黔西南高砷煤中砷赋存状态的XAFS和铁的Mssbauer谱研究

利用X射线吸收精细结构分析 (XAFS)和铁的穆斯堡尔谱 (M ssbauer)对黔西南高砷煤中砷和铁的存在形式进行了研究。研究发现 ,高砷煤中的砷主要以高价砷的形式存在 ,也有少量以As2 O3 、砷黄铁矿、砷硫化物的形式存在。除 1个样品中的铁全部以顺磁性针铁矿或超顺磁性的针铁矿的形式存在外 ,其它样品中的Fe主要是黄铁矿中的Fe,约占全铁的 6 0 %～ 91% ;其次是黄铁钾矾中的Fe ,约占全铁的 9%～ 4 0 %。

The Global Boundary Stratotype Section and Point （GSSP） for the base of Changhsingian Stage （Upper Permian）

The Global Stratotype Section and Point （GSSP） for the base-Changhsingian Stage is defined at the First Appearance Datum （FAD） of the conodont Clarkina wangi within the lineage from C. longicuspidata to C. wangi at a point 88 cm above the base of the Changxing Limestone in the lower part of Bed 4 （base of 4α-2） at Meishan D section, Changxing County, Zhejiang Province, South China. This level is consistent with the first appearance of Changhsingian index fusulinid Palaeofusulina sinensis and tapashanitid ammonoids. The speciation event from Clarkina longicuspidata to C. wangi occurs just above the flooding surface of the second parasequence in the Changxing Limestone. In addition, the boundary interval is clearly recognizable by the depletion of isotopic carbon ratios and the normal polarity zone appearing above the Late Wuchiapingian reversed polarity zone. Section C, about 300 m to the west of Section D, exposes more of the upper Longtan Formation. It clearly shows the transitional nature of deposition across the Longtan/Changxing formational boundary, and thus is described as a supplementary reference section.

A Spectral Index for Estimating Soil Salinity in the Yellow River Delta Region of China Using EO-1 Hyperion Data

Soil salinization is one of the most common land degradation processes. In this study, spectral measurements of saline soil samples collected from the Yellow River Delta region of China were conducted in laboratory and hyperspectral data were acquired from an EO-1 Hyperion sensor to quantitatively map soil salinity in the region. A soil salinity spectral index (SSI) was constructed from continuum-removed reflectance (CR-reflectance) at 2052 and 2203 nm, to analyze the spectral absorption features of the salt-affected soils. There existed a strong correlation (r = 0.91) between the SSI and soil salt content (SSC). Then, a model for estimation of SSC with SSI was established using univariate regression and validation of the model yielded a root mean square error (RMSE) of 0.986 and an R2 of 0.873. The model was applied to a Hyperion reflectance image on a pixel-by-pixel basis and the resulting quantitative salinity map was validated successfully with RMSE = 1.921 and R2 = 0.627. These suggested that the satellite hyperspectral data had the potential for predicting SSC in a large area.

The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

It is quite evident that it is not anomalous metal transport,nor unique depositional conditions,nor any single factor at the deposit scale,that dictates whether a mineral deposit becomes a giant or not.A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments.For giant orogenic,intrusion-related gold systems（IRGS） and Carlin-type gold deposits and iron oxide-copper-gold（IOCG） deposits,there are common factors among all of these at the lithospheric to crustal scale.All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or,in the case of most Phanerozoic orogenic giants,define the primary suture zones between tectonic terranes.Giant provinces of IRGS,IOCG,and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province.The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids,whereas the association of such melts with Carlin-type ores is more indirect and enigmatic.Giant orogenic gold provinces show no direct relationship to such magmatism.forming from metamorphic fluids,but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.In contrast to their province scale similarities,the different giant gold deposit styles show contrasting critical controls at the district to deposit scale.For orogenic gold deposits,the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits,with resultant geometrical and lithostratigraphic complexity as a guide to their location.There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits,and those few giants are essentially preservational exceptions.Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks,enriched in syngenetic gold,to be located below an impermeable cap along antiformal ＂trends＂.Hydrocarbons probably played an important role in concentrating metal.The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock.All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources,partly due to economic factors for this relatively poorly understood,low Cu-Au grade deposit type.The supergiant Olympic Dam deposit,the most shallowly formed deposit among the larger IOCGs,probably owes its origin to eruption of volatile-rich hybrid magma at surface,with formation of a large maar and intense and widespread brecciation,alteration and Cu-Au-U deposition in a huge rock volume.

Improving Land Resource Evaluation Using Fuzzy Neural Network Ensembles

Land evaluation factors often contain continuous-, discrete- and nominal-valued attributes. In traditional land evaluation, these different attributes are usually graded into categorical indexes by land resource experts, and the evaluation results rely heavily on experts＇ experiences. In order to overcome the shortcoming, we presented a fuzzy neural network ensemble method that did not require grading the evaluation factors into categorical indexes and could evaluate land resources by using the three kinds of attribute values directly. A fuzzy back propagation neural network （BPNN）, a fuzzy radial basis function neural network （RBFNN）, a fuzzy BPNN ensemble, and a fuzzy RBFNN ensemble were used to evaluate the land resources in Guangdong Province. The evaluation results by using the fuzzy BPNN ensemble and the fuzzy RBFNN ensemble were much better than those by using the single fuzzy BPNN and the single fuzzy RBFNN, and the error rate of the single fuzzy RBFNN or fuzzy RBFNN ensemble was lower than that of the single fuzzy BPNN or fuzzy BPNN ensemble, respectively. By using the fuzzy neural network ensembles, the validity of land resource evaluation was improved and reliance on land evaluators＇ experiences was considerably reduced.

Soil Quality Assessment Using Weighted Fuzzy Association Rules

Fuzzy association rules (FARs) can be powerful in assessing regional soil quality, a critical step prior to land planning and utilization; however, traditional FARs mined from soil quality database, ignoring the importance variability of the rules, can be redundant and far from optimal. In this study, we developed a method applying different weights to traditional FARs to improve accuracy of soil quality assessment. After the FARs for soil quality assessment were mined, redundant rules were eliminated according to whether the rules were significant or not in reducing the complexity of the soil quality assessment models and in improving the comprehensibility of FARs. The global weights, each representing the importance of a FAR in soil quality assessment, were then introduced and refined using a gradient descent optimization method. This method was applied to the assessment of soil resources conditions in Guangdong Province, China. The new approach had an accuracy of 87%, when 15 rules were mined, as compared with 76% from the traditional approach. The accuracy increased to 96% when 32 rules were mined, in contrast to 88% from the traditional approach. These results demonstrated an improved comprehensibility of FARs and a high accuracy of the proposed method.

A study on 3-D velocity structure of crust and upper mantle in Sichuan -Yunnan region, China

Based on the first arrival P and S data of 4 625 regional earthquakes recorded at 174 stations dispersed in the Yunnan and Sichuan Provinces, the 3-D velocity structure of crust and upper mantle in the region is determined, incorporating with previous deep geophysical data. In the upper crust, a positive anomaly velocity zone exists in the Sichuan basin, whereas a negative anomaly velocity zone exists in the western Sichuan plateau. The boundary between the positive and negative anomaly zones is the Longmenshan fault zone. The images of lower crust and upper mantle in the Longmenshan fault, Xianshuihe fault, Honghe fault and others show the characteristic of tectonic boundary, indicating that the faults likely penetrate the Moho discontinuity. The negative velocity anomalies at the depth of 50 km in the Tengchong volcanic area and the Panxi tectonic zone appear to be associated with the temperature and composition variations in the upper mantle. The overall features of the crustal and the upper mantle structures in the SichuanYunnan region are the lower average velocity in both crust and uppermost mantle, the large crustal thickness variations, and the existence of high conductivity layer in the crust or/and upper mantle, and higher geothermal value. All these features are closely related to the collision between the India and the Asia plates. The crustal velocity in the SichuanYunnan rhombic block generally shows normal value or positive anomaly, while the negative anomaly exists in the area along the large strike-slip faults as the block boundary. It is conducive to the crustal block side-pressing out along the faults. In the major seismic zones, the seismicity is relative to the negative anomaly velocity. Most strong earthquakes occurred in the upper-mid crust with positive anomaly or normal velocity, where the negative anomaly zone generally exists below.

