Flexible supercapacitors are promising energy storage devices in wearable smart electronics. Exploring cost-efficient electrodes with high capacitance would promote the wide-scale application of such capacitors. Herei...Flexible supercapacitors are promising energy storage devices in wearable smart electronics. Exploring cost-efficient electrodes with high capacitance would promote the wide-scale application of such capacitors. Herein, in order to explore a methodology for preparing low cost, flexible, tough, and up-scalable supercapacitor electrodes, silk textile is directly carbonized to make a conductive free-standing textile substrate. Through mildly baking the surfactant-free TiCTflakes suspension loaded on the carbonized silk cloth, a uniform and adhesive coating consisting of nanometer-thick TiCTflakes is well established on the conductive fabric support, forming a MXene-coated flexible textile electrode. The fabricated electrode exhibits a high areal capacitance of 362 m F/cm~2 with excellent cyclability and flexibility. Moreover,capacitance changes neglegibly under the bending deformation mode. This study elucidates the feasibility of using silk-derived carbon cloth from biomss for MXene-based flexible supercapacitor.展开更多
The application of wavy structures in stretchable electrochemical energy storage devices is reviewed. First, the mechanical anaJysis of wavy structures, specific to flexible electronics, is introduced. Second, stretch...The application of wavy structures in stretchable electrochemical energy storage devices is reviewed. First, the mechanical anaJysis of wavy structures, specific to flexible electronics, is introduced. Second, stretchable electrochemical energy storage devices with wavy structures are discussed. Finally, the present problems and challenges are reviewed, and possible directions for future research are outlined.展开更多
Cu bicrystals of different sizes with a sole twin boundary(TB) inclined at 45?with respect to the loading direction were deformed under unidirectional and cyclic loading, respectively. It is found that the slip ba...Cu bicrystals of different sizes with a sole twin boundary(TB) inclined at 45?with respect to the loading direction were deformed under unidirectional and cyclic loading, respectively. It is found that the slip bands(SBs) parallel to the TB can be activated near the TB at all scales without obeying the Schmid's law.It is concerned with the local stress enhancement in the macroscale while it is more closely related to the scarce dislocation sources in the microscale. Moreover, a wedge-shaped zone formed near the TB in the microscale ascribed to the limited specimen size.展开更多
Phase structure of sputtered Ta coating in the negative glow space and LPH effect were explored.The whole coating/substrate system is substrate→physically gas-absorbed Fe surface→oxygen-enriched TaOx layer→amorphou...Phase structure of sputtered Ta coating in the negative glow space and LPH effect were explored.The whole coating/substrate system is substrate→physically gas-absorbed Fe surface→oxygen-enriched TaOx layer→amorphous Ta→αandβdual phase→singleαphase.After LPH course,micro structure of Ta coating shows intact,only a few cracks emerge after 100 laser pulses,exhibiting thin HAZ but thick Fe/Ta ICZ,without martensitic transformation.For the electrodeposited Cr coating,continuous thermal stresses produce many extra micro-crack,substrate oxidation and martensitic transformation,leading to crack propagations and final bulk delamination,without any ICZ.展开更多
In this study, interstitial free (IF) steel plates were subjected to double-sided friction stir processing (FSP). The fine-grained structure with an average grain size of about 12 μm was obtained in tbe processed...In this study, interstitial free (IF) steel plates were subjected to double-sided friction stir processing (FSP). The fine-grained structure with an average grain size of about 12 μm was obtained in tbe processed zone (PZ)with a thickness of about 2.5mm. The yield strength (325 MPa) and ultimate tensile strength (451 MPa) of FSP IF steel were significantly higher than those of base material (BM) (192 and 314 MPa), while the elongation (67.5%) almost remained unchanged compared with the BM (66.2%). The average microhardness value of the PZ was about 130 HV, 1.3 times bigher than that of the BM. In addition, the FSP IF steel showed a more positive corrosion potential and lower corrosion current density than the BM, exhibiting lower corrosion tendency and corrosion rates in a 3.5 wt% NaCl solution. Furtbernlore, FSP IF steel exhibited higher fatigue life than the BM both in air and NaCl solution. Corrosion fatigue fracture surfaces of FSP IF steel mainly exhihited a typical transgranular fracture with fatigue striations, while the BM predominantly presented an intergranular fracture. Enhanced corrosion fatigue performance was mainly attributed to the increased resistance of nucleation and growth of fatigue cracks. The corrosion fatigue mechanism was primarily controlled by anodic dissolution under the combined effect of cyclic stress and corrosive solution.展开更多
基金supported by the Youth Innovation Promotion Association,Chinese Academy of Sciences(CAS)under grant no.2011152Shenyang National Laboratory for Materials Science,Institute of Metal Research,CAS,under grant no.2017RP06
文摘Flexible supercapacitors are promising energy storage devices in wearable smart electronics. Exploring cost-efficient electrodes with high capacitance would promote the wide-scale application of such capacitors. Herein, in order to explore a methodology for preparing low cost, flexible, tough, and up-scalable supercapacitor electrodes, silk textile is directly carbonized to make a conductive free-standing textile substrate. Through mildly baking the surfactant-free TiCTflakes suspension loaded on the carbonized silk cloth, a uniform and adhesive coating consisting of nanometer-thick TiCTflakes is well established on the conductive fabric support, forming a MXene-coated flexible textile electrode. The fabricated electrode exhibits a high areal capacitance of 362 m F/cm~2 with excellent cyclability and flexibility. Moreover,capacitance changes neglegibly under the bending deformation mode. This study elucidates the feasibility of using silk-derived carbon cloth from biomss for MXene-based flexible supercapacitor.
