The mineralogical, petrological and geochemical studies on Keliyang (克里阳) potassic dykes have been carried out to understand their rock types, the petrogenesis and the nature of their mantle sources. They arc pot...The mineralogical, petrological and geochemical studies on Keliyang (克里阳) potassic dykes have been carried out to understand their rock types, the petrogenesis and the nature of their mantle sources. They arc potassic lamprophyre, not lamproites as the previous researchers believed. In this study, the whole-rock major and trace element compositions of another 6 lamproite dykes recently discovered are reported. Major elements were determined by X-ray fluorescence spectrometry (XRF) techniques, while REE and trace elements were determined by inductively coupled plasma mass spectrometry (ICP-MS). They can be classified into phlogopite-diopside lamprophyre, leucite-diopside lamprophyre and granular carbonatite-bearing diopside lamprophyre on the basis of their mineral components. They are all characterized by relatively low SiO2 (41.31% --44. 84% ), TIO2 (0.75%-0.86% ) and high MgO (7.30%-11.33%), K2O (4.01%-6.01%) concentrations with K2O/Na2O ratios of 2.77-12.49. In addition, they display enrichment in large-ion lithophile elements (LILEs, e. g., Rb, Sr, Ba) and LREE, but a relative depletion in high-field-strength elements (HFSEs, e.g. , Nb, Ta, Zr, Hf and Ti). They display similar chondrite-normalized REE patterns with slight negative Eu anomalies (δEu=0.64-0.82), and high initial ^87 Sr/^86Sr ratios, which resemble those of high K/Ti and Iow-Ti potassic magmas formed in subduction-related settings. Consequently, we suggest that the parental magma was generated by partial melting of the phlogopite-amphibole-bearing garnet lherzolite within the lithospheric mantle that might have been metasomatized by a potassium-bearing fluid released from a sabdaction oceanic crust.展开更多
In the past decades,global land cover datasets have been produced but also been criticized for their low accuracies,which have been affecting the applications of these datasets.Producing a new global dataset requires ...In the past decades,global land cover datasets have been produced but also been criticized for their low accuracies,which have been affecting the applications of these datasets.Producing a new global dataset requires a tremendous amount of efforts;however,it is also possible to improve the accuracy of global land cover mapping by fusing the existing datasets.A decision-fuse method was developed based on fuzzy logic to quantify the consistencies and uncertainties of the existing datasets and then aggregated to provide the most certain estimation.The method was applied to produce a 1-km global land cover map(SYNLCover)by integrating five global land cover datasets and three global datasets of tree cover and croplands.Efforts were carried out to assess the quality:1)inter-comparison of the datasets revealed that the SYNLCover dataset had higher consistency than these input global land cover datasets,suggesting that the data fusion method reduced the disagreement among the input datasets;2)quality assessment using the human-interpreted reference dataset reported the highest accuracy in the fused SYNLCover dataset,which had an overall accuracy of 71.1%,in contrast to the overall accuracy between 48.6%and 68.9%for the other global land cover datasets.展开更多
We propose the design of an observation station to establish a reliable datum for displacement and deformation analysis at the first working-face subsidence observation station of Liuzhuang Mine. The design considers ...We propose the design of an observation station to establish a reliable datum for displacement and deformation analysis at the first working-face subsidence observation station of Liuzhuang Mine. The design considers various geologic and mining con-ditions. Having analyzed the aims of the joint survey and the comprehensive survey, we propose design principles, and work modes, for adopting GPS technology as the position measuring technique to be used in these two stages. Baseline vectors and spatial ad-justments of the GPS network were calculated after study of data processing and quality estimation methods. A coordinate system transformation and error estimates of the transformed GPS network data are discussed. The error estimates in all stages show that the GPS control network of the observation station has sufficient accuracy and is highly efficient. The network thus provides a reli-able datum for analyzing the laws of surface displacement and deformation induced by mining.展开更多
