Discovery of the Plagiogranites in the Diyanmiao Ophiolite,Southeastern Central Asian Orogenic Belt,Inner Mongolia,China and Its Tectonic Significance

In this study, plagiogranites in the Diyanmiao ophiolite of the southeastern Central Asian Orogenic Belt(Altaids) were investigated for the first time. The plagiogranites are composed predominantly of albite and quartz, and occur as irregular intrusive veins in pillow basalts. The plagiogranites have high SiO_2(74.37–76.68 wt%) and low Al_2O_3(11.99–13.30 wt%), and intensively high Na_2O(4.52–5.49 wt%) and low K_2O(0.03–0.40 wt%) resulting in high Na_2O/K_2O ratios(11.3–183). These rocks are classified as part of the low-K tholeiitic series. The plagiogranites have low total rare earth element contents(∑REE)(23.62–39.77 ppm), small negative Eu anomalies(δEu=0.44–0.62), and flat to slightly LREE-depleted chondrite-normalized REE patterns((La/Yb)N=0.68–0.76), similar to N-MORB. The plagiogranites are also characterized by Th, U, Zr, and Hf enrichment, and Nb, P, and Ti depletion, have overall flat primitivemantle-normalized trace element patterns. Field and petrological observations and geochemical data suggest that the plagiogranites in the Diyanmiao ophiolite are similar to fractionation-type plagiogranites. Furthermore, the REE patterns of the plagiogranites are similar to those of the gabbros and pillow basalts in the ophiolite. In plots of SREE–SiO_2, La–SiO_2, and Yb–SiO_2, the plagiogranites, pillow basalts, and gabbros show trends typical of crystal fractionation. As such, the plagiogranites are oceanic in origin, formed by crystal fractionation from basaltic magmas derived from depleted mantle, and are part of the Diyanmiao ophiolite. LA–ICP–MS U–Pb dating of zircons from the plagiogranites yielded ages of 328.6±2.1 and 327.1±2.1 Ma, indicating an early Carboniferous age for the Diyanmiao ophiolite. These results provide petrological and geochronological evidence for the identification of the Erenhot–Hegenshan oceanic basin and Hegenshan suture of the Paleo-Asian Ocean.

Effects of hydrocarbon generation on fluid flow in the Ordos Basin and its relationship to uranium mineralization

诺思中国的 Ordos 盆是不仅一个重要的铀矿化作用省，而且在中国的油，气体和煤的一个主要制片人。在铀矿化作用和烃之间的基因关系被认出了由很多以前的研究，而是它很好没以盆液体的水动力学被理解流动。我们在以前的研究证明了在 Ordos 侏罗记节的上面的部分的白垩纪铀矿化作用的优先的本地化可能与在向上的流动之间的接口有关，减少液体并且向下流动，氧化液体。这个接口可能被在与不平衡沉积压缩有关的液体过压之间的相互影响控制了并且它驾驶了向上的流动，和地志的地势，它开车了向下流动。在这研究，我们执行了为对液体过压的发展的油和煤气的产生的贡献的数字建模，除了沉积压缩并且加热。当烃产生没被考虑时，我们的结果显示当烃产生被考虑时，液体过压非常与模拟比较在白垩纪期间被加倍。而且，在沉积的结束的液体过压驱散相对没有烃产生盒子慢下来。这些结果建议烃产生可能在铀矿化作用，不是仅仅在规定减少为矿化作用要求的代理人，而且在贡献驱动力维持向上的流动起了一个重要作用。

Late Mesozoic Ore-forming Events in the Ningwu Ore District, Middle-Lower Yangtze River Polymetallic Ore Belt, East China: Evidence from Zircon U-Pb Geochronology and Hf Isotopic Compositions of the Granodioritic Stocks

