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Application of multi-algorithm ensemble methods in high-dimensional and small-sample data of geotechnical engineering:A case study of swelling pressure of expansive soils
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作者 Chao Li Lei Wang +1 位作者 Jie Li Yang Chen 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第5期1896-1917,共22页
Geotechnical engineering data are usually small-sample and high-dimensional,which brings a lot of challenges in predictive modeling.This paper uses a typical high-dimensional and small-sample swell pressure(P_(s))data... Geotechnical engineering data are usually small-sample and high-dimensional,which brings a lot of challenges in predictive modeling.This paper uses a typical high-dimensional and small-sample swell pressure(P_(s))dataset to explore the possibility of using multi-algorithm hybrid ensemble and dimensionality reduction methods to mitigate the uncertainty of soil parameter prediction.Based on six machine learning(ML)algorithms,the base learner pool is constructed,and four ensemble methods,Stacking(SG),Blending(BG),Voting regression(VR),and Feature weight linear stacking(FWL),are used for the multi-algorithm ensemble.Furthermore,the importance of permutation is used for feature dimensionality reduction to mitigate the impact of weakly correlated variables on predictive modeling.The results show that the proposed methods are superior to traditional prediction models and base ML models,where FWL is more suitable for modeling with small-sample datasets,and dimensionality reduction can simplify the data structure and reduce the adverse impact of the small-sample effect,which points the way to feature selection for predictive modeling.Based on the ensemble methods,the feature importance of the five primary factors affecting P_(s) is the maximum dry density(31.145%),clay fraction(15.876%),swell percent(15.289%),plasticity index(14%),and optimum moisture content(13.69%),the influence of input parameters on P_(s) is also investigated,in line with the findings of the existing literature. 展开更多
关键词 Expansive soils Swelling pressure Machine learning(ML) Multi-algorithm ensemble Sensitivity analysis
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Grain boundary engineering for enhancing intergranular damage resistance of ferritic/martensitic steel P92
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作者 Lei Peng Shang-Ming Chen +6 位作者 Jing-Yi Shi Yong-Jie Sun Yi-Fei Liu Yin-Zhong Shen Hong-Ya He Hui-Juan Wang Jie Tian 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期186-199,共14页
Ferritic/martensitic(F/M)steel is widely used as a structural material in thermal and nuclear power plants.However,it is susceptible to intergranular damage,which is a critical issue,under service conditions.In this s... Ferritic/martensitic(F/M)steel is widely used as a structural material in thermal and nuclear power plants.However,it is susceptible to intergranular damage,which is a critical issue,under service conditions.In this study,to improve the resistance to intergranular damage of F/M steel,a thermomechanical process(TMP)was employed to achieve a grain boundary engineering(GBE)microstructure in F/M steel P92.The TMP,including cold-rolling thickness reduction of 6%,9%,and 12%,followed by austenitization at 1323 K for 40 min and tempering at 1053 K for 45 min,was applied to the as-received(AR)P92 steel.The prior austenite grain(PAG)size,prior austenite grain boundary character distribution(GBCD),and connectivity of prior austenite grain boundaries(PAGBs)were investigated.Compared to the AR specimen,the PAG size did not change significantly.The fraction of coincident site lattice boundaries(CSLBs,3≤Σ≤29)and Σ3^(n) boundaries along PAGBs decreased with increasing reduction ratio because the recrystallization fraction increased with increasing reduction ratio.The PAGB connectivity of the 6%deformed specimen slightly deteriorated compared with that of the AR specimen.Moreover,potentiodynamic polarization studies revealed that the intergranular damage resistance of the studied steel could be improved by increasing the fraction of CSLBs along the PAGBs,indicating that the TMP,which involves low deformation,could enhance the intergranular damage resistance. 展开更多
关键词 Grain boundary engineering Ferritic/martensitic steel Prior austenite grain boundary character distribution Grain boundary connectivity Intergranular damage resistance
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THREE KINDS OF DENTABILITIES IN BANACH SPACES AND THEIR APPLICATIONS
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作者 张子厚 周晶 《Acta Mathematica Scientia》 SCIE CSCD 2024年第2期445-454,共10页
In this paper,we study some dentabilities in Banach spaces which are closely related to the famous Radon-Nikodym property.We introduce the concepts of the weak^(*)-weak denting point and the weak^(*)-weak^(*)denting p... In this paper,we study some dentabilities in Banach spaces which are closely related to the famous Radon-Nikodym property.We introduce the concepts of the weak^(*)-weak denting point and the weak^(*)-weak^(*)denting point of a set.These are the generalizations of the weak^(*)denting point of a set in a dual Banach space.By use of the weak^(*)-weak denting point,we characterize the very smooth space,the point of weak^(*)-weak continuity,and the extreme point of a unit ball in a dual Banach space.Meanwhile,we also characterize an approximatively weak compact Chebyshev set in dual Banach spaces.Moreover,we define the nearly weak dentability in Banach spaces,which is a generalization of near dentability.We prove the necessary and sufficient conditions of the reflexivity by nearly weak dentability.We also obtain that nearly weak dentability is equivalent to both the approximatively weak compactness of Banach spaces and the w-strong proximinality of every closed convex subset of Banach spaces. 展开更多
关键词 weak^(*)-weak denting point nearly weak dentability very smooth space point of weak^(*)-weak continuity extreme point approximatively weak compactness w-strong proximinality REFLEXIVITY
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Enhancing Relational Triple Extraction in Specific Domains:Semantic Enhancement and Synergy of Large Language Models and Small Pre-Trained Language Models
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作者 Jiakai Li Jianpeng Hu Geng Zhang 《Computers, Materials & Continua》 SCIE EI 2024年第5期2481-2503,共23页
In the process of constructing domain-specific knowledge graphs,the task of relational triple extraction plays a critical role in transforming unstructured text into structured information.Existing relational triple e... In the process of constructing domain-specific knowledge graphs,the task of relational triple extraction plays a critical role in transforming unstructured text into structured information.Existing relational triple extraction models facemultiple challenges when processing domain-specific data,including insufficient utilization of semantic interaction information between entities and relations,difficulties in handling challenging samples,and the scarcity of domain-specific datasets.To address these issues,our study introduces three innovative components:Relation semantic enhancement,data augmentation,and a voting strategy,all designed to significantly improve the model’s performance in tackling domain-specific relational triple extraction tasks.We first propose an innovative attention interaction module.This method significantly enhances the semantic interaction capabilities between entities and relations by integrating semantic information fromrelation labels.Second,we propose a voting strategy that effectively combines the strengths of large languagemodels(LLMs)and fine-tuned small pre-trained language models(SLMs)to reevaluate challenging samples,thereby improving the model’s adaptability in specific domains.Additionally,we explore the use of LLMs for data augmentation,aiming to generate domain-specific datasets to alleviate the scarcity of domain data.Experiments conducted on three domain-specific datasets demonstrate that our model outperforms existing comparative models in several aspects,with F1 scores exceeding the State of the Art models by 2%,1.6%,and 0.6%,respectively,validating the effectiveness and generalizability of our approach. 展开更多
关键词 Relational triple extraction semantic interaction large language models data augmentation specific domains
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Effects of cross-Kerr coupling on transmission spectrum of double-cavity optomechanical system
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作者 陈立滕 秦立国 +3 位作者 田立君 黄接辉 周南润 龚尚庆 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期390-396,共7页