Although compatibility is highly advocated in traditional Chinese medicine (TCM), inappropriate combination of some herbs may reduce the therapeutic action and even produce toxic effects. Kansui and licorice, one of T...Although compatibility is highly advocated in traditional Chinese medicine (TCM), inappropriate combination of some herbs may reduce the therapeutic action and even produce toxic effects. Kansui and licorice, one of TCM “Eighteen Incompatible Medicaments”, are the most representative cases of improper herbal combination, which may still be applied simultaneously under given conditions. However, the potential mechanism of their compatibility and incompatibility is unclear. In the present study, two different ratios of kansui and licorice, representing their compatibility and incompatibility respectively, were designed to elucidate their interaction by comparative plasma/tissue metabolomics and a heatmap with relative fold change. As a result, glycocholic acid, prostaglandin F2a, dihydroceramide and sphinganine were screened out as the principal alternative biomarkers of compatibility group;sphinganine, dihydroceramide, arachidonic acid, leukotriene B4, acetoacetic acid and linoleic acid were those of incompatibility group. Based on the values of biomarkers in each tissue, the liver was identified as the compatible target organ, while the heart, liver, and kidney were the incompatible target organs. Furthermore, important pathways for compatibility and incompatibility were also constructed. These results help us to better understand and utilize the two herbs, and the study was the first to reveal some innate characters of herbs related to TCM “Eighteen Incompatible Medicaments”.展开更多
High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),China.To improve the performance of crude-oil removal,mi...High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),China.To improve the performance of crude-oil removal,microbiota was further immobilized by two methods,i.e.,sodium alginate(SA),and polyvinyl alcohol and sodium alginate(PVA+SA).Results showed that the crude oil was effectively removed by the enrichment with an average degrading ratio of 19.42-31.45 mg(L d)^(−1).The optimal inoculum size for the n-alkanes removal was 10%and 99.89%.Some members of genera Acinetobacter,Actinophytocola,Aquabac-terium,Dysgonomonas,Frigidibacter,Sphingobium,Serpens,and Pseudomonas dominated in crude-oil degrading microflora.Though the removal efficiency was lower than free bacteria when the temperature was 15℃,SA and PVA+SA immobilization im-proved the resistance to salinity.The composite crude-oil degrading microbiota in this study demonstrated a perspective potential for crude oil removal from surface water under high salinity and low temperature conditions.展开更多
The Action Group called‘Standardized methods across Permafrost Landscapes:from Arctic Soils to Hydrosystems’(SPLASH)is a community-driven effort aiming to provide a suite of standardized field strategies for samplin...The Action Group called‘Standardized methods across Permafrost Landscapes:from Arctic Soils to Hydrosystems’(SPLASH)is a community-driven effort aiming to provide a suite of standardized field strategies for sampling mineral and organic components in soils,sediments,and water across permafrost landscapes.This unified approach will allow data from different landscape interfaces,field locations and seasons to be shared and compared,thus improving our understanding of the processes occurring during lateral transport in circumpolar Arctic watersheds.展开更多
Long-chain n-alkanols and n-alkanes in core sediments from the northern South China Sea(SCS)were measured to make a comparison during terrestrial vegetation reconstruction from~42 ka to~7 ka.The results showed that te...Long-chain n-alkanols and n-alkanes in core sediments from the northern South China Sea(SCS)were measured to make a comparison during terrestrial vegetation reconstruction from~42 ka to~7 ka.The results showed that terrestrial vegetation record from long-chain n-alkanes matched well with previous studies in nearby cores,showing that more C_(4)plants developed during the Last Glacial Maximum(LGM)and C_(3)plants dominated in the interglacial period.However,these scenarios were not revealed by terrestrial vegetation reconstruction using long-chain n-alkanols,which showed C_(3)plant expansion during the LGM.The discrepancy during the interglacial period could be attributed to the aerobic degradation of functionalized long-chain n-alkanols in the oxygen-rich bottom water,resulting in poor preservation of terrestrial vegetation signals.On the other hand,the different advantages of functionalized n-alkanols and non-functional n-alkanes to record local and distal vegetation signals,respectively,may offer a potential explanation for the contradiction during the LGM when the SCS was characterized by low-oxygen deep water.Nevertheless,large variations on n-alkyl lipid compositions in C_(3)/C_(4)plants could play a part in modulating sedimentary long-chain n-alkanols and n-alkanes toward different vegetation signals,thereby suggesting that caution must be taken in respect to the terrestrial vegetation reconstruction using long-chain n-alkanes and long-chain n-alkanols.展开更多
Family-based tests of association between a genetic marker and a disease constitute a common design to dissect the genetic architecture of complex traits. The FBAT software is one of the most popular tools to perform ...Family-based tests of association between a genetic marker and a disease constitute a common design to dissect the genetic architecture of complex traits. The FBAT software is one of the most popular tools to perform such studies. However, researchers are also often interested in the genetic contribution to a more specific manifestation of the phenotype (e.g. severe vs. non-severe form) known as a secondary outcome. Here, what we demonstrate is the limited power of the classical formulation of the FBAT statistic to detect the effect of genetic variants that influence a secondary outcome, in particular when these variants also impact on the onset of the disease, the primary outcome. We prove that this loss of power is driven by an implicit hypothesis, and we propose a derivation of the original FBAT statistic, free from this implicit hypothesis. Finally, we demonstrate analytically that our new statistic is robust and more powerful than FBAT for the detection of association between a genetic variant and a secondary outcome.展开更多
