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Preparation of entangledW states based on the cavity QED system
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作者 Ke Li Jun-Long Zhao 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期290-296,共7页
We present a qubit-loss-free(QLF)fusion scheme for generating large-scale atom W states in cavity quantum electrodynamics(QED)system.Compared to the most current fusion schemes which are conditioned on the case where ... We present a qubit-loss-free(QLF)fusion scheme for generating large-scale atom W states in cavity quantum electrodynamics(QED)system.Compared to the most current fusion schemes which are conditioned on the case where one particle can be extracted from each initial W state to the fusion process,our scheme will access one or two particles from each W state.Based on the atom–cavity-field detuned interaction,three jWin+m+t states can be generated from the jWin,jWim,and jWit states with the help of two auxiliary atoms,and three jWin+m+t+q states can be generated from jWin,jWim,jWit,and a jWiq state with the help of three auxiliary atoms.Comparing the numerical simulations of the resource cost of fusing three small-size W states based on the previous schemes,our fusion scheme seems to be more efficient.This QLF fusion scheme can be generalized to the case of fusing k different or identical particle W states.Furthermore,with no qubit loss,it greatly reduces the number of fusion steps and prepares W states with larger particle numbers. 展开更多
关键词 W STATE detuned interaction STATE FUSION CAVITY quantum ELECTRODYNAMICS
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Multiple factors influencing high-purity indium electrolytic refining
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作者 Hong-Qiang Fan Fei Li +5 位作者 Hong-Xing Zheng Wu-ji Pan Mei-Zhen Wu Yashar Behnamian Ju-Bo Peng Dong-Hai Lin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第7期148-160,共13页
The effects of various contaminants in the electrolytic refinement of indium were investigated using a glow discharge mass spectrometer(GDMS).The effects of several factors such as the indium ion(In3+)concentration,th... The effects of various contaminants in the electrolytic refinement of indium were investigated using a glow discharge mass spectrometer(GDMS).The effects of several factors such as the indium ion(In3+)concentration,the sodium chloride(NaCl)concentration,the current density,the gelatin concentration,the pH,and the electrode distance,were examined.Significant variations in impurity levels concerning gelatin concentration were observed.Both the gelatin and In3+concentration were moderately positively correlated with the Pb content.The Sb concentration was associated positively with the NaCl concentration,while the Ti concentration had an adverse correlation with the NaCl concentration.The Bi element content was positively linked to the electrode distance.As the current density increased,Cu,Pb,and Bi impurities initially rose and then eventually declined.Notably,a critical current density of 45 A·m^(-2) was identified in this behavior. 展开更多
关键词 High-purity indium ELECTROLYSIS Multiple factors ELECTROCHEMISTRY Purification
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Development of High Accurate Family-use Digital Refractometer Based on CMOS
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作者 WANG Zhenxing JIA Zhenyuan 《Instrumentation》 2023年第3期12-22,共11页
This study aims to develop a low-cost refractometer for measuring the sucrose content of fruit juice,which is an important factor affecting human health.While laboratory-grade refractometers are expensive and unsuitab... This study aims to develop a low-cost refractometer for measuring the sucrose content of fruit juice,which is an important factor affecting human health.While laboratory-grade refractometers are expensive and unsuitable for personal use,existing low-cost commercial options lack stability and accuracy.To address this gap,we propose a refractometer that replaces the expensive CCD sensor and light source with a conventional LED and a reasonably priced CMOS sensor.By analyzing the output waveform pattern of the CMOS sensor,we achieve high precision with a personal-use-appropriate accuracy of 0.1%.We tested the proposed refractometer by conducting 100 repeated measurements on various fruit juice samples,and the results demonstrate its reliability and consistency.Running on a 48 MHz ARM processor,the algorithm can acquire data within 0.2 seconds.Our low-cost refractometer is suitable for personal health management and small-scale production,providing an affordable and reliable method for measuring sucrose concentration in fruit juice.It improves upon the existing low-cost options by offering better stability and accuracy.This accessible tool has potential applications in optimizing the sucrose content of fruit juice for better health and quality control. 展开更多
关键词 Brix Meter High-precision Refractometer OVERSAMPLING 1D CMOS Sensor
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Application of PCA Numalgorithm in Remote Sensing Image Processing
