The recent deep prospecting results in the Jiaojia area of Eastern Shandong Province indicate that the Jiaojia ore field composed of several individual gold deposits as previously suggested is actually an ultra-large ...The recent deep prospecting results in the Jiaojia area of Eastern Shandong Province indicate that the Jiaojia ore field composed of several individual gold deposits as previously suggested is actually an ultra-large gold deposit.This deposit covers an area of ~40 km2,and shows a structural control by the Jiaojia fault and its secondary faults.Gold orebodies generally occur along the same mineralization-alteration belt,and the main orebodies intersect with each other or exhibit a parallel or overlapping distribution.This deposit's reserves are estimated to be 1,200t of gold,being the first gold deposit of more than 1000t gold reserves in China.The No.Ⅰ-1 orebody in the Shaling-deep Sizhuang ore blocks holds gold reserves greater than 350 t,or 29 percent of the total reserves,followed by the No.Ⅰ orebody in Matang-Jiaojia ore blocks with exceeding 150t gold reserves.This deposit mainly occurs in the footwall of the Jiaojia fault,and presents zoned patterns in mineralization,alteration and structures.The strongly mineralized zones agree with strongly altered and tectonically fractured zones.These orebodies display strataform-like,veinlike or lenticular shapes,and generally show characteristics of pinching out and reappearing,branching and converging,expanding and shrinking.The orebodies commonly occur along positions where the fault strike changes and in gentle locations with dips changing from steep to gentle.The main orebodies are parallel to the main plane of the orecontrolling fault,and tend to be gentle from the surface to the deep.The orebodies mainly plunge to the southwest,with plunge angle of 45°-606° Orebodies near the main plane of the ore-controlling fault have more gold resource than those away from main fault zone.The slant depth of orebodies is generally larger than the length along its strike direction; orebodies become thick and gold grades become low from the shallow area to the deep area.Ore-forming fluids are H2O-CO2-NaCl±CH4 type with medium-temperature and moderate to low salinity.Sulfur isotopic values (δ34SCDT) for gold ores range between 11.08‰ and 12.58‰,indicating mixed sulfur sources; hydrogen isotopic values (δDVSMOW) range from-83.68‰ to-116.95‰ and oxygen isotopic values (δ18OV-SMOW) range between 12.04‰ and 16.28‰.The hydrogen and oxygen isotopes suggest that ore-forming fluids originated from primary magma,and mixing with a large amount of atmospheric water during the late stage.The Eastern Shandong Province gold deposits are associated with magmatic activities which have mantle crust-mixed source,and also share some similarities with orgenic and epithermal hydrothermal golddeposits.Because Eastern Shandong Province gold deposits with unique metailogenic features and formation setting which are different from other gold deposit types in the world,we call it the Jiaojiatype gold deposits.The kiloton class Jiaojia gold deposit is related to fluid activities,extension and detachment resulted from thermal upweiling of magmas.The strong magmatic activities in the middle to late stage of early Cretaceous in Eastern Shandong Province lead to active fluids,and provided abundant ore-forming materials for gold depsoits.Moreover,many extensional structures resulting from crustal extension provided favourable space for orebody positioning.展开更多
The newly discovered Shanzhuang BIF is hosted in the Shancaoyu Formation of the Taishan Group within the Eastern Block,southeastern margin of the North China Craton.The ores can be subdivided into three types in terms...The newly discovered Shanzhuang BIF is hosted in the Shancaoyu Formation of the Taishan Group within the Eastern Block,southeastern margin of the North China Craton.The ores can be subdivided into three types in terms of mineral assemblages,corresponding to three types(Ⅰ,Ⅱ,Ⅲ).The element concentration of the type Ⅰ magnetite is similar to that of the type Ⅱ magnetite,while the type Ⅲ magnetite is similar to that of the schist.In general,magnetite and hemat ite grains from the ores show high concentrations of Mn(1317,1162 ppm),Co(787,1023 ppm),Al(2224,2435 ppm)and Ti(540,300 ppm),Whereas magnetite is depleted in Si(420 ppm)and hematite enriched in Si(1690 ppm).Detailed petrographic and mineral chemical analysis of magnetite,hematite,amphibole/hornblende and pyroxene,reveals that almost all the minerals occur as subhedral-anhedral grains with pits and fractures,and the BIF is recrystallized to metamorphic assemblages of high amphibolite facies.Hornblende is highly enriched in Fe,Mg and Ca,but depleted in K and Na,mostly belonging to magnesiohornblende.In addition,the ratios of Mg/(Mg+Fe^2+),Fe^3+/(Fe^3++Fe^2+),Si/(Si+Ti+Al)and Al/Si are 0.48-0.64,0.17-0.36,0.79-0.88 and 0.14-0.27,respectively.It is suggested that hornblende is neither a typical magmatic origin nor a typical metamorphic.Pyroxene has the characteristics of high Ca and Fe,but low Ti and Al,with end-member components En,Wo and Fs in the ranges of 25.22-28.64 wt%,43.71-46.40 wt%and 24.51-27.62 wt%,respectively,belonging to clinopyroxene,and mostly diopside,might be formed during the prograde metamorphism in the absence of H2 O.The carbonate such as dolomite-ankerite series is probably a precursor mineral of the BIF deposit.Mass mineral chemical and structural characteristics indicate that the Shanzhuang iron deposit has been subjected to varying degrees of oxidized hydrothermal superimposed reformation,metamorphism,and supergenesis after mineralization,during which some elements have been migrated in some degree.展开更多