Late Mesozoic volcanic-subvolcanic rocks and related iron deposits, known as porphyry iron deposits in China, are widespread in the Ningwu ore district (Cretaceous basin) of the middle-lower Yangtze River polymetallic ore belt, East China. Two types of Late Mesozoic magmatic rocks are exposed: one is dioritic rocks closely related to iron mineralization as the hosted rock, and the other one is granodioritic (-granitic) rocks that cut the ore bodies. To understand the age of the iron mineralization and the ore-forming event, detailed zircon U-Pb dating and Hf isotope measurement were performed on granodioritic stocks in the Washan, Gaocun-Nanshan, Dongshan and Heshangqiao iron deposits in the basin. Four emplacement and crystallization (typically for zircons) ages of granodioritic rocks were measured as 126.1±0.5 Ma, 126.8±0.5 Ma, 127.3±0.5 Ma and 126.3±0.4 Ma, respectively in these four deposits, with the LA-MC-ICP-MS zircon U-Pb method. Based on the above results combined with previous dating, it is inferred that the iron deposits in the Ningwu Cretaceous basin occurred in a very short period of 131-127 Ma. In situ zircon Hf compositions of εHf(t) of the granodiorite are mainly from -3 to -8 and their corresponding 176Hf/177Hf ratio are from 0.28245 to 0.28265, indicating similar characteristics of dioritic rocks in the basin. We infer that granodioritic rocks occurring in the Ningwu ore district have an original relationship with dioritic rocks. These new results provide significant evidence for further study of this ore district so as to understand the ore-forming event in the study area.

3D Positional and Quantitative Prediction of the Xiaoqinling Gold Ore Belt in Tongguan, Shaanxi, China

Quantitative prediction of deep orebody based on 3D visualization technology is of great significance in mineral exploration. Based on the 2D traditional quantitative predicting method, the geoanomaly theory and the mineral exploration model idea, we constructed 3D models of the topography, strata, structure, magmatite and prospecting engineering of the study area using the commercial 3D modeling software Micromine, delineated eight prospective areas and estimated the gold resources amount with methods of Abundance Estimation and Volume Estimation. Then, we compared and counted the known ore blocks and the predicted blocks, which quantitatively explains this prediction's validity. The results show that Xiaoqinling gold belt in Tongguan has convincing potential for gold development and utilization and the prediction method based on 3D visualization technology proves to be effective.

Identification of the anomaly component using BEMD combined with PCA from element concentrations in the Tengchong tin belt, SW China

Concentration of elements or element groups in a geological body is the result of multiple stages of rockforming and ore-forming geological processes.An ore-forming element group can be identified by PCA(principal component analysis)and be separated into two components using BEMD(bi-dimensional empirical mode decomposition):(1)a high background component which represents the ore-forming background developed in rocks through various geological processes favorable for mineralization(i.e.magmatism,sedimentation and/or metamorphism);(2)the anomaly component which reflects the oreforming anomaly that is overprinted on the high background component developed during mineralization.Anomaly components are used to identify ore-finding targets more effectively than ore-forming element groups.Three steps of data analytical procedures are described in this paper;firstly,the application of PCA to establish the ore-forming element group;secondly,using BEMD on the o re-forming element group to identify the anomaly components created by different types of mineralization processes;and finally,identifying ore-finding targets based on the anomaly components.This method is applied to the Tengchong tin-polymetallic belt to delineate ore-finding targets,where four targets for Sn(W)and three targets for Pb-Zn-Ag-Fe polymetallic mineralization are identified and defined as new areas for further prospecting.It is shown that BEMD combined with PCA can be applied not only in extracting the anomaly component for delineating the ore-finding target,but also in extracting the residual component for identifying its high background zone favorable for mineralization from its oreforming element group.