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作者 Hong Dai 《Modern Electronic Technology》 2023年第1期17-21,共5页
A numerical algorithm of principal component analysis (PCA) is proposed and its application in remote sensing image processing is introduced: (1) Multispectral image compression;(2) Multi-spectral image noise cancella... A numerical algorithm of principal component analysis (PCA) is proposed and its application in remote sensing image processing is introduced: (1) Multispectral image compression;(2) Multi-spectral image noise cancellation;(3) Information fusion of multi-spectral images and spot panchromatic images. The software experiments verify and evaluate the effectiveness and accuracy of the proposed algorithm. 展开更多
关键词 PCA numerical algorithm Remote sensing image processing Multi-spectral image
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Investigation on Uniaxial Tensile Instability of USIBOR1500 Steel Sheets at Elevated Temperature 被引量:9
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作者 MIN Junying LIN Jianping +2 位作者 TIAN Haobin SUN Guohua XU Zhou 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2010年第1期94-99,共6页
In the sheet forming process with stretch, diffuse instability and localized instability usually occur in the process one after another. The necking rate has a great impact on the instability process and the forming l... In the sheet forming process with stretch, diffuse instability and localized instability usually occur in the process one after another. The necking rate has a great impact on the instability process and the forming limits of the rate sensitive material, such as USIBOR1500 steel sheets at elevated temperature. The available reports about this steel mainly focus on hot uniaxial tensile, martensitic transformation and forming process, but there are few investigations on instability behavior and forming limits. Based on Inoue Kachiro's flow stress constitutive model at elevated temperature, combined with Swift's diffuse instability rule and Hill's localized instability nile, the relation is theoretically deduced between the diffuse necking rate along with the localized necking rate and the exponent of strain rate sensitivity together with the strain rate in the case of the USIBOR1500 steel sheets at elevated temperature. According to the time-temperature characteristics of the hot stamping process, tensile tests of the steel sheets were carried out on Gleeble3800, and the stress-strain curves were obtained at different temperatures and different strain rates. Then the values of the exponent of strain rate sensitivity and the hardening exponent were obtained through fitting the curves by least squares. The tests also helped to provide the distribution laws of the major strain of the specimens and the uniform strains as well as the necking width. The uniform strains obtained from the tests are matched well with the theoretical calculations. 展开更多
关键词 USIBOR1500 uniaxial tensile INSTABILITY uniform strain necking rate
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Orbital-abrasion-assisted Electroforming of Non-rotating Parts 被引量:5
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作者 李学磊 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2011年第5期827-831,共5页
A novel technique of electroforming with orbital moving cathode was carried out for the fabrication of non-rotating thin-walled parts.This technique features a large number of insulating and insoluble hard particles a... A novel technique of electroforming with orbital moving cathode was carried out for the fabrication of non-rotating thin-walled parts.This technique features a large number of insulating and insoluble hard particles as a real-time polishing to the cathode.When cathode moves,hard particles polish its surface and provide the nickel non-rotating parts with near-mirror finishing.Morphology,microstructure,surface roughness and micro hardness of deposits fabricated by novel method were studied in contrast with the sample produced by traditional electroforming methods.Theoretical analysis and experimental results showed that the novel technique could effectively remove the hydrogen bubbles and nodules,disturb the crystal nucleation,and refine the grains of layer.The mechanical properties were significantly improved over traditional method.The micro-hardness of the layer was in a uniform distribution ranging from 345 HV to 360 HV.It was confirmed that this technique had practical significance to non-rotating thin-walled parts. 展开更多
关键词 ELECTROFORMING orbital cathode ABRASION non-rotating parts
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Online Supervision of Penicillin Cultivations Based on Rolling MPCA 被引量:9
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作者 汪志锋 袁景淇 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2007年第1期92-96,共5页
