New interpretation on the provenance changes of the upper Pinghu–lower Huagang Formation within Xihu Depression,East China Sea Shelf Basin

Both Pinghu and Huagang formations are important hydrocarbon reservoirs of the Xihu Depression in the East China Sea Shelf Basin.Clarifying the source suppliers and restoring source-to-sink transport routes are of great significance to the future petroleum and gas undertakings.Previous researchers were largely confined by either limitation of geological records,highly dependence on a singular method or low-precision dating techniques.Our study integrated heavy mineral assemblages,geochemical analyses and detrital zircon U-Pb dating to reconstruct multiple source-to-sink pathways,and to provide a better understanding on the provenance evolution for the upper Pinghu–lower Huagang depositions of the Xihu Depression.At least three major provenances have been confirmed and systematically investigated for their separate compositional features.The Hupijiao Uplift(or even farther northern area)was dominated by a major Paleoproterozoic population peaked at ca.1830 Ma along with minor Mesozoic clusters.The Haijiao Uplift to the west and the Yushan Low Uplift to the southwest,on the other hand,generate opposite U-Pb age spectra with apparently larger peaks of Indosinian and Yanshanian-aged zircons.To be noted,both Indosinian and Paleoproterozoic peaks are almost identical in proportion for the Haijiao Uplift.The overall sedimentary pattern of late Eocene-early Oligocene was featured by both spatial and temporal distinction.The Hupijiao Uplift was likely to cast limited impact during the late Eocene,whereas the broad southern Xihu Depression was transported by a large abundance of materials from the nearby Haijiao and Yushan Low Uplifts.The northern source substantially extended its influence to the farther south during the early Oligocene by delivering plentiful sediments of higher-degree metamorphic parent rocks.Combined with the proximal western and southwestern suppliers,the overall Xihu Depression was under control from both distant and local provenances.

The dominant driving force for supercontinent breakup: Plume push or subduction retreat?

Understanding the dominant force responsible for supercontinent breakup is crucial for establishing Earth＇s geodynamic evolution that includes supercontinent cycles and plate tectonics. Conventionally,two forces have been considered： the push by mantle plumes from the sub-continental mantle which is called the active force for breakup, and the dragging force from oceanic subduction retreat which is called the passive force for breakup. However, the relative importance of these two forces is unclear. Here we model the supercontinent breakup coupled with global mantle convection in order to address this question. Our global model features a spherical harmonic degree-2 structure, which includes a major subduction girdle and two large upwelling（superplume） systems. Based on this global mantle structure,we examine the distribution of extensional stress applied to the supercontinent by both subsupercontinent mantle upwellings and subduction retreat at the supercontinent peripheral. Our results show that：（1） at the center half of the supercontinent, plume push stress is ～3 times larger than the stress induced by subduction retreat;（2） an average hot anomaly of no higher than 50 K beneath the supercontinent can produce a push force strong enough to cause the initialization of supercontinent breakup;（3） the extensional stress induced by subduction retreat concentrates on a ～600 km wide zone on the boundary of the supercontinent, but has far less impact to the interior of the supercontinent. We therefore conclude that although circum-supercontinent subduction retreat assists supercontinent breakup, sub-supercontinent mantle upwelling is the essential force.

Formation of Hengchun Accretionary Prism Turbidites and Implications for Deep-water Transport Processes in the Northern South China Sea

Located at the end of the northern Manila Trench,the Hengchun Peninsula is the latest exposed part of Taiwan Island,and preserves a complete sequence of accretionary deep-sea turbidite sandstones.Combined with extensive field observations,a’source-to-sink’approach was employed to systematically analyze the formation and evolutionary process of the accretionary prism turbidites on the Hengchun Peninsula.Lying at the base of the Hengchun turbidites are abundant mafic normal oceanic crust gravels with a certain degree of roundness.The gravels with U-Pb ages ranging from 25.4 to23.6 Ma are underlain by hundreds-of-meters thickness of younger deep-sea sandstone turbidites with interbedded gravels.This indicates that large amounts of terrigenous materials from both the’Kontum-Ying-Qiong’River of Indochina and the Pearl River of South China were transported into the deep-water areas of the northern South China Sea during the late Miocene and further eastward in the form of turbidity currents.The turbidity flow drastically eroded and snatched mafic materials from the normal South China Sea oceanic crust along the way,and subsequently unloaded large bodies of basic gravel-bearing sandstones to form turbidites near the northern Manila Trench.With the Philippine Sea Plate drifting clockwise to the northwest,these turbidite successions eventually migrated and,since the Middle Pleistocene,were exposed as an accretionary prism on the Hengchun Peninsula.

