The title compound N-phenyl-2-deoxy-D-ribopyranosylamine featuring a single conformation and pyranose-ring has been synthesized and characterized by NMR spectrum and X-ray diffraction. X-ray crystal structure analysis...The title compound N-phenyl-2-deoxy-D-ribopyranosylamine featuring a single conformation and pyranose-ring has been synthesized and characterized by NMR spectrum and X-ray diffraction. X-ray crystal structure analysis shows that its crystal belongs to the monoclinic system, space group P21 with a = 6.5375（9）, b = 7.7140（9）, c = 10.7865（16）A, β= 97.578（11）^o, Z = 2, V= 539.22（13）A^3, Dc = 1.289 g/cm^3, F（000） = 224, μ（MoKa） --- 4.533 mm^-1, R = 0.0305 and wR = 0.0639 for 1093 observed reflections （I 〉 2σ（I）. This compound exists as a-conformation and ^1C4 chair-like configuration.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 20132020)
文摘The title compound N-phenyl-2-deoxy-D-ribopyranosylamine featuring a single conformation and pyranose-ring has been synthesized and characterized by NMR spectrum and X-ray diffraction. X-ray crystal structure analysis shows that its crystal belongs to the monoclinic system, space group P21 with a = 6.5375（9）, b = 7.7140（9）, c = 10.7865（16）A, β= 97.578（11）^o, Z = 2, V= 539.22（13）A^3, Dc = 1.289 g/cm^3, F（000） = 224, μ（MoKa） --- 4.533 mm^-1, R = 0.0305 and wR = 0.0639 for 1093 observed reflections （I 〉 2σ（I）. This compound exists as a-conformation and ^1C4 chair-like configuration.
