Rational construction of CuFe_(2)O_(4)@C/Cd_(0.9)Zn_(0.1)S S-scheme heterojunction photocatalyst for extraordinary photothermal-assisted photocatalytic H_(2) evolution

Rational design of photocatalyst to maximize the use of sunlight is one of the issues to be solved in photocatalysis technology.In this study,the CuFe_(2)O_(4)@C/Cd_(0.9)Zn_(0.1)S(CFO@C/CZS)S-scheme photocatalyst with photothermal effect was synthesized by ultrasonic self-assembly combined with calcination.The dark CFO@C absorbed visible light and partly converted into heat to promote the hydrogen evolution reaction.The presence of heterojunctions inhibited the photogenerated electron-hole recombination.The graphite-carbon layer provided a stable channel for electron transfer,and the presence of magnetic CFO made recycle easier.Under the action of photothermal assistance and heterojunction,the hydrogen evolution rate of the optimal CFO@C/CZS was 80.79 mmol g^(-1) h^(-1),which was 2.55 times and 260.61 times of that of pure CZS and CFO@C,respectively.Notably,the composite samples also exhibit excellent stability and a wide range of environmental adaptability.Through experimental tests and first-principles simulation calculation methods,the plausible mechanism of photoactivity enhancement was proposed.This work provided a feasible strategy of photothermal assistance for the development of heterojunction photocatalysts with distinctive hydrogen evolution.

Majorana noise model and its influence on the power spectrum

Majorana quantum computation offers a potential approach to securely manipulating and storing quantum data in a topological manner that may effectively resist the decoherence induced by local noise. However, actual Majorana qubit setups are susceptible to noise. In this study, from a quantum dynamics perspective, we develop a noise model for Majorana qubits that accounts for quasi-particle poisoning and Majorana overlapping with fluctuation. Furthermore, we focus on Majorana parity readout methodologies, specifically those leveraging an ancillary quantum dot, and carry out an indepth exploration of continuous measurement techniques founded on the quantum jump model of a quantum point contact.Utilizing these methodologies, we proceed to analyze the influence of noise on the afore-mentioned noise model, employing numerical computation to evaluate the power spectrum and frequency curve. In the culmination of our study, we put forward a strategy to benchmark the presence and detailed properties of noise in Majorana qubits.

Exceptional points and quantum dynamics in a non-Hermitian two-qubit system

We study the exceptional-point(EP) structure and the associated quantum dynamics in a system consisting of a non-Hermitian qubit and a Hermitian qubit. We find that the system possesses two sets of EPs, which divide the systemparameter space into PT-symmetry unbroken, partially broken and fully broken regimes, each with distinct quantumdynamics characteristics. Particularly, in the partially broken regime, while the PT-symmetry is generally broken in the whole four-dimensional Hilbert space, it is preserved in a two-dimensional subspace such that the quantum dynamics in the subspace are similar to those in the PT-symmetry unbroken regime. In addition, we reveal that the competition between the inter-qubit coupling and the intra-qubit driving gives rise to a complex pattern in the EP variation with system parameters.

Time evolution of angular momentum coherent state derived by virtue of entangled state representation and a new binomial theorem

We study how can an angular momentum coherent state |τ> keeps its form-invariant during time evolution governed by the Hamiltonian H = f(t)J++ f^*(t)J-+ g(t)Jz. We discuss this topic in the context of boson realization of |τ>. By employing the entangled state representation |ζ> and deriving a new binomial theorem involving two-subscript Hermite polynomials, we derive the wave function <ζ|τ>, which turns out to be a single-subscript Hermite polynomial. Based on this result the maintenance of angular momentum coherent state during time evolution is examined, and the value of τ(t) is totally determined by the parameters involved in the Hamiltonian.

