The hydrogen reduction of Panzhihua ilmenite concentrate in the temperature range of 900?1050 °C was systematicallyinvestigated by thermogravimetric analysis (TG), X-ray diffraction (XRD) and scanning electron mi...The hydrogen reduction of Panzhihua ilmenite concentrate in the temperature range of 900?1050 °C was systematicallyinvestigated by thermogravimetric analysis (TG), X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. It wasshown that the products of the Panzhihua ilmenite reduced at 900 °C were metallic iron and rutile. Above 1000 °C, ferrouspseudobrookite solid solution was generated. During the reduction process, element Mg gradually concentrated to form Mg-rich zonewhich can influence the metallization process. The reduction reaction proceeded topochemically and its related reduction kineticswere also discussed. The kinetics of the reduction indicated that the rate-controlling step was the diffusion process. The apparentactivation energy of the hydrogen reduction of Panzhihua ilmenite was calculated to be 117.56 kJ/mol, which was larger than that ofsynthetic ilmenite under the same reduction condition.展开更多
The broadening effect of stacking disorder in hexagonal graphite is found experimentally by XRD to be identical to that of stacking faults in hexagonal-closed-packing(HCP) structure,which has obvious selective broaden...The broadening effect of stacking disorder in hexagonal graphite is found experimentally by XRD to be identical to that of stacking faults in hexagonal-closed-packing(HCP) structure,which has obvious selective broadening effect.The Langford's method for dealing with the twofold broadening effects of the crystallite-faults in hexagonal ZnO has been extended in this paper,and then applied to the deter-mination of stacking disorder in 2H-graphite,which indicates that our extension method is convenient to both the experiments and data process,and may be generalized further.Two stacking disorder model in 2H-graphite and data processing method have been proposed in this study.The two disorder degrees of PAB and PABC can be computed when the two reliable FWHMs of 101 and 102 diffraction peaks were obtained.展开更多
An ambient pressure-induced calcination process was proposed to prepare g-C3 N4 with different structures.The porcelain boat with designed porosity is used to control the ambient pressure to change the diffusion behav...An ambient pressure-induced calcination process was proposed to prepare g-C3 N4 with different structures.The porcelain boat with designed porosity is used to control the ambient pressure to change the diffusion behavior of the reaction molecules,thereby controlling the layer structure and rich pyridinic N content of g-C3 N4,thus renders superior lithium storage performance.展开更多
基金Project(2014CB643403)supported by the National Basic Research Program of ChinaProjects(51225401,51304132,51574164)supported by the National Natural Science Foundation of China+1 种基金Project(14JC1491400)supported by the Science and Technology Commissions of Shanghai Municipality,ChinaProject(2013GZ0146)supported by the Sichuan Province,China
文摘The hydrogen reduction of Panzhihua ilmenite concentrate in the temperature range of 900?1050 °C was systematicallyinvestigated by thermogravimetric analysis (TG), X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. It wasshown that the products of the Panzhihua ilmenite reduced at 900 °C were metallic iron and rutile. Above 1000 °C, ferrouspseudobrookite solid solution was generated. During the reduction process, element Mg gradually concentrated to form Mg-rich zonewhich can influence the metallization process. The reduction reaction proceeded topochemically and its related reduction kineticswere also discussed. The kinetics of the reduction indicated that the rate-controlling step was the diffusion process. The apparentactivation energy of the hydrogen reduction of Panzhihua ilmenite was calculated to be 117.56 kJ/mol, which was larger than that ofsynthetic ilmenite under the same reduction condition.
基金Supported by the National Natural Science Foundation of China (Grant No. 20773157)
文摘The broadening effect of stacking disorder in hexagonal graphite is found experimentally by XRD to be identical to that of stacking faults in hexagonal-closed-packing(HCP) structure,which has obvious selective broadening effect.The Langford's method for dealing with the twofold broadening effects of the crystallite-faults in hexagonal ZnO has been extended in this paper,and then applied to the deter-mination of stacking disorder in 2H-graphite,which indicates that our extension method is convenient to both the experiments and data process,and may be generalized further.Two stacking disorder model in 2H-graphite and data processing method have been proposed in this study.The two disorder degrees of PAB and PABC can be computed when the two reliable FWHMs of 101 and 102 diffraction peaks were obtained.
基金financial support from National Natural Science Foundation of China(Nos.51702046,51772050 and 51822202)the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University。
文摘An ambient pressure-induced calcination process was proposed to prepare g-C3 N4 with different structures.The porcelain boat with designed porosity is used to control the ambient pressure to change the diffusion behavior of the reaction molecules,thereby controlling the layer structure and rich pyridinic N content of g-C3 N4,thus renders superior lithium storage performance.