We theoretically study the transmission spectrum of the cavity field in a double-cavity optomechanical system with cross-Kerr(CK) effect. The system consists of two tunneling coupling optomechanical cavities with a me... We theoretically study the transmission spectrum of the cavity field in a double-cavity optomechanical system with cross-Kerr(CK) effect. The system consists of two tunneling coupling optomechanical cavities with a mechanical resonator as a coupling interface. By doping CK medium into the mechanical resonator, CK couplings between the cavity fields and the mechanical resonator are introduced. We investigate the effects of CK coupling strength on the transmission spectrum of the cavity field, including the transmission rate, nonreciprocity and four-wave mixing(FWM). We find that the transmission spectrum of the probe field can show two obvious transparent windows, which can be widened by increasing the CK coupling strength. For the transmission between the two cavity fields, the perfect nonreciprocity and reciprocity are present and modulated by CK coupling and phase difference between two effective optomechanical couplings. In addition, the effects of the optomechanical and CK couplings on FWM show that the single peak of FWM is split into three symmetrical peaks due to the introduction of the CK effect. 展开更多
关键词 cross-Kerr transmission rate NONRECIPROCITY four-wave mixing
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A Coordinate-Free Approach to the Design of Generalized Griffis-Duffy Platforms
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作者 Chengwei Shen Xu Pei +1 位作者 Lubin Hang Jingjun Yu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第3期95-103,共9页
Architectural singularity belongs to the Type II singularity,in which a parallel manipulator(PM)gains one or more degrees of freedom and becomes uncontrollable.PMs remaining permanently in a singularity are beneficial... Architectural singularity belongs to the Type II singularity,in which a parallel manipulator(PM)gains one or more degrees of freedom and becomes uncontrollable.PMs remaining permanently in a singularity are beneficial for linearto-rotary motion conversion.Griffis-Duffy(GD)platform is a mobile structure admitting a Bricard motion.In this paper,we present a coordinate-free approach to the design of generalized GD platforms,which consists in determining the shape and attachment of both the moving platform and the fixed base.The generalized GD platform is treated as a combination of six coaxial single-loop mechanisms under the same constraints.Owing to the inversion,hidden in the geometric structure of these single-loop mechanisms,the mapping from a line to a circle establishes the geometric transformation between the fixed base and the moving platform based on the center of inversion,and describes the shape and attachment of the generalized GD platform.Moreover,the center of inversion not only identifies the location of rotation axis,but also affects the shape of the platform mechanism.A graphical construction of generalized GD platforms using inversion,proposed in the paper,provides geometrically feasible solutions of the manipulator design for the requirement of the location of rotation axis. 展开更多
关键词 Generalized Griffis-Duffy platforms SELF-MOTION INVERSION Coordinate-free determination Manipulator design
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The study of intelligent algorithm in particle identification of heavy-ion collisions at low and intermediate energies
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作者 Gao-Yi Cheng Qian-Min Su +1 位作者 Xi-Guang Cao Guo-Qiang Zhang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期170-182,共13页
Traditional particle identification methods face timeconsuming,experience-dependent,and poor repeatability challenges in heavy-ion collisions at low and intermediate energies.Researchers urgently need solutions to the... Traditional particle identification methods face timeconsuming,experience-dependent,and poor repeatability challenges in heavy-ion collisions at low and intermediate energies.Researchers urgently need solutions to the dilemma of traditional particle identification methods.This study explores the possibility of applying intelligent learning algorithms to the particle identification of heavy-ion collisions at low and intermediate energies.Multiple intelligent algorithms,including XgBoost and TabNet,were selected to test datasets from the neutron ion multi-detector for reaction-oriented dynamics(NIMROD-ISiS)and Geant4 simulation.Tree-based machine learning algorithms and deep learning algorithms e.g.TabNet show excellent performance and generalization ability.Adding additional data features besides energy deposition can improve the algorithm’s performance when the data distribution is nonuniform.Intelligent learning algorithms can be applied to solve the particle identification problem in heavy-ion collisions at low and intermediate energies. 展开更多
关键词 Heavy-ion collisions at low and intermediate energies Machine learning Ensemble learning algorithm Particle identification Data imbalance