基金supported by the National Basic Research Program of China(Grant Nos.2011CB932604 and 2014CB932402)the National Natural Science Foundation of China(Grant Nos.51221264,51172242+1 种基金51525206,and U1401243)the Key Research Program of Chinese Academy of Sciences(Grant No.KGZDEW-T06)
文摘The application of wavy structures in stretchable electrochemical energy storage devices is reviewed. First, the mechanical anaJysis of wavy structures, specific to flexible electronics, is introduced. Second, stretchable electrochemical energy storage devices with wavy structures are discussed. Finally, the present problems and challenges are reviewed, and possible directions for future research are outlined.
基金supported by the National Natural Science Foundation of China (NSFC) under grant Nos. 51171194, 51501197, 51571198, 51471170the IMR SYNL-T.S. Kê Research Fellowship
文摘Cu bicrystals of different sizes with a sole twin boundary(TB) inclined at 45?with respect to the loading direction were deformed under unidirectional and cyclic loading, respectively. It is found that the slip bands(SBs) parallel to the TB can be activated near the TB at all scales without obeying the Schmid's law.It is concerned with the local stress enhancement in the macroscale while it is more closely related to the scarce dislocation sources in the microscale. Moreover, a wedge-shaped zone formed near the TB in the microscale ascribed to the limited specimen size.
基金financial support of the project from the National Natural Science Foundation of China(No.51701223)。
文摘Phase structure of sputtered Ta coating in the negative glow space and LPH effect were explored.The whole coating/substrate system is substrate→physically gas-absorbed Fe surface→oxygen-enriched TaOx layer→amorphous Ta→αandβdual phase→singleαphase.After LPH course,micro structure of Ta coating shows intact,only a few cracks emerge after 100 laser pulses,exhibiting thin HAZ but thick Fe/Ta ICZ,without martensitic transformation.For the electrodeposited Cr coating,continuous thermal stresses produce many extra micro-crack,substrate oxidation and martensitic transformation,leading to crack propagations and final bulk delamination,without any ICZ.
基金sponsorship from the National Natural Science Foundation of China under grant Nos.51404180,51274161 and U1360105
文摘In this study, interstitial free (IF) steel plates were subjected to double-sided friction stir processing (FSP). The fine-grained structure with an average grain size of about 12 μm was obtained in tbe processed zone (PZ)with a thickness of about 2.5mm. The yield strength (325 MPa) and ultimate tensile strength (451 MPa) of FSP IF steel were significantly higher than those of base material (BM) (192 and 314 MPa), while the elongation (67.5%) almost remained unchanged compared with the BM (66.2%). The average microhardness value of the PZ was about 130 HV, 1.3 times bigher than that of the BM. In addition, the FSP IF steel showed a more positive corrosion potential and lower corrosion current density than the BM, exhibiting lower corrosion tendency and corrosion rates in a 3.5 wt% NaCl solution. Furtbernlore, FSP IF steel exhibited higher fatigue life than the BM both in air and NaCl solution. Corrosion fatigue fracture surfaces of FSP IF steel mainly exhihited a typical transgranular fracture with fatigue striations, while the BM predominantly presented an intergranular fracture. Enhanced corrosion fatigue performance was mainly attributed to the increased resistance of nucleation and growth of fatigue cracks. The corrosion fatigue mechanism was primarily controlled by anodic dissolution under the combined effect of cyclic stress and corrosive solution.