transect using diurnal water table fluctuations

Groundwater is a vital water resource in arid and semi-arid areas.Diurnal groundwater table fluctuations are widely used to quantify rainfall recharge and groundwater evapotranspiration(ET_(g)).To assess groundwater resources for sustainable use,we estimated groundwater recharge and ET_(g) using the diurnal water table fluctuations at three sites along a section with different depths to water table(DWT)within a wetland of the Mukai Lake in the Ordos Plateau,Northwest China.The water table level was monitored at an hourly resolution using a Keller DCX-22 A data logger that measured both the total pressure and barometric pressure,so that the effect of barometric pressure could be removed.At this study site,a rapid water table response to rainfall was observed in two shallow wells(i.e.,Obs1 and Obs2),at which diurnal water table fluctuations were also observed over the study period during rainless days,indicating that the main factors influencing water table variation are rainfall and ET_(g).However,at the deep-water table site(Obs3),the groundwater level only reacted to the heaviest rainfalls and showed no diurnal variations.Groundwater recharge and ET_(g) were quantified for the entire hydrological year(June 2017–June 2018)using the water table fluctuation method and the Loheide method,respectively,with depth-dependent specific yields.The results show that the total annual groundwater recharge was approximately 207 mm,accounting for 52%of rainfall at Obs1,while groundwater recharge was approximately 250 and 21 mm at Obs2 and Obs3,accounting for 63%and 5%of rainfall,respectively.In addition,the rates of groundwater recharge were mainly determined by rainfall intensity and DWT.The daily mean ET_(g) at Obs1 and Obs2 over the study period was 4.3 and 2.5 mm,respectively,and the main determining factors were DWT and net radiation.

Simulation of groundwater level recovery in abandoned mines, Fengfeng coalfield, China

Abandoned mines are of high potential risk as they could be a large underground storage of pollutants(heavy metals and organic wastes, etc.). Various physical, chemical and biological reactions would take place when groundwater flows into underground spaces, which makes abandoned mine a huge potential hazard to groundwater environment. The recovery of groundwater level is one of the key elements controlling the reactions and causing such hazards. This paper simulated groundwater level recovery processes in the abandoned mines, Fengfeng coalfield by using the computer program FEFLOW. The paper integrated the pipe flow model, "three zones" model and groundwater inrush(discharge) model in the simulation of groundwater in the complex laneway-aquifer system. Groundwater flow in the laneway systems was considered pipe flow and described in Bernoulli equation. The water-bearing medium(coal seam roof) overlying the laneway systems was divided into "three zones" composed of the caving zone, fissure zone and bending zone based on the disruption degrees of previous mining. Groundwater in the Ordovician limestone aquifer(bottom of coal seam) flowing into laneway systems was considered a major inrush/recharge source, and its flow rate was calculated by an inrush(discharge) model which was newly developed in this study and incorporated into FEFLOW. The results showed that it would take approximately 95 days for groundwater in abandoned mines to recover to regional groundwater level elevation, and the total amount of water filling up would be about 1.41195×10~7 m^3, which is consistent with the actual data. The study could be of theoretical and practical significance to mitigate abandoned mines' hazards and improve mine groundwater utilization.

Water scaling predication for typical sandstone geothermal reservoirs in the Xi'an Depression

The Xi'an Depression in the Guanzhong Basin of western China has been suggested to contain geothermal resources that could aid China in achieving carbon neutrality and optimizing energy structure.However,the high concentration of total dissolved solids(TDS)and scale-forming ions in geothermal water from the depression causes severe scaling problems in harvesting geothermal energy.To reduce scale-related problems,accurate identification of scale types and prediction of scaling during geothermal energy utilization are crucial.This study starts with identifying the types and trends of scaling in the study area,using index-based discriminant methods and hydrogeochemical simulation to calculate and analyze the mineral saturation index of water samples from some wellheads and of reconstructed fluid samples of geothermal reservoirs.The results indicate that the scales are mostly calcium carbonate scales rather than sulfate scales as a result of temperature changes.Several portions of the geothermal water systems are found to have distinct mineral scaling components.Quartz and chalcedony are formed in low temperature areas,while carbonate minerals are in high temperature areas.Despite the low iron content of geothermal water samples from the study area,scaling is very common due to scaling-prone iron minerals.The findings can be used to evaluate geothermal drainage systems and guide anti-scaling during geothermal energy utilization in similar settings.

Evaluation on water resources carrying capacity of Changchun-Jilin Region

Based on such principles as sustainable development and ecological cycle, this paper evaluates the water resources carrying capacity(WCC) of Changchun-Jilin region using a population-economy-water resources correlation evaluation model built on the basis of WCC evaluation method as elaborated in the methodology of Functional Zoning of Population Development. Results show that the annual WCC of Changchun-Jilin region is able to support the population there, as a basic balance is struck between population and water resources. The incorporation of WCC into overall urban planning is one of the building blocks for sustainable city development with an advisable size.