Electron probe micro-analysis(EPMA) and scanning electron microscopy(SEM) equipped with energy dispersive spectrometry(EDS) have been used to investigate the principal ore minerals and coexisting metallic mineral incl...Electron probe micro-analysis(EPMA) and scanning electron microscopy(SEM) equipped with energy dispersive spectrometry(EDS) have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit, which consists of a high-sulfidation epithermal system(HSES) and a porphyry system(PS). Molybdenite,chalcopyrite, bornite, tennantite, enargite, digenite, anilite, covellite, and tetrahedrite have been identified by EPMA. Intergrowth, cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite ± bornite ± hematite(stage 2),then bornite ± Cu-sulfides ± Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides ±Cu-sulfides(stage 4). Pyrite is developed throughout all the stages. Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite, chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier. The pervasive binary equilibrium phases of calaverite and altaite constrain fin the range from ~-6.5 to ~-8 and f<-11.The intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the PS.Contrastingly, the dominance of chalcopyrite in the PS, with minor bornite, suggests relatively high temperature conditions. These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant No. 41230311)the National Science and Technology Support Program (Grant No.2011BAB04B09)
文摘The recent deep prospecting results in the Jiaojia area of Eastern Shandong Province indicate that the Jiaojia ore field composed of several individual gold deposits as previously suggested is actually an ultra-large gold deposit.This deposit covers an area of ~40 km2,and shows a structural control by the Jiaojia fault and its secondary faults.Gold orebodies generally occur along the same mineralization-alteration belt,and the main orebodies intersect with each other or exhibit a parallel or overlapping distribution.This deposit's reserves are estimated to be 1,200t of gold,being the first gold deposit of more than 1000t gold reserves in China.The No.Ⅰ-1 orebody in the Shaling-deep Sizhuang ore blocks holds gold reserves greater than 350 t,or 29 percent of the total reserves,followed by the No.Ⅰ orebody in Matang-Jiaojia ore blocks with exceeding 150t gold reserves.This deposit mainly occurs in the footwall of the Jiaojia fault,and presents zoned patterns in mineralization,alteration and structures.The strongly mineralized zones agree with strongly altered and tectonically fractured zones.These orebodies display strataform-like,veinlike or lenticular shapes,and generally show characteristics of pinching out and reappearing,branching and converging,expanding and shrinking.The orebodies commonly occur along positions where the fault strike changes and in gentle locations with dips changing from steep to gentle.The main orebodies are parallel to the main plane of the orecontrolling fault,and tend to be gentle from the surface to the deep.The orebodies mainly plunge to the southwest,with plunge angle of 45°-606° Orebodies near the main plane of the ore-controlling fault have more gold resource than those away from main fault zone.The slant depth of orebodies is generally larger than the length along its strike direction; orebodies become thick and gold grades become low from the shallow area to the deep area.Ore-forming fluids are H2O-CO2-NaCl±CH4 type with medium-temperature and moderate to low salinity.Sulfur isotopic values (δ34SCDT) for gold ores range between 11.08‰ and 12.58‰,indicating mixed sulfur sources; hydrogen isotopic values (δDVSMOW) range from-83.68‰ to-116.95‰ and oxygen isotopic values (δ18OV-SMOW) range between 12.04‰ and 16.28‰.The hydrogen and oxygen isotopes suggest that ore-forming fluids originated from primary magma,and mixing with a large amount of atmospheric water during the late stage.The Eastern Shandong Province gold deposits are associated with magmatic activities which have mantle crust-mixed source,and also share some similarities with orgenic and epithermal hydrothermal golddeposits.Because Eastern Shandong Province gold deposits with unique metailogenic features and formation setting which are different from other gold deposit types in the world,we call it the Jiaojiatype gold deposits.The kiloton class Jiaojia gold deposit is related to fluid activities,extension and detachment resulted from thermal upweiling of magmas.The strong magmatic activities in the middle to late stage of early Cretaceous in Eastern Shandong Province lead to active fluids,and provided abundant ore-forming materials for gold depsoits.Moreover,many extensional structures resulting from crustal extension provided favourable space for orebody positioning.
