Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration.

Apatite Fission Track Thermochronology of Granite from the Xiazhuang Uranium Ore Field,South China:Implications for Exhumation History and Ore Preservation

Xiazhuang uranium ore field,located in the southern part of the Nanling Metallogenic Belt,is considered one of the largest granite-related U regions in South China.In this paper,we contribute new apatite fission track data and thermal history modeling to constrain the exhumation history and evaluate preservation potential of the Xiazhuang Uranium ore field.Nine Triassic outcrop granite samples collected from different locations of Xiazhuang Uranium ore field yield AFT ages ranging from 43 to 24 Ma with similar mean confined fission track lengths ranging from 11.8±2.0 to 12.9±1.9μm and Dpar values between 1.01 and 1.51μm.The robustness time-temperature reconstructions of samples from the hanging wall of Huangpi fault show that the Xiazhuang Uranium ore field experienced a time of monotonous and slow cooling starting from middle Paleocene to middle Miocene(~60-10 Ma),followed by relatively rapid exhumation in the late Miocene(~10-5 Ma)and nearly thermal stability in the Pliocene-Quaternary(~5-0 Ma).The amount of exhumation after U mineralization since the Middle Paleogene was estimated as~4.3±1.8 km according to the integrated thermal history model.Previous studies indicate that the ore-forming ages of U deposits in the Xiazhuang ore field are mainly before Middle Paleocene and the mineralization depths are more than 4.4±1.2 km.Therefore,the exhumation history since middle Paleocene plays important roles in the preservation of the Xiazhuang Uranium ore field.

In-situ analysis and genetic investigation of Li-bearing minerals in McDermitt clay-type lithium deposit,Nevada,USA

Clay-type Li deposits are poised to play a pivotal role in addressing the surging global demand for Li.The McDermitt clay-type Li deposit,located in Nevada,is the largest Li deposit in the United States,with Li hosted by a clay-rich sequence of smectite-dominated intervals and illite-dominated intervals,respectively.However,the occurrence of Li and the genesis of Li-bearing minerals within smectite-dominated intervals have not been thoroughly investigated in previous research.Here,we studied the mineralogy,the in-situ Li distribution,and the bonding environments of Li within the smectite intervals using a combination of instru-mental techniques including scanning electron microscope,transmission electron microscope,time-of-flight secondary ion mass spectrometry,and nuclear magnetic resonance.Our results indicate that the smectite exhibits low crystallinity characteristics of lacustrine clay authigenesis and is com-monly found tofill the interstices among volcanic minerals or envelop them;Li is mainly hosted by Mg-smectite rather than the volcanic minerals.Within the tuffaceous sediment samples,the volcanic glass has undergone a transformation,resulting in its complete disappearance and alteration into clay minerals.Owing to the octahedral sites of Mg-smectite bounded in Li,it is referred to be hectorite.We interpret that the hectorite’s precipitation occurs in a high saline-alkaline water environment,a result of McDermitt tuffdissolution.This conclusion can be supported by the coexistence of spherulitic calcite and hectorite.Overall,this study confirms hectorite as the main Li-bearing mineral and increases the understanding of the genetic model of hectorite formation in intracontinental caldera basins.

Crustal structure in the Anyuan Coal Mine and its adjacent areas of Jiangxi Province by P-wave receiver functions

We collected high-quality teleseismic events recorded by 12 broadband seismographs deployed in the Anyuan Coal Mine and its adjacent areas in Pingxiang City,Jiangxi Province for nearly two years.The H-κ-c stacking method was employed to obtain the crustal thickness and Poisson's ratio distribution,then the characteristics of crustal structure below the stations were obtained by using the time-domain linear inversion method.The crustal thickness in the Anyuan Coal Mine and its adjacent areas ranges from approximately 32~35 km,with an average thickness of 33 km,which is consistent with the crustal thickness results in South China from previous studies using the receiver function method.The average Poisson's ratio of the crustal bulk composition in the study area varies between 0.22 and 0.25,which is lower than the global value with a 0.27 average,indicating a predominantly intermediate-acidic or felsic crustal composition.There is a weak negative correlation between Poisson's ratio and crustal thickness estimates in the Anyuan Coal Mine and its adjacent areas,suggesting that the absence of mafic-ultramafic materials in the lower crust is associated with the process of crustal delamination.The velocity inversion results indicate that the crustal structure including three velocity discontinuity interfaces,with the first at a depth of approximately 1.5 km,the second at about 10~15 km,and the third being the Moho.The study also indicates that the results obtained by the H-κ-c stacking method are significantly better than those obtained by the H-κmethod,effectively reducing the standard deviation and dispersion of crustal thickness and vP/vSratio.