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Aging Characteristics of Lithium-Ion Battery Under Fast Charging Based on Electrochemical-thermalmechanical Coupling Model
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作者 Dong-Xu Zuo Pei-Chao Li 《电化学(中英文)》 CAS 北大核心 2024年第9期10-24,共15页
The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multip... The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures. 展开更多
关键词 Lithium-ion battery Aging characteristics Fast charging Electrochemical-thermal-mechanical coupling model
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A Study of the Effect of the Miller Cycle on the Combustion of a Supercharged Marine Diesel Engine
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作者 Lingjie Zhao Cong Li 《Energy Engineering》 EI 2024年第5期1363-1380,共18页
The Miller cycle is a program that effectively reduces NOx emissions from marine diesel engines by lowering the maximum combustion temperature in the cylinder,thereby reducing NOx emissions.To effectively investigate ... The Miller cycle is a program that effectively reduces NOx emissions from marine diesel engines by lowering the maximum combustion temperature in the cylinder,thereby reducing NOx emissions.To effectively investigate the impact of Miller cycle optimum combustion performance and emission capability under high load conditions,this study will perform a one-dimensional simulation of the performance of a marine diesel engine,as well as a threedimensional simulation of the combustion in the cylinder.A 6-cylinder four-stroke single-stage supercharged diesel engine is taken as the research object.The chassis dynamometer and other related equipment are used to build the test system,carry out the diesel engine bench test,and collect experimental data.The simulation results are compared with the test results,and the error is less than 5%.In this study,the authors will use simulation software to simulate several Miller cycle scenarios designed for early inlet valve closure and analyze the impact of the Miller cycle on combustion and emissions at 100%load conditions.By comparing the flow field distribution of the engine at 1500 r/min condition,it was found that proper EIVC can prolong the ignition latency period and homogeneous fuel-air mixture combustion acceleration,but it can reduce pressure and temperature within the piston chamber and NOx emission.However,the Miller cycle reduces end-of-compression temperatures,which increases combustion duration and exhaust temperatures,making it difficult to improve fuel economy at the optimum fuel consumption point,and closing the intake valves prematurely leads to excessive fuel expenditure.Furthermore,temperature and heat release rate within the piston chamber,NOx,and SOOT generation were significantly enhanced. 展开更多
关键词 Miller cycle EIVC COMBUSTION NOx emissions marine diesel
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Effect of antioxidants on the efficiency of jet milling and the powder characteristics of Sm2Co17 permanent magnets
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作者 Da-Shuai Xu Lei Liu +6 位作者 Jian-Hui Yuan Bo Zhou Chuang-Hui Dong Feng-Qing Wang Yong Ding Ying-Li Sun A-Ru Yan 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期615-620,共6页
This study investigated the effect of antioxidants on the grinding efficiency,magnetic powder characteristics,microstructure,and magnetic properties of 2:17 type SmCo permanent magnet materials.The results show that a... This study investigated the effect of antioxidants on the grinding efficiency,magnetic powder characteristics,microstructure,and magnetic properties of 2:17 type SmCo permanent magnet materials.The results show that adding antioxidants helps improve the dispersion among magnetic powders,leading to a 33.3%decrease in jet milling time and a 15.8%increase in magnet powder production yield.Additionally,adding antioxidants enhances the oxidation resistance of the magnetic powders.After being stored in a constant temperature air environment at 25C for 48 h,the O content in the powder decreased by 33%compared to samples without antioxidants.While in the magnet body,the O content decreased from 0.21 wt.%to 0.14 wt.%,which helps increase the effective Sm content and domain wall pinning uniformity in the magnet.Excellent magnetic properties were obtained in the magnet with added antioxidants:B_(r)=11.6 kGs,SF=79.6%,H_(cj)=16.8 kOe,and(BH)_(max)=32.5 MGOe. 展开更多
关键词 ANTIOXIDANT SmCo permanent magnet oxidation resistance grinding efficiency
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Simulation Study of Diesel Spray Tilt Angle and Ammonia Energy Ratio Effect on Ammonia-Diesel Dual-Fuel Engine Performance