Evolution of the Pearl River and its Implication for East Asian Continental Landscape Reversion

As the link connecting the South China Continent and the northern South China Sea(SCS),the Pearl River is the focus of sedimentology and petroleum geology research.Its evolutionary process and controlling factors are of great significance in revealing the East Asian continental landscape reorganization during the Late Cenozoic.Based on published data,’source-to-sink’provenance analyses allow systematic deliberation on the birth and evolutionary history of the Pearl River.Close to the Oligocene/Miocene boundary,an abrupt shift in the sedimentary composition indicates significant westward and northward expansion of the river’s watershed area,followed by the establishment of a near-modern fluvial network.This sedimentary change generally concurred with a series of regional geological events,including the onset of the Yangtze throughflow,large-scale development of the loess plateau,and formation of the northwestern arid zone and Asian Monsoon system.These major changes in the geology-climate-ecoenvironment system are in close response to the process of the Cenozoic Xizang(Tibetan)Plateau uplift.Consequently,the East Asian continental landscape and most of midCenozoic drainage systems underwent critical reversion into east-tilting,or east-flowing networks.

Source and possible tectonic driver for Jurassic-Cretaceous gold deposits in the West Qinling Orogen, China

The West Qinling Orogen(WQO) in Central China Orogenic Belt contains numerous metasedimentary rock-hosted gold deposits(>2000 t Au), which mainly formed during two pulses: one previously recognized in the Late Triassic to Early Jurassic(T3 - J1) and one only recently identified in the Late Jurassic to Early Cretaceous(J3 - K1). Few studies have focused on the origin and geotectonic setting of the J3 - K1 gold deposits.Textural relationships, LA-ICP-MS trace element and sulfur isotope compositions of pyrites in hydrothermally altered T3 dykes within the J3 - K1 Daqiao deposit were used to constrain relative timing relationships between mineralization and pyrite growth in the dykes, and to characterize the source of ore fluid. These results are integrated with an overview of the regional geodynamic setting, to advance understanding of the tectonic driver for J3 - K1 hydrothermal gold systems. Pyrite in breccia-and dykehosted gold ores at Daqiao have similar chemical and isotopic compositions and are considered to be representative of J3 - K1 gold deposits in WQO. Co/Ni and sulfur isotope ratios suggest that ore fluids were derived from underlying Paleozoic Ni-and Se-rich carbonaceous sedimentary rocks. The geochemical data do not support the involvement of magmatic fluids. However, in the EQO(East Qinling Orogen), J3 - K1 deposits are genetically related to magmatism. Gold mineralization in WQO is contemporaneous with magmatic deposits in the EQO and both are mainly controlled by NE-and EWtrending structures produced by changes in plate motion of the Paleo-Pacific plate as it was subducted beneath the Eurasian continent. We therefore infer that the J3 - K1 structural regime facilitated the ascent of magma in the EQO and metamorphic fluids in the WQO with consequent differences in the character of contemporaneous ore deposits. If this is correct, then the far-field effects of subduction along the eastern margin of NE Asia extended 1000's of km into the continental interior.

Zircon geochronology reveals polyphase magmatism and crustal anatexis in the Buchan Block,NE Scotland:Implications for the Grampian Orogeny

The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.