Aluminosilicate small pore zeolites belonging to ABC-6 family play crucially important roles in the high methanol conversion with the high selectivity of light olefins,gas separation and storage,and selective catalyti...Aluminosilicate small pore zeolites belonging to ABC-6 family play crucially important roles in the high methanol conversion with the high selectivity of light olefins,gas separation and storage,and selective catalytic reduction of NO_(x).In this work,we report a general method,called the epitaxial growth approach,for designing ABC-6 family small pore zeolites.It is mainly realized through the epitaxial growth on the nonporous SOD-type zeolite in the presence of inorganic cations(Na^(+)and K^(+))combined with a variety of organic structure directing agents(OSDAs).In this case,a series of ABC-6 family small pore zeolites such as ERI-,SWY-,LEV-,AFX-,and PTT-type zeolites have been successfully synthesized within a few hours.More importantly,the advanced focused ion beam(FIB)and the low-dose high-resolution transmission electron microscopy(HRTEM)imaging technique have been utilized for unraveling the zeolite heterojunction at the atomic level during the epitaxial growth process.It turns out(222)crystallographic planes of the SOD-type zeolite substrate provide unique pre-building units,which facilitate the growth of targeted ABC-6 family small pore zeolites along its c-axis.Moreover,the morphologies of ERI-type zeolite can also be tuned through the epitaxial growth approach,achieving a longer lifetime in the methanol conversion.展开更多
基于植被降水利用效率(rainfall use efficiency,RUE)模型,综合气候、土地利用/覆盖及光学遥感3个维度,分离人为干预(增加/减少)因素,监测生长季RUE时空演变特征,进一步采用地理探测器法探讨其驱动力。结果显示:(1)宝鸡地区经过两轮退...基于植被降水利用效率(rainfall use efficiency,RUE)模型,综合气候、土地利用/覆盖及光学遥感3个维度,分离人为干预(增加/减少)因素,监测生长季RUE时空演变特征,进一步采用地理探测器法探讨其驱动力。结果显示:(1)宝鸡地区经过两轮退耕还林(草)工程,RUE整体上呈提高趋势,尤其是第一轮后(2009—2013年)呈显著提高趋势的像元面积占比最高,达65.69%。全区由第一轮工程实施下(2001—2008年)的以人为干预增加区域为主转变为以人为干预减少为主;(2)夏季降水量最为充裕,春季雨量较差,表现为夏季RUE的提高速率[0.07·(10a)-1]和春季RUE的降低速率[-0.06·(10a)-1]均最为显著。年际、夏秋季,林地的RUE值最高,春季城乡用地的RUE值最高;(3)植被覆盖率、相对湿度、日照时数、粮食总产量、最大风速、降水量、气温、人口密度、造林面积对RUE的相关性依次递减(置信水平95%),植被类型、坡度、坡向对RUE的相关性不显著。交互作用下RUE空间分布的相关性表现为:气候环境因素>自然资源因素>人类活动因素>地理环境因素。随着坡度的增加,RUE呈先增加后减少的变化趋势,在坡度26°~31°出现拐点;造林面积与RUE具有同步增减的变化趋势;植被对RUE的促进作用显著,人口密度对RUE的胁迫作用显著。此外,665.51~679.80 mm的降水量提高RUE的风险最高,集中于陈仓区东-西水平线区域上。展开更多
Denitrification is one of the major processes causing nitrogen loss from arable soils.This study aimed to investigate the responses of nir S-type denitrifier communities to different chronic fertilization regimes acro...Denitrification is one of the major processes causing nitrogen loss from arable soils.This study aimed to investigate the responses of nir S-type denitrifier communities to different chronic fertilization regimes across the black soil region of Northeast China.Soil samples were collected from sites located in the north(NB),middle(MB),and south(SB)of the black soil region of Northeast China,each with four chronic fertilization regimes:no fertilizer(No F),chemical fertilizer(CF),manure(M),and chemical fertilizer plus manure(CFM).Methods of quantitative polymerase chain reaction(q PCR)and Illumina Mi Seq sequencing were applied to assess the abundance and composition of denitrifier communities by targeting the nir S gene.The results showed that the M and CFM regimes significantly increased the abundances of nir S-type denitrifiers compared with No F at the three locations.The majority of nir S sequences were grouped as unclassified denitrifiers,and the different fertilizers induced little variation in the relative abundance of known nir S-type denitrifier taxa.Over 90%of the sequences were shared among the four fertilization regimes at each location,but none of the abundant operational taxonomic units(OTUs)were shared among the three locations.Principal coordinate analysis(PCo A)revealed that the communities of nir S-type denitrifier were separated into three groups that corresponded with their locations.Although similar fertilization regimes did not induce consistent changes in the nir S-type denitrifier communities,soil p H and NO-3-N content simultaneously and significantly influenced the structure of nir S-type denitrifier communities at the three locations.Our results highlight that geographical separation rather than chronic fertilization was the dominant factor determining the nir S-type denitrifier community structures,and similar chronic fertilization regimes did not induce consistent shifts of nir S-type denitrifier communities in the black soils.展开更多
基金This paper is supported by the National Natural Science Foundationof China (No .40072061) the Programfor New Century ExcellentTalents in University (No. NCET-04-0728) the Fund of the K-ey Subject on Mineral Prospecting and Exploration Ⅰin Xinjiang .
