Microstructure of Steel 5Cr21Mn9Ni4N Alloyed by Rare Earth

The microstructure, composition and shape of precipitated phase under as-cast and finished product state of 5Cr21Mn9Ni4N steel with different rare earth （RE） amount were studied. Mechanical properties of 5Cr21Mn9Ni4N steels withont RE addition and with RE added by 0. 2% in mass percent were tested respectively. The results indicate that the solid solution amount of RE is about 10^-6 -10^-5 order of magnitude in 5Cr21Mn9Ni4N steel. Dendrite of as-cast condition is refined obviously and dimension of interstitial phase is shortened when RE is added by 0.10%-0.20%. But the microstructure will be coarser if surplus RE is added. Precipitated phase under finished product state distributes evenly in nearly same size with RE added by 0. 2% which leads to a largely improved high temperature mechanical property.

High-Temperature Oxidation Behavior of 5Cr21Mn9Ni4N Steel Micro-Alloyed by Rare Earth

The oxidation resistance of 5Cr21Mn9Ni4N steel micro-alloying by RE at 700 - 900 ℃ was investigated. The results indicate that oxidation exponent n and oxidation activation energy are increased, and oxidation velocity constant kp is decreased when 0.2% RE is added in 5Cr21Mn9Ni4N steel. The addition of RE elements does not alter phase constitution of oxidation scale, however it improves the configuration of oxidation scale, and increases thermal stability and adhesivity of oxidation scale, which results in the raise of oxidation resistance of 5Cr21Mn9Ni4N steel at high temperature. The oxidation scale constitutes of refractory steel transfer from manganic oxide mostly to ferric oxide mostly with the increase of temperature, which leads to descend of compactness and desquamation resistance of oxidation scale. The mass increase of ferric oxide in the oxidation scale and the looseness of oxidation scale are the main reason to descend the oxidation resistance of refractory steel.

Influence of Rare Earth on Microstructure and Mechanical Properties of 5Cr21Mn9Ni4N Steel

The influence of different rare earth amounts on microstructure and mechanical properties of 5Cr21Mn9Ni4N steel was studied. The microstructure and composition and shape of inclusions under as-cast, as well as hot rolling state of 5Cr21Mn9Ni4N steel were observed under metallographic microscope and SEM. The results indicate that dendrite of as-cast condition is refined obviously, the extent of segregation is lightened, dimension of inclusions is lessened, and the shape of inclusions is changed from polygon to ellipse when appropriate amount of mixed rare earth is added. Appropriate rare earth also can lighten the extent of hot rolling texture and improve distribution of carbide under hot rolling state. The results of room temperature and 500 ℃ tensile test show that room temperature tensile strength is firstly improved and then appreciably descended. The elongation percentage decreased with the increase of rare earth amount. Appropriate rare earth amount can improve the high temperature tensile strength and ductility of 5Cr21Mn9Ni4N. Fracture surface observation and energy spectrum analysis indicate that complicated rare earth inclusions appear in the fracture surface when 0.10% (mass fraction) rare earth is added in experimental steels, and tough nests of fracture surface become fine without big hole.

Effect of deformation temperature on transformation-induced plasticity effect of lean duplex stainless steel

Effects of deformation temperature on the mechanical properties and microstructure of lean duplex stainless steels B2102 and S32101 have been investigated. It was found that the strength decreased continuously with increases in temperature from -60 ℃ to 100 ℃. The strength of S32101 was higher than that of B2102 owing to its higher nitrogen content. Plasticity of B2102 increased with an increase in deformation temperature from - 60 ℃ and reached the optimal elongation ratio of 49% - 54% after deformation at 20 - 50 ^（2. Martensite transformation was observed during deformation due to the transformation-induced plasticity effect. The optimal elongation was achieved at deformation temperatures close to the Md（3O/50） temperatures of 62 ℃ and 6 ℃ for B2102 and S32101. respectively.

Numerical analysis of carbon saving potential in a top gas recycling oxygen blast furnace

Aiming at the current characteristics of blast furnace （BF） process, carbon saving potential of blast furnace was investigated from the perspective of the relationship between degree of direct reduction and carbon consumption. A new relationship chart between carbon consumption and degree of direct reduction, which can reflect more real situation of blast furnace operation, was established. Further- more, the carbon saving potential of hydrogen-rich oxygen blast furnace （OBF） process was ana- lyzed. Then, the policy implications based on this relationship chart established were suggested. On this basis, the method of improving the carbon saving potential of blast furnace was recycling the top gas with removal of CO2 and H2O or increasing hydrogen in BF gas and full oxygen blast. The results show that the carbon saving potential in traditional blast furnace （TBF） is only 38 56 kg · t ^-1 while that in OBF is 138 kg · t ^-1. Theoretically, the lowest carbon consumpt!on of OBF is 261 kg · t ^-1 and the corresponding degree of direct reduction is 0.04. In addition, the theoretical lowest carbon consumption of hydrogen-rich OBF is 257 kg · t ^-1. The modeling analysis can be used to estimate the carbon savings potential in new ironmaking process and its related CO2 emissions.