Effects of hydrogen bonds on solid state TATB,RDX,and DATB under high pressures

To probe the behavior of hydrogen bonds in solid energetic materials, we conduct ReaxFF and SCC-DFTB molecular dynamics simulations of crystalline TATB, RDX, and DATB. By comparing the intra- and inter-molecular hydrogen bond- ing rates, we find that the crystal structures are stabilized by inter-molecular hydrogen bond networks. Under high-pressure, the inter- and intra-molecular hydrogen bonds in solid TATB and DATB are nearly equivalent. The hydrogen bonds in solid TATB and DATB are much shorter than in solid RDX, which suggests strong hydrogen bond interactions existing in these energetic materials. Stretching of the C-H bond is observed in solid RDX, which may lead to further decomposition and even detonation.

Wigner function for squeezed negative binomial state and evolution of density operator for amplitude decay

Using the thermal-entangled state representation and the operator-ordering method, we investigate Wigner function(WF) for the squeezed negative binomial state(SNBS) and the analytical evolution law of density operator in the amplitude decay channel.The results show that the analytical WF is related to the square of the module of single-variable Hermite polynomials, which leads to a new two-variable special function and its generating function, and the parameters s and γplay opposite roles in the WF distributions.Besides, after undergoing this channel, the initial pure SNBS evolves into a new mixed state related to two operator Hermite polynomials within normal ordering, and fully loses its nonclassicality and decays to vacuum at long decay time.

Recast combination functions of coordinate and momentum operators into their ordered product forms

By using the parameter differential method of operators,we recast the combination function of coordinate and momentum operators into its normal and anti-normal orderings,which is more ecumenical,simpler,and neater than the existing ways.These products are very useful in obtaining some new differential relations and useful mathematical integral formulas.Further,we derive the normally ordered form of the operator(fQ+gP)^-n with n being an arbitrary positive integer by using the parameter tracing method of operators together with the intermediate coordinate-momentum representation.In addition,general mutual transformation rules of the normal and anti-normal orderings,which have good universality,are derived and hence the anti-normal ordering of(fQ+gP)^-n is also obtained.Finally,the application of some new identities is given.

Regulation of Ionic Bond in GroupⅡB Transition Metal Iodides

Using a swarm intelligence structure search method combining with first-principles calculations,three new structures of Zn-I and Hg-I compounds are discovered and pressure-composition phase diagrams are determined.An interesting phenomenon is found,that is,the compounds that are stable at 0 GPa in both systems will decompose into their constituent elements under certain pressure,which is contrary to the general intuition that pressure always makes materials more stability and density.A detailed analysis of the decomposition mechanism reveals the increase of formation enthalpy with the increase of pressure due to contributions from bothΔU andΔ[P V].Pressure-dependent studies of theΔV demonstrate that denser materials tend to be stabilized at higher pressures.Additionally,charge transfer calculations show that external pressure is more effective in regulating the ionic bond of Hg-I,resulting in a lower decomposition pressure for HgI_(2)than for ZnI_(2).These findings have important implications for designs and syntheses of new materials,as they challenge the conventional understanding on how pressure affects stability.

Pressure-Induced Distinct Self-Trapped Exciton Emission in Sb^(3+)-Doped Cs_(2)NaInCl_(6)Double Perovskite

The Cs_(2)NaInCl_(6)double perovskite is one of the most promising lead-free perovskites due to its exceptional stability and straightforward synthesis.However,it faces challenges related to inefficient photoluminescence.Doping and high pressure are employed to tailor the optical properties of Cs_(2)NaInCl_(6).Herein,Sb^(3+)doped Cs_(2)NaInCl_(6)(Sb^(3+):Cs_(2)NaInCl_(6))was synthesized and it exhibits blue emission with a photoluminescence quantum yield of up to 37.3%.Further,by employing pressure tuning,a blue stable emission under a very wide range from 2.7 GPa to 9.8 GPa is realized in Sb^(3+):Cs_(2)NaInCl_(6).Subsequently,the emission intensity of Sb^(3+):Cs_(2)NaInCl_(6)experiences a significant increase(3.3 times)at 19.0 GPa.It is revealed that the pressure-induced distinct emissions can be attributed to the carrier self-trapping and detrapping between Cs_(2)NaInCl_(6)and Sb^(3+).Notably,the lattice compression in the cubic phase inevitably modifies the band gap of Sb^(3+):Cs_(2)NaInCl_(6).Our findings provide valuable insights into effects of the high pressure in further boosting unique emission characteristics but also offer promising opportunities for development of doped double perovskites with enhanced optical functionalities.