Efficient and selective extraction of uranium from seawater based on a novel pulsed liquid chromatography radionuclide separation method

The novel pulsed liquid chromatography radionuclide separation method presented here provides a new and promising strategy for the extraction of uranium from seawater.In this study,a new chromatographic separation method was proposed,and a pulsed nuclide automated separation device was developed,alongside a new chromatographic column.The length of this chromatographic column was 10 m,with an internal warp of 3 mm and a packing size of 1 mm,while the total separation units of the column reached 12,250.The most favorable conditions for the separation of nuclides were then obtained through optimizing the separation conditions of the device:Sample pH in the column=2,sample injection flow rate=5.698 mL/min,chromatographic column heating temperature=60℃.Separation experiments were also carried out for uranium,europium,and sodium ions in mixed solutions;uranium and sodium ions in water samples from the Ganjiang River;and uranium,sodium,and magnesium ions from seawater samples.The separation factors between the different nuclei were then calculated based on the experimental data,and a formula for the separation level was derived.The experimental results showed that the separation factor in the mixed solution of uranium and europium(1:1)was 1.088,while achieving the initial separation of uranium and europium theoretically required a 47-stage separation.Considering the separation factor of 1.50for the uranium and sodium ions in water samples from the Ganjiang River,achieving the initial separation of uranium and sodium ions would have theoretically required at least a 21-stage separation.Furthermore,for the seawater sample separation experiments,the separation factor of uranium and sodium ions was 1.2885;therefore,more than 28 stages of sample separation would be required to achieve uranium extraction from seawater.The novel pulsed liquid chromatography method proposed in this study was innovative in terms of uranium separation and enrichment,while expanding the possibilities of extracting uranium from seawater through chromatography.

Re–Os and Pb isotope features of pyrite in the Shihangli graphite deposit:implications of coal-generated graphite mineralization in central Hunan,South China

The coal metamorphism in Central Hunan pro-vides valuable information about hydrothermal activity and water/rock reactions.Learning how to collect age data on hydrothermal fluid systems is necessary for understanding the history and genetic mechanisms of large-scale coal-generated graphite deposits.The Shihangli graphite deposit,formed by significant siliceous hydrothermal alteration,is the most distinctive in Central Hunan.Re–Os dating of pyrite from the Shihangli graphite deposit demonstrates that the coal-generated graphite mineraliza-tion age is-127.6±3.8 Ma.Based on in-situ mineral analysis,the hydrothermal pyrite in the Shihangli graphite deposit is mostly enriched in Sb,As,Au,W,Ag,Cu,Pb,and Zn.Based on the pyrite Re–Os isochron,the initial(^(187)Os/^(188)Os)values of pyrite were 1.03±0.24 and the Os(t)values varied from 571.8 to 755.1.Pyrite from the Shihangli graphite deposit comprises a Pb isotope composition similar to that of the Madiyi Formation bulk rock and stibnite from the Xikuangshan Sb deposit.Based on the Re–Os,Sr,S,and Pb isotopic compositions of sul-fides in the graphite and Sb deposits in Central Hunan,the Madiyi Formation was likely the primary source of ore-forming elements(Sb,Au,and As).The Re–Os and Pb isotope compositions of pyrite most likely reflect when large-scale fluid migration and coal-generated graphite mineralization occurred in Central Hunan.

Delineation of Integrated Anomaly with Generative Adversarial Networks and Deep Neural Networks in the Zhaojikou Pb-Zn Ore District,Southeast China

Geochemical maps are of great value in mineral exploration.Integrated geochemical anomaly maps provide comprehensive information about mapping assemblages of element concentrations to possible types of mineralization/ore,but vary depending on expert's knowledge and experience.This paper aims to test the capability of deep neural networks to delineate integrated anomaly based on a case study of the Zhaojikou Pb-Zn deposit,Southeast China.Three hundred fifty two samples were collected,and each sample consisted of 26 variables covering elemental composition,geological,and tectonic information.At first,generative adversarial networks were adopted for data augmentation.Then,DNN was trained on sets of synthetic and real data to identify an integrated anomaly.Finally,the results of DNN analyses were visualized in probability maps and compared with traditional anomaly maps to check its performance.Results showed that the average accuracy of the validation set was 94.76%.The probability maps showed that newly-identified integrated anomalous areas had a probability of above 75%in the northeast zones.It also showed that DNN models that used big data not only successfully recognized the anomalous areas identified on traditional geochemical element maps,but also discovered new anomalous areas,not picked up by the elemental anomaly maps previously.

A new liquid membrane diffusion model for characterizing the adsorption kinetics of europium by using a continuous measurement of adsorption platform

To explore the kinetic adsorption under continuous and nonequilibrium states, an integration of continuous measurement and adsorption platform kinetics method was proposed, which was initially called the ICM-AP kinetics method, and a corresponding kinetic adsorption experimental method was developed. Adsorption experiments of europium(Eu) on Ca-bentonite,Na-bentonite, and the D231 cation exchange resin were performed using the ICM-AP kinetics method and continuous measurements. Because the kinetic experimental results observed in this study were different from those of traditional batch adsorption data, pseudo-first-order or pseudo-second-order kinetic models were unsuitable for fitting the experimental data.Hence, a liquid membrane diffusion(LMD) model was developed based on the assumption of simultaneous adsorption/desorption to discuss the mechanism of kinetic adsorption. The kinetic adsorption mechanism was also studied by using XPS.The results indicated that the proposed adsorption model can fit the experimental data more suitably, and the adsorption/desorption behaviors of Eu on bentonite and the D231 resin were simultaneously observed, suggesting that the adsorption kinetics of Eu(Ⅲ) was mainly dominated by hydrated Eu(Ⅲ) ions on the liquid membrane.

Origin of Tafoni in the Late Cretaceous Aeolian Sandstones,Danxiashan UNESCO Global Geopark,South China

Tafoni occur generally in granular rocks around the world, but their origin remains controversial. In this study,the roles of lithology, micro–climate, and organism in tafoni development are investigated in the Danxiashan UNESCO Global Geopark of South China. The Jinshiyan Temple and Luyitang sites along the Jinjiang River are chosen to conduct tafoni morphometry, bedrock petrography, and micro–climate analyses. The research methods used in this study include field observations and measurements, Voronoi diagrams, polarizing microscopic and scanning electron microscopic(SEM)image analysis, and meteorological detection. The tafoni are mostly 2–10 cm in length and elliptical in shape. The Late Cretaceous Jinshiyan sandstones are characterized by a grain–to–grain contact fabric and moderate sorting with a high proportion of soluble grains and cements. The Voronoi diagrams developed through the Arc GIS software are largely consistent with the tafoni openings. Moreover, owing to exposure to solar insolation, the external temperature values are higher than the internal ones, while the external relative humidity values are lower than the internal ones. Therefore, the permeable Jinshiyan sandstones are fundamental for tafoni development, while the abundant moisture from the Jinjiang River and frequent rains is favorable for salt weathering in tandem with biological activities. At last, a five–stage development model is proposed for the tafoni progression in the study area.

Origin of beaded tafoni in cliffs of Danxia landscapes,Longhushan Global Geopark, South China

The tafoni that develop in sandstone cliffs have attracted the interest of both scientists and the general public. A necklace-like tafone system, referred to here as beaded tafoni, has developed in the prominent cliffs of the Danxia landscapes within the Longhushan Global Geopark in the subtropical zone of South China. This paper presents a new model of the formation of this system of extraordinary beaded tafoni. The cliffs of the Danxia landscapes of the study area are composed of an alluvial conglomerate(i.e.,red beds). These Danxia landscapes have subrounded summits that are covered by vegetation and experience a nearly vertical water flow induced by gravity. Erosion and collapse of the outsized gravels and concentrated pebbles in the red beds give rise to the initial development of the beaded tafoni. The tafoni then become rounded and beaded as a result of reworking and decay by fluvial outwash. During storms, intense water flows run vertically down the cliffs and generate a whirling motion in the tafoni.Consequently, the inside walls of the tafoni gradually become wider and smoother. During the late development stage, the beaded tafoni tend to become indistinct or disappear because of the interconnection of the tafoni and subsequent merging with the bedding-controlled cavities.

Paleozoic post-collisional magmatism and high-temperature granulite-facies metamorphism coupling with lithospheric delamination of the East Kunlun Orogenic Belt,NW China

Lithosphere extension and upwelling of asthenosphere at post-collisional stage of an orogenic cycle generally induce diverse magmatism and/or associated high-temperature metamorphism. Nevertheless, the intimate coexistence of post-collisional magmatic activity and high-temperature metamorphism is rare.In this contribution, a lithological assemblage composing of diverse magmatic rocks deriving from distinct magma sources and coeval high-temperature metamorphism was identified in eastern Kunlun.Petrography, ages, mineral chemistry and whole-rock geochemistry demonstrated that those intimately coexistent diverse rocks were genetically related to post-collisional extension. The garnet-bearing mafic granulites in Jinshuikou area interior of the East Kunlun Orogenic Belt are mainly composed of garnet,orthopyroxene, and plagioclase, with peak metamorphic P–T conditions of ~ 701–756 ℃and 5.6–7.0 kbar,representing a granulite-facies metamorphism at 409.7 ± 1.7 Ma. The diverse contemporaneous magmatic rocks including hornblendites, gabbros and granites yield zircon U–Pb ages of 408.6 ± 2.5 Ma,413.4 ± 4.6 Ma, and 387–407 Ma, respectively. The hornblendites show N-MORB-like REE patterns with(La/Sm)Nvalues of 0.85–0.94. They have positive zircon εHf(t) values of 0.1–4.9 and whole-rock εNd(t) values of 3.9–4.7 but relatively high(^(87)Sr/^(86)Sr)_(i)values of 0.7081 to 0.7088. These features demonstrate that the hornblendites derived from a depleted asthenospheric mantle source with minor continental crustal materials in source. As for the gabbros, they exhibit arc-like elemental signatures, low zircon εHf(t) values(-4.3 to 2.5) and variable whole-rock εNd(t) values(-4.9 to 1.2) as well as high(^(87)Sr/86 Sr)ivalues(0.7068 to 0.7126), arguing for that they were originated from partial melting of heterogeneous lithospheric mantle anteriorly metasomatized by subducted-sediment released melts. Geochemistry of the granites defines their strongly peraluminous S-type signatures. Zircons from the granites yield a large range of εHf(t) values ranging from -30.8 to -5.1, while the whole-rock samples yield consistent(^(87)Sr/86 Sr)ivalues(0.7301 to 0.7342) and negative εNd(t) values(-10.1 to -12.4). These features indicate that the S-type granites could be generated by reworking of an ancient crust. Taken together, the penecontemporaneous magmatism and metamorphic event, demonstrated the early-middle Devonian transition from crustal thickening to extensional collapse. The post-collisional mantle-derived magmas serve as an essential driving force for the high-temperature granulite-facies metamorphism and anataxis of the crust associated with formation of S-type granite. This study not only constructs a more detail Proto-Tethys evolution process of the eastern Kunlun, but also sheds new light on better understanding the intimate relationship between magmatism and metamorphism during post-collisional extensional collapse.

Research on the temperature field of a partially freezing sand barrier with groundwater seepage

To study the distribution characteristics and variation regularity of the temperature field during the process of seepage freezing,a simulated-freezing test with seepage of Xuzhou sand was completed by using a model test developed in-house equipment.By means of three group freezing tests with different seepage velocities,we discovered the phenomenon of the asymmetry of the temperature field under the influence of seepage.The temperature upstream was obviously higher than that downstream.The temperature gradient upstream was also steeper than that downstream.With a higher seepage velocity,the asymmetry of the temperature field is more pronounced.The asymmetry for the interface temperature profile is more strongly manifest than for the main surface temperature profile.The cryogenic barrier section is somewhat"heartshaped".With the increasing velocity of the seepage flow,the cooling rate of the soil decreases.It takes much time to reach the equilibrium state of the soil mass.In our study,seepage flow velocities of 0 m/d,7.5 m/d,and 15 m/d showed the soilcooling rate of 4.35°C/h,4.96°C/h,and 1.72°C/h,respectively.

Lithological and environmental controls on large tafoni along conglomerate cliffs in subtropic humid Danxiashan UNESCO Global Geopark

Tafoni are a type of cavernous weathering features widespread in different climate zones around the world,but their origin has not been fully understood.Little attention was paid on tafoni in conglomerates.Danxiashan UNESCO Global Geopark,located within the subtropic humid region of South China,has a landscape of large tafoni that occur on cliffs of red conglomerates.Both the Dinosaur Rock and Pagoda Peak of the geopark were selected to investigate the formation mechanisms of tafoni in conglomerates.During the field investigation,the size,rock hardness,and the external and internal meteorology of tafoni were measured and tested.The texture and composition of rock samples were observed,and the ion chromatography experiments were performed as well.Results show that tafoni have well ellipsoidal openings.Clasts of the conglomerates are largely sub-rounded and poorly sorted,and the cement is dominantly composed of calcite and iron oxide.The hardness of the lips is almost equal to that of the columns,and both are slightly higher than the backwalls.Compared with the external intense environmental changes,the interior of the tafoni is characterized by smaller temperature and relative humidity ranges and windless condition.Therefore,the porous and permeable conglomerates provide favorable lithology for tafoni development,and the micro-environment within the caverns is conducive to improving water utilization efficiency and enhancing salt weathering.The salts mainly consist of sulfates and nitrates,which might be derived from frequent raining,water evaporation and red beds as well.Consequently,tafoni are the result of the synergistic effects by multiple factors,rather than a single mechanism.

Digitalization of inverting filter shaping circuit for nuclear pulse signals

In the design of filter shaping circuits for nuclear pulse signals,inverting filter shaping circuits perform better than non-inverting filter shaping circuits.Because these circuits facilitate changing the phase of a pulse signal,they are widely used in processing nuclear pulse signals.In this study,the transfer functions of four types of inverting filter shaping circuits,namely the common inverting filter shaping,improved inverting filter shaping,multiple feedback low-pass filter shaping,and third-order multiple feedback low-pass filter shaping,in the Laplacian domain,are derived.We establish the numerical recursive function models and digitalize the four circuits,obtain the transfer functions in the Z domain,and analyze the filter performance and amplitude-frequency response characteristics in the frequency domain.Based on the actual nuclear pulse signal of the Si-PIN detector,we realize four types of inverting digital shaping.The results show that under the same shaping parameters,the common inverting digital shaping has better amplitude extraction characteristics,the third-order multiple feedback low-pass digital shaping has better noise suppression performance,and the multiple feedback digital shaping takes into account both pulse amplitude extraction and noise suppression performance.

Timing of granite pegmatite-type high-purity quartz deposit in the Eastern Qinling,China:constraints from in-situ LA-ICP-MS trace analyses of quartz and monazite U–Pb dating

Eastern Qinling,China is one of the important rare metal metallogenic provinces with extensively distributed granite pegmatite dikes.The No.5 granite pegmatite intruded into the granitic gneiss of the Qinling Group,and the major minerals are quartz(39.8%),K-feldspar(18.8%),albite(36.3%),muscovite(3.4%),and garnet(1.1%).Monazite U–Pb isotopic dating indicates that the No.5 pegmatite from the Eastern Qinling was emplaced at ca.420.2±2.2 Ma,which confirms that highpurity quartz mineralization probably formed during the Early Devonian.In-situ laser ablation inductively coupled plasma mass spectrometry analysis of quartz show that quartz samples from Eastern Qinling have total trace element concentrations(Al,Ti,Sc,Li,B,Cr,Mn,and Fe)ranging from 23.2 to 52.8 ppm,slightly higher than the quartz(impurity element content from 13.4 to 25.9 ppm)of the Spruce Pine high-purity quartz deposit in western North Carolina.The No.5 pegmatite of Eastern Qinling could be defined as one high-purity quartz deposit of China.