To reduce the variations of the production process in penicillin cultivations, a rolling multivariate statis-tical approach based on multiway principle component analysis (MPCA) is developed and used for fault diagnos... To reduce the variations of the production process in penicillin cultivations, a rolling multivariate statis-tical approach based on multiway principle component analysis (MPCA) is developed and used for fault diagnosis of penicillin cultivations. Using the moving data windows technique, the static MPCA is extended for use in dy-namic process performance monitoring. The control chart is set up using the historical data collected from the past successful batches, thereby resulting in simplification of monitoring charts, easy tracking of the progress in each batch run, and monitoring the occurrence of the observable upsets. Data from the commercial-scale penicillin fer-mentation process are used to develop the rolling model. Using this method, faults are detected in real time and the corresponding measurements of these faults are directly made through inspection of a few simple plots (t-chart, SPE-chart, and T2-chart). Thus, the present methodology allows the process operator to actively monitor the data from several cultivations simultaneously. 展开更多
关键词 multiway principle component analysis FERMENTATION online supervision fault diagnosis ROLLING
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Study of the toluene absorption capacity and mechanism of ionic liquids using COSMO-RS prediction and experimental verification 被引量:3
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作者 Chenglong Zhang Jin Wu +4 位作者 Ruixue Wang En Ma Liang Wu Jianfeng Bai Jingwei Wang 《Green Energy & Environment》 SCIE CSCD 2021年第3期339-349,共11页
As green solvents,ionic liquids(ILs)are quite suitable for the absorption of volatile organic compounds(VOCs)such as benzene and its homologues.However,solvent selection is the key to the VOC absorption process.In the... As green solvents,ionic liquids(ILs)are quite suitable for the absorption of volatile organic compounds(VOCs)such as benzene and its homologues.However,solvent selection is the key to the VOC absorption process.In the present study,a rapid solvent screening tool,Conductor-like Screening Model for Real Solvents(COSMO-RS),was used to predict the solubility of toluene in 816 ILs.The effects of four structure characters,namely,the type and alkyl chain length of the cations and anions on the solubility of toluene were discussed.The following conclusions were drawn from the results:(1)ILs with pyrrolidinium-based cations showed better solubility than pyridinium-and imidazoliumbased ones.(2)The solubility of toluene in PF6-based ILs increased with the increasing alkyl chain length,while its solubility in Ac-based ILs exhibited the opposite trend.(3)Toluene showed greater solubility in Cl-based ILs than those based on other anions.(4)The solubility of toluene increased with the anion alkyl chain length.Ac-based ILs were chosen as the most promising potential solvents,and further studied to determine the relationship between various interaction energy parameters and toluene solubility.The results showed that the misfit energy played a dominant role during the absorption process.Furthermore,several ILs were selected for experimental verification of the predicted solubility behavior using liquid and gaseous toluene.The results demonstrated that COSMO-RS could be used to semi-quantitatively and qualitatively predict the solubility of toluene,and this model had promising prospects in screening ILs for VOCs absorption.In summary,this study provided a fundamental basis and practical data for the control and treatment of VOCs. 展开更多
关键词 Solubility prediction COSMO-RS TOLUENE Ionic liquids
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Bio-dissolution of pyrite by Phanerochaete chrysosporium 被引量:2
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作者 Hong-ying YANG Qian LIU +2 位作者 Guo-bao CHEN Lin-lin TONG Auwalu ALI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第4期766-774,共9页
The dissolution of pyrite was studied with Phanerochaete chrysosporium(P.chrysosporium).This fungus resulted in the dissolution of 18%iron and 33%sulfur.The oxidization layer was formed on the pyrite surface,which pro... The dissolution of pyrite was studied with Phanerochaete chrysosporium(P.chrysosporium).This fungus resulted in the dissolution of 18%iron and 33%sulfur.The oxidization layer was formed on the pyrite surface,which probably consisted of iron oxide,iron oxy-hydroxide,iron sulfate,elemental sulfur and mycelia.The electrochemical characteristics of pyrite were studied in the systems without and with P.chrysosporium.P.chrysosporium could accelerate the dissolution of pyrite by decreasing pitting potential and polarization resistance plus improving polarization current,corrosion potential and corrosion current density.The dissolution of pyrite is the combined effect of enzymes,hydrogen peroxide,ferric iron and organic acids.Enzymes attack the chemical bonds by free radicals.Organic acids dissolve pyrite by acidolysis and complexolysis.Enzymes and hydrogen peroxide play an essential role in this process. 展开更多