Prograde and retrograde growth of monazite in migmatites:An example from the Nagercoil Block,southern India

Data from a migmatised metapelite raft enclosed within charnockite provide quantitative constraints on the pressure-temperature-time[P-T-t) evolution of the Nagercoil Block at the southernmost tip of peninsular India.An inferred peak metamorphic assemblage of garnet,K-feldspar.sillimanite,plagioclase,magnetite,ilmenite,spinel and melt is consistent with peak metamorphic pressures of 6-8 kbar and temperatures in excess of 900℃.Subsequent growth of cordierite and biotite record high-temperature retrograde decompression to around 5 kbar and 800 C.SHRIMP U-Pb dating of magmatic zircon cores suggests that the sedimentary protoliths were in part derived from felsic igneous rocks with Palaeoproterozoic crystallisation ages.New growth of metamorphic zircon on the rims of detrital grains constrains the onset of melt crystallisation,and the minimum age of the metamorphic peak,to around560 Ma.The data suggest two stages of monazite growth.The first generation of REE-enriched monazite grew during partial melting along the prograde path at around 570 Ma via the incongruent breakdown of apatite.Relatively REE-depleted rims,which have a pronounced negative europium anomaly,grew during melt crystallisation along the retrograde path at around 535 Ma.Our data show the rocks remained at suprasolidus temperatures for at least 35 million years and probably much longer,supporting a long-lived high-grade metamorphic history.The metamorphic conditions,timing and duration of the implied clockwise P-T-t path are similar to that previously established for other regions in peninsular India during the Ediacaran to Cambrian assembly of that part of the Gondwanan supercontinent.

LA-ICP-MS Zircon U-Pb Dating of Intermediate-Acidic Intrusive Rocks and Molybdenite Re-Os Dating from the Bangpu Mo (Cu) Deposit, Tibet and its Geological Implication

The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1 Ma (mean square of weighted deviates (MSWD) =9.5, n=8) and 60.60±0.31 Ma (MSWD=3.8, n=16), which belong to the late Cretaceous-early Paleocene in age. That means, they are products of an early tectonicmagmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19 Ma (MSWD=2.0, n=26) and 15.16±0.09 Ma (MSWD=3.9, n=5) separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2 Ma (MSWD=1.18, n=7) were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic-early Jurassic. Molybdenum (copper) ore-bodies produced in the monzogranite porphyry and copper (molybdenum) ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97-15.84 Ma, while isochron ages are 14.09±0.49 Ma (MSWD=26). The isochron ages of seven molybdenite from molybdenum (copper) ore with monzogranite porphyry type are 14.11±0.31 Ma (MSWD=5.2). There is great error in the isochron ages of four molybdenite from copper (molybdenum) ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2 Ma (MSWD=41), which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09 Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others.

Origin of Listwanite in the Luobusa Ophiolite,Tibet,Implications for Chromite Stability in Hydrothermal Systems

Listwanite from the Luobusa ophiolite,Tibet,forms a narrow,discontinuous band along the eastern part of the southern boundary fault. We undertook a detailed petrographic and geochemical study to understand the mineral transformation processes and the behaviour of major and trace elements during listwanite formation. Three alteration zones characterized by distinct mineral components and texture are recognized and,in order of increasing degree of alteration,these are: zoneIII is rich in serpentine minerals; zoneII is rich in talc and carbonates; and zoneI is mainly composed of carbonates and quartz. Geochemical data for the three alteration zones show significant modification of some major and trace elements in the protolith,although some oxides show linear correlations with Mg O. Gold mineralization is recognized in the Luobusa listwanite and may signify an important target for future mineral exploration. Gold enrichment occurs in both zoneI and zoneIIand is up to 0.91 g/t in one sample from zoneI. We show that CO2-rich hydrothermal fluids can modify both the occurrence and composition of chromite grains,indicating some degree of chromite mobility. Low-Cr anhedral grains are more easily altered than high-Cr varieties. The compositions of chromite and olivine grains in the listwanite suggest a dunite protolith.

