Compliance verification and probabilistic analysis of state-wide power quality monitoring data

This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communication protocols are formulated for data transmission. Big data platform and related technologies are utilized for data storage and computation. Compliance verification analysis and a power quality performance assessment are conducted, and a visualization tool for result presentation is finally presented.

Development of a gaseous and solid-state hybrid system for stationary hydrogen energy storage

Hydrogen can serve as a carrier to store renewable energy in large scale.However,hydrogen storage still remains a challenge in the current stage.It is difficult to meet the technical requirements applying the conventional storage of compressed gaseous hydrogen in high-pressure tanks or the solid-state storage of hydrogen in suitable materials.In the present work,a gaseous and solid-state(G-S)hybrid hydrogen storage system with a low working pressure below 5 MPa for a 10 kW hydrogen energy storage experiment platform is developed and validated.A Ti-Mn type hydrogen storage alloy with an effective hydrogen capacity of 1.7 wt%was prepared for the G-S hybrid hydrogen storage system.The G-S hybrid hydrogen storage tank has a high volumetric hydrogen storage density of 40.07 kg H_(2)m^(-3) and stores hydrogen under pressure below5 MPa.It can readily release enough hydrogen at a temperature as low as-15C when the FC system is not fully activated and hot water is not available.The energy storage efficiency of this G-S hybrid hydrogen storage system is calculated to be 86.4%-95.9%when it is combined with an FC system.This work provides a method on how to design a G-S hydrogen storage system based on practical demands and demonstrates that the G-S hybrid hydrogen storage is a promising method for stationary hydrogen storage application.

A review of the etched terminal structure of a 4H-SiC PiN diode

The comparison of domestic and foreign studies has been utilized to extensively employ junction termination extension(JTE)structures for power devices.However,achieving a gradual doping concentration change in the lateral direction is difficult for SiC devices since the diffusion constants of the implanted aluminum ions in SiC are much less than silicon.Many previously reported studies adopted many new structures to solve this problem.Additionally,the JTE structure is strongly sensitive to the ion implantation dose.Thus,GA-JTE,double-zone etched JTE structures,and SM-JTE with modulation spacing were reported to overcome the above shortcomings of the JTE structure and effectively increase the breakdown voltage.They provided a theoretical basis for fabricating terminal structures of 4H-SiC PiN diodes.This paper summarized the effects of different terminal structures on the electrical properties of SiC devices at home and abroad.Presently,the continuous development and breakthrough of terminal technology have significantly improved the breakdown voltage and terminal efficiency of 4H-SiC PiN power diodes.

The establishment of Boron nitride@sodium alginate foam/polyethyleneglycol composite phase change materials with high thermal conductivity, shape stability, and reusability

Adopting organic phase change materials(PCMs) for the management of electronic devices is restricted by low thermal conductivity. In this paper, the composite PCMs are established by freeze-drying and vacuum impregnation. Herein, polyethylene glycol(PEG) is induced as heat storage materials, boron nitride(BN) is embedded as filler stacking in an orderly fashion on the foam walls to improve thermal conductivity and sodium alginate(SA) is formed as supporting material to keep the shape of the composite stable. X-ray diffractometry, scanning electron microscopy-energy dispersive spectrometer, thermal gravimetric analysis, thermal conductivity meter, differential scanning calorimeter, and Fourier transform infrared were used to characterize the samples and thermal cycles were employed to measure the shape stability. The results exhibit the BN@SA/PEG composite PCMs have good chemical compatibility, stable morphology, and thermal stability. Due to the high porosity of foam, PEG endows the composite PCMs with high latent heat(149.11 and 141.59 J·g^(-1)). Simultaneously, BN@SA/PEG shows an excellent heat performance with high thermal conductivity(0.99 W·m^(-1)·K^(-1)), reusability, and shape stability, contributing the composite PCMs to application in the energy storage field. This study provides a strategy to manufacture flexible, long-serving, and shape-stable PCMs via introducing BN@SA foam as a storage framework, and these PCMs have great potential in thermal management in the electronic field.

Two-dimensional vanadium carbide for simultaneously tailoring the hydrogen sorption thermodynamics and kinetics of magnesium hydride

Magnesium hydride(MgH_(2))is a potential material for solid-state hydrogen storage.However,the thermodynamic and kinetic properties are far from practical application in the current stage.In this work,two-dimensional vanadium carbide(V_(2)C)MXene with layer thickness of 50−100 nm was fist synthesized by selectively HF-etching the Al layers from V_(2)AlC MAX phase and then introduced into MgH_(2) to improve the hydrogen sorption performances of MgH_(2).The onset hydrogen desorption temperature of MgH_(2) with V_(2)C addition is significantly reduced from 318℃ for pure MgH_(2) to 190℃,with a 128℃ reduction of the onset temperature.The MgH_(2)+10 wt%V_(2)C composite can release 6.4 wt%of H_(2) within 10 min at 300℃ and does not loss any capacity for up to 10 cycles.The activation energy for the hydrogen desorption reaction of MgH_(2) with V_(2)C addition was calculated to be 112 kJ mol^(−1) H_(2) by Arrhenius’s equation and 87.6 kJ mol^(−1) H_(2) by Kissinger’s equation.The hydrogen desorption reaction enthalpy of MgH_(2)+10 wt%V_(2)C was estimated by van’t Hoff equation to be 73.6 kJ mol^(−1) H_(2),which is slightly lower than that of the pure MgH_(2)(77.9 kJ mol^(−1) H_(2)).Microstructure studies by XPS,TEM,and SEM showed that V_(2)C acts as an efficient catalyst for the hydrogen desorption reaction of MgH_(2).The first-principles density functional theory(DFT)calculations demonstrated that the bond length of Mg−H can be reduced from 1.71A for pure MgH_(2) to 2.14A for MgH_(2) with V_(2)C addition,which contributes to the destabilization of MgH_(2).This work provides a method to significantly and simultaneously tailor the hydrogen sorption thermodynamics and kinetics of MgH_(2) by two-dimensional MXene materials.

Research on power electronic transformer applied in AC/DC hybrid distribution networks

The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/DC hybrid distribution network is put forward according to the demands of power grid, with advantages of accepting DG and DC loads, while clearing DC fault by blocking the clamping double sub-module(CDSM) of input stage. Then, this paper shows the typical structure of AC/DC distribution network that is hand in hand. Based on the new topology, this paper designs the control and modulation strategies of each stage, where the outer loop controller of input stage is emphasized for its twocontrol mode. At last, the rationality of new topology and the validity of control strategies are verified by the steady and dynamic state simulation. At the same time, the simulation results highlight the role of PET in energy regulation.

Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction.Capsaicin and acryloyl chloride were firstly esterified,and then applied to solution polymerization with acrylate monomers and styrene.The yield of the esterified products was about 85.3%.The polymer was characterized by Fourier transform infrared spectroscopy(FTIR),gel permeation chromatography(GPC),thermogravimetric analysis(TGA),contact angle(CA)and antibacterial ring tests.The number-average molecular weight(M_n)of the polymer was 27214,based on the capsaicin-acrylate dosage of 6.5 wt%.The TGA revealed a stable thermal property.The contact angles of the polymers films on tinplate increased from 77.5°to 86.2°with the increasing amount of capsaicin-acrylate.The antibacterial tests demonstrated excellent antimicrobial capability of the polymers.

Influence of epitaxial layer structure and cell structure on electrical performance of 6.5 kV SiC MOSFET

Silicon carbide(SiC)material features a wide bandgap and high critical breakdown field intensity.It also plays an important role in the high efficiency and miniaturization of power electronic equipment.It is an ideal choice for new power electronic devices,especially in smart grids and high-speed trains.In the medium and high voltage fields,SiC devices with a blocking voltage of more than 6.5 kV will have a wide range of applications.In this paper,we study the influence of epitaxial material properties on the static characteristics of 6.5 kV SiC MOSFET.6.5 kV SiC MOSFETs with different channel lengths and JFET region widths are manufactured on three wafers and analyzed.The FN tunneling of gate oxide,HTGB and HTRB tests are performed and provide data support for the industrialization process for medium/high voltage SiC MOSFETs.

