Selecting suitable materials to adsorb the C_(4)F_(7)N mixtures decomposition products could not only keep the stable operation of the environmentally friendly insulating gas switch cabinet,but also ensure the safety ...Selecting suitable materials to adsorb the C_(4)F_(7)N mixtures decomposition products could not only keep the stable operation of the environmentally friendly insulating gas switch cabinet,but also ensure the safety of operation and maintenance personnel.It is necessary to study the interaction of three types of molecular sieves with the C_(4)F_(7)N mixture and its decomposition products,which could provide a theoretical basis for the selection of adsorbents in the C_(4)F_(7)N gas switch cabinet.In this research,the molecular dynamics simulation was used to study the C_(4)F_(7)N-CO_(2)mixture and its ten kinds of decomposition products CO,CF_(4),C_(2)F_(6),C_(3)F_(6),C_(3)F_(8),CF_(3)H,CF_(3)CN,C_(2)F_(5)CN,C_(2)N_(2),and COF_(2)in three molecular sieves adsorption process(NaA,NaZSM-5,and NaX).The gas concentration distribution curve and interaction energy parameters were obtained by simulation.The interaction energies of C_(3)F_(8)in NaA,C_(4)F_(7)N in NaZSM-5,and C_(3)F_(6)in NaX molecular sieve are the largest,which are−368.35 kJ/mol,−174.93 kJ/mol,and−340.09 kJ/mol respectively.Then,the theoretical results were verified by the fluorocarbon gases adsorption experiment.The adsorption performance of three molecular sieves for all gases was obtained by combining the experimental results and dynamics parameters.The adsorption rate of the NaA molecular sieve for fluorocarbon gas is less than 35%,and its adsorption performance for all gases is weak.NaZSM-5 and NaX molecular sieves show excellent adsorption performance for C_(3)F_(6)and C_(3)F_(8),and the adsorption rates are over 70%.NaZSM-5 molecular sieve shows good adsorption capacity for CF_(3)CN,C_(2)F_(6),C_(2)N_(2),C_(3)F_(6),C_(3)F_(8),C_(4)F_(7)N,and C_(2)F_(5)CN.NaX molecular sieve shows good adsorption capacity for C_(3)F_(6),C_(3)F_(8),C_(4)F_(7)N,and C_(2)F_(5)CN.Both of them have the potential to be used as adsorbents in environmental protection insulated gas switch cabinet.展开更多
基金The National Natural Science Foundation of China,Grant/Award Number:52107145The Natural Science Foundation of Hubei Province,Grant/Award Number:2021CFA025。
文摘Selecting suitable materials to adsorb the C_(4)F_(7)N mixtures decomposition products could not only keep the stable operation of the environmentally friendly insulating gas switch cabinet,but also ensure the safety of operation and maintenance personnel.It is necessary to study the interaction of three types of molecular sieves with the C_(4)F_(7)N mixture and its decomposition products,which could provide a theoretical basis for the selection of adsorbents in the C_(4)F_(7)N gas switch cabinet.In this research,the molecular dynamics simulation was used to study the C_(4)F_(7)N-CO_(2)mixture and its ten kinds of decomposition products CO,CF_(4),C_(2)F_(6),C_(3)F_(6),C_(3)F_(8),CF_(3)H,CF_(3)CN,C_(2)F_(5)CN,C_(2)N_(2),and COF_(2)in three molecular sieves adsorption process(NaA,NaZSM-5,and NaX).The gas concentration distribution curve and interaction energy parameters were obtained by simulation.The interaction energies of C_(3)F_(8)in NaA,C_(4)F_(7)N in NaZSM-5,and C_(3)F_(6)in NaX molecular sieve are the largest,which are−368.35 kJ/mol,−174.93 kJ/mol,and−340.09 kJ/mol respectively.Then,the theoretical results were verified by the fluorocarbon gases adsorption experiment.The adsorption performance of three molecular sieves for all gases was obtained by combining the experimental results and dynamics parameters.The adsorption rate of the NaA molecular sieve for fluorocarbon gas is less than 35%,and its adsorption performance for all gases is weak.NaZSM-5 and NaX molecular sieves show excellent adsorption performance for C_(3)F_(6)and C_(3)F_(8),and the adsorption rates are over 70%.NaZSM-5 molecular sieve shows good adsorption capacity for CF_(3)CN,C_(2)F_(6),C_(2)N_(2),C_(3)F_(6),C_(3)F_(8),C_(4)F_(7)N,and C_(2)F_(5)CN.NaX molecular sieve shows good adsorption capacity for C_(3)F_(6),C_(3)F_(8),C_(4)F_(7)N,and C_(2)F_(5)CN.Both of them have the potential to be used as adsorbents in environmental protection insulated gas switch cabinet.