Stratigraphy and Geochronology of Vertebrate Fossil-Bearing Jurassic Strata from Linglongta,Jianchang County,Western Liaoning,Northeastern China

Northeastern China contains widely distributed Jurassic terrestrial strata that have yielded many spectacular mammal and pterosaur fossils, in addition to feathered dinosaur fossils and more recent discoveries from Jianchang, particularly from western Liaoning. However, the fossil-bearing stratigraphic succession, regional correlation, and age estimates of the fossils found in Jianchang County and nearby areas have been contentious. Here, we report on the vertebrate fossil-bearing Jurassic stratigraphy from Linglongta, Jianchang County, western Liaoning, including a SHRIMP U-Pb zircon date unambiguously associated with the fossil horizons. The primary goal was to determine the vertebrate fossil-bearing succession. A further aim was to provide age estimations for the fossil-bearing horizon as well as the earliest appearance of feathered dinosaurs, the eutherian-placental clade, and transitional pterosaurs. Field investigations showed that the vertebrate fossil-bearing stratigraphic succession in Jianchang County mainly consists of basal andesites overlain by rhythmic tuffs and tuffaceous lacustrine sediments, with the upper intermediate or acidic lavas interbedded with laminated more or less tuffaceous lacustrine deposits. This sequence correlates well with the Middle Jurassic Lanqi/Tiaojishan Formation in northeastern China. Detailed and accurate field observations showed that the well-preserved vertebrate fossils were buried in either the middle or the upper fine-grained laminated lacustrine deposits. Previous and current SHRIMP U-Pb zircon dates provide an age estimation of 161-159 Myr for the fossil-bearing horizon and vertebrates. This indicates that the earliest appearance of feathered dinosaurs here was more than 159 Myr ago and unquestionably older than Archaeopteryx from Germany, making these the earliest known feathered dinosaurs in the world. Furthermore, the eutherian-placental clade and the known transitional pterosaurs first emerged no later than 161 Myr. The vertebrate assemblage unearthed recently from Linglongta and neighboring areas in Jianchang County belongs to the Daohugou Biota. In addition to feathered dinosaurs, this biota was characterized by mammals, primitive pterosaurs, insects, and plants and was present in Inner Mongolia, western Liaoning, and northern Hebei in northeastern China during the Middle-Late Jurassic.

Diversity of Mineralization and Spectrum of the Gejiu Superlarge Tin-Copper Polymetallic Deposit,Yunnan,China

The Gejiu (个旧) deposit is a superlarge tin-copper polymetallic ore-forming concentration area characterized by excellent metallogenic geological settings and advantageous ore-controlling factors. The deposit displays diverse mineralization properties due to different minerals and mineral deposit types. Based on the principal metallogenic factors, metallogenic mechanisms, mineralized components, and occurrence of mineral deposits or ore bodies, the Gejiu mineral district can be divided into 2 combinations of metallogenic series, 4 metallogenic series, 8 subseries, and 27 mineral deposit types. Spatial zonality is evident. The distribution regularity of the elements in both plane and section is Be-W, Sn (Cu, Mo, Bi, Be)-Sn, Pb, Ag-Pb, Zn around a granitic intrusion. The metallogenic epoch is mainly concentrated in the late Yanshanian. During this period, large-scale metallogenic processes related to movement caused by tectonics and magmatism occurred, and a series of magmatic hydrothermal deposits formed. The ore-forming processes can be divided into 4 stages: the silicate stage, the oxide stage, the sulphide stage, and the carbonate stage. Based on the orderliness and diversity (in terms of time, space, and genesis) of the mineralization, the authors have developed a comprehensive spectrum of ore deposits in the Gejiu area. This newly proposed diversity of mineralization and the spectrum developed in this work are useful not only for interpreting the genesis of the Gejiu deposit but also for improving mineral exploration in the area, and in particular, for finding large deposits.