Cavernous Weathering in Aeolian Sandstones: An Example from the Yongningshan Hill of the Loess Plateau, Northwest China

Cavernous weathering is commonly found on sandstone slopes in different environments. Either a single dominant process or polygenetic agents require to be invoked in order to interpret the development. The Yongningshan hill of the central Loess Plateau is representative of cliff dwellings in Northwest China, which is characterized by well-developed cavernous weathering features and provides a good opportunity for the better understanding of sandstone weathering in the Loess Plateau. Multiple methods, including field survey, in-situ rock strength measurement, along with experiments on samples for microscopic observation, element composition and salt chemistry, were employed to investigate the controlling factors of cavernous weathering. The results show that cavern development is different on the four slopes with the western slope hosting massive honeycombs, tafoni and hardened surfaces. The porous and permeable aeolian sandstones are fundamental, because they provide space and pathways for the transportation of water and salt, honeycombs dominantly aligning within the lamination of cross-beds. The environmental factors such as the seasonal wetting and drying cycle, aeolian salt, moisture and water vapor are key factors for the development of cavernous weathering forms. The northern and northwestern wind-blown dust storms have brought abundant salts, the lengthier dry periods of the wetting and drying cycle being beneficial for salt accumulation within caverns, favoring salt weathering.

Corrosion behavior of high-level waste container materials Ti and Ti-Pd alloy under long-term gamma irradiation in Beishan groundwater

Titanium and titanium-palladium alloys are important potential materials for nuclear waste container,which will endure both intenseγ-irradiation and groundwater erosion.Therefore,it is very important to investigate the corrosion behavior of the container materials.In this research,the cumulative dose effect of TA8-1 type titanium-palladium alloy(TA8-1)and TA2-type pure titanium(TA2)underγ-irradiation was studied based on the geological disposal of nuclear wastes.The irradiation experiments were performed at room temperature using^(60)Co gamma sources with a 5.0-kGy·h^(-1)intensity for 40,80 or 160 days,respectively.The pH value and conductivity of Beishan groundwater were investigated.The results showed that the pH value changed from alkaline(8.22)to acidic(2.46 for TA8-1 and 2.44 for TA2),while the un-irradiated solution remained alkaline(8.17 for TA8-1 and 8.20 for TA2)after 160 days.With the increase of irradiation dose,the conductivity increases rapidly and then tends to become stable,which indicates that the titanium dioxide corrosion layer formed on the surface of the sample surface effectively prevents further corrosion.Meanwhile,XRD and SEM-EDS analysis results show that the main components of corrosion products are TiO_(2) and TiO.The titanium on the surface of the sample is oxidized,resulting in slight uneven local corrosion.The results show that TA8-1 and TA2 are suitable to be used as candidate materials for high-level waste(HLW)disposal containers due to their excellent performance under long-term and high-dose irradiation corrosion.

Facile Preparation of Novel Manganese Dioxide Modified Nanofiber and Its Uranium Adsorption Performance

In this study a novel manganese dioxide modified nanofiber was facile prepared using the electrospinning technique. The as-prepared manganese dioxide/poly(vinyl alcohol)/poly (acrylic acid) (briefly as MnO2-PVA/PAA) was firstly characterized by SEM, FT-IR, XRD, stress-strain test and secondly tested as an adsorbent to remove uranium from aqueous solution. Effect of pH, ionic strength, initial uranium concentration, mixing time, temperature on the adsorption, reusability and adsorption mechanism were illustrated. The theoretical adsorption amount of MnO2-PVA/PAA calculated as 398.85 mg/g was competitive compared with the reported values. The study proved MnO2-PVA/PAA is promising in the uranium removal from aqueous medium.

