As a promising magneto-optical(MO)material applied in Faraday isolators,magneto-optical ceramics possess excellent comprehensive properties and have attracted much attention these years.Herein,we review the fabricatio...As a promising magneto-optical(MO)material applied in Faraday isolators,magneto-optical ceramics possess excellent comprehensive properties and have attracted much attention these years.Herein,we review the fabrication and properties of magneto-optical ceramics including garnet,sesquioxide,and A_(2)B_(2)O_(7) ceramics.Some of the ceramics have been proved to possess applicable performance,while further studies are still needed for most of the magneto-optical ceramics.Aiming at the application for isolators,the research status,existing problems,and development trends of magneto-optical ceramics are shown and discussed in this review.展开更多
The major advantage of laser lighting over white light-emitting-diode is the possibility to achieve ultra-high luminance.However,phosphors usually suffer laser-induced luminescence saturation,which limits the peak lum...The major advantage of laser lighting over white light-emitting-diode is the possibility to achieve ultra-high luminance.However,phosphors usually suffer laser-induced luminescence saturation,which limits the peak luminance of laser lighting devices.The aim of the present study is to develop LuAG:Ce/Al_(2)O_(3)composite ceramics(LACCs)with a high saturation threshold for high-luminance laser lighting.Owning to the rigid crystal structure,proper synthetic process,and optimized thermal design,the LACCs possess small thermal quenching(16%loss in luminescence at 225℃),high quantum yield(>95%),and excellent luminescence properties.When the LACCs are irradiated by blue laser diodes in a reflection mode,a high luminous flux of 4634 lm and luminous efficacy of 283 lm·W^(−1)are realized.Furthermore,they show no sign of luminescence saturation even when the power density reaches 20.5 W·mm^(−2).With these favorable properties,the designed LACCs show great potential in high-luminance laser lighting.展开更多
(Gd,Y,Ce)_(3)(Y_(x)Ga_(1−x))_(2)GaAl_(2)O_(12)(GYGAG:Ce)scintillation ceramics with different Y excess,where x=0.005−0.08,were fabricated by the solid-state reaction method.The effects of stoichiometry on the phase co...(Gd,Y,Ce)_(3)(Y_(x)Ga_(1−x))_(2)GaAl_(2)O_(12)(GYGAG:Ce)scintillation ceramics with different Y excess,where x=0.005−0.08,were fabricated by the solid-state reaction method.The effects of stoichiometry on the phase composition,optical quality,and microstructure of GYGAG:Ce ceramics were analyzed.GYGAG:Ce ceramics have a pure garnet phase and obtain good in-line transmittance when x<0.04,while more Y excess leads to the creation of the secondary phase.The change of x value influences the sintering behavior of the GYGAG:Ce ceramics:The excess of Y works as the self-sintering aid and significantly reduces the sintering temperature of ceramics.When x=0.01–0.04,the X-ray excited luminescence(XEL)spectra and light yields of GYGAG:Ce ceramics are similar.The fast scintillation decay time and afterglow intensity of GYGAG:Ce ceramics show a slight decrease with increasing x value.Finally,additional 50–500 ppm MgO and 100–500 ppm CaO were introduced to the GYGAG:Ce ceramic with x=0.04,and both were found to significantly increase the fast scintillation component and reduce the afterglow intensity by two orders of magnitude to 0.01%after X-ray cut-off.展开更多
Non-stoichiometric Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)(x=-0.07-0.45)magneto-optical ceramics were fabricated by solid-state reactive sintering in vacuum combined with hot isostatic pressing(HIP)posttreatment without any...Non-stoichiometric Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)(x=-0.07-0.45)magneto-optical ceramics were fabricated by solid-state reactive sintering in vacuum combined with hot isostatic pressing(HIP)posttreatment without any sintering aids.The phase composition,densification process,microstructure,optical transmittance,and Verdet constant of Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)ceramics were investigated.The in-line transmittance of(Tb_(0.93)Hf_(0.04))_(2)Hf_(2)O_(7.07)ceramics with a thickness of 2.0 mm reaches 74.6%at 1064 nm.The Verdet constant of Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)ceramics is-153.4,-155.8,and-181.2 rad/(T-m)at the wavelength of 633 nm when x=-0.07,0,and 0.1,respectively.The Verdet constant increases with the increase of Tb content,and these values are higher than that of the commercial Tb_(3)Ga_(5)O_(12) crystal,indicating that non-stoichiometric Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)ceramics have a great potential for the application in Faraday isolators.展开更多