文摘The mineralogical, petrological and geochemical studies on Keliyang (克里阳) potassic dykes have been carried out to understand their rock types, the petrogenesis and the nature of their mantle sources. They arc potassic lamprophyre, not lamproites as the previous researchers believed. In this study, the whole-rock major and trace element compositions of another 6 lamproite dykes recently discovered are reported. Major elements were determined by X-ray fluorescence spectrometry (XRF) techniques, while REE and trace elements were determined by inductively coupled plasma mass spectrometry (ICP-MS). They can be classified into phlogopite-diopside lamprophyre, leucite-diopside lamprophyre and granular carbonatite-bearing diopside lamprophyre on the basis of their mineral components. They are all characterized by relatively low SiO2 (41.31% --44. 84% ), TIO2 (0.75%-0.86% ) and high MgO (7.30%-11.33%), K2O (4.01%-6.01%) concentrations with K2O/Na2O ratios of 2.77-12.49. In addition, they display enrichment in large-ion lithophile elements (LILEs, e. g., Rb, Sr, Ba) and LREE, but a relative depletion in high-field-strength elements (HFSEs, e.g. , Nb, Ta, Zr, Hf and Ti). They display similar chondrite-normalized REE patterns with slight negative Eu anomalies (δEu=0.64-0.82), and high initial ^87 Sr/^86Sr ratios, which resemble those of high K/Ti and Iow-Ti potassic magmas formed in subduction-related settings. Consequently, we suggest that the parental magma was generated by partial melting of the phlogopite-amphibole-bearing garnet lherzolite within the lithospheric mantle that might have been metasomatized by a potassium-bearing fluid released from a sabdaction oceanic crust.
基金Funding support for this work were provided by the following programs:the Strategic Priority Research Program of the Chinese Academy of Sciences[Grant No.XDA20100104]the Basic Resources Investigation of Science and Technology[Grant No.2017FY100900]and the National Earth System Science Data Sharing Infrastructure,National Science&Technology Infrastructure of China[Grant No.2005DKA32300].
文摘In the past decades,global land cover datasets have been produced but also been criticized for their low accuracies,which have been affecting the applications of these datasets.Producing a new global dataset requires a tremendous amount of efforts;however,it is also possible to improve the accuracy of global land cover mapping by fusing the existing datasets.A decision-fuse method was developed based on fuzzy logic to quantify the consistencies and uncertainties of the existing datasets and then aggregated to provide the most certain estimation.The method was applied to produce a 1-km global land cover map(SYNLCover)by integrating five global land cover datasets and three global datasets of tree cover and croplands.Efforts were carried out to assess the quality:1)inter-comparison of the datasets revealed that the SYNLCover dataset had higher consistency than these input global land cover datasets,suggesting that the data fusion method reduced the disagreement among the input datasets;2)quality assessment using the human-interpreted reference dataset reported the highest accuracy in the fused SYNLCover dataset,which had an overall accuracy of 71.1%,in contrast to the overall accuracy between 48.6%and 68.9%for the other global land cover datasets.
文摘We propose the design of an observation station to establish a reliable datum for displacement and deformation analysis at the first working-face subsidence observation station of Liuzhuang Mine. The design considers various geologic and mining con-ditions. Having analyzed the aims of the joint survey and the comprehensive survey, we propose design principles, and work modes, for adopting GPS technology as the position measuring technique to be used in these two stages. Baseline vectors and spatial ad-justments of the GPS network were calculated after study of data processing and quality estimation methods. A coordinate system transformation and error estimates of the transformed GPS network data are discussed. The error estimates in all stages show that the GPS control network of the observation station has sufficient accuracy and is highly efficient. The network thus provides a reli-able datum for analyzing the laws of surface displacement and deformation induced by mining.
