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Co-promoted Mo-carbide catalytic system for sustainable manufacturing of chemicals via co-processing of CO_(2) with ethane
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作者 Vera Bikbaeva Nikolay Nesterenko +1 位作者 Nuria García-Moncada Valentin Valtchev 《Green Carbon》 2023年第1期94-103,共10页
The study reports progress in developing a molybdenum carbide-based catalyst for co-processing ethane and CO_(2).The cobalt promoting of molybdenum carbide improved the activity and stability of ethane transformation ... The study reports progress in developing a molybdenum carbide-based catalyst for co-processing ethane and CO_(2).The cobalt promoting of molybdenum carbide improved the activity and stability of ethane transformation in the presence of CO_(2) substantially without any impact on ethylene selectivity.The Mo-Co supported catalyst also showed interesting performance in catalyzing ethane dry reforming and that application could be a perspective further use for this system.In addition,the comprehensive analysis of mono-and bi-metallic catalysts revealed that Co-promoting prevented rapid Mo-carbide oxidation.Further,tuning operation conditions allowed to control catalyst’s selectivity and maximize CO_(2) utilization or ethylene formation. 展开更多
关键词 CO_(2)utilization Oxidative dehydrogenation CO_(2)negative ethylene production Cobalt-molybdenum synergy Embryonic zeolite
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