TiAl alloy with high Nb content,nominally Ti-45Al-10Nb,was prepared by powder metallurgy,and the oxidation resistance at 850,900,and 950℃was investigated.The high-temperature oxidation-resistance mechanism and oxidat...TiAl alloy with high Nb content,nominally Ti-45Al-10Nb,was prepared by powder metallurgy,and the oxidation resistance at 850,900,and 950℃was investigated.The high-temperature oxidation-resistance mechanism and oxidation dynamics were discussed following the oxide skin morphology and microstructural evolution analysis.The oxide skin structures were similar for 850 and 900℃,with TiO_(2)+Al_(2)O_(3)mixture covering TiO_(2)with dispersed Nb_(2)O_(5).At 950℃,the oxide skin was divided into four sublayers,from the outside to the parent metal:loose TiO_(2)+Al_(2)O_(3),dense Al_(2)O_(3),dense TiO_(2)+Nb_(2)O_(5),and TiO_(2)matrix with dispersed Nb_(2)O_(5).The Nb layer suppressed the outward diffusion of Ti atoms,hindering the growth of TiO_(2),and simultaneously promote the formation of a continuous Al_(2)O_(3)protective layer,providing the alloy with long-term high-temperature oxidation resistance.展开更多
基金financially supported by the National Natural Science Foundation of China (No. 51704088)the Natural Science Foundation of Heilongjiang Province of China (No. YQ2020E030)the Young Innovative Talents Training Plan of Heilongjiang Province, China (No. UNPYSCT-2017084)
文摘TiAl alloy with high Nb content,nominally Ti-45Al-10Nb,was prepared by powder metallurgy,and the oxidation resistance at 850,900,and 950℃was investigated.The high-temperature oxidation-resistance mechanism and oxidation dynamics were discussed following the oxide skin morphology and microstructural evolution analysis.The oxide skin structures were similar for 850 and 900℃,with TiO_(2)+Al_(2)O_(3)mixture covering TiO_(2)with dispersed Nb_(2)O_(5).At 950℃,the oxide skin was divided into four sublayers,from the outside to the parent metal:loose TiO_(2)+Al_(2)O_(3),dense Al_(2)O_(3),dense TiO_(2)+Nb_(2)O_(5),and TiO_(2)matrix with dispersed Nb_(2)O_(5).The Nb layer suppressed the outward diffusion of Ti atoms,hindering the growth of TiO_(2),and simultaneously promote the formation of a continuous Al_(2)O_(3)protective layer,providing the alloy with long-term high-temperature oxidation resistance.