From Topological Nodal-Line Semimetals to Quantum Spin Hall Insulators in Tetragonal SnX Monolayers(X=F,Cl,Br,I)

Two-dimensional(2D)topological materials have recently garnered significant interest due to their profound physical properties and promising applications for future quantum nanoelectronics.Achieving various topological states within one type of materials is,however,seldom reported.Based on first-principles calculations and tightbinding models,we investigate topological electronic states in a novel family of 2D halogenated tetragonal stanene(T-SnX,X=F,Cl,Br,I).All the four monolayers are found to be unusual topological nodal-line semimetals(NLSs),protected by a glide mirror symmetry.When spin-orbit coupling(SOC)is turned on,T-SnF and TSnCl are still ascertained as topological NLSs due to the remaining band inversion,primarily composed of Sn pxy orbitals,while T-Sn Br and T-SnI become quantum spin Hall insulators.The phase transition is ascribed to moving up in energy of Sn s orbitals and increasing of SOC strengths.The topology origin in the materials is uniformly rationalized through elementary band representations.The robust and diverse topological states found in the 2D T-SnX monolayers position them as an excellent material platform for development of innovative topological electronics.

Density-matrix-formalism based scheme for polarization mode dispersion monitoring and compensation in optical fiber communication systems

We propose a density-matrix-formalism based scheme to study polarization mode dispersion(PMD)monitoring and compensation in optical fiber communication systems.Compared to traditional monitoring and compensation schemes based on the PMD vector in the Stokes space,the scheme we proposed requires no auxiliary matrices and can be handily extended to any higher-dimensional modal space,which is advantageous in mode-division multiplexing(MDM)systems.A 28 GBaud polarization division multiplexing quadrature phase-shift keying(PDM-QPSK)coherent simulation system is built to demonstrate that our scheme can implement the monitoring and compensation of 170 ps large differential-group-delay(DGD)that far exceeds the typical DGDs in practical optical communication systems.The results verify the effectiveness of the density-matrix-formalism based scheme in PMD monitoring and compensation,thus pave the way for further applications of the scheme in more general MDM optical communication systems.

Kraus operator solutions to a fermionic master equation describing a thermal bath and their matrix representation

We solve the fermionic master equation for a thermal bath to obtain its explicit Kraus operator solutions via the fermionic state approach. The normalization condition of the Kraus operators is proved. The matrix representation for these solutions is obtained, which is incongruous with the result in the book completed by Nielsen and Chuang [Quan- tum Computation and Quantum Information, Cambridge University Press, 2000]. As especial cases, we also present the Kraus operator solutions to master equations for describing the amplitude-decay model and the diffusion process at finite temperature.

Stretchable supercapacitor based on a hierarchical PPy/CNT electrode and hybrid hydrogel electrolyte with a wide operating temperature

Hydrogel is frequently used as a solid electrolyte for all solid-state supercapacitors(SCs)because of its liquid-like ion-transport property and high conformability.However,due to the higher water content,the hydrogel electrolyte undergoes inevitable freezing and/or dehydration with climate change.Herein,polypyrrole/carbon all-solid-state SCs(PCSCs)were developed based on a hierarchical polypyrrole/carbon nanotube electrode and a highly stretchable double-network polymer hydrogel electrolyte with LiCl/ethylene glycol as a mixed solvent.The PCSCs showed excellent electrochemical performance and cycle stability with a wide operating temperature.The specific capacitances could reach 202.2 and 112.3 mF cm^(−2) at current densities of 0.5 and 3.0 mA cm^(−2),respectively.Meanwhile,the PCSCs showed outstanding mechanical properties in maintaining a high areal capacitance under deformations of bending and tension.The excellent water retention of the device also ensured the stable electrochemical performance of PCSCs in a wide temperature range(30–80℃),which could potentially represent a reliable application in various harsh environments.

s-parameterized Weyl transformation and the corresponding quantization scheme

By extending the usual Weyl transformation to the s-parameterized Weyl transformation with s being a real parameter,we obtain the s-parameterized quantization scheme which includes P–Q quantization, Q–P quantization, and Weyl ordering as its three special cases. Some operator identities can be derived directly by virtue of the s-parameterized quantization scheme.