Late Eocene–early Miocene provenance evolution of the Crocker Fan in the southern South China Sea

There are many large-scale Cenozoic sedimentary basins with plentiful river deltas,deep-water fans and carbonate platforms in the southern South China Sea.The Crocker Fan was deposited as a typical submarine fan during the late Eocene–early Miocene,and stretches extensively across the entire Sarawak–Sabah of the northern Borneo area.However,systematic analyses are still lacking regarding its sediment composition and potential source suppliers.No consensus has been reached yet on the provenance evolution and sedimentary infilling processes,which seriously impeded the oil-and-gas exploration undertakings.By combining with sedimentaryfacies identification,heavy mineral assemblages,elemental geochemistry and detrital zircon U-Pb dating,this paper aims to generalize an integrated analysis on the potential provenance terranes and restore source-to-sink pathways of the Crocker Fan.In general,the Crocker Fan was initially formed over the Cretaceous–lower/middle Eocene Rajang Group by an angular Rajang unconformity.The continual southward subduction of the protoSouth China Sea resulted in magmatic activities and subsequent regional deformation and thrusting along the Lupar Line in the northern Borneo.The lowermost Crocker sequence is featured by a thick conglomerate layer sourced from in-situ or adjacent paleo-uplifts.From the late Eocene to the early Miocene,the Crocker Fan was constantly delivered with voluminous detritus from the Malay Peninsula of the western Sundaland.The Zengmu Basin was widely deposited with delta plain and neritic facies sediments,while the Brunei-Sabah Basin,to the farther east,was ubiquitously characterized by turbiditic sequences.The Crocker Fan successions are overall thick layers of modest-grained sandstones,which formed high-quality reservoirs in the southern South China Sea region.

Reinterpretation of the northern South China Sea pre-Cenozoic basement and geodynamic implications of the South China continent: constraints from combined geological and geophysical records

The pre-Cenozoic northern South China Sea(SCS)Basin basement was supposed to exist as a complex of heterogeneous segments,divided by dozens of N-S faulting.Unfortunately,only the Hainan Island and the northeastern SCS region were modestly dated while the extensive basement remains roughly postulated by limited geophysical data.This study presents a systematic analysis including U-Pb geochronology,elemental geochemistry and petrographic identification on granite and meta-clastic borehole samples from several key areas.Constrained from gravity-magnetic joint inversion,this interpretation will be of great significance revealing the tectono-magmatic evolution along the southeastern margin of the Eurasian Plate.Beneath the thick Cenozoic sediments,the northern SCS is composed of a uniform Mesozoic basement while the Precambrian rocks are only constricted along the Red River Fault Zone.Further eastern part of the northern SCS below the Cenozoic succession was widely intruded by granites with Jurassic-to-early Cretaceous ages.Further western part,on the other hand,is represented by meta-sedimentary rocks with relatively sporadic granite complexes.To be noted,the western areas derived higher-degree and wider metamorphic zones,which is in contrast with the lowerdegree and narrower metamorphic belt developed in the eastern region.Drastic collisions between the Indochina Block and South China continent took place since at least late Triassic,resulting in large-scale suturing and deformation zones.At the westernmost part of the northern SCS,the intracontinental amalgamation with closure of the Meso-Tethys has caused fairly stronger and broader metamorphism.One metamorphic biotite granite is located on the suturing belt and yields a Precambrian U-Pb age.It likely represents the relict from the ancient Gondwana supercontinent or its fringes.Arc-continental collision between the Paleo-Pacific and the southeast China Block,on the other hand,results in a relatively narrow NE–SW trending metamorphic belt during the late Mesozoic.Within the overall geological setting,the Cenozoic SCS oceanic basin was subsequently generated from a series of rifting and faulting processes along the collisional-accretionary continental margin.

Deconvolving the pre-Himalayan Indian margin-Tales of crustal growth and destruction