Arsenic variability and groundwater age in three water supply wells in southeast New Hampshire

Three wells in New Hampshire were sampled bimonthly over three years to evaluate the temporal variability of arsenic concentrations and groundwater age.All samples had measurable concentrations of arsenic throughout the entire sampling period and concentrations in individual wells had a mean variation of more than 7 μg/L.The time series data from this sampling effort showed that arsenic concentrations ranged from a median of 4 mg/L in a glacial aquifer well (SGW-65) to medians of 19 μg/L and 37 μg/L in wells (SGW-93 and KFW-87) screened in the bedrock aquifer,respectively.These high arsenic concentrations were associated with the consistently high pH (median ≥- 8) and low dissolved oxygen (median <0.1 mg/L) in the bedrock aquifer wells,which is typical of fractured crystalline bedrock aquifers in New Hampshire.Groundwater from the glacial aquifer often has high dissolved oxygen,but in this case was consistently low.The pH also is generally acidic in the glacial aquifer but in this case was slightly alkaline (median =7.5).Also,sorption sites may be more abundant in glacial aquifer deposits than in fractured bedrock which may contribute to lower arsenic concentrations.Mean groundwater ages were less than 50 years old in all three wells and correlated with conservative tracer concentrations,such as chloride;however,mean age was not directly correlated with arsenic concentrations.Arsenic concentrations at KFW-87 did correlate with water levels,in addition,there was a seasonal pattern,which suggests that either the timing of or multiple sampling efforts may be important to define the full range of arsenic concentrations in domestic bedrock wells.Since geochemically reduced conditions and alkaline pHs are common to both bedrock and glacial aquifer wells in this study,groundwater age correlates less strongly with arsenic concentrations than geochemical conditions.There also is evidence of direct hydraulic connection between the glacial and bedrock aquifers,which can influence arsenic concentrations.Correlations between arsenic concentrations and the age of the old fraction of water in SGW-65 and the age of the young fraction of water in SGW-93 suggest that water in the two aquifers may be mixing or at least some of the deeper,older water captured by the glacial aquifer well may be from a similar source as the shallow young groundwater from the bedrock aquifer.The contrast in arsenic concentrations in the two aquifers may be because of increased adsorption capacity of glacio-fluvial sediments,which can limit contaminants more than fractured rock.In addition,this study illustrates that long residence times are not necessary to achieve more geochemically evolved conditions such as high pH and reduced conditions as is typically found with older water in other regions.

The IUGS/IAGC Task Group on Global Geochemical Baselines

The Task Group on Global Geochemical Baselines,operating under the auspices of both the International Union of Geological Sciences(IUGS) and the International Association of Geochemistry(IAGC),has the long-term goal of establishing a global geochemical database to document the concentration and distribution of chemical elements in the Earth's surface or near-surface environment.The database and accompanying element distribution maps represent a geochemical baseline against which future human-induced or natural changes to the chemistry of the land surface may be recognized and quantified.In order to accomplish this long-term goal,the activities of the Task Group include:(1) developing partnerships with countries conducting broad-scale geochemical mapping studies;(2) providing consultation and training in the form of workshops and short courses;(3) organizing periodic international symposia to foster communication among the geochemical mapping community;(4) developing criteria for certifying those projects whose data are acceptable in a global geochemical database;(5) acting as a repository for data collected by those projects meeting the criteria for standardization;(6) preparing complete metadata for the certified projects;and(7) preparing,ultimately,a global geochemical database.This paper summarizes the history and accomplishments of the Task Group since its first predecessor project was established in 1988.

The dilemma of the Jiaodong gold deposits: Are they unique?

The ca. 126e120 Ma Au deposits of the Jiaodong Peninsula, eastern China, define the country＇s largest gold province with an overall endowment estimated as＆gt;3000 t Au. The vein and disseminated ores are hosted by NE-to NNE-trending brittle normal faults that parallel the margins of ca. 165e150 Ma, deeply emplaced, lower crustal melt granites. The deposits are sited along the faults for many tens of kilometers and the larger orebodies are associated with dilatational jogs. Country rocks to the granites are Pre-cambrian high-grade metamorphic rocks located on both sides of a Triassic suture between the North and South China blocks. During early Mesozoic convergent deformation, the ore-hosting structures developed as ductile thrust faults that were subsequently reactivated during Early Cretaceous ＂Yan-shanian＂intracontinental extensional deformation and associated gold formation. 〈br〉 Classification of the gold deposits remains problematic. Many features resemble those typical of orogenic Au including the linear structural distribution of the deposits, mineralization style, ore and alteration assemblages, and ore fluid chemistry. However, Phanerozoic orogenic Au deposits are formed by prograde metamorphism of accreted oceanic rocks in Cordilleran-style orogens. The Jiaodong de-posits, in contrast, formed within two Precambrian blocks approximately 2 billion years after devolati-lization of the country rocks, and thus require a model that involves alternative fluid and metal sources for the ores. A widespread suite of ca. 130e123 Ma granodiorites overlaps temporally with the ores, but shows a poor spatial association with the deposits. Furthermore, the deposit distribution and mineral-ization style is atypical of ores formed from nearby magmas. The ore concentration requires fluid focusing during some type of sub-crustal thermal event, which could be broadly related to a combination of coeval lithospheric thinning, asthenospheric upwelling, paleo-Pacific plate subduction, and seismicity along the continental-scale Tan-Lu fault. Possible ore genesis scenarios include those where ore fluids were produced directly by the metamorphism of oceanic lithosphere and overlying sediment on the subducting paleo-Pacific slab, or by devolatilization of an enriched mantle wedge above the slab. Both the sulfur and gold could be sourced from either the oceanic sediments or the serpentinized mantle. A better understanding of the architecture of the paleo-Pacific slab during Early Cretaceous below the eastern margin of China is essential to determination of the validity of possible models.