Episodic crustal growth and reworking at the southeastern margin of the North China Craton: evidence from zircon U–Pb and Lu–Hf isotopes of Archean tonalite–trondhjemite–granodiorite gneisses in the Bengbu-Wuhe area

The cratonization history of the North China Craton(NCC)and the nature of tectonothermal events are still highly controversial.Tonalite-trondhjemite-granodiorite(TTG)gneisses,as the dominant lithological assemblages in Archean metamorphic terranes,can provide significant clues to the magmatic and metamorphic evolution of Precambrian crust.This study presents zircon laser-ablation inductively-coupled-plasma mass spectrometry U–Pb ages,trace-element,and in-situ LA-MC-ICPMS zircon Hf isotope data for the TTG gneisses from the Bengbu-Wuhe area on the southeastern margin of the NCC.Cathodoluminescence images and trace elements indicated that magmatic zircons display the characteristics of euhedral-subhedral crystals with oscillatory growth zoning structures,high RREE contents,marked Ce positive anomalies,and Pr–Eu negative anomalies.The metamorphic zircons display the spherical-oval crystals with distinct core-rim structures,high and homogeneous luminescent intensity,lower RREE,Nb,Ta,Hf contents,relative flat REE patterns,weak Ce positive anomalies,and Pr-Eu negative anomalies.The Ti–in–zircon geothermometer data indicate that the crystallization temperature of the TTG gneiss ranged from 754 to 868℃.Zircon U–Pb ages indicate that the TTG gneisses formed at 2.79–2.77 Ga and 2.50 Ga and underwent metamorphism at 2.57–2.52 Ga.The Hf isotopic data indicate that the magmatic zircons exhibit high,positive eHf(t)values close to those of the coeval depleted mantle,whereas the metamorphic zircons exhibit negative or nil eHf(t)values.This implies that the TTG gneisses were derived from the partial melting of the~2.9–2.6 Ga juvenile crustal sources mixed with~3.0–2.8 Ga ancient crustal materials.Combined with the regional tectonic evolution,we propose that the metamorphic basement at the southeastern margin of the NCC underwent episodic crustal growth at~2.7 and~2.5 Ga and subsequently underwent crustal reworking or re-melting of the ancient crust during the Neoarchean.The Neoarchean TTG gneisses might have been derived from the partial melting of lower crustal materials related to plate subduction.

Oceanic lithosphere heterogeneity in the eastern Paleo-Tethys revealed by PGE and Re-Os isotopes of mantle peridotites in the Jinshajiang ophiolite

Platinum group elements(PGE)and Re-Os isotopes of mantle peridotites in the Jinshajiang ophiolite(SW China)were investigated in this study,in order to constrain the evolution of the lithospheric mantle beneath the Jinshajiang-Ailaoshan Ocean,which was a branch of the eastern Paleo-Tethys.The Jinshajiang peridotites have whole-rock compositions(e.g.,MgO=32.7-38.1 wt.%;Al_(2)O_(3)=0.67-1.30 wt.%)and spinels with moderate Cr#values(0.4-0.6)similar to those of abyssal peridotites,which indicate moderate degrees of partial melting(15%-20%).These peridotites exhibit U-shaped chondrite-normalized REE patterns that could be caused by hydrothermal alteration or melt-rock interaction after mantle melting.In addition,Pd concentrations and(Pd/Ir)_(N)ratios of the Jinshajiang peridotites increases with decreasing Al_(2)O_(3) concentrations.These negative correlations cannot be explained by simple partial melting but record a melt-rock reaction event after mantle melting.This study therefore demonstrates the efficiency of PGE in detecting the melt-rock reaction process relative to whole-rock major and trace elements.The suprachondritic^(187)Os/^(188)Os ratios(0.1272-0.1374)further indicate that the later percolating melt derived from a mantle domain with distinct^(187)Os-enriched isotopic compositions.In comparison with peridotites in the Ailaoshan ophiolite belt,which were not significantly affected by melt percolation,this study further highlights that the lithospheric mantle compositions beneath different segments of the same ocean basin are highly variable and might be controlled by distinct mantle processes in response to different rifting mechanisms.