The metamorphic core of the Himalaya is composed of Indian cratonic rocks with two distinct crustal affinities that are defined by radiogenic isotopic geochemistry and detrital zircon age spectra. One is derived predominantly from the Paleoproterozoic and Archean rocks of the Indian cratonic interior and is either represented as metamorphosed sedimentary rocks of the Lesser Himalayan Sequence(LHS) or as slices of the distal cratonic margin. The other is the Greater Himalayan Sequence(GHS) whose provenance is less clear and has an enigmatic affinity. Here we present new detrital zircon Hf analyses from LHS and GHS samples spanning over 1000 km along the orogen that respectively show a striking similarity in age spectra and Hf isotope ratios. Within the GHS, the zircon age populations at 2800-2500 Ma,1800 Ma, 1000 Ma and 500 Ma can be ascribed to various Gondwanan source regions; however, a pervasive and dominant Tonianage population(～860-800 Ma) with a variably enriched radiogenic Hf isotope signature(eHf = 10 to-20) has not been identified from Gondwana or peripheral accreted terranes. We suggest this detrital zircon age population was derived from a crustal province that was subsequently removed by tectonic erosion. Substantial geologic evidence exists from previous studies across the Himalaya supporting the Cambro-Ordovician Kurgiakh Orogeny. We propose the tectonic removal of Tonian lithosphere occurred prior to or during this Cambro-Ordovician episode of orogenesis in a similar scenario as is seen in the modern Andean and Indonesian orogenies, wherein tectonic processes have removed significant portions of the continental lithosphere in a relatively short amount of time. This model described herein of the pre-Himalayan northern margin of Greater India highlights the paucity of the geologic record associated with the growth of continental crust. Although the continental crust is the archive of Earth history, it is vital to recognize the ways in which preservation bias and destruction of continental crust informs geologic models.

Time-resolved, defect-hosted, trace element mobility in deformedWitwatersrand pyrite

The Pb isotopic composition of rocks is widely used to constrain the sources and mobility of melts and hydrothermal fluids in the Earth's crust. In many cases, the Pb isotopic composition appears to represent mixing of multiple Pb reservoirs. However, the nature, scale and mechanisms responsible for isotopic mixing are not well known. Additionally, the trace element composition of sulphide minerals are routinely used in ore deposit research, mineral exploration and environmental studies, though little is known about element mobility in sulphides during metamorphism and deformation. To investigate the mechanisms of trace element mobility in a deformed Witwatersrand pyrite(FeS_2), we have combined electron backscatter diffraction(EBSD) and atom probe microscopy(APM). The results indicate that the pyrite microstructural features record widely different Pb isotopic compositions, covering the entire range of previously published sulphide Pb compositions from the Witwatersrand basin. We show that entangled dislocations record enhanced Pb, Sb, Ni, Tl and Cu composition likely due to entrapment and short-circuit diffusion in dislocation cores. These dislocations preserve the Pb isotopic composition of the pyrite at the time of growth(~3 Ga) and show that dislocation intersections, likely to be common in deforming minerals, limit trace element mobility. In contrast, Pb, As, Ni, Co, Sb and Bi decorate a highangle grain boundary which formed soon after crystallisation by sub-grain rotation recrystallization.Pb isotopic composition within this boundary indicates the addition of externally-derived Pb and trace elements during greenschist metamorphism at ~2 Ga. Our results show that discrete Pb reservoirs are nanometric in scale, and illustrate that grain boundaries may remain open systems for trace element mobility over 1 billion years after their formation.

Biostratigraphy versus isotope geochronology: Testing the Urals island arc model

Formation of the Urals volcanic-hosted massive sulphide(VHMS) deposits is considered to be related with the intra-oceanic stage of island arc(s) development in the Upper Ordoviciane Middle Devonian based on the biostratigraphic record of ore-hosting sedimentary rocks. However, the direct Re-Os dating of four known VHMS systems in the Urals gives significantly younger Re-Os isochron ages ranging from355 ± 15 Ma up to 366 ± 2 Ma. To address this discrepancy, we performed SHRIMP U-Pb dating on zircons extracted from rhyodacites(Eifelian biostratigraphic age of 393 -388 Ma) from the footwall of the Alexandrinka VHMS deposit which has a Re-Os isochron age of sulphides of 355 ± 15 Ma.New ^(206) Pb/^(238) U mean age of 374 ± 3 Ma(MSWD ? 1.4 and probability ? 0.11) is considered to be the crystallisation age of the host volcanic rock. This age is ca. 15 Ma younger than the Eifelian(393 -388 Ma)biostratigraphic age and overlaps the Frasniane Famennian boundary(372 ± 2 Ma), characterised by the final stages of Magnitogorsk Arc e East European continent collision. Such an inconsistency with geochronological age may be due to a reburial of conodonts during resedimentation as a result of erosion of older rocks in younger sedimentary sequences.