Active forest management accelerates carbon storage in plantation forests in Lishui,southern China

Background:China has committed to achieving peak CO_(2)emissions before 2030 and carbon neutrality before 2060;therefore,accelerated efforts are needed to better understand carbon accounting in industry and energy fields as well as terrestrial ecosystems.The carbon sink capacity of plantation forests contributes to the mitigation of climate change.Plantation forests throughout the world are intensively managed,and there is an urgent need to evaluate the effects of such management on long-term carbon dynamics.Methods:We assessed the carbon cycling patterns of ecosystems characterized by three typical plantation species(Chinese fir(Cunninghamia lanceolata(Lamb.)Hook.),oak(Cyclobalanopsis glauca(Thunb.)Oerst.),and pine(Pinus massoniana Lamb.))in Lishui,southern China,by using an integrated biosphere simulator(IBIS)tuned with localized parameters.Then,we used the state-and-transition simulation model(STSM)to study the effects of active forest management(AFM)on carbon storage by combining forest disturbance history and carbon cycle regimes.Results:1)The carbon stock of the oak plantation was lower at an early age(<50 years)but higher at an advanced age(>50 years)than that of the Chinese fir and pine plantations.2)The carbon densities of the pine and Chinese fir plantations peaked at 70 years(223.36 Mg⋅ha^(‒1))and 64 years(232.04 Mg⋅ha^(‒1)),respectively,while the carbon density in the oak plantation continued increasing(>100 years).3)From 1989 to 2019,the total carbon pools of the three plantation ecosystems followed an upward trend(an annual increase of 0.16–0.22 Tg C),with the largest proportional increase in the aboveground biomass carbon pool.4)AFM increased the recovery of carbon storage after 1996 and 2009 in the pine and Chinese fir plantations,respectively,but did not result in higher growth in the oak plantation.5)The proposed harvest planning is reasonable and conducive to maximizing the carbon sequestration capacity of the forest.Conclusions:This study provides an example of a carbon cycle coupling model that is potentially suitable for simulating China's plantation forest ecosystems and supporting carbon accounting to monitor peak CO_(2)emissions and reach carbon neutrality.

Tracking domestic ducks:A novel approach for documenting poultry market chains in the context of avian influenza transmission

Agro-ecological conditions associated with the spread and persistence of highly pathogenic avian inlfuenza （HPAI） are not well understood, but the trade of live poultry is suspected to be a major pathway. Although market chains of live bird trade have been studied through indirect means including interviews and questionnaires, direct methods have not been used to identify movements of individual poultry. To bridge the knowledge gap on quantitative movement and transportation of poultry, we introduced a novel approach for applying telemetry to document domestic duck movements from source farms at Poyang Lake, China. We deployed recently developed transmitters that record Global Positioning System （GPS） locations and send them through the Groupe Spécial Mobile （GSM） cellular telephone system. For the ifrst time, we were able to track individually marked ducks from 3 to 396 km from their origin to other farms, distribution facilities, or live bird markets. Our proof of concept test showed that the use of GPS-GSM transmitters may provide di-rect, quantitative information to document the movement of poultry and reveal their market chains. Our ifndings provide an initial indication of the complexity of source-market network connectivity and highlight the great potential for future telemetry studies in poultry network analyses.