关键词 Phanerochaete chrysosporium PYRITE bio-dissolution Carlin-type gold ores ELECTROCHEMISTRY
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Design of task priority model and algorithm for imaging observation problem 被引量:2
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作者 WU Jian LU Fang +2 位作者 ZHANG Jiawei YANG Jinghui XING Lining 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2020年第2期321-334,共14页
In the imaging observation system, imaging task scheduling is an important topic. Most scholars study the imaging task scheduling from the perspective of static priority, and only a few from the perspective of dynamic... In the imaging observation system, imaging task scheduling is an important topic. Most scholars study the imaging task scheduling from the perspective of static priority, and only a few from the perspective of dynamic priority. However,the priority of the imaging task is dynamic in actual engineering. To supplement the research on imaging observation, this paper proposes the task priority model, dynamic scheduling strategy and Heuristic algorithm. At first, this paper analyzes the relevant theoretical basis of imaging observation, decomposes the task priority into four parts, including target priority, imaging task priority, track, telemetry & control(TT&C)requirement priority and data transmission requirement priority, summarizes the attribute factors that affect the above four types of priority in detail, and designs the corresponding priority model. Then, this paper takes the emergency tasks scheduling problem as the background, proposes the dynamic scheduling strategy and heuristic algorithm. Finally, the task priority model,dynamic scheduling strategy and heuristic algorithm are verified by experiments. 展开更多
关键词 IMAGING OBSERVATION system IMAGING TASK PRIORITY TASK PRIORITY model dynamic SCHEDULING strategy HEURISTIC algorithm
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Performance of thermoelectric generator with graphene nanofluid cooling 被引量:1
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作者 邢姣娇 吴子华 +3 位作者 谢华清 王元元 李奕怀 毛建辉 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第10期276-282,共7页
Improvement of the heat transfer of the cold side is one of the approaches to enhance the performance of TEG systems. As a new type of heat transfer media, nanofluids can enhance the heat transfer performance of worki... Improvement of the heat transfer of the cold side is one of the approaches to enhance the performance of TEG systems. As a new type of heat transfer media, nanofluids can enhance the heat transfer performance of working liquid signiticantly. Based on a three-dimensional and steady-state numerical model,the heat transfer and thermoelectric conversion properties of TEG systems were studied. Graphene anoplatelet aqueous nanoftuids were used as the coolants for the cold side of the TEG system to improve the heat transfer capacity of the cold side. The results showed that the heat absorbed by the hot side, voltage, output power, and conversion efficiency of the TEG system were increased greatly by the nanoftuid coolants. The output power and the conversion efficiency using 0.1-wt% graphene nanoplatelet aqueous nanofluid as the coolant are enhanced by 26.39% and 14.74%, respectively. 展开更多
关键词 thermoelectric devices conversion efficiency cooling enhancement nanofluids
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On-line Fault Detection Using SVM-based Dynamic MPLS for Batch Processes 被引量:1
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作者 李运锋 汪志锋 袁景淇 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第6X期754-758,共5页
In this article, a nonlinear dynamic multiway partial least squares (MPLS) based on support vector ma- chines (SVM) is developed for on-line fault detection in batch processes. The approach, referred to as SVM-based D... In this article, a nonlinear dynamic multiway partial least squares (MPLS) based on support vector ma- chines (SVM) is developed for on-line fault detection in batch processes. The approach, referred to as SVM-based DMPLS, integrates the SVM with the MPLS model. Process data from normal historical batches are used to de- velop the MPLS model, and a series of single-input-single-output SVM networks are adopted to approximate nonlinear inner relationship between input and output variables. In addition, the application of a time-lagged win- dow technique not only makes the complementarities of unmeasured data of the monitored batch unnecessary, but also significantly reduces the computation and storage requirements in comparison with the traditional MPLS. The proposed approach is validated by a simulation study of on-line fault detection for a fed-batch penicillin production. 展开更多
关键词 FAULT detection multiway PARTIAL least SQUARES support vector MACHINES time-lagged WINDOW
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Scheduling and Subcontracting under Parallel Machines 被引量:2
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作者 陈荣军 唐国春 《Chinese Quarterly Journal of Mathematics》 CSCD 2012年第4期590-597,共8页
