The dynamical Lie algebraic method is used for the description of statistical mechanics of rotationally inelastic molecule-surface scattering. It can give the time-evolution operators about the low power of and by s...The dynamical Lie algebraic method is used for the description of statistical mechanics of rotationally inelastic molecule-surface scattering. It can give the time-evolution operators about the low power of and by solving a set of coupled nonlinear differential equations. For considering the contribution of the high power of and , we use the Magnus formula. Thus, with the time-evolution operators we can get the statistical average values of the measurable quantities in terms of the density operator formalism in statistical mechanics. The method is applied to the scattering of (rigid rotor) by a flat, rigid surface to illustrate its general procedure. The results demonstrate that the method is useful for describing the statistical dynamics of gas-surface scattering.展开更多
基金The project supported by Natural Science Foundation of Shandong Province of China+2 种基金National Natural Science Foundation of Chinathe Doctor Foundation of the Ministry of Education of China
文摘The dynamical Lie algebraic method is used for the description of statistical mechanics of rotationally inelastic molecule-surface scattering. It can give the time-evolution operators about the low power of and by solving a set of coupled nonlinear differential equations. For considering the contribution of the high power of and , we use the Magnus formula. Thus, with the time-evolution operators we can get the statistical average values of the measurable quantities in terms of the density operator formalism in statistical mechanics. The method is applied to the scattering of (rigid rotor) by a flat, rigid surface to illustrate its general procedure. The results demonstrate that the method is useful for describing the statistical dynamics of gas-surface scattering.
