Terephthalic acid(PTA) is practically one of the main materials of polyester. Its corresponding solid-liquid equilibrium data will provide essential support for industry design and further theoretical studies. In this...Terephthalic acid(PTA) is practically one of the main materials of polyester. Its corresponding solid-liquid equilibrium data will provide essential support for industry design and further theoretical studies. In this work,solid-liquid equilibriums of terephthalic acid in four solvents, N,N-dimethylformamide, N,N-dimethylacetamide,dimethylsulphoxide and N-methyl-2-ketopyrrolidene, were determined in the temperature range from 293.15 K to 364.6 K by dynamic method. All these data were regressed by λh model, Wilson model and NRTL model, average absolute relative deviations of which are 1.25%, 15.02% and 7.22% respectively. It indicates that λh model is mostsuitable for description of the solid-liquid equilibrium containing PTA.展开更多
Experimental densities,viscosities and heat capacities at different emperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water,Density values were used in the de...Experimental densities,viscosities and heat capacities at different emperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water,Density values were used in the determination of excess molar volumes,V^E,At the same time,the excess viscosity was in vestigated,The values of V^E and η^E were fitted to the Redlich-kister equation.Good agreement was observed,The excess volumes are negative over the entire range of composition.They show an U-shaped-concentration dependence and decrease in abolute values with increase of temperature,Values of η^E are negative over the entire range of the composition,and has a trend very similar to that of V^E ,The analysis shows that at any temperature the specific heat of mixture is a linear function of the composition as x1>20%,All the extended lines intersect at one point.An empirical equation is obtained to calculate the specific heat to mixture at any composition and temperature in the experimental range.展开更多
A novel experiment method for chemical solubility determination was brought forward, in which optics and chemistry principles are united and the change of laser intensity indicates the process of chemical dissolving. ...A novel experiment method for chemical solubility determination was brought forward, in which optics and chemistry principles are united and the change of laser intensity indicates the process of chemical dissolving. The more undissolved solid exists in the mixture of solute and solvent, the less transmitted laser intensity is detected. Only when the transmitted laser intensity in stirring state and that in static state comes into equalization, the dissolving process stops. Under the help of laser intensity judgement, measurements turn to be more feasible and objective, especially at high pressure. The average relative errors for the solubility data determined in this paper are 2.3% for those in the minor value scope and 1.7% for those in the high value scope respectively. Comparison of the experimental solubility data with the literature ones demonstrates that the laser-aid solubility determination apparatus is stable and reliable.展开更多
基金Supported by China Petroleum & Chemical Corporation(No.200049).
文摘Terephthalic acid(PTA) is practically one of the main materials of polyester. Its corresponding solid-liquid equilibrium data will provide essential support for industry design and further theoretical studies. In this work,solid-liquid equilibriums of terephthalic acid in four solvents, N,N-dimethylformamide, N,N-dimethylacetamide,dimethylsulphoxide and N-methyl-2-ketopyrrolidene, were determined in the temperature range from 293.15 K to 364.6 K by dynamic method. All these data were regressed by λh model, Wilson model and NRTL model, average absolute relative deviations of which are 1.25%, 15.02% and 7.22% respectively. It indicates that λh model is mostsuitable for description of the solid-liquid equilibrium containing PTA.
基金Supported by China Petroleum & Chemical Corporation (No.200049).
文摘Experimental densities,viscosities and heat capacities at different emperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water,Density values were used in the determination of excess molar volumes,V^E,At the same time,the excess viscosity was in vestigated,The values of V^E and η^E were fitted to the Redlich-kister equation.Good agreement was observed,The excess volumes are negative over the entire range of composition.They show an U-shaped-concentration dependence and decrease in abolute values with increase of temperature,Values of η^E are negative over the entire range of the composition,and has a trend very similar to that of V^E ,The analysis shows that at any temperature the specific heat of mixture is a linear function of the composition as x1>20%,All the extended lines intersect at one point.An empirical equation is obtained to calculate the specific heat to mixture at any composition and temperature in the experimental range.
基金The authors would like to thank SINOPEC Joint-stock Company for the financial support(No. 200049).
文摘A novel experiment method for chemical solubility determination was brought forward, in which optics and chemistry principles are united and the change of laser intensity indicates the process of chemical dissolving. The more undissolved solid exists in the mixture of solute and solvent, the less transmitted laser intensity is detected. Only when the transmitted laser intensity in stirring state and that in static state comes into equalization, the dissolving process stops. Under the help of laser intensity judgement, measurements turn to be more feasible and objective, especially at high pressure. The average relative errors for the solubility data determined in this paper are 2.3% for those in the minor value scope and 1.7% for those in the high value scope respectively. Comparison of the experimental solubility data with the literature ones demonstrates that the laser-aid solubility determination apparatus is stable and reliable.