In this paper,we study a model on joint decisions of scheduling and subcontracting, in which jobs(orders) can be either processed by parallel machines at the manufacturer in-house or subcontracted to a subcontractor.T... In this paper,we study a model on joint decisions of scheduling and subcontracting, in which jobs(orders) can be either processed by parallel machines at the manufacturer in-house or subcontracted to a subcontractor.The manufacturer needs to determine which jobs should be produced in-house and which jobs should be subcontracted.Furthermore,it needs to determine a production schedule for jobs to be produced in-house.We discuss five classical scheduling objectives as production costs.For each problem with different objective functions,we give optimality conditions and propose dynamic programming algorithms. 展开更多
关键词 SCHEDULING SUBCONTRACTING dynamic programming parallel machines
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Quasi-Periodic Waves and Asymptotic Property for Boiti-Leon-Manna-Pempinelli Equation 被引量:1
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作者 罗琳 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第8期208-214,共7页
In this paper,multi-periodic (quasi-periodic) wave solutions are constructed for the Boiti-Leon-Manna-Pempinelli(BLMP) equation by using Hirota bilinear method and Riemann theta function.At the same time,weanalyze in ... In this paper,multi-periodic (quasi-periodic) wave solutions are constructed for the Boiti-Leon-Manna-Pempinelli(BLMP) equation by using Hirota bilinear method and Riemann theta function.At the same time,weanalyze in details asymptotic properties of the multi-periodic wave solutions and give their asymptotic relations betweenthe periodic wave solutions and the soliton solutions. 展开更多
关键词 BLMP equation Hirota bilinear method Riemann theta function quasi-periodic wave solutions
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PID Pan-Boolean algebra control 被引量:1
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作者 陈进 周瑾 +2 位作者 洪晓鸥 陈冠玲 汪志锋 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2009年第S1期154-157,共4页
Single input single output system was studied. With proportion, differential, integral results of deviation between given input and output as controller input, the logic rules in control process was analyzed, these lo... Single input single output system was studied. With proportion, differential, integral results of deviation between given input and output as controller input, the logic rules in control process was analyzed, these logic rule with Pan-Boolean algebra was described, therefore a PID Pan-Boolean algebra control algorithm was obtained. The simulation results indicates that the new control algorithm is more effective compared to the traditional PID algorithm, having advantages such as more than 3 adjustable parameters of controllers, better result, and so on. 展开更多
关键词 Pan-Boolean ALGEBRA CONTROL PID CONTROL
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A Bi-layer Composite Film Based on TiO_2 Hollow Spheres, P25,and Multi-walled Carbon Nanotubes for Efficient Photoanode of Dye-sensitized Solar Cell 被引量:1
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作者 Putao Zhang Zhiqiang Hu +3 位作者 Yan Wang Yiying Qin Wenqin Li Jinmin Wang 《Nano-Micro Letters》 SCIE EI CAS 2016年第3期232-239,共8页
A bi-layer photoanode for dye-sensitized solar cell(DSSC) was fabricated, in which TiO_2 hollow spheres(THSs) were designed as a scattering layer and P25/multi-walled carbon nanotubes(MWNTs) as an under-layer. The THS... A bi-layer photoanode for dye-sensitized solar cell(DSSC) was fabricated, in which TiO_2 hollow spheres(THSs) were designed as a scattering layer and P25/multi-walled carbon nanotubes(MWNTs) as an under-layer. The THSs were synthesized by a sacrifice template method and showed good light scattering ability as an over-layer of the photoanode. MWNTs were mixed with P25 to form an under-layer of the photoanode to improve the electron transmission ability of the photoanode. The power conversion efficiency of this kind of DSSC with bi-layer was enhanced to 5.13 %,which is 14.25 % higher than that of pure P25 DSSC.Graphical Abstract A bi-layer composite photoanode based on P25/MWNTs-THSs with improved light scattering and electron transmission, which will provide a new insight into fabrication and structure design of highly efficient dyesensitized solar cells. 展开更多
关键词 DYE-SENSITIZED solar cell TiO2 Hollow SPHERES Carbon nanotubes
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Working Pressure Dependence of Properties of Al2O3 Thin Films Prepared by Electron Beam Evaporation 被引量:1
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作者 占美琼 吴中林 范正修 《Chinese Physics Letters》 SCIE CAS CSCD 2008年第2期563-565,共3页
