In industrial areas, tree leaves contaminated by metals and metalloids could constitute a secondary source of pollutants. In the present study, water extraction kinetics of inorganic elements (IE: Pb, Zn, Cd, As, Fe...In industrial areas, tree leaves contaminated by metals and metalloids could constitute a secondary source of pollutants. In the present study, water extraction kinetics of inorganic elements (IE: Pb, Zn, Cd, As, Fe and Mn), dissolved organic carbon, pH and biological activity were studied for industrial contaminated poplar leaves. Moreover, the distribution of the IE through the size fractions of the associated top soil was measured. High quantities ofMn, Zn and As and polysaccharides were released in the solution from the strongly contaminated leaves. The kinetic of release varied with time and metal type. The solution pH decreased while dissolved organic contents increased with time after 30 days. Therefore, these contaminated leaves could constitute a source of more available organic metals and metalloids than the initial inorganic process particles. However, the distribution of the IE through the size fractions of the top soil suggested that a great part of the released IE was adsorbed, reducing in consequence their transfers and bioavailability. It's concluded that mobility/boioavailability and speciation of metals and metalloids released from the decomposition of polluted tree leaves depends on soil characteristics, pollutant type and litter composition, with consequences for environmental risk assessment.展开更多
We propose theoretically and demonstrate experimentally the generation of light pulses whose polarization varies temporally to cover selected areas of the Poincare´sphere with both tunable swirling speed and tota...We propose theoretically and demonstrate experimentally the generation of light pulses whose polarization varies temporally to cover selected areas of the Poincare´sphere with both tunable swirling speed and total duration(1 ps and 10 ps,respectively,in our implementation).The effect relies on the Rabi oscillations of two polariton polarized fields excited by two counter-polarized and delayed pulses.The superposition of the oscillating fields result in the precession of the Stokes vector of the emitted light while polariton lifetime imbalance results in its drift from a circle of controllable radius on the Poincare´sphere to a single point at long times.The positioning of the initial circle and final point allows to engineer the type of polarization spanning,including a full sweeping of the Poincare´sphere.The universality and simplicity of the scheme should allow for the deployment of time-varying full-Poincare´polarization fields in a variety of platforms,timescales,and regimes.展开更多
Slow motion for scalar Allen-Cahn type equation is a well-known phenomenon,precise motion law for the dynamics of fronts having been established first using the socalled geometric approach inspired from central manifo...Slow motion for scalar Allen-Cahn type equation is a well-known phenomenon,precise motion law for the dynamics of fronts having been established first using the socalled geometric approach inspired from central manifold theory(see the results of Carr and Pego in 1989). In this paper, the authors present an alternate approach to recover the motion law, and extend it to the case of multiple wells. This method is based on the localized energy identity, and is therefore, at least conceptually, simpler to implement. It also allows to handle collisions and rough initial data.展开更多
文摘In industrial areas, tree leaves contaminated by metals and metalloids could constitute a secondary source of pollutants. In the present study, water extraction kinetics of inorganic elements (IE: Pb, Zn, Cd, As, Fe and Mn), dissolved organic carbon, pH and biological activity were studied for industrial contaminated poplar leaves. Moreover, the distribution of the IE through the size fractions of the associated top soil was measured. High quantities ofMn, Zn and As and polysaccharides were released in the solution from the strongly contaminated leaves. The kinetic of release varied with time and metal type. The solution pH decreased while dissolved organic contents increased with time after 30 days. Therefore, these contaminated leaves could constitute a source of more available organic metals and metalloids than the initial inorganic process particles. However, the distribution of the IE through the size fractions of the top soil suggested that a great part of the released IE was adsorbed, reducing in consequence their transfers and bioavailability. It's concluded that mobility/boioavailability and speciation of metals and metalloids released from the decomposition of polluted tree leaves depends on soil characteristics, pollutant type and litter composition, with consequences for environmental risk assessment.
基金We acknowledge funding from the MIUR project Beyond Nano,the ERC Grant POLAFLOW(308136)the IEF project SQUIRREL(623708)and the support from IRSES project POLAPHEN.
文摘We propose theoretically and demonstrate experimentally the generation of light pulses whose polarization varies temporally to cover selected areas of the Poincare´sphere with both tunable swirling speed and total duration(1 ps and 10 ps,respectively,in our implementation).The effect relies on the Rabi oscillations of two polariton polarized fields excited by two counter-polarized and delayed pulses.The superposition of the oscillating fields result in the precession of the Stokes vector of the emitted light while polariton lifetime imbalance results in its drift from a circle of controllable radius on the Poincare´sphere to a single point at long times.The positioning of the initial circle and final point allows to engineer the type of polarization spanning,including a full sweeping of the Poincare´sphere.The universality and simplicity of the scheme should allow for the deployment of time-varying full-Poincare´polarization fields in a variety of platforms,timescales,and regimes.
文摘Slow motion for scalar Allen-Cahn type equation is a well-known phenomenon,precise motion law for the dynamics of fronts having been established first using the socalled geometric approach inspired from central manifold theory(see the results of Carr and Pego in 1989). In this paper, the authors present an alternate approach to recover the motion law, and extend it to the case of multiple wells. This method is based on the localized energy identity, and is therefore, at least conceptually, simpler to implement. It also allows to handle collisions and rough initial data.