he nano-graphite sheet/alumina composites were prepared in situ by a facile impregnation-reduction process.The microstructure of the composites was analyzed by X-ray diffraction （XRD）,and the final phase composition...he nano-graphite sheet/alumina composites were prepared in situ by a facile impregnation-reduction process.The microstructure of the composites was analyzed by X-ray diffraction （XRD）,and the final phase composition after reduction is Al2O3,metal Fe and graphite crystal.Scanning electron microscopy （SEM） images show that the particle size of Fe is about 20 nm,and the lamellae thickness of the graphite is about 30 nm.Then,the dielectric properties and conductive mechanism of the composites were investigated experimentally in the frequency range of 0.01-1.00 GHz by impedance analyzer.The results show that the real part of permittivity of composites increases with Fe3＋ concentration,which is due to the increase in interfacial polarization between Fe and A12O3 and the three-dimensional network of lamellar graphite formation.Therefore,tunable microtopography and electrical parameters of nano-graphite sheet/alumina composites can be realized by changing Fe3＋ concentration.展开更多
The properties of a series of imide oligomers were characterized according to their molecular weights, solubility, and thermal and rheological properties. This series of imide oligomers was synthesized via a two-step ...The properties of a series of imide oligomers were characterized according to their molecular weights, solubility, and thermal and rheological properties. This series of imide oligomers was synthesized via a two-step method using 2,2′,3,3′-biphenyltetracarboxylic dianhydride(3,3′-BPDA) and aromatic diamines as the monomers, and 4-phenylethynyl phtlialic anhydride(PEPA) as the end-capping agent. The imide oligomers based on 3,3′-BPDA showed excellent solubility in low boiling point solvents and low melt viscosity, which were attributed to their unique bent architectures. High-performance thermosetting polyimides were produced from these oligomers via thermal crosslinking of the phenylethynyl groups. The mechanical and thermal properties of the thermosets were studied using tensile testing, dynamic mechanical thermal analysis(DMTA), and thermogravimetric analysis(TGA). The 3,3′EPDA-based thermosets exhibited excellent thermal properties, with glass transition temperatures of up to 455℃, and 5% mass loss temperatures of up to 569℃ in air. The thermosets based on 3,3-BPDA showed superior thermal properties compared to those derived from TriA-X series oligomers.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.50772061 and 51172131)
文摘he nano-graphite sheet/alumina composites were prepared in situ by a facile impregnation-reduction process.The microstructure of the composites was analyzed by X-ray diffraction （XRD）,and the final phase composition after reduction is Al2O3,metal Fe and graphite crystal.Scanning electron microscopy （SEM） images show that the particle size of Fe is about 20 nm,and the lamellae thickness of the graphite is about 30 nm.Then,the dielectric properties and conductive mechanism of the composites were investigated experimentally in the frequency range of 0.01-1.00 GHz by impedance analyzer.The results show that the real part of permittivity of composites increases with Fe3＋ concentration,which is due to the increase in interfacial polarization between Fe and A12O3 and the three-dimensional network of lamellar graphite formation.Therefore,tunable microtopography and electrical parameters of nano-graphite sheet/alumina composites can be realized by changing Fe3＋ concentration.
基金the Technology Innovation Fund of Chinese Academy of Sciences(NO.CXJJ-17-M159)the National Natural Science Foundation of China(No.51473157).
文摘The properties of a series of imide oligomers were characterized according to their molecular weights, solubility, and thermal and rheological properties. This series of imide oligomers was synthesized via a two-step method using 2,2′,3,3′-biphenyltetracarboxylic dianhydride(3,3′-BPDA) and aromatic diamines as the monomers, and 4-phenylethynyl phtlialic anhydride(PEPA) as the end-capping agent. The imide oligomers based on 3,3′-BPDA showed excellent solubility in low boiling point solvents and low melt viscosity, which were attributed to their unique bent architectures. High-performance thermosetting polyimides were produced from these oligomers via thermal crosslinking of the phenylethynyl groups. The mechanical and thermal properties of the thermosets were studied using tensile testing, dynamic mechanical thermal analysis(DMTA), and thermogravimetric analysis(TGA). The 3,3′EPDA-based thermosets exhibited excellent thermal properties, with glass transition temperatures of up to 455℃, and 5% mass loss temperatures of up to 569℃ in air. The thermosets based on 3,3-BPDA showed superior thermal properties compared to those derived from TriA-X series oligomers.