The effects of working pressure on properties of Al2O3 thin films are investigated. Transmittance of the Al2O3 thin film is measured by a Lambda 900 spectrometer. Laser-induced damage threshold (LIDT) is measured by... The effects of working pressure on properties of Al2O3 thin films are investigated. Transmittance of the Al2O3 thin film is measured by a Lambda 900 spectrometer. Laser-induced damage threshold (LIDT) is measured by a Nd:YAG laser at 355 nm with a pulse width of 7ns. Microdefects were observed under a Nomarski microscope. The samples are characterized by optical properties and defect, as well as LIDT under the 355 nm Nd:YAG laser radiation. It is found that the working pressure has fundamental effect on the LIDT. It is the absorption rather than the microdefect that plays an important role on the LIDT of Al2O3 thin film. 展开更多
关键词 PULSARS x-ray spectra relativity and gravitation REDSHIFT
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Synthesis of Nitrogen Incorporated Carbon Nanotubes with Different Diameters by Catalytic Pyrolysis of Butylamine 被引量:1
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作者 JIN Hai-ying BING Nai-ci WANG Ling-ling WANG Li-jun 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2011年第6期903-905,共3页
Bamboo-like nitrogen-doped carbon(CNx) nanotubes were synthesized by chemical vapor deposition (CVD) at a high reaction temperature of 600―900 °C. The butylamine and Fe/SBA-15 molecular sieve have been used ... Bamboo-like nitrogen-doped carbon(CNx) nanotubes were synthesized by chemical vapor deposition (CVD) at a high reaction temperature of 600―900 °C. The butylamine and Fe/SBA-15 molecular sieve have been used as precursor and catalyst, respectively. Transmission electron microscopy(TEM) and high resolution transmission electron microscopy(HRTEM) observations show that the outer diameter and wall thickness as well as the inner diameter were increased with increasing reaction temperature in a temperature range of 600―800 °C. A synergism mechanism of the growth through bulk diffusion and the competitive growth through surface diffusion functions during the synthesis of CNx nanotubes was proposed. 展开更多
关键词 Carbon nanotube Bamboo-like structure Nitrogen-doped carbon Multilayer structure
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A Novel Vertical Handoff Algorithm with Dynamic Weights in Wireless Heterogeneous Networks 被引量:2
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作者 Liu Xia Zhao Fangming Jiang Lingge 《China Communications》 SCIE CSCD 2010年第5期70-76,共7页
In order to enhance the quality of vertical handoff in an overlay wireless network, multiple attributes are taken into account when optimizing the vertical handoff decision including user-based and network-based QoS f... In order to enhance the quality of vertical handoff in an overlay wireless network, multiple attributes are taken into account when optimizing the vertical handoff decision including user-based and network-based QoS factors. In this paper, we develop a novel vertical handoff algorithm in an integrated 3G cellular and Wireless LAN networks. The proposed algorithm can adjust the weight of each QoS attribute dynamically as the networks change, trace the network condition and choose the optimal access point at transient regions. Simulation results show that this algorithm is able to provide accurate handoff decision, resulting in small unnecessary handoff numbers, good performance of throughput and handoff delay in heterogeneous environments. 展开更多
关键词 vertical handoff multiple attrbute dynamic weight heterogeneous networks
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Hydrothermal Synthesis and Crystal Structure of a Novel Binuclear Cd(Ⅱ) Coordination Polymer Based on 1,2-Benzenedicarboxylate and Imidazole 被引量:1
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作者 郭锋 于伟 张秀玲 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第9期1123-1126,共4页
The hydrothermal reaction of Cd(OAc)2.H2O with 1,2-benzenedicarboxylate (1,2-BDC), imidazole and H2O resulted in the formation of a binuclear polymeric Cd( Ⅱ ) complex {[Cd2(1,2-BDC)2(Im)4].(H2O)}n which ... The hydrothermal reaction of Cd(OAc)2.H2O with 1,2-benzenedicarboxylate (1,2-BDC), imidazole and H2O resulted in the formation of a binuclear polymeric Cd( Ⅱ ) complex {[Cd2(1,2-BDC)2(Im)4].(H2O)}n which was then characterized by elemental analyses and single-crystal X-ray diffraction analysis. The crystal is of monoclinic system, space group P21/c with a = 14.6455(3), b = 9.3530(2), c = 23.7838(5)A, β= 106.6290(10)°, Cl12H104CdgN32O36, Mr = 3373.47, V = 3121.64(11)A^3, Dc = 1.795 g/cm^3, F(000) = 1672,μ= 1.428 cm^-1 and Z = 1. The final R = 0.0316 and wR = 0.0687 for 5045 reflections with I 〉 2σ(I). In the title complex, the two Cd( Ⅱ) ions are in different coordination environments with distorted octahedral and pengonal bipyramidal geometries, respectively. Two Cd polyhedra are linked together through one μ2-η^1:η^1 and one μ2-η^1:η^1 carboxylate groups from different 1,2-BDC ligands, giving rise to a binuclear Cd( Ⅱ ) cluster, and such clusters are connected by bridged 1,2-BDC ligands to form a 2-D structure along the c axis. The inter- and intermolecular hydrogen bonds further connect the 2-D structures into a 3-D supramolecular network. 展开更多
关键词 cadmium complex crystal structure 1 2-benzenedicarboxylate IMIDAZOLE
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