Prograde and retrograde growth of monazite in migmatites:An example from the Nagercoil Block,southern India

Data from a migmatised metapelite raft enclosed within charnockite provide quantitative constraints on the pressure-temperature-time （P-T-t） evolution of the Nagercoil Block at the southernmost tip of peninsular India. An inferred peak metamorphic assemblage of garnet, K-feldspar, sillimanite, plagioclase, magnetite, ilmenite, spinel and melt is consistent with peak metamorphic pressures of 6-8 kbar and temperatures in excess of 900 ℃. Subsequent growth of cordierite and biotite record high-temperature retrograde decompression to around 5 kbar and 800 ℃. SHRIMP U-Pb dating of magmatic zircon cores suggests that the sedimentary protoliths were in part derived from felsic igneous rocks with Palae- oproterozoic crystallisation ages. New growth of metamorphic zircon on the rims of detrital grains constrains the onset of melt crystallisation, and the minimum age of the metamorphic peak, to around 560 Ma. The data suggest two stages of monazite growth. The first generation of REE-enriched monazite grew during partial melting along the prograde path at around 570 Ma via the incongruent breakdown of apatite. Relatively REE-depleted rims, which have a pronounced negative europium anomaly, grew during melt crystallisation along the retrograde path at around 535 Ma. Our data show the rocks remained at suprasolidus temperatures for at least 35 million years and probably much longer, supporting a long-lived high-grade metamorphic history. The metamorphic conditions, timing and duration of the implied clockwise P-T-t path are similar to that previously established for other regions in peninsular India during the Ediacaran to Cambrian assembly of that part of the Gondwanan supercontinent.

Thermal evolution of an ancient subduction interface revealed by Lue Hf garnet geochronology, Halilba■? Complex(Anatolia)

The thermal structure of subduction zones exerts a major influence on deep-seated mechanical and chemical processes controlling arc magmatism, seismicity, and global element cycles. Accretionary complexes exposed inland may comprise tectonic blocks with contrasting pressureetemperature(Pe T)histories, making it possible to investigate the dynamics and thermal evolution of former subduction interfaces. With this aim, we present new Lue Hf geochronological results for mafic rocks of the Halilbag?Complex(Anatolia) that evolved along different thermal gradients. Samples include a lawsoniteeepidote blueschist, a lawsoniteeepidote eclogite, and an epidote eclogite(all with counter-clockwise Pe T paths),a prograde lawsonite blueschist with a "hairpin"-type Pe T path, and a garnet amphibolite from the overlying sub-ophiolitic metamorphic sole. Equilibrium phase diagrams suggest that the garnet amphibolite formed at w0.6 -0.7 GPa and 800 -850℃, whereas the prograde lawsonite blueschist records burial from 2.1 GPa and 420℃ to 2.6 GPa and 520℃. Well-defined Lue Hf isochrons were obtained for the epidote eclogite(92.38 ± 0.22 Ma) and the lawsoniteeepidote blueschist(90.19 ± 0.54 Ma),suggesting rapid garnet growth. The lawsoniteeepidote eclogite(87.30 ± 0.39 Ma) and the prograde lawsonite blueschist(ca. 86 Ma) are younger, whereas the garnet amphibolite(104.5 ± 3.5 Ma) is older.Our data reveal a consistent trend of progressively decreasing geothermal gradient from granulite-facies conditions at ~104 Ma to the epidote-eclogite facies around 92 Ma, and the lawsonite blueschist-facies between 90 Ma and 86 Ma. Three Lue Hf garnet dates(between 92 Ma and 87 Ma) weighted toward the growth of post-peak rims(as indicated by Lu distribution in garnet) suggest that the HP/LT rocks were exhumed continuously and not episodically. We infer that HP/LT metamorphic rocks within the Halilbag?Complex were subjected to continuous return flow, with "warm" rocks being exhumed during the tectonic burial of "cold" ones. Our results, combined with regional geological constraints, allow us to speculate that subduction started at a transform fault near a mid-oceanic spreading centre. Following its formation, this ancient subduction interface evolved thermally over more than 15 Myr, most likely as a result of heat dissipation rather than crustal underplating.

Assessing volcanic origins within detrital zircon populations——A case study from the Mesozoic non-volcanic margin of southern Australia

Detrital zircon U/Pb geochronology is a common tool used to resolve stratigraphic questions,inform basin evolution and constrain regional geological histories.In favourable circumstances,detrital zircon populations can contain a concomitant volcanic contribution that provides constraints on the age of deposition.However,for non-volcanic settings,proving isolated detrital zircon grains are from contemporaneous and potentially remote volcanism is challenging.Here we use same grain(U-Th)/He thermochronology coupled with U/Pb geochronology to identify detrital zircon grains of contemporary volcanic origin.(U-Th)/He ages from Cretaceous zircon grains in southern Australia define a single population with a weighted mean age of 104±6.1 Ma.indistinguishable from zircon U/Pb geochronology and palynology(~104.0-107.5 Ma).Detrital zircon trace-element geochemistry is consistent with a continental signature for parent rocks and coupled with detrital grain ages,supports derivation from a>2000 km distant early-to mid-Cretaceous Whitsunday Volcanic Province in eastern Australia.Thus,integration of biostratigraphy,single-grain zircon double-dating(geochronology and thermochronology)and grain geochemistry enhances fingerprinting of zircon source region and transport history.A distal volcanic source and rapid continental-scale transport to southern Australia is supported here.

Warm Climate in the “Boring Billion” Era

The"Boring Billion"refers the era between c.1.8 and 0.8 billion years ago(Ga)(Holland,2006;Young,2013).Especially,the period from 1.6 to 1.0 Ga is known as"the dullest time in Earth’s deep-time history"(Buick et al.,1995).The reason why this period is referred to as the"Boring Billion"is because there were very few’special’or’interesting’events discovered in the geological or geochemical records over nearly one-fourth of Earth's deep-time history.

Trial by fire:Testing the paleolongitude of Pangea of competing reference frames with the African LLSVP

Paleogeography can be reconstructed using various crust-or mantle-based reference frames that make fundamentally different assumptions.The various reconstruction models differ significantly in continental paleolongitude,but it has been difficult to assess which models are more valid.We suggest here a "LLSVP test",where an assumed correlation between present-day large low velocity shear-wave provinces and the paleogeography of supercontinent Pangea at breakup ca.200 million years ago can be used to assess the relative accuracy of published reconstructions.Closest correlations between continental paleolongitude and the African LLSVP are achieved with mantle-based reference frames(moving hotspots and true polar wander),whereas shallower crustbased reference frames are shown to be invalid.The relative success of mantle-based frames,and thus the importance of the depth of reference frame,supports the notion that mantle convection is largely vertical compared to the horizontal plate motion of tectonics.

Reappraising the P-T evolution of the Rogaland-Vest Agder Sector,southwestern Norway

The Rogaland-Vest Agder Sector of southwestern Norway comprises high-grade metamorphic rocks intruded by voluminous plutonic bodies that include the ~1000 km^2 Rogaland Igneous Complex（RIC）.New petrographic observations and thermodynamic phase equilibria modelling of three metapelitic samples collected at various distances（30 km,10 km and ~ 10 m） from one of the main bodies of RIC anorthosite were undertaken to assess two alternative P-T-t models for the metamorphic evolution of the area.The results are consistent with a revised two-phase evolution.Regional metamorphism followed a clockwise P-T path reaching peak conditions of ~ 850-950 ℃ and ~7-8 kbar at ~1035 Ma followed by high-temperature decompression to ~5 kbar at ~950 Ma,and resulted in extensive anatexis and melt loss to produce highly residual rocks.Subsequent emplacement of the RIC at ~930 Ma caused regional-scale contact metamorphism that affected country rocks 10 km or more from their contact with the anorthosite.This thermal overprint is expressed in the sample proximal to the anorthosite by replacement of sillimanite by coarse intergrowths of cordierite plus spinel and growth of a second generation of garnet,and in the intermediate（10 km） sample by replacement of sapphirine by coarse intergrowths of cordierite,spinel and biotite.The formation of late biotite in the intermediate sample may suggest the rocks retained small quantities of melt produced by regional metamorphism and remained at temperatures above the solidus for up to 100 Ma.Our results are more consistent with an accretionary rather than a collisional model for the Sveconorwegian Orogen.