基金financially supported by the National Basic Research Program of China (2011CB505300,2011CB505303)the National Natural Science Foundation of China (81603258, 81673599,81773882)+4 种基金Key Research Project in Basic Science of Jiangsu College and University (14KJA360001)Youth Talent Project Funded by Shaanxi Higher Education Association for Science and Technology (20180307)333 High Level Talents Training Project Funded by Jiangsu Province (BRA2016387)financially supported by a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)the Discipline Innovation Team Program of Shaanxi University of Chinese Medicine (2019-YL10)
文摘Although compatibility is highly advocated in traditional Chinese medicine (TCM), inappropriate combination of some herbs may reduce the therapeutic action and even produce toxic effects. Kansui and licorice, one of TCM “Eighteen Incompatible Medicaments”, are the most representative cases of improper herbal combination, which may still be applied simultaneously under given conditions. However, the potential mechanism of their compatibility and incompatibility is unclear. In the present study, two different ratios of kansui and licorice, representing their compatibility and incompatibility respectively, were designed to elucidate their interaction by comparative plasma/tissue metabolomics and a heatmap with relative fold change. As a result, glycocholic acid, prostaglandin F2a, dihydroceramide and sphinganine were screened out as the principal alternative biomarkers of compatibility group;sphinganine, dihydroceramide, arachidonic acid, leukotriene B4, acetoacetic acid and linoleic acid were those of incompatibility group. Based on the values of biomarkers in each tissue, the liver was identified as the compatible target organ, while the heart, liver, and kidney were the incompatible target organs. Furthermore, important pathways for compatibility and incompatibility were also constructed. These results help us to better understand and utilize the two herbs, and the study was the first to reveal some innate characters of herbs related to TCM “Eighteen Incompatible Medicaments”.
基金supported by the National Key R&D Program of China(No.2018YFD0900805)the Start up Foundation for Introducing Talent of Nanjing Univer-sity of Information Science and Technology。
文摘High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),China.To improve the performance of crude-oil removal,microbiota was further immobilized by two methods,i.e.,sodium alginate(SA),and polyvinyl alcohol and sodium alginate(PVA+SA).Results showed that the crude oil was effectively removed by the enrichment with an average degrading ratio of 19.42-31.45 mg(L d)^(−1).The optimal inoculum size for the n-alkanes removal was 10%and 99.89%.Some members of genera Acinetobacter,Actinophytocola,Aquabac-terium,Dysgonomonas,Frigidibacter,Sphingobium,Serpens,and Pseudomonas dominated in crude-oil degrading microflora.Though the removal efficiency was lower than free bacteria when the temperature was 15℃,SA and PVA+SA immobilization im-proved the resistance to salinity.The composite crude-oil degrading microbiota in this study demonstrated a perspective potential for crude oil removal from surface water under high salinity and low temperature conditions.
文摘The Action Group called‘Standardized methods across Permafrost Landscapes:from Arctic Soils to Hydrosystems’(SPLASH)is a community-driven effort aiming to provide a suite of standardized field strategies for sampling mineral and organic components in soils,sediments,and water across permafrost landscapes.This unified approach will allow data from different landscape interfaces,field locations and seasons to be shared and compared,thus improving our understanding of the processes occurring during lateral transport in circumpolar Arctic watersheds.
基金The Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)under contract No.GML2019ZD0104the Science and Technology Program of Guangzhou,China under contract No.201804010264+3 种基金the Guangdong MEPP Fund under contract No.GDOE[2019]A41the National Natural Science Foundation of China under contract No.41706059the Fund of Institution of South China Sea Ecology and Environmental Engineering,Chinese Academy of Sciences under contract No.ISEE2020YB05the State Key R&D Project under contract No.2016YFA0601104。
文摘Long-chain n-alkanols and n-alkanes in core sediments from the northern South China Sea(SCS)were measured to make a comparison during terrestrial vegetation reconstruction from~42 ka to~7 ka.The results showed that terrestrial vegetation record from long-chain n-alkanes matched well with previous studies in nearby cores,showing that more C_(4)plants developed during the Last Glacial Maximum(LGM)and C_(3)plants dominated in the interglacial period.However,these scenarios were not revealed by terrestrial vegetation reconstