The pressure broadening in the far wings, where the sodium Na(3 p ← 3 s) resonance line is perturbed by ground lithium Li(2 s) atoms, has been theoretically analyzed. The NaLi potential–energy curves and the transit...The pressure broadening in the far wings, where the sodium Na(3 p ← 3 s) resonance line is perturbed by ground lithium Li(2 s) atoms, has been theoretically analyzed. The NaLi potential–energy curves and the transition dipole moments are constructed by using a reliable ab initio data points to carry out the reduced-absorption coefficients k_r(ν, T). This quantum-mechanical investigation have demonstrated that the NaLi profile spectra show a satellite future in the red wing at wavelength λ = 685 nm in the temperature range 4000 K–1.8 × 10~4 K. The computation could also exhibit a second satellite, in the blue wing, near the wavelength λ = 574 nm beyond 6000 K and a third peak located at λ = 490 nm which begins to appear at 1.8 × 10~4 K.展开更多
文摘The pressure broadening in the far wings, where the sodium Na(3 p ← 3 s) resonance line is perturbed by ground lithium Li(2 s) atoms, has been theoretically analyzed. The NaLi potential–energy curves and the transition dipole moments are constructed by using a reliable ab initio data points to carry out the reduced-absorption coefficients k_r(ν, T). This quantum-mechanical investigation have demonstrated that the NaLi profile spectra show a satellite future in the red wing at wavelength λ = 685 nm in the temperature range 4000 K–1.8 × 10~4 K. The computation could also exhibit a second satellite, in the blue wing, near the wavelength λ = 574 nm beyond 6000 K and a third peak located at λ = 490 nm which begins to appear at 1.8 × 10~4 K.