油气藏铼-锇同位素定年的进展与挑战

铼(Re)、锇(Os)元素具有对氧化还原的敏感性和亲有机质特性,富集于烃源岩、油砂、原油、沥青等油气藏相关地质样品中,并被用于油气藏同位素定年。该方法既可通过Re-Os等时线直接获取油气成藏过程的绝对地质年龄,又可利用Os同位素初始值开展油源对比。分析近十余年来油气藏Re-Os同位素年代学研究的进展与不足,指出为推动该定年技术的发展及其在油气勘探实践中的应用,学术界和工业界应密切合作共同探索Re-Os同位素在油气系统中的分馏机理,全面评价硫酸盐热化学还原反应(TSR)、热解事件等后期地质过程对Re-Os同位素体系的潜在影响;综合运用无机和有机地球化学方法,建立判别油气来源的有效工具,以帮助合理选择满足同源特征的Re-Os同位素定年对象。这些问题的解决将有助于尽快建立油气藏Re-Os同位素定年的实用技术方案,并为业内的终端用户提供完整的使用指南。

胶莱盆地晚白垩世玄武岩的年代学和地球化学特征及其对华北岩石圈减薄-增生的制约

已有研究认为华北岩石圈减薄的时空不均一是显著的,主要表现在软流圈来源的岩浆最早出现的时间呈现南北差异。本文通过40Ar-39Ar法获得胶莱盆地西官庄拉斑玄武岩的年龄为96±3Ma,属于青山群火山岩的一部分,早于王氏群大西庄碱性玄武岩(73Ma)。两套岩石均缺乏Nb、Ta负异常,分别具有与E-MORB和OIB类似的微量元素配分特征。西官庄拉斑玄武岩((87Sr/86Sr)t=0.7058,εNd(t)=0.37～0.57)和大西庄碱性玄武岩((87Sr/86Sr)t=0.7040,εNd(t)=5.5～5.7)的同位素组成特征均显示软流圈的印记。前者为软流圈熔体与古老富集岩石圈地幔相互反应的产物,而后者是软流圈部分熔融的产物。研究区岩浆的εNd(t)值随年龄的降低而逐渐增大,暗示古老岩石圈减薄过程中软流圈的上涌,说明研究区晚白垩世-早新生代岩石圈仍在经历减薄作用。类似的岩浆演化趋势在辽西和辽东地区也有发现,不过演化的时间分别为120～100Ma和80～60Ma,再次证明华北岩石圈减薄作用的时空不均一性。

Strategies towards robust interpretations of in situ zircon Lu-Hf isotope analyses

The combination of U-Pb and Lu-Hf compositions measured in zircon crystals is a remarkably powerful isotopic couplet that provides measures on both the timing of mineral growth and the radiogenic enrichment of the source from which the zircon grew.The U-Pb age documents the timing of zircon crystallization/recrystallization and Hf isotopes inform on the degree to which the host melt was derived from a radiogenic reservoir(e.g.depleted mantle) versus an unradiogenic reservoir(e.g.ancient continental crust),or some mixture of these sources.The ease of generating large quantities of zircon U-Pb and Lu-Hf data has been in large part facilitated by instrument advances.However,the dramatic increase in time constrained zircon Lu-Hf analyses in the Earth science community has brought to the fore the importance of careful data collection and reduction workflows,onto which robust geological interpretations may be based.In this work,we discuss the fundamentals of Lu-Hf isotopes in zircon,which then allows us to provide a robust,accessible,methodology for the assessment of data quality.Additionally,we discuss some novel techniques for:data visualization—that facilitates better transparency of data interpretation;integration of geographic information—that may reveal spatial trends where temporal trends were only apparent before;and some novel statistical evaluation tools—that may provide more rigorous interand intra-sample comparisons.