Sedimentary characteristics and depositional model of a Paleocene-Eocene salt lake in the Jiangling Depression,China

We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation,thin section identification,scanning electron microscopy,and X-ray diffraction analysis.On the basis of sedimentary characteristics we have summarized the petrological and mineralogical characteristics of the salt lake and proposed 9 types of grade IV salt rhythms.The deposition shows a desalting to salting order of halite-argillaceous-mudstone-mud dolostonemud anhydrock-glauberite-halite.The relationship among grade IV rhythms,water salinity and climate fluctuations was analyzed.Based on the analysis of the relationship between boron content and mudstone color and by combining the mineralogy and sedimentary environment characteristics,we propose that the early and late Paleocene Shashi Formation in the Jiangling Depression was a paleolacustrine depositional environment with a high salt content,which is a representation of the shallow water salt lake depositional model.The middle Paleocene Shashi Formation and the early Eocene Xingouzui Formation were salt and brackish sedimentary environments with low salt content in a deep paleolake,which represents a deep salt lake depositional model.

Formation of the Yalong Downstream Terraces in the SE Tibetan Plateau and Its Implication for the Uplift of the Plateau

The Yalong River is an important river that runs across the abruptly changing terrain of the SE Tibetan Plateau. The terraces and Quaternary sediments in its valleys preserve the information of tectonic uplift,climate changes,and landform evolution since the Middle Pleistocene. Based on geomorphological,sedimentological,and chronological investigations,6–8 terraces are identified in the lower reaches of Yalong catchment and its tributary—the Anning River. The electron spin resonance(ESR) or optically stimulated luminescence(OSL) data on the alluvial sediments in the upper portion of terraces indicate that they formed in 1.10,0.90,0.72,0.06–0.04,0.03–0.02,and 0.01 Ma. Tectonic uplift and the climatic cycle controlled the formation of the Yalong River terraces. The former dominated the dissection depths and incision rates,whereas the latter controlled the transformation between accumulation,which developed during the glacial period,and incision,which developed during the glacial-interglacial transition. The Yalong downstream incised rapidly from 1.10 to 0.72 Ma and rapidly from 0.06 Ma until the present; the terraces developed during these two periods. The incision rates in space during the two periods indicate the uplifting extent of the Jinpingshan area,which decreases toward the east and the south. The results reveal two rapidly uplifting stages in the SE Tibetan Plateau,including an accelerated uplifting since 0.06 Ma. Since the Middle Pleistocene,the tectonic uplift of the SE and NE parts of the Tibetan Plateau is synchronous,according to the same development stages of the river terraces of the Yalong downstream and the Yellow River in the Lanzhou area of the NE Tibetan Plateau. The difference in the horizontal displacement between the Xianshuihe Fault and the Anninghe Fault bend resulted in the rapid uplift of the Jinpingshan area. The incision rate for the spatial distribution of the Yalong downstream is the geomorphological response of crustal shortening and uplift differences in the SE margin block of the Tibetan Plateau. The southeastward diffusion process of the Tibetan Plateau was recorded.

A study of soil organic carbon distribution and storage in the Northeast Plain of China

采用联合起来的土壤碳数量(USCA ) 途径，土壤碳存储基于在 20042006 进行的多种用途的地区性的 Geochemical 调查(MRGS ) 越过中国的东北平原被计算。结果显示在表层土(00.2 m ) 的器官的碳(SOC ) 存储，心土(01 m ) 和深土壤(01.8 m ) 是的土壤有 3327.8 t/km2， 12,904.7 t/km2 和 16,157.5 t/km2 的密度的 768.1 山， 2978.4 山和 3729.2 山分别地。而土壤碳密度从东北平原(辽宁)的南部的区域显示出一个清楚的增加趋势，这些价值以表层土特别地与国家一般水准一致，到中间(吉林)和北平原( Heilongjiang )碳密度，从 2284.2 增加了，到 3436.7 和 3861.5 t/km2 ，分别地。与在 19841986 从第二国家土壤调查获得的碳数据(SNSS ) 相比，从 MRGS 的表层土 SOC 存储值被发现由 320.59 山(29.4%) 减少了，与在 20 年的 16.0 山(l.73%) 的平均年度衰落。在平原的南部、中间、北的区域，分别地，土壤碳密度为整个平原与 1389.0 t/km2 的平均价值由 1060.6 t/km2， 1646.4 t/km2 和 1300.2 t/km2 减少了。这些调查结果显示在土壤碳密度的减少根据不同生态系统和陆地使用类型变化了。因此，土壤碳密度的比率被计算以便学习碳，并且进一步探索分发特征在生态系统之间的动态平衡，以及 SOC 的隐遁潜力。

Zircon SHRIMP U-Pb Dating of the Tourmalinites from Boron-bearing Series of Borate Deposits in Eastern Liaoning and its Geological Implications

This paper focused on the zircon sensitive high resolution ion micro-probeU-Pb geochronology of the tourmalinites from boron-bearing series of borate deposits in Eastern Liaoning.The zircons commonly have core-rim structures,most cores show oscillatory zoning in cathodoluminescence and plane polarized light images,suggesting a magmatic detrital origin.Ages of the magmatic detrital zircons from the hyalotourmalite samples(N13) and(N14) are 2175±5Ma and 2171±9Ma,respectively.Moreover,metamorphic zircon from the sample(N13) shows an age of 1906±4Ma.Zircon core and rim from the hyalotourmalite sample(N02) record ages of 2171±6Ma and 1889±62Ma,which are explained as indicating the formation and metamorphic ages.Combined with the geological and geochemical studies,it can be concluded that the tourmalinites are formed during sedimentary exhalative mineralizations in the mid-Paleoproterozoic(～2170Ma) and underwent the metamorphism in the late-Paleoproterozoic(～1900Ma).The tourmalinites are the products of submarine acid volcanism in the extension rifting phase of the Liaoji Paleoproterozoic Rift,the rock-forming materials of which are derived from the mantle sources with recycling crustal contamination.The emergence of tourmalinites not only indicates the mid-Paleoproterozoic tectonic-magmatic processes,but also provides impetus,heat and material sources for the mineralization of borate deposits in Eastern Liaoning.

A Microscopic and Nanoscale Understanding of the Formation of Gold Geochemical Provinces

Gold geochemical provinces in China were delineated through stream sediment or catchment sediment sampling in this study. Each gold geochemical province delineated by a threshold value of 2.5 ng/g covers an area of thousands of kilometers. It is a dilemma that geochemists traditionally thought that gold could not migrate for a long distance in rivers or streams to form a large-scale geochemical anomaly due to its chemical inertness and high specific density. The quantitative spectroscopic analysis and observations under a scanning electron microscope(SEM) indicate the presence of submicroscopic gold particles(<5 μm in diameter) in large quantities, and observations under a Transmission Electron Microscopy(TEM) further suggest the presence of nanoscale gold particles(several tens of nanometre in diameter) in ores, rocks, soils and stream sediments. Particularly, submicroscopic and nanoscale gold particles less than 5 μm were only found in samples having a low gold content(<10ng/g). This result shows that geochemical provinces, delineated by a threshold value of 2.5 ng/g, are formed by long-distance transport of ultrafine gold in streams. The findings may provide direct microscopic evidence for gold migration to form geochemical provinces.

Genesis of the Bianjiadayuan Pb-Zn polymetallic deposit, Inner Mongolia, China:Constraints from in-situ sulfur isotope and trace element geochemistry of pyrite