In-Situ SHRIMP U-Pb Dating of Xenotime Outgrowth on Detrital Zircon Grains from the Changzhougou Formation of the Ming Tomb District, Beijing

SHRIMP U-Pb dating of diagenetic xenotime from sedimentary rocks has provided age constraints for sedimentary diagenesis （McNaughton et al., 1999; Fletcher et al., 2000; England et al., 2001; Rasmussen et al., 2004; Vallini et al., 2007）. Xenotime （YPO4） may grow during early diagenesis, typically being present as a trace constituent in siliciclastic sedimentary rocks （Rasmussen, 2005）, in the form of syntaxial outgrowths on detrital zircon grains. Diagenetic xenotime occurs in a wide variety of rock types, including conglomerate,

Discussion on the dextral movement and its effect in continental China and adjacent areas since Cenozoic

Continental China has moved dextral Eastward since Cenozoic time,driven by the collision of the Indian with the Eurasian plate.Evidence for this comes from landscape evolution,the distribution of earthquake epicenters,Cenozoic sedimentary and volcanic rocks,and the measurement of GPS velocity vectors,the distribntion of crustal stress,paleomagnetic data,and deep mantle structure,among others.This movement commenced around 40 Ma,coupled with thickened lithosphere and widespread stress release along strikeslip faults that bound the continental Chinese block.Because of continued Northward subduction of the Indian plate,manifestation of the dextral movement has intensified since 25 Ma.Far-reaching effects include extensive strike-slip movement on the Tan-Lu fault in Eastern China,formation of the Dabie ultrahigh pressure metamorphic terrane,extensive thrust faults in East China,delamination and thickening of the lithosphere of South China,a possible tectonic doubling of the Middle-Lower Yangtze Valley metallogenic belt,and the formation of the Japan,Huanghai (East China),and South China Sea.

History and evaluation of national-scale geochemical data sets for the United States

Six national-scale,or near national-scale,geochemical data sets for soils or stream sediments exist for the United States.The earliest of these,here termed the ＇Shacklette＇ data set,was generated by a U.S. Geological Survey（USGS） project conducted from 1961 to 1975.This project used soil collected from a depth of about 20 cm as the sampling medium at 1323 sites throughout the conterminous U.S.The National Uranium Resource Evaluation Hydrogeochemical and Stream Sediment Reconnaissance（NUREHSSR） Program of the U.S.Department of Energy was conducted from 1975 to 1984 and collected either stream sediments,lake sediments,or soils at more than 378,000 sites in both the conterminous U.S.and Alaska.The sampled area represented about 65%of the nation.The Natural Resources Conservation Service（NRCS）,from 1978 to 1982,collected samples from multiple soil horizons at sites within the major crop-growing regions of the conterminous U.S.This data set contains analyses of more than 3000 samples.The National Geochemical Survey,a USGS project conducted from 1997 to 2009,used a subset of the NURE-HSSR archival samples as its starting point and then collected primarily stream sediments, with occasional soils,in the parts of the U.S.not covered by the NURE-HSSR Program.This data set contains chemical analyses for more than 70,000 samples.The USGS,in collaboration with the Mexican Geological Survey and the Geological Survey of Canada,initiated soil sampling for the North American Soil Geochemical Landscapes Project in 2007.Sampling of three horizons or depths at more than 4800 sites in the U.S.was completed in 2010,and chemical analyses are currently ongoing.The NRCS initiated a project in the 1990s to analyze the various soil horizons from selected pedons throughout the U.S.This data set currently contains data from more than 1400 sites.This paper（1） discusses each data set in terms of its purpose,sample collection protocols,and analytical methods;and（2） evaluates each data set in terms of its appropriateness as a national-scale geochemical database and its usefulness for nationalscale geochemical mapping.

Structural stability of methane hydrate at high pressures

The structural stability of methane hydrate under pressure at room temperature was examined by both in-situ single-crystal and powder X-ray diffraction techniques on samples with structure types I, II, and H in diamond-anvil ceils. The diffraction data for types II （slI） and H （sH） were refined to the known structures with space groups Fd3m and P63/mmc, respectively. Upon compression, sl methane hydrate transforms to the sll phase at 120 MPa, and then to the sH phase at 600 MPa. The slI methane hydrate was found to coexist locally with sI phase up to 500 MPa and with sH phase up to 600 MPa. The pure sH structure was found to be stable between 600 and 900 MPa. Methane hydrate decomposes at pressures above 3 GPa to form methane with the orientationally disordered Fm3m structure and ice VII （Pn3m）. The results highlight the role of guest （CH4）-host （H2O） interactions in the stabilization of the hydrate structures under pressure.

Identification of the Early Jurassic mylonitic granitic pluton and tectonic implications in Namling area,southern Tibet

A number of studies revealed that the Gangdese magmatic belt of southern Tibet was closely related to the northward subduction of the Neo-Tethys oceanic lithosphere and Indo-Asian collision.However,pre-Cretaceous magmatism is still poorly constrained in the Gangdese magmatic belt,southern Tibet.Here,we conducted systematically geochronology and geochemistry studies on a newly-identified granitic pluton in the middle Gangdese magmatic belt(Namling area),southern Tibet.Zircon SHRIMPⅡU-Pb dating for one representative sample gives a weighted age of 184.2±1.8 Ma(MSWD=±1.11),corresponding to emplacement and crystallization age of the granitic pluton in the Early Jurassic(Pliensbachian).High SiO2(68.9-72.1 wt.%)contents and intermediate Mg#values(35-38)together suggest that the newly-identified granitic pluton was probably formed by partial melting of crustal material with minor injection of mantle-derived magma,precluding an origin from melting of metasedimentary rocks that are characterized by low Mg#and high zirconδ^18O values(>8‰).Geochemically,the newly-identified granitic pluton belongs to typical I-type granitic affinity,whereas this is inconsistent with aluminium saturation index(ASI=A/CNK ratios)and geochemical signatures.This suggests that zircon oxygen isotopes(4.30‰-5.28‰)and mineral features(lacking Al-rich minerals)are reliable indicators for discriminating granitic origin.Significantly depleted whole-rock Sr-Nd-Hf isotopic compositions and zirconεHf(t)values indicate that the granitic pluton was derived from partial melting of depleted arc-type lavas.In addition,the granitic pluton shows zirconδ^18O values ranging from 4.30‰to 5.28‰(with a mean value of 4.77‰)that are consistent with mantle-derived zircon values(5.3‰±0.6‰)within the uncertainties,indicating that the granitic pluton might have experienced weak short-living high-temperature hydrous fluid-rock interaction.Combined with the Sr-Nd-Hf-O isotopes and geochemical signatures,we propose that the newly-identified granitic pluton was originated from partial melting of depleted mafic lower crust,and experienced only negligible wall-rock contamination during ascent.Integrated with published data,we also propose that the initial subduction of the Neo-Tethys oceanic lithosphere occurred no later than the Pliensbachian of the Early Jurassic.

South Carolina forestland owners’ willingness to accept compensations for carbon sequestration

Background: Carbon sequestration through recommended forest management practices is an ecosystem service that helps mitigate climate change and its impacts while generating carbon credits for forestland owners to sell in cap-and-trade programs. The California’s cap-and-trade program (California’s carbon market hereafter) allows forestland owners from any part of the contiguous United States to supply carbon credits to compliance entities. In this study, we estimate South Carolina (SC) private forestland owners’willingness to accept compensations to participate in the California’s carbon market using a contingent valuation method. Results: We estimate forestland owners’mean willingness to accept as$67 per acre per year. Our results reveal higher probability of participation of forestland owners with interests in preserving forest ecosystems than those who do not. Additionally, forestland owners who trust in information about climate change from scientists or government are willing to participate more than those who do not. Conclusions: Various factors hinder landowners’ability to participate in carbon markets. Forestland owners in SC consider legislative uncertainty and long-time commitment as the main barriers to participation in California’s carbon market. From this research, average forestland tenure in SC is 27 years, which is far less than the 100-year time commitment of the California’s carbon market. Of those who agreed to participate, choosing between adopting and not adopting any of the three main forest management practices in the California’s carbon market:28% are likely to adopt improved forest management (IFM) practices, 24% are likely to adopt reforestation due to understocked forestlands, and 14% are likely to adopt avoided conversion. In another development, the concept of aggregation has dominated discussions in the California’s carbon market of late. It is an advocacy to include small-scale forestlands in the California’s carbon market. To aggregate, different forestland owners will combine their forestlands to participate. We find that 79% of SC forestland owners are willing to aggregate to participate. However, this research is unable to determine how much total forestland is available in SC for carbon market. We recommend future research in the State on forestland owners’participation in carbon market should consider evaluating forestland availability.