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作者 Zhifeng Zhao Xuelong Miao +4 位作者 Xu Chen Jinbao Zheng Yage Di Zhenjie Bao Zhuo Yang 《Energy Engineering》 EI 2024年第9期2603-2620,共18页
Ammonia-diesel dual fuel(ADDF)engines for transportation applications are an important way to reduce carbon emissions.In order to achieve better combustion of ammonia in diesel engines.A small-bore single-cylinder eng... Ammonia-diesel dual fuel(ADDF)engines for transportation applications are an important way to reduce carbon emissions.In order to achieve better combustion of ammonia in diesel engines.A small-bore single-cylinder engine was converted into an ADDF engine with the help of mature computational fluid dynamics(CFD)simulation software to investigate the performance of an engine with a high ammonia energy ratio(AER),and to study the effect of spray tilt angle on ADDF engine.The results showed that the increase in AER reduced nitric oxide(NO)and nitrogen dioxide(NO2)emissions but increased nitrous oxide(N2O)and unburned ammonia emissions.AER in the range of 50%-70%achieved lower greenhouse gases(GHG)emissions than the pure diesel mode.Relative to the pure diesel mode,when the AER was 60%,the indicated thermal efficiency(ITE)was increased by 0.2%and the GHG emissions were decreased by 22.3%,but carbon monoxide(CO)and Hydrocarbon(HC)emissions were increased.Increasing the in-cylinder combustion temperature or high-temperature region range of the ADDF engine could reduce GHG emissions.At an AER of 60%,an increase in the spray tilt angle helped the ammonia combustion in the residual gap to reduce the unburned ammonia emissions.Compared to the pure diesel mode with a spray tilt angle of 75°,an AER of 60%with a spray tilt angle of 77.5°improved the ITE by 1.5%,and reduced theGHGemissions by 25.7%.Adjusting the spray tilt angle of theADDFengine also reducedCOandHCemissions.This is an effective way to improve ADDF engine performance by adjusting the spray tilt angle. 展开更多
关键词 Ammonia-diesel engine ammonia energy ratio greenhouse gases carbon-free fuel
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A novel DPSS filter optimization scheme to reduce the intrinsic interference of FBMC-QAM systems
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作者 董琪阳 MA Tianming +1 位作者 JIN Jie WU Zhong 《High Technology Letters》 EI CAS 2024年第1期68-74,共7页
In order to reduce the intrinsic interference of the filter bank multicarrier-quadrature amplitude modulation(FBMC-QAM)system,a novel filter optimization scheme based on discrete prolate spheroidal sequences(DPSS)is p... In order to reduce the intrinsic interference of the filter bank multicarrier-quadrature amplitude modulation(FBMC-QAM)system,a novel filter optimization scheme based on discrete prolate spheroidal sequences(DPSS)is proposed.Firstly,a prototype filter function based on DPSS is designed,since the eigenvalue can be used as an indicator of the energy concentration of DPSS,so a threshold is set,and the sequence with the most concentrated energy is selected under the threshold,that is,the sequence with the eigenvalue higher than the threshold,and the prototype filter function is rewritten as a weighted sum function of multiple eigenvectors.Under the energy constraints of the filter,the relationship between the eigenvectors and the intrinsic interference function is established,and the function problem is transformed into an optimization problem for the weighted coefficients.Through the interior point method,the most suitable weight is found to obtain the minimum intrinsic interference result.Theoretical analysis and simulation results show that compared with the prototype filters such as Type1 and CaseC,the DPSS filter applying the proposed optimization algorithm can effectively suppress the intrinsic interference of the system and obtain a better bit error rate(BER)performance. 展开更多
关键词 filter bank multicarrier-quadrature amplitude modulation(FBMC-QAM) intrinsic interference discrete prolate spheroidal sequences(DPSS) interior point method
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Differential pressure difference based altitude control of a stratospheric satellite
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作者 陈丽 WANG Xiaoliang 《High Technology Letters》 EI CAS 2024年第1期1-12,共12页