The Southern Great Xing’an Range (SGXR) which forms part of the eastern segment of the Central Asian Orogenic Belt (CAOB) is known as one of the most important Cu-Mo-Pb-Zn-Ag-Au metallogenic belts in China,hosting a number of porphyry Mo (Cu),skarn Fe (Sn),epithermal Au-Ag,and hydrothermal veintype Ag-Pb-Zn ore deposits.Here we investigate the Bianjiadayuan hydrothermal vein-type Ag-Pb-Zn ore deposit in the southern part of the SGXR.Porphyry Sn ±Cu ± Mo mineralization is also developed to the west of the Ag-Pb-Zn veins in the ore field.We identify a five-stage mineralization process based on field and petrologic studies including (i) the early porphyry mineralization stage,(ii) main porphyry mineralization stage,(iii) transition mineralization stage,(iv) vein-type mineralization stage and (v) late mineralization stage.Pyrite is the predominant sulfide mineral in all stages except in the late mineralization stage,and we identify corresponding four types of pyrites: Py1 is medium-grained subhedral to euhedral occurring in the early barren quartz vein;Py2 is medium- to fine-grained euhedral pyrite mainly coexisting with molybdenite,chalcopyrite,minor sphalerite and galena;Py3 is fine-grained,subhedral to irregular pyrite and displays cataclastic textures with micro-fractures;Py4 occurs as euhedral microcrystals and forms irregularly shaped aggregate with sphalerite and galena.LA-ICP-MS trace element analyses of pyrite show that Cu,Pb,Zn,Ag,Sn,Cd and Sb are partitioned into pyrite as structurally bound metals or mineral micro/nano-inclusions,whereas Co,Ni,As and Se enter the lattice via isomorphism in all types of pyrite.The Cu,Zn,Ag,Cd concentrations gradually increase from Py1 to Py4,which we correlate with cooling and mixing of ore-forming fluid with meteoric water.Py2 contains the highest contents of Co,Ni,Se,Te and Bi,suggesting high temperature conditions for the porphyry mineralization stage.Ratios of Co/Ni (0.03-10.79,average 2.13) and sulphur isotope composition of sulfide indicate typical hydrothermal origin for pyrites.The δ^34SCDT values of Py1 (0.42‰-1.61‰,average 1.16‰),Py2 (-1.23‰ to 0.82‰,average 0.35‰),Py3 (-0.36‰ to 2.47‰,average 0.97‰),Py4 (2.51‰-3.72‰,average 3.06‰),and other sulfides are consistent with those of typical porphyry deposit (-5‰ to 5‰),indicating that the Pb-Zn polymetallic mineralization in the Bianjiadayuan deposit is genetically linked to the Yanshanian (JurassiceCretaceous) magmatic-hydrothermal events.Variations of d34S values are ascribed to the changes in physical and chemical conditions during the evolution and migration of the ore-forming fluid.We propose that the high Sn content of pyrite in the Bianjiadayuan hydrothermal vein-type PbeZn polymetallic deposit can be used as a possible pathfinder to prospect for Sn mineralization in the surrounding area or deeper level of the ore field in this region.

Climate change during the last glacial period on the southeast margin of Badain Jaran Desert, Northwest China

Reconstruction of the desert paleoclimate is important to understand the mechanisms that triggered and/or enhanced climate change.Through optically stimulated luminescence(OSL)dating,grain size,magnetic susceptibility,X-ray powder diffraction(XRD)and geochemical indicators,we provide a welldated record of a sedimentary outcrop on the southeast margin of the Bardain Jaran Desert,Northwest China,during the last glacial period.Four Qz-OSL ages are obtained,41.0±3.4 ka,54.7±4.4 ka,59.5±5.0 ka and 66.8±5.8 ka,corresponding to the depths of 35 cm,70 cm,150 cm and 200 cm respectively.Indicators like grain size,clay content,magnetic susceptibility,XRD and geochemical index(e.g.Sr,Ba,Sr/Ca)jointly indicate abrupt climate changes at the depth of 35 cm(age,ca.41.0 ka)and200 cm(age,ca.67 ka).Namely,the 280 cm sedimentary outcrop perfectly records a warm wet climate stage,corresponding to the late Marine Isotope Stages(MIS)4 to the early MIS 3.Besides,there is a trend of grain size increase after around 40ka BP,which is most likely a signal of wind strength change.Our research supports that enhancing Siberian High pressure system during the late MIS 3played a key role in NW East Asia climate evolution.

