In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,cr...In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,crystalline structure,and single fiber strength of the PPTA paperbased materials as well as the different bonding behaviors between the PPTA fibers and PPTA fibrids obtained before and after the hot calendering process were examined.The results indicated that a high linear pressure would result in a limited improvement of the strength owing to the unimproved paper structure.The optimal values of tensile index and dielectric strength of 56.6 N·m/g and 27.6 kV/mm,respectively,could only be achieved with a synergistic effects of hot calendering temperature and linear pressure(240℃ and 110 k N/m,respectively).This result suggested it was possible to achieve a significant reinforcement and improvement in the interfacial bonding of functional PPTA paper-based materials,and avoid the formation of unexpected pleats and cracks in PPTA paper-based materials during the hot calendering process.展开更多
Phosphotungstic acid(H_3PW_(12)O_(40), HPW), a kind of solid acid, is widely used for hydrolyzing cellulose to prepare microcrystalline cellulose(MCC). MCC is usually used in food, synthetic leather, chemical and phar...Phosphotungstic acid(H_3PW_(12)O_(40), HPW), a kind of solid acid, is widely used for hydrolyzing cellulose to prepare microcrystalline cellulose(MCC). MCC is usually used in food, synthetic leather, chemical and pharmaceutical industries. The use of response surface methodology(RSM)can help avoid the random error caused by single factor experimental design,reduce test times and cost, and improve quality. The RSM was used in this study to determine the following optimal process conditions: H^+ molar quantity, 31 mmol/L; reaction temperature, 93℃; reaction time, 2 h; and solid to liquid ratio, 1∶38. Under these conditions, the crystallinity of MCC was77.4%. Thus, the use of RSM allows the preparation of MCC with higher performance and increased crystallinity.展开更多
In the context of economic globalization, the knowledge economy, information networking background, the worldwide human resource management are facing the challenge of change, it shows a series of trends and they are ...In the context of economic globalization, the knowledge economy, information networking background, the worldwide human resource management are facing the challenge of change, it shows a series of trends and they are summarized in this article of the worldwide enterprise human resource management six trends, namely strategy, information technology, professional, people management, and human resources outsourcing and comprehensive human resource management, in order to change the direction of the future, it is still in its infancy inspire and should learn from the human resource management of Chinese enterprises.展开更多
Traditionally, basis weight control valve is driven by a constant frequency pulse signal. Therefore, it is difficult for the valve to match the control precision of basis weight. Dynamic simulation research using Matl...Traditionally, basis weight control valve is driven by a constant frequency pulse signal. Therefore, it is difficult for the valve to match the control precision of basis weight. Dynamic simulation research using Matlab/Simulink indicates that there is much more overshoot and fluctuating during the valve-positioning process. In order to improve the valve-positioning precision, the control method of trapezoidal velocity curve was studied. The simulation result showed that the positioning steady-state error was less than 0.0056%, whereas the peak error was less than 0.016% by using trapezoidal velocity curve at 10 positioning steps. A valve-positioning precision experimental device for the stepper motor of basis weight control valve was developed. The experiment results showed that the error ratio of 1/10000 positioning steps was 4% by using trapezoidal velocity curve. Furthermore, the error ratio of 10/10000 positioning steps was 0.5%. It proved that the valve-positioning precision of trapezoidal velocity curve was much higher than that of the constant frequency pulse signal control strategy. The new control method of trapezoidal velocity curve can satisfy the precision requirement of 10000 steps.展开更多
基金the financial support to this research from the open fund of state key laboratory for modification of chemical fibers and polymer materials (LK1601)projects of education department of Shaanxi provincial government (15JF012)National Natural Science Foundation of China (51402180)
文摘In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,crystalline structure,and single fiber strength of the PPTA paperbased materials as well as the different bonding behaviors between the PPTA fibers and PPTA fibrids obtained before and after the hot calendering process were examined.The results indicated that a high linear pressure would result in a limited improvement of the strength owing to the unimproved paper structure.The optimal values of tensile index and dielectric strength of 56.6 N·m/g and 27.6 kV/mm,respectively,could only be achieved with a synergistic effects of hot calendering temperature and linear pressure(240℃ and 110 k N/m,respectively).This result suggested it was possible to achieve a significant reinforcement and improvement in the interfacial bonding of functional PPTA paper-based materials,and avoid the formation of unexpected pleats and cracks in PPTA paper-based materials during the hot calendering process.
基金supported by the National Key Research and Development Program of China (2017YFB0307900)the Key Research and Development Project of Shaanxi Province (2017ZDXM-SF-090)the State Key Laboratory of Donghua University (NO. LK1601)
文摘Phosphotungstic acid(H_3PW_(12)O_(40), HPW), a kind of solid acid, is widely used for hydrolyzing cellulose to prepare microcrystalline cellulose(MCC). MCC is usually used in food, synthetic leather, chemical and pharmaceutical industries. The use of response surface methodology(RSM)can help avoid the random error caused by single factor experimental design,reduce test times and cost, and improve quality. The RSM was used in this study to determine the following optimal process conditions: H^+ molar quantity, 31 mmol/L; reaction temperature, 93℃; reaction time, 2 h; and solid to liquid ratio, 1∶38. Under these conditions, the crystallinity of MCC was77.4%. Thus, the use of RSM allows the preparation of MCC with higher performance and increased crystallinity.
文摘In the context of economic globalization, the knowledge economy, information networking background, the worldwide human resource management are facing the challenge of change, it shows a series of trends and they are summarized in this article of the worldwide enterprise human resource management six trends, namely strategy, information technology, professional, people management, and human resources outsourcing and comprehensive human resource management, in order to change the direction of the future, it is still in its infancy inspire and should learn from the human resource management of Chinese enterprises.
基金supported by the International S&T Cooperation Program of China(GrantNo.2010DFB43660)National Natural Science Foundation of China(Grant No.51375286)Scientific Research Program Funded by Shaanxi Provincial Education Department(Program No.16JF005)
文摘Traditionally, basis weight control valve is driven by a constant frequency pulse signal. Therefore, it is difficult for the valve to match the control precision of basis weight. Dynamic simulation research using Matlab/Simulink indicates that there is much more overshoot and fluctuating during the valve-positioning process. In order to improve the valve-positioning precision, the control method of trapezoidal velocity curve was studied. The simulation result showed that the positioning steady-state error was less than 0.0056%, whereas the peak error was less than 0.016% by using trapezoidal velocity curve at 10 positioning steps. A valve-positioning precision experimental device for the stepper motor of basis weight control valve was developed. The experiment results showed that the error ratio of 1/10000 positioning steps was 4% by using trapezoidal velocity curve. Furthermore, the error ratio of 10/10000 positioning steps was 0.5%. It proved that the valve-positioning precision of trapezoidal velocity curve was much higher than that of the constant frequency pulse signal control strategy. The new control method of trapezoidal velocity curve can satisfy the precision requirement of 10000 steps.