An autonomous altitude adjustment system for a stratospheric satellite(StratoSat)platform is proposed.This platform consists of a helium balloon,a ballonet,and a two-way blower.The helium balloon generates lift to bal... An autonomous altitude adjustment system for a stratospheric satellite(StratoSat)platform is proposed.This platform consists of a helium balloon,a ballonet,and a two-way blower.The helium balloon generates lift to balance the platform gravity.The two-way blower inflates and deflates the ballonet to regulate the buoyancy.Altitude adjustment is achieved by tracking the differential pressure difference(DPD),and a threshold switching strategy is used to achieve blower flow control.The vertical acceleration regulation ability is decided not only by the blower flow rate,but also by the designed margin of pressure difference(MPD).Pressure difference is a slow-varying variable compared with altitude,and it is adopted as the control variable.The response speed of the actuator to disturbance can be delayed,and the overshoot caused by the large inertia of the platform is inhibited.This method can maintain a high tracking accuracy and reduce the complexity of model calculation,thus improving the robustness of controller design. 展开更多
关键词 stratospheric satellite(StratoSat) differential pressure difference(DPD) altitude adjustment threshold switching strategy margin of pressure difference(MPD)
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Review of Fabric Defect Detection Based on Computer Vision 被引量:3
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作者 朱润虎 辛斌杰 +1 位作者 邓娜 范明珠 《Journal of Donghua University(English Edition)》 CAS 2023年第1期18-26,共9页
In textile inspection field,the fabric defect refers to the destruction of the texture structure on the fabric surface.The technology of computer vision makes it possible to detect defects automatically.Firstly,the ov... In textile inspection field,the fabric defect refers to the destruction of the texture structure on the fabric surface.The technology of computer vision makes it possible to detect defects automatically.Firstly,the overall structure of the fabric defect detection system is introduced and some mature detection systems are studied.Then the fabric detection methods are summarized,including structural methods,statistical methods,frequency domain methods,model methods and deep learning methods.In addition,the evaluation criteria of automatic detection algorithms are discussed and the characteristics of various algorithms are analyzed.Finally,the research status of this field is discussed,and the future development trend is predicted. 展开更多
关键词 computer vision fabric defect detection algorithm evaluation textile inspection
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Electrospinning organic solvent resistant preoxidized poly(acrylonitrile)nanofiber membrane and its properties 被引量:2
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作者 Zhiwei Du Jinxue Cheng +2 位作者 Qinglin Huang Mingxing Chen Changfa Xiao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第1期289-299,共11页
A high performance preoxidized poly(acrylonitrile)(O-PAN)nanofiber membrane with excellent solvent resistance,thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane.... A high performance preoxidized poly(acrylonitrile)(O-PAN)nanofiber membrane with excellent solvent resistance,thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane.The performance of resultant O-PAN nanofiber membrane was optimized by altering the PAN concentration and preoxidation temperature.The results showed that the O-PAN nanofiber membrane which made from PAN concentration of 14%(mass)and preoxidation temperature of 250.0℃ have a more optimal comprehensive performance.In the long-term separation test of SiO2 particle(1 μm)in DMAc suspension,the permeate flux of O-PAN nanofiber membrane stabilized at 227.91 L·m^(-2)·h^(-1)(25℃,0.05 MPa)while the SiO2 rejection above 99.6%,which showed excellent solvent resistance and separation performance.In order to further explore the application of the O-PAN nanofiber membrane,the OPAN nanofiber membrane was treated with fluoride and used in oil/water separation process.The O-PAN nanofiber membrane after hydrophobic treatment showed excellent hydrophobicity and good oil/water separation performance with the permeate flux about 969.59 L·m^(-2)·h^(-1)while the separation efficiency above 96.1%.The O-PAN nanofiber membrane exhibited a potential application prospect in harsh environment separation. 展开更多
关键词 Poly(acrylonitrile)(PAN) PREOXIDATION Nanofiber membrane Solvent resistance Oil/water separation
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Synergistic double-atom catalysts of metal-boron anchored on g-C_(2)N for electrochemical nitrogen reduction:Mechanistic insight and catalyst screening 被引量:1
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作者 Yang Li Wei An 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第5期350-360,I0009,共12页
The rational design of a novel catalytic center with a sound basis remains both challenging and rewarding for the electrochemical reduction of N2(e NRR),which has provided a feasible route for achieving clean and sust... The rational design of a novel catalytic center with a sound basis remains both challenging and rewarding for the electrochemical reduction of N2(e NRR),which has provided a feasible route for achieving clean and sustainable NH3production under ambient conditions.Herein,using density functional theory calculations,we demonstrate that hybrid metal(M)-boron(B)double-atom catalysts(DACs)embedded in gC_(2)N substrate(M-B@C_(2)N,M=3d,4d and 5d transition metals)can achieve both high catalytic activity and high selectivity in e NRR.The proposed M-B@C_(2)N DACs have exhibited impressive feasibility and stability thanks to the resilient and robust C_(2)N substrate with abundant pyridinic N atoms distributed among right-sized pore structures.Our results reveal that like the metal center,the embedded B atom can actively involve in N≡N bond activation viaπ*-backdonation mechanism concomitant with the substantial charge transfer to adsorbed*N2,leading to sizable NAN bond elongation.Accordingly,both adsorption energy and NAN bond length of*N2can be employed as catalytic descriptors for predicting e NRR activity in terms of the limiting potentials(UL).Using high-throughput screening method,we found that six M-B@C_(2)N candidates have stood out as the outstanding electrocatalysts for driving e NRR,namely,M=Ti(UL=0 V),Mo(UL=0 V),Nb(UL=-0.04 V),W(UL=-0.23 V),Zr(UL=-0.26 V),V(UL=-0.28 V).The underlying origin is attributed to the balanced and constrained N-affinity of M-B dual site working in synergy,which can thus be used as one important guide of catalyst design. 展开更多
关键词 ELECTROCATALYSIS N_(2)reduction Double-atom catalyst Synergistic effect DFT
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Two-dimensional plane strain consolidation of unsaturated soils considering the depth-dependent stress 被引量:1
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作者 Lei Wang Sidong Shen +2 位作者 Tianyi Li Minjie Wen Annan Zhou 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第6期1603-1614,共12页
In practical engineering,the total vertical stress in the soil layer is not constant due to stress diffusion,and varies with time and depth.Therefore,the purpose of this paper is to investigate the effect of stress di... In practical engineering,the total vertical stress in the soil layer is not constant due to stress diffusion,and varies with time and depth.Therefore,the purpose of this paper is to investigate the effect of stress diffusion on the two-dimensional(2D)plane strain consolidation properties of unsaturated soils when the stress varies with time and depth.A series of semi-analytical solutions in terms of excess pore air and water pressures and settlement for 2D plane strain consolidation of unsaturated soils can be derived with the joint use of Laplace transform and Fourier sine series expansion.Then,the inverse Laplace transform of the semi-analytical solution is given in the time domain using a self-programmed code based on Crump’s method.The reliability of the obtained solutions is proved by the degeneration.Finally,the 2D plots of excess pore pressures and the curves of settlement varying with time,considering different physical parameters of unsaturated soil stratum and depth-dependent stress,are depicted and analyzed to study the 2D plane strain consolidation properties of unsaturated soils subjected to the depthdependent stress. 展开更多
关键词 Semi-analytical solutions Two-dimensional(2D)plane strain CONSOLIDATION Unsaturated soils Depth-dependent stress Laplace transform
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Influence of element substitutions on poisoning behavior of ZrV_(2)alloy:theoretical and experimental investigations 被引量:1
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作者 Shuang Yang Run-Jie Fang +5 位作者 Guo Yang Li-Jun Lv Xing-Bo Han Wei Liu Xiu-Jie He Peng-Fei Zhu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第7期253-266,共14页