Faraday isolators can prevent the front-end system from disturbance and damage caused by a back-reflected beam,so they are important elements in laser systems.As magneto-optical materials are the most important compon...Faraday isolators can prevent the front-end system from disturbance and damage caused by a back-reflected beam,so they are important elements in laser systems.As magneto-optical materials are the most important component in Faraday isolators,the studies on magneto-optical materials have attracted much attention these years.Tb_(3)Al_(5)O_(12)(TAG)ceramics are considered to be one of the most promising magneto-optical materials for visible to near-infrared wavelength band application because of their outstanding comprehensive magneto-optical performance.However,the optical quality of TAG ceramics needs further optimization to meet the application requirements.In this work,high optical quality(Tb_(1−x)Y_(x))_(3)Al_(5)O_(12)(x=0,0.05,0.1,0.2,and 0.3)magneto-optical ceramics were fabricated successfully by solid-state reaction sintering combined with hot isostatic pressing(HIP)post-treatment.All the ceramics obtained showed a single garnet phase for different values of x in the range studied.The addition of Y2O3 was found to suppress the secondary phase and improve optical quality significantly.The ceramic samples obtained had clear grain boundaries and possessed the in-line transmittance values of 82.9%at 1064 nm and 82.2%at 633 nm,respectively.The Verdet constants of(Tb_(1−x)Y_(x))_(3)Al_(5)O_(12)ceramics with x=0,0.05,0.1,0.2,and 0.3 were−188.1,−175.4,−168.5,−143.0,and−119.9 rad/(T·m),respectively.The thermal conductivity of TAG ceramics was found to be 5.23 W/(m·K)at 25℃,and when 20%Y was substituted in place of Tb,the thermal conductivity decreased by only 9.4%.展开更多
基金supported by the General Program of Shanghai Natural Science Foundation(Grant No.22ZR1471500)the International Partnership Program of Chinese Academy of Sciences(Grant No.121631KYSB20200039)+1 种基金the International Cooperation Project of Shanghai Science and Technology Commission(Grant No.20520750200)The IChHPS RAS work was supported by the Russian Science Foundation(Grant No.18-13-00355).
文摘As a promising magneto-optical(MO)material applied in Faraday isolators,magneto-optical ceramics possess excellent comprehensive properties and have attracted much attention these years.Herein,we review the fabrication and properties of magneto-optical ceramics including garnet,sesquioxide,and A_(2)B_(2)O_(7) ceramics.Some of the ceramics have been proved to possess applicable performance,while further studies are still needed for most of the magneto-optical ceramics.Aiming at the application for isolators,the research status,existing problems,and development trends of magneto-optical ceramics are shown and discussed in this review.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA22010301)the key research project of the frontier science of the Chinese Academy of Sciences(Grant No.QYZDB-SSW-JSC022).
文摘The major advantage of laser lighting over white light-emitting-diode is the possibility to achieve ultra-high luminance.However,phosphors usually suffer laser-induced luminescence saturation,which limits the peak luminance of laser lighting devices.The aim of the present study is to develop LuAG:Ce/Al_(2)O_(3)composite ceramics(LACCs)with a high saturation threshold for high-luminance laser lighting.Owning to the rigid crystal structure,proper synthetic process,and optimized thermal design,the LACCs possess small thermal quenching(16%loss in luminescence at 225℃),high quantum yield(>95%),and excellent luminescence properties.When the LACCs are irradiated by blue laser diodes in a reflection mode,a high luminous flux of 4634 lm and luminous efficacy of 283 lm·W^(−1)are realized.Furthermore,they show no sign of luminescence saturation even when the power density reaches 20.5 W·mm^(−2).With these favorable properties,the designed LACCs show great potential in high-luminance laser lighting.
