Self-sacrificial template, which is freshly precipitated Ni(OH)2 colloid, is used to fabricate ultrafine core-shell nickel spheres. The size distribution, morphology, chemical and catalyzed properties of the synthesiz...Self-sacrificial template, which is freshly precipitated Ni(OH)2 colloid, is used to fabricate ultrafine core-shell nickel spheres. The size distribution, morphology, chemical and catalyzed properties of the synthesized spheres can be controlled by regulating the preparation conditions. The varying conditions are: initial nickel ion concentration, the pH value of the solution, the scouring agent and the anion in saline solution. With very little Ni2+ concentration in the solution, the hollow spheres are formed. The higher the alkali content, the more the ultrafine colloidal cores.展开更多
基金Project(50474004) supported by the National Natural Science Foundation of China Projects(0452nm046 05nm05004) supported by the Nano Special Fund of Shanghai Science and Technology Committee, China
文摘Self-sacrificial template, which is freshly precipitated Ni(OH)2 colloid, is used to fabricate ultrafine core-shell nickel spheres. The size distribution, morphology, chemical and catalyzed properties of the synthesized spheres can be controlled by regulating the preparation conditions. The varying conditions are: initial nickel ion concentration, the pH value of the solution, the scouring agent and the anion in saline solution. With very little Ni2+ concentration in the solution, the hollow spheres are formed. The higher the alkali content, the more the ultrafine colloidal cores.