A ZrV_(2)alloy is typically susceptible to poisoning by impurity gases,which causes a considerable reduction in the hydrogen storage properties of the alloy.In this study,the adsorption characteristics of oxygen on Zr... A ZrV_(2)alloy is typically susceptible to poisoning by impurity gases,which causes a considerable reduction in the hydrogen storage properties of the alloy.In this study,the adsorption characteristics of oxygen on ZrV_(2)surfaces doped with Hf,Ti,and Pd are investigated,and the effect of oxygen on the hydrogen storage performance of the alloy was discussed.Subsequently,the adsorption energy,bond-length change,density of states,and differential charge density of the alloy before and after doping are analyzed using the first-principles method.The theoretical results show that Ti doping has a limited effect on the adsorption of oxygen atoms on the ZrV_(2)surface,whereas Hf doping decreases the adsorption energy of oxygen on the ZrV_(2)surface.Oxygen atoms are more difficult to adsorb at most adsorption sites on Pd-substituting surfaces,which indicates that Pd has the best anti-poisoning properties,followed by Hf.The analysis of the differential charge density and partial density of states show that the electron interaction between the oxygen atom and surface atom of the alloys is weakened,and the total energy is reduced after Hf and Pd doping.Based on theoretical calculations,the hydrogen absorption kinetics of ZrV_(2),Zr_(0.9)Hf_(0.1)V_(2),and Zr(V_(0.9)Pd_(0.1))_(2) alloys are studied in a hydrogen-oxygen mixture of 0.5 vol%O_(2) at 25℃.The experimental results show that the hydrogen storage capacities of ZrV_(2),Zr_(0.9)Hf_(0.1)V_(2),and Zr(V_(0.9)Pd_(0.1))_(2) decrease to 19%,69%,and 80%of their original values,respectively.The order of alloy resistance to 0.5 vol%O_(2) poisoning is Zr(V_(0.9)Pd_(0.1))_(2)>Zr_(0.9)Hf_(0.1)V_(2)>ZrV_(2).Pd retains its original hydrogen absorption performance to a greater extent than undoped surfaces,and it has the strongest resistance to poisoning,which is consistent with previous theoretical calculations. 展开更多
关键词 Hydrogen storage ZrV_(2) FIRST-PRINCIPLES Poisoning effect
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Appeal of 3 + 4 Program: Good Students are Few but Growing at Secondary Vocational Schools in Shanghai
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作者 XU Hui XIE Peng-yang 《Sino-US English Teaching》 2018年第6期278-283,共6页
Secondary vocational education in Shanghai continues to experiment in an attempt to find ways to solve the decline of student enrollment and adjust to rapidly changing social and economic environments. The 3 + 4 Pilo... Secondary vocational education in Shanghai continues to experiment in an attempt to find ways to solve the decline of student enrollment and adjust to rapidly changing social and economic environments. The 3 + 4 Pilot Program (three-year secondary vocational education and four-year undergraduate education) has been under experiment since 2014. It has attracted more and more academically good junior middle school graduates to secondary vocational schools with the national and local favorable policies and laws. Except the three-year’s hand-on practice, what appeals most to the junior middle school graduates is the academic transfer under the Program, a breakthrough in history of vocation education in China. However, only initiating a new program is not enough. Shanghai government should map out a long-term plan to set up promotion to increase the public awareness to change the long prevailing outdated ideology in order to add more to its appeal of the Program. There is still much work to be done before expanding the scope of the Program. 展开更多
关键词 APPEAL Pilot Program student enrollment secondary vocational schools
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Research on the moderation of endowment insurance in Shanghai
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作者 ZHAO Bowen 《International English Education Research》 2019年第1期51-53,共3页
Old-age insurance is related to the quality of life of the elderly population in a country or region after retirement, the impact of economic crisis and the aggravation of the population aging crisis, so that the appr... Old-age insurance is related to the quality of life of the elderly population in a country or region after retirement, the impact of economic crisis and the aggravation of the population aging crisis, so that the appropriateness of the level of old-age insurance has been paid more and more attention by the society. At present, the academic research on the appropriate level of endowment insurance is still at an exploratory stage. Most scholars mainly study the endowment insurance from the qualitative point of view, but lack quantitative analysis of the level of endowment insurance. Pension expenditure must be in line with the level of national productivity development and various aspects of affordability. Shanghai is the fastest growing city in China and the earliest city in China to enter an aging society. It is of typical significance to study the appropriateness of the endowment insurance level in Shanghai. 展开更多
关键词 COMPARATIVE analysis of SOCIAL ENDOWMENT INSURANCE in SHANGHAI
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