基金financially supported by the National Natural Science Foundation of China(Grants No.41503038,41140025,41672084,41372086)Special fund for“Taishan scholars”project in Shandong Province,Key R&D Program of Shandong Province(Grant No.2019GSF109101)+2 种基金Key R&D Program of China(Grants No.2016YFC0600105-04,2016YFC0600606)Shandong Provincial Natural Science Foundation(Grant No.ZR2019PD005)Shandong Key Laboratory of Mineralization Geological Processes and Resources Utilization in Metallic Minerals(Grant No.kfkt201809)。
文摘The newly discovered Shanzhuang BIF is hosted in the Shancaoyu Formation of the Taishan Group within the Eastern Block,southeastern margin of the North China Craton.The ores can be subdivided into three types in terms of mineral assemblages,corresponding to three types(Ⅰ,Ⅱ,Ⅲ).The element concentration of the type Ⅰ magnetite is similar to that of the type Ⅱ magnetite,while the type Ⅲ magnetite is similar to that of the schist.In general,magnetite and hemat ite grains from the ores show high concentrations of Mn(1317,1162 ppm),Co(787,1023 ppm),Al(2224,2435 ppm)and Ti(540,300 ppm),Whereas magnetite is depleted in Si(420 ppm)and hematite enriched in Si(1690 ppm).Detailed petrographic and mineral chemical analysis of magnetite,hematite,amphibole/hornblende and pyroxene,reveals that almost all the minerals occur as subhedral-anhedral grains with pits and fractures,and the BIF is recrystallized to metamorphic assemblages of high amphibolite facies.Hornblende is highly enriched in Fe,Mg and Ca,but depleted in K and Na,mostly belonging to magnesiohornblende.In addition,the ratios of Mg/(Mg+Fe^2+),Fe^3+/(Fe^3++Fe^2+),Si/(Si+Ti+Al)and Al/Si are 0.48-0.64,0.17-0.36,0.79-0.88 and 0.14-0.27,respectively.It is suggested that hornblende is neither a typical magmatic origin nor a typical metamorphic.Pyroxene has the characteristics of high Ca and Fe,but low Ti and Al,with end-member components En,Wo and Fs in the ranges of 25.22-28.64 wt%,43.71-46.40 wt%and 24.51-27.62 wt%,respectively,belonging to clinopyroxene,and mostly diopside,might be formed during the prograde metamorphism in the absence of H2 O.The carbonate such as dolomite-ankerite series is probably a precursor mineral of the BIF deposit.Mass mineral chemical and structural characteristics indicate that the Shanzhuang iron deposit has been subjected to varying degrees of oxidized hydrothermal superimposed reformation,metamorphism,and supergenesis after mineralization,during which some elements have been migrated in some degree.
基金supported by Public Science and Technology Research Funds Projects, Ministry of Land Resources of the People's Republic of China (project No. 201511017 and 201511022-05)the Basic Research Fund of Chinese Academy of Geological Sciences (Grant No. YYWF201608)+1 种基金the National Natural Science Foundationof China (Grant No. 41402178)Geological Survey Project of the China Geological Survey (project 1212011405040)
文摘Electron probe micro-analysis(EPMA) and scanning electron microscopy(SEM) equipped with energy dispersive spectrometry(EDS) have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit, which consists of a high-sulfidation epithermal system(HSES) and a porphyry system(PS). Molybdenite,chalcopyrite, bornite, tennantite, enargite, digenite, anilite, covellite, and tetrahedrite have been identified by EPMA. Intergrowth, cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite ± bornite ± hematite(stage 2),then bornite ± Cu-sulfides ± Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides ±Cu-sulfides(stage 4). Pyrite is developed throughout all the stages. Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite, chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier. The pervasive binary equilibrium phases of calaverite and altaite constrain fin the range from ~-6.5 to ~-8 and f<-11.The intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the PS.Contrastingly, the dominance of chalcopyrite in the PS, with minor bornite, suggests relatively high temperature conditions. These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems.