The effect of kinetics and shape factor on barium sulfate precipitation in a continuous stirred tank has been investigated numerically through solving the standard momentum and mass transport equations in combination ...The effect of kinetics and shape factor on barium sulfate precipitation in a continuous stirred tank has been investigated numerically through solving the standard momentum and mass transport equations in combination with the moment equations for crystal population balance.The numerical method was validated with the literature data.The simulated results include the distribution of the local supersaturation ratio in the reactor,the mean crystal size,and the coefficient of variation.The simulation results show that the value of shape factor used in the model affected greatly the mean crystal size and the moments of the crystal size distribution.The influence of the kinetic expressions on the simulation is also analyzed.It is important to investigate the relationship of the shape factor with the precipitator type and other operation conditions to obtain reliable simulation results and suitable kinetic equations of crystal nucleation and growth rates.展开更多
基金Financial support from the National Natural Science Foundation of China(Grant Nos.20236050,50404009 and 50134020)the National Basic Research Priorities Program(No.2004CB217604)the National High Technology Research and Development Program of China(Grant No.2007AA060904)is gratefully acknowledged.
文摘The effect of kinetics and shape factor on barium sulfate precipitation in a continuous stirred tank has been investigated numerically through solving the standard momentum and mass transport equations in combination with the moment equations for crystal population balance.The numerical method was validated with the literature data.The simulated results include the distribution of the local supersaturation ratio in the reactor,the mean crystal size,and the coefficient of variation.The simulation results show that the value of shape factor used in the model affected greatly the mean crystal size and the moments of the crystal size distribution.The influence of the kinetic expressions on the simulation is also analyzed.It is important to investigate the relationship of the shape factor with the precipitator type and other operation conditions to obtain reliable simulation results and suitable kinetic equations of crystal nucleation and growth rates.
