Nanocrystalline yttrium vanadate doped with europium ions powders were synthesized via sol-gel method based on decomposition of metal-polymer complex. X-ray diffraction analysis showed that samples had pure tetragonal...Nanocrystalline yttrium vanadate doped with europium ions powders were synthesized via sol-gel method based on decomposition of metal-polymer complex. X-ray diffraction analysis showed that samples had pure tetragonal phase without any impurities. Scanning electron microscopy and static light scattering technique were used to study morphology and size of prepared nanoparticles. Average diameter of the nanoparticles was about 40 nm. The changes in structural and luminescence properties were observed as a function of the first and second calcination temperature. The optimal conditions for synthesis of nanoparticles were determined as Т1=500℃, t1=1 h; Т2=950 ℃, t2=1.5 h. The effect of different media surrounding the nanoparticles on their luminescence properties and lifetime was investigated and discussed in terms of effective refractive index. It was found that the observed lifetime of YVO4：Eu^3＋ 5 at.% nanophosphor was decreased from 0.64 ms in air（nmed=1） to 0.45 ms in chalcogenide glass As39S61（nmed=2.39）.展开更多
The paper presents bounded volume heat sources and the corresponding functional-analytical expressions for the temperature field. The power density distributions considered here are normal, exponential and parabolic. ...The paper presents bounded volume heat sources and the corresponding functional-analytical expressions for the temperature field. The power density distributions considered here are normal, exponential and parabolic. The sources model real heat sources like the welding arc, laser beam, electron beam, etc., the convection in the weld pool as well as the latent heat due to fusion and solidification. The parameters of the heat source models are unknown a priori and have to be evaluated by solving an inverse heat conduction problem. The functional-analytical technique for calculating 3D temperature fields in butt welding is developed. The proposed technique makes it possible to reduce considerably the total time for data input and solution. It is demonstrated with an example of laser beam welding of steel plates.展开更多
文摘Nanocrystalline yttrium vanadate doped with europium ions powders were synthesized via sol-gel method based on decomposition of metal-polymer complex. X-ray diffraction analysis showed that samples had pure tetragonal phase without any impurities. Scanning electron microscopy and static light scattering technique were used to study morphology and size of prepared nanoparticles. Average diameter of the nanoparticles was about 40 nm. The changes in structural and luminescence properties were observed as a function of the first and second calcination temperature. The optimal conditions for synthesis of nanoparticles were determined as Т1=500℃, t1=1 h; Т2=950 ℃, t2=1.5 h. The effect of different media surrounding the nanoparticles on their luminescence properties and lifetime was investigated and discussed in terms of effective refractive index. It was found that the observed lifetime of YVO4：Eu^3＋ 5 at.% nanophosphor was decreased from 0.64 ms in air（nmed=1） to 0.45 ms in chalcogenide glass As39S61（nmed=2.39）.
文摘The paper presents bounded volume heat sources and the corresponding functional-analytical expressions for the temperature field. The power density distributions considered here are normal, exponential and parabolic. The sources model real heat sources like the welding arc, laser beam, electron beam, etc., the convection in the weld pool as well as the latent heat due to fusion and solidification. The parameters of the heat source models are unknown a priori and have to be evaluated by solving an inverse heat conduction problem. The functional-analytical technique for calculating 3D temperature fields in butt welding is developed. The proposed technique makes it possible to reduce considerably the total time for data input and solution. It is demonstrated with an example of laser beam welding of steel plates.