Fluorescence enhancement of radix angelica dahurica by binding to single silver sphere

We present a theoretical study of the influence of a single silver sphere on the fluorescence of radix angelica dahurica, which is a kind of traditional Chinese medicine. The enhancement factors of the excitation and the relaxation processes are deduced. The excitation can be enhanced more than 100 times at 315 nm. The enhancement factor of the emission can reach up to 9 at a center wavelength of 400 nm.

Dual-function beam splitter of high contrast gratings

we preset the design and rabrication of a novel auai-iunction hign contrast gratings that can De usea as a polarizationselective beam splitter with transverse magnetic polarization,which performs two independent functions,i.e.,reflection focusing and power equalization at a wavelength of 1550 nm.This dual-function grating profile is optimized by the rigorous coupled-wave analysis and the finite-element method.Simple analytical expressions of phase and modal guideline for the beam splitter design are given.The beam splitter based on the grating structure is experimentally studied at a distance of 160 μm from the reflection plane,the results are consistent with the theoretical results basically.

Hugoniot curve calculation of nitromethane decomposition mixtures:A reactive force field molecular dynamics approach

We investigate the Hugoniot curve, shock-particle velocity relations, and Chapman-Jouguet conditions of the hot dense system through molecular dynamics （MD） simulations. The detailed pathways from crystal nitromethane to reacted state by shock compression are simulated. The phase transition of N2 and CO mixture is found at about 10 GPa, and the main reason is that the dissociation of the C-O bond and the formation of C-C bond start at 10.0-11.0 GPa. The unreacted state simulations of nitromethane are consistent with shock Hugoniot data. The complete pathway from unreacted to reacted state is discussed. Through chemical species analysis, we find that the C-N bond breaking is the main event of the shock-induced nitromethane decomposition.

Nonclassicality of photon-modulated atomic coherent states in the Schwinger bosonic realization

We theoretically introduce two new photon-modulated atomic coherent states(ACSs)via using the Schwinger bosonic representation of the angular momentum operators(the sequential operations J±n)on an ACS,and investigate their nonclassicality using the Wigner distribution,photon number distribution,and entanglement entropy.It is found that photonmodulated ACSs possess more stronger nonclassicality than the original ACS in certain regions ofτ,the nonclassicality enhances with increasing number n of the operations J±and the operation J+(-)n enhances the entanglement in the region of small(large)τ.

Nonclassicality of photon-modulated spin coherent states in the Holstein-Primakoff realization

Two new photon-modulated spin coherent states(SCSs)are introduced by operating the spin ladder operators J±on the ordinary SCS in the Holstein-Primakoff realization and the nonclassicality is exhibited via their photon number distribution,second-order correlation function,photocount distribution and negativity of Wigner distribution.Analytical results show that the photocount distribution is a Bernoulli distribution and the Wigner functions are only associated with two-variable Hermite polynomials.Compared with the ordinary SCS,the photon-modulated SCSs exhibit more stronger nonclassicality in certain regions of the photon modulated number k and spin number j,which means that the nonclassicality can be enhanced by selecting suitable parameters.

Finite-dimensional pair coherent state engendered via the nonlinear Bose operator realization and its Wigner phase-space distributions

We theoretically analyze the photon number distribution,entanglement entropy,and Wigner phase-space distribution,considering the finite-dimensional pair coherent state(FDPCS)generated in the nonlinear Bose operator realization.Our results show that the photon number distribution is governed by the two-mode photon number sum q of the FDPCS,the entanglement of the FDPCS always increases quickly at first and then decreases slowly for any q,and the nonclassicality of the FDPCS for odd q is more stronger than that for even q.