Incised valley filling deposits:an important pathway system for long-distance hydrocarbon migration—a case study of the Fulaerji Oilfield in the Songliao Basin

In this paper,incised valley filling deposits,which formed an important pathway system for long-distance hydrocarbon migration,are discussed in detail based on core and logging data.The sequence SQy23 of the Cretaceous Yaojia Formation is the main hydrocarbon-bearing layer in the Fulaerji Oilfield.The hydrocarbon source of the oilfield is the Qijia-Gulong Sag which is about 80 km away from the Fulaerji Oilfield.The transport layer of long-distance hydrocarbon migration is the overlapped sandstone complex which fills the incised valley.The incised valley developed during the depositional period from the late Qingshankou Formation to the early Yaojia Formation of Cretaceous(SQqn4-SQy1) was about 70 km long and 20 km wide,and extended in the NW-SE direction.The overlapped filling of the incised valley mainly occurred in the expanding system tract of the third-order sequence SQy23 (ESTy23 ). Towards the basin,incised valley filling deposits overlapped on the delta developed in the early period, and towards the basin margin,incised valley filling deposits were covered by the shore-shallow lacustrine sandy beach bar developed in the maximum flooding period.All of the delta,the incised valley filling and the shore-shallow sandy beach bar are sandstone-rich,and have high porosity and permeability,and can form an effective hydrocarbon migration and accumulation system.Deltaic sand bodies collected and pumped hydrocarbon from the active source,incised valley filling depositional system completed the long-distance hydrocarbon migration,and lithological traps of shore-shallow lacustrine sandy beach bar accumulated hydrocarbon.The incised valley filling sequences are multi-cycle:an integrated short- term filling cycle was developed on the erosion surface,and the sequences upward were mud-gravel stone,medium-fine sandstone containing terrigenous gravels and muddy pebbles with cross bedding,silty mudstone with ripple bedding,and mudstone.The incised valley filling deposits are characterized by a strong heterogeneity and the main hydrocarbon migration pathway is the medium-fine sandstone interval.

Geochronology and Geochemistry of Zengga Mesozoic Grantoids from East Gangdese Batholith, Implications for the Remelting Mechanism of Granite Formation

1 Geological Background This paper reports geochemistry(major and trace elements),zircon U-Pb and Lu-Hf isotope studies of leucogranite,granodiorite and clinopyroxene-bearing diorite from the Zengga intrusive body,eastern Gangdese batholith,Tibet.Massive granodiorite is mainly composed of fine-and medium-grained plagioclase(65 modal%),

Analysis of the Ore-Controlling Structure of Ductile Shear Zone Type Gold Deposit in Southern Beishan Area, Gansu, Northwest China

The ductile shear zone-type gold deposit is a kind that both the ore-forming mechanism and ore-controlling factors are closely related to the ductile shear zone and its evolution. Ductile shear zone develops in Beishan area, Gansu of Northwest China, and develops especially well in the south belt. The controls of the ductile shear zone on gold deposits are as follows. (1) The regional distribution of gold deposits (and gold spots) is controlled by the ductile shear zone. (2) The ductile-brittle shear zone is formed in the evolution process of ductile shear zone and both are only ore-bearing structures and con- trol the shape, attitude, scale, and distribution of mineralization zones and ore-bodies. (3) Com- presso-shear ductile deformation results in that the main kind of gold mineralization is altered mylonite type and the main alteralization is metasomatic. (4) Ore-bearing fracture systems are mainly P-type ones, some D-type and R-type ones, but only individual R’-type and T-type ones. (5) Dynamic differen- tiation and dynamic metamorphic hydrothermal solution resulting from ductile deformation is one of the sources of ore-forming fluid of gold mineralization, and this is identical with that ore-forming ma- terials are mainly from metamorphic rocks, and ore-forming fluid is mainly composed of metamorphic water, and with the fluid inclusion and geo-chemical characteristics of the deposit. (6) There is a nega- tive correlation between the gold abundance and susceptibility anisotropy (P) of the altered mylonite samples from the deposit, which shows that the gold mineralization is slightly later than the structural deformation. All above further expound the ore-forming model of the ductile shear zone type of gold deposits.