Improvement of the electrical resistivity of epoxy resin at elevated temperature by adding a positive temperature coefficient BaTiO3-based compound

The DC electrical resistivity-temperature characteristic is an important property for insulating materials to operate at a high stress level.In order to improve the DC electrical resistivity at elevated temperature in a targeted way,a positive temperature coefficient(PTC)material(Ba Ti O3-based compound(BT60))was selected as the filler in this paper,whose electrical resistivity has a PTC effect when the temperature exceeds its Curie temperature.The BT60 was treated with hydrogen peroxide and(3-Aminopropyl)triethoxysilane.Epoxy composites with different loadings of BT60 fillers(0 wt%,0.5 wt%,and 2 wt%of epoxy)were prepared,denoted as EP-0,EP-0.5,and EP-2.It was shown that BT60 was able to maintain the DC breakdown strength when its loading was less than 2 wt%of epoxy.As the temperature exceeds 60°C,BT60 will compensate for the negative temperature coefficient effect of epoxy resin to some extent.The electrical resistivity of EP-2 was improved by 55%compared with that of neat epoxy at 90°C.It was found that the potential barrier at the grain boundary of BT60 and the deep traps in the interface between BT60 and the epoxy resin hinder the migration of carriers and thus increase the electrical resistivity of epoxy composite.

Passivation effects of phosphorus on 4H-SiC (0001) Si dangling bonds： A first-principles study

The effect of phosphorus passivation on 4H-SiC（0001） silicon （Si） dangling bonds is investigated using ab initio atomistic thermodynamic calculations. Phosphorus passivation commences with chemisorption of phosphorus atoms at high-symmetry coordinated sites. To determine the most stable structure during the passivation process of phosphorus, a surface phase diagram of phosphorus adsorption on SiC （0001） surface is constructed over a coverage range of 1/9-1 monolayer （ML）. The calculated results indicate that the 1/3 ML configuration is most energetically favorable in a reasonable environment. At this coverage, the total electron density of states demonstrates that phosphorus may effectively reduce the interface state density near the conduction band by removing 4H-SiC （0001） Si dangling bonds. It provides an atomic level insight into how phosphorus is able to reduce the near interface traps.

Key stress extraction and equivalent test method for hybrid DC circuit breaker

Firstly, relevant stress properties of millisecond level breaking process and microsecond level commutation process of hybrid HVDC circuit breaker are studied in detail on the basis of the analysis for the application environment and topological structure and operating principles of hybrid circuit breakers, and key stress parameters in transient state process of two time dimensions are extracted. The established digital simulation circuit for PSCAD/EMTDC device-level operation of the circuit breaker has verified the stress properties of millisecond level breaking process and microsecond level commutation process. Then, equivalent test method, circuits and parameters based on LC power supply are proposed on the basis of stress extraction. Finally, the results of implemented breaking tests for complete 200 kV circuit breaker, 100 kV and 50 kV circuit breaker units, as well as single power electronic module have verified the accuracy of the simulation circuit and mathematical analysis. The result of this paper can be a guide to electrical structure and test system design of hybrid HVDC circuit breaker.

Influence of Triangle Structure Defect on the Carrier Lifetime of the 4H-SiC Ultra-Thick Epilayer

Effect of triangle structure defects in a 180-μm-thick as-grown n-type 4H-SiC homoepitaxial layer on the carrier lifetime is quantitatively analyzed, which is grown by a horizontal hot-wall chemical vapor deposition reactor.By microwave photoconductivity decay lifetime measurements and photoluminescence measurements, the results show that the average carrier lifetime of as-grown epilayer across the whole wafer is 2.59μs, while it is no more than 1.34μs near a triangle defect（TD）. The scanning transmission electron microscope results show that the triangle structure defects have originated from 3C-SiC polytype and various types of as-grown stacking faults.Compared with the as-grown stacking faults, the 3C-SiC polytype has a great impact on the lifetime. The reduction of TD is essential to increasing the carrier lifetime of the as-grown thick epilayer.

Simulation of recrystallization based on EBSD data using a modified Monte Carlo model that considers anisotropic effects in cold-rolled ultra-thin grain-oriented silicon steel

A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction measurements were used as input information for simulation.Three types of nucleation mechanisms,namely,random nucleation,high-stored-energy site nucleation(HSEN),and high-angle boundary nucleation(HABN),were considered for simulation.In particular,the nucleation and growth behaviors of Goss-oriented({011}<100>)grains were investigated.Results showed that Goss grains had a nucleation advantage in HSEN and HABN.The amount of Goss grains was the highest according to HABN,and it matched the experimental measurement.However,Goss grains lacked a size advantage across all mechanisms during the recrystallization process.

Effective Ultra-High-Speed Identification Scheme of Lightning Strikes Suitable for VSC-Based DC Grids

To ensure their sound and continuous operation to the greatest extent,VSC-based DC girds have extremely stringent requirements for transmission line relay protection.In terms of guaranteeing their reliability,accurate identification of lightning strikes on DC transmission lines is one of the urgent key problems to be solved.An effective ultra-high-speed identification scheme of lightning strikes suitable for the VSC-based DC grid is proposed in this paper.First,an 1-mode reverse voltage traveling wave(RVTW)is constructed applying the pole-mode transformation theory.Next,fault traveling wave propagation characteristics along the DC transmission line are analyzed in depth utilizing Peterson's law.Then,differences of time-frequency electromagnetic transient characteristics of 1-mode RVTWs between disturbances and faults caused by lightning strikes are distinguished in detail by means of the classical wavelet transformation multi-resolution analysis theory.Finally,extensive simulations are carried out to evaluate the performance of the proposed identification scheme,and by which its excellent rapidity,reliability and robustness are validated.Index Terms-Lightning-strike identification,Multi-resolution analysis,Relay protection,Traveling-wave protection,VsC-based DC grid,Wavelet transformation.

Comparisons and Improvements of Key Operating Characteristics of Current Source Converter Applied in HVDC System

Because of its controlled power factor and no commutation failure,current source converter(CSC)made up of reverse-blocking IGCTs(RB-IGCTs)offers broad application prospects in the field of HVDC system.Valve voltage and power operating range as the most important operating characteristics should be paid attention to but they are always contradictory.First,the relationship between valve voltage and modulation index is obtained.In particular,valve voltage of converter under the three typical modulation methods is compared,analyzed,and verified.Second,with the help of the independent control strategy and coordinated control strategy of both ends,power operating ranges of the three modulation methods are comprehensively analyzed and compared.Third,in order to solve power coupling at a low active power,the improved coordination control strategy at both ends in this paper is proposed and the relationships among active power,reactive power,DC current and phase angle difference are given in detail.Finally,a 500 kV/3 kA simulation system was built in PSCAD/EMTDC to obtain comparison results of the key operating characteristics of CSC under different modulation methods and the converter can realize unity power operation under random active power after adopting the improved coordinated control strategy,and DC current does not decrease to zero,verifying effectiveness of the coordinated control strategy.

Optimal dispatch approach for rural multi-energy supply systems considering virtual energy storage

In response to the underutilization of energy and insufficient flexible operation capability of rural energy supply systems in China,this study proposes an optimal dispatch approach for a rural multi-energy supply system(RMESS)considering virtual energy storage(VES).First,to enable the flexible utilization of rural biomass resources and the thermal inertia of residential building envelopes,this study constructed VES-I and VES-II models that describe electrical-thermal and electrical-gas coupling from an electrical viewpoint.Subsequently,an RMESS model encompassing these two types of VES was formulated.This model delineates the intricate interplay of multi-energy components within the RMESS framework and facilitates the precise assessment of the adjustable potential for optimizing RMESS operations.Based on the above models,a day-ahead optimal dispatch model for an RMESS considering a VES is proposed to achieve optimal economic performance while ensuring efficient energy allocation.Comparative simulations validated the effectiveness of the VES modeling and the day-ahead optimal dispatch approach for the RMESS.

Lithium metal batteries for high energy density:Fundamental electrochemistry and challenges

The dependence on portable devices and electrical vehicles has triggered the awareness on the energy storage systems with ever-growing energy density.Lithium metal batteries(LMBs)has revived and attracted considerable attention due to its high volumetric(2046 m Ah cm-3),gravimetric specific capacity(3862 m Ah g^(-1))and the lowest reduction potential(-3.04 V vs.SHE.).However,during the electrochemical process of lithium anode,the growth of lithium dendrite constitutes the biggest stumbling block on the road to LMBs application.The undesirable dendrite not only limit the Coulombic efficiency(CE)of LMBs,but also cause thermal runaway and other safety issues due to short-circuits.Understanding the mechanisms of lithium nucleation and dendrite growth provides insights to solve these problems.Herein,we summarize the electrochemical models that inherently describe the lithium nucleation and dendrite growth,such as the thermodynamic,electrodeposition kinetics,internal stress,and interface transmission models.Essential parameters of temperature,current density,internal stress and interfacial Li+flux are focused.To improve the LMBs performance,state-of-the-art optimization procedures have been developed and systematically illustrated with the intrinsic regulation principles for better lithium anode stability,including electrolyte optimization,artificial interface layers,threedimensional hosts,external field,etc.Towards practical applications of LMBs,the current development of pouch cell LMBs have been further introduced with different assembly systems and fading mechanism.However,challenges and obstacles still exist for the development of LMBs,such as in-depth understanding and in-situ observation of dendrite growth,the surface protection under extreme condition and the self-healing of solid electrolyte interface.

The Averaged-value Model of a Flexible Power Electronics Based Substation in Hybrid AC/DC Distribution Systems

The concept of a flexible power electronics substation(FPES)was first applied in the Zhangbei DC distribution network demonstration project.As a multi-port power electronics transformer(PET)with different AC and DC voltage levels,the FPES has adopted a novel topology integrating modular multilevel converter(MMC)and four-winding medium frequency transformer(FWMFT)based multiport DC-DC converter,which can significantly reduce capacitance in each sub-module(SM)of a MMC and also save space and cost.In this paper,in order to accelerate speed of electromagnetic transient(EMT)simulations of FPES based hybrid AC/DC distribution systems,an averaged-value model(AVM)is proposed for efficient and accurate representation of FPES.Assume that all SM capacitor voltages are perfectly balanced in the MMC,then the MMC behavior can be modeled using controlled voltage sources based on modulation voltages from control systems.In terms of the averaged current transfer characteristics among the windings of the FWMFT,we consider that all multiport DC-DC converters are controlled with the same dynamics,a lumped averaged model using controlled current and voltage sources has been developed for these four-port DC-DC converters connected to the upper or lower arms of the MMC.The presented FPES AVM model has been tested and validated by comparison with a detailed IGBT-based EMT model.Results show that the AVM is significantly more efficient while maintaining its accuracy in an EMT simulation.

Design and fabrication of bipolar plates for PEM water electrolyser

Hydrogen energy,whether in generation plants or utilization facilities,plays a decisive role in the mission to achieve net-zero greenhouse gas emissions,all to minimize pollution.The growing demand for clean energy carrier steadily accelerates the development of hydrogen production processes,and therein proton exchange membrane(PEM)water electrolysis is deemed a promising long-term strategy for hydrogen preparation and collection.This review retrospects recent developments and applications of bipolar plates(BPs)as key components in PEM fuel cells and water electrolysers.The main content includes multifaceted challenges in the R&D or fabrication of BPs and potential future trends have also been proposed.Specific details cover the BPs matrix(metallic materials and carbon composites)and the surface coating types(metal and compound coatings,carbon-based coatings,and polymer coatings),as well as the influence of flow field design for mass transport.Long-term development and feasible researches of BPs are prospected.Especially in the following aspects:(1)Structural and functional integration of components,such as material fabrication and flow field geometry optimization using 3D printing technology;(2)Introduction of environment-friendly renewable energy for hydrogen production;(3)Research on hydrogen energy reversible systems;(4)Composition optimization of surface coatings based on computational materials science and(5)systematic design expected to evolve into the next generation of BPs.

Modeling of High-frequency Electromagnetic Oscillation for DC Fault in MMC-HVDC Systems

DC short-circuit faults pose a hazard to the operation of a modular multilevel converter(MMC)-based high voltage direct current(HVDC)system,necessitating reliable fault clearing solutions with rapid reaction.However,because the parasitic capacitances of the main equipment oscillate with the lumped inductances of the HVDC system,strong electromagnetic oscillations with multiple frequencies occur during clearance transients.These oscillations will disturb the HVDC system’s protection and control systems.Therefore,this paper focuses on the modeling of these oscillations.First,an equivalent circuit for the MMC-based HVDC system is proposed,taking into account the parasitic capacitances of the system’s major components,such as DC reactors,connecting cables,and DC circuit breakers(DCCBs).Second,four distinct oscillation stages are postulated based on action coordination of MMCs and DCCBs,and the associated analytical equations for the oscillation frequencies are derived.Third,a 200 kV MMC-based DC converter station is subjected to an 6ms/6kA pole-to-pole(PTP)short-circuit test.Electromagnetic oscillations have a frequency range of several kHz to several hundreds of kHz.The measured waveforms correspond well with simulated results,including the parasitic characteristics.Additionally,the relative errors between the simulated and measured frequencies are less than 5%.