基金supported by the International Partnership Program of Chinese Academy of Sciences(Grant No.121631KYSB20200039)the International Cooperation Project of Shanghai Science and Technology Commission(Grant No.20520750200)+3 种基金the National Key R&D Program of China(Grant No.2021YFE0104800)the Key Research Project of the Frontier Science of the Chinese Academy of Sciences(Grant No.QYZDB-SSW-JSC022)support of the Czech Ministry of Education,Youth and Sports under Project SOLID21 CZ.02.1.(Grant No.01/0.0/0.0/16_019/0000760)Czech Science Foundation project(Grant No.GA21-17731S)is acknowledged with thanks。
文摘(Gd,Y,Ce)_(3)(Y_(x)Ga_(1−x))_(2)GaAl_(2)O_(12)(GYGAG:Ce)scintillation ceramics with different Y excess,where x=0.005−0.08,were fabricated by the solid-state reaction method.The effects of stoichiometry on the phase composition,optical quality,and microstructure of GYGAG:Ce ceramics were analyzed.GYGAG:Ce ceramics have a pure garnet phase and obtain good in-line transmittance when x<0.04,while more Y excess leads to the creation of the secondary phase.The change of x value influences the sintering behavior of the GYGAG:Ce ceramics:The excess of Y works as the self-sintering aid and significantly reduces the sintering temperature of ceramics.When x=0.01–0.04,the X-ray excited luminescence(XEL)spectra and light yields of GYGAG:Ce ceramics are similar.The fast scintillation decay time and afterglow intensity of GYGAG:Ce ceramics show a slight decrease with increasing x value.Finally,additional 50–500 ppm MgO and 100–500 ppm CaO were introduced to the GYGAG:Ce ceramic with x=0.04,and both were found to significantly increase the fast scintillation component and reduce the afterglow intensity by two orders of magnitude to 0.01%after X-ray cut-off.
基金supported by the National Key R&D Program of China(Grant No.2021YFE0104800)the NSFC-RFBR Cooperative Research Project(Grant No.61911530135)the Key Research Project of the Frontier Science of the Chinese Academy of Sciences(No.QYZDB-SSWJSC022)。
文摘Non-stoichiometric Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)(x=-0.07-0.45)magneto-optical ceramics were fabricated by solid-state reactive sintering in vacuum combined with hot isostatic pressing(HIP)posttreatment without any sintering aids.The phase composition,densification process,microstructure,optical transmittance,and Verdet constant of Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)ceramics were investigated.The in-line transmittance of(Tb_(0.93)Hf_(0.04))_(2)Hf_(2)O_(7.07)ceramics with a thickness of 2.0 mm reaches 74.6%at 1064 nm.The Verdet constant of Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)ceramics is-153.4,-155.8,and-181.2 rad/(T-m)at the wavelength of 633 nm when x=-0.07,0,and 0.1,respectively.The Verdet constant increases with the increase of Tb content,and these values are higher than that of the commercial Tb_(3)Ga_(5)O_(12) crystal,indicating that non-stoichiometric Tb_(2)(Hf_(1-x)Tb_(x))_(2)O_(7-x)ceramics have a great potential for the application in Faraday isolators.
基金the National Key R&D Program of China(Nos.2021YFE0104800 and 2023YFB3812000)the General Project of Shanghai Natural Science Foundation(No.22ZR1471500)+2 种基金the International Partnership Program of Chinese Academy of Sciences(No.121631KYSB20200039)the International Cooperation Project of Shanghai Science and Technology Commission(No.20520750200)and National Center for Research and Development(Contract No.WPC2/1/SCAPOL/2021).Partial work was also financially supported by the Hengdian Group.
文摘Faraday isolators can prevent the front-end system from disturbance and damage caused by a back-reflected beam,so they are important elements in laser systems.As magneto-optical materials are the most important component in Faraday isolators,the studies on magneto-optical materials have attracted much attention these years.Tb_(3)Al_(5)O_(12)(TAG)ceramics are considered to be one of the most promising magneto-optical materials for visible to near-infrared wavelength band application because of their outstanding comprehensive magneto-optical performance.However,the optical quality of TAG ceramics needs further optimization to meet the application requirements.In this work,high optical quality(Tb_(1−x)Y_(x))_(3)Al_(5)O_(12)(x=0,0.05,0.1,0.2,and 0.3)magneto-optical ceramics were fabricated successfully by solid-state reaction sintering combined with hot isostatic pressing(HIP)post-treatment.All the ceramics obtained showed a single garnet phase for different values of x in the range studied.The addition of Y2O3 was found to suppress the secondary phase and improve optical quality significantly.The ceramic samples obtained had clear grain boundaries and possessed the in-line transmittance values of 82.9%at 1064 nm and 82.2%at 633 nm,respectively.The Verdet constants of(Tb_(1−x)Y_(x))_(3)Al_(5)O_(12)ceramics with x=0,0.05,0.1,0.2,and 0.3 were−188.1,−175.4,−168.5,−143.0,and−119.9 rad/(T·m),respectively.The thermal conductivity of TAG ceramics was found to be 5.23 W/(m·K)at 25℃,and when 20%Y was substituted in place of Tb,the thermal conductivity decreased by only 9.4%.