Due to their excellent stability and layer-dependent photoelectronic properties,transition metal dichalcogenides(TMDs)are one of the most extensively studied two-dimensional semiconductor materials in the postgraphene...Due to their excellent stability and layer-dependent photoelectronic properties,transition metal dichalcogenides(TMDs)are one of the most extensively studied two-dimensional semiconductor materials in the postgraphene era.However,its low luminescence quantum yield limits its application in displays,lighting,and imaging.Here,a 1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile(HATCN)layer was grown on the surface of chemical vapor deposition(CVD)-grown monolayer molybdenum disulfide(MoS_(2))by vacuum evaporation,which increased the photoluminescence intensity of MoS_(2)by 15 times.The enhanced luminescence originates from the charge transfer from the conduction band of MoS_(2)to the lowest unoccupied molecular orbital(LUMO)of HATCN,which suppresses the emission of the negatively charged exciton(trion)while increasing the emission of the neutral exciton.Temperature-dependent fluorescence and Raman spectra demonstrate the feasibility of organic−inorganic hybrid heterojunctions for regulating excitons.This facile and practical organic−inorganic hybrid heterojunction can elevate TMD applications,such as light-emitting diodes.展开更多
基金the National Natural Science Foundation of China(21788102),the Research Grants Council of Hong Kong(16305320 and C6014-20W)the Shenzhen Key Laboratory of Functional Aggregate Materials(ZDSYS20211021111400001)+1 种基金the Science Technology Innovation Commission of Shenzhen Municipality(KQTD20210811090142053,GJHZ20210705141810031,and GJHZ20210705143204013)the Innovation and Technology Commission(ITC-CNERC14SC01).
文摘Due to their excellent stability and layer-dependent photoelectronic properties,transition metal dichalcogenides(TMDs)are one of the most extensively studied two-dimensional semiconductor materials in the postgraphene era.However,its low luminescence quantum yield limits its application in displays,lighting,and imaging.Here,a 1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile(HATCN)layer was grown on the surface of chemical vapor deposition(CVD)-grown monolayer molybdenum disulfide(MoS_(2))by vacuum evaporation,which increased the photoluminescence intensity of MoS_(2)by 15 times.The enhanced luminescence originates from the charge transfer from the conduction band of MoS_(2)to the lowest unoccupied molecular orbital(LUMO)of HATCN,which suppresses the emission of the negatively charged exciton(trion)while increasing the emission of the neutral exciton.Temperature-dependent fluorescence and Raman spectra demonstrate the feasibility of organic−inorganic hybrid heterojunctions for regulating excitons.This facile and practical organic−inorganic hybrid heterojunction can elevate TMD applications,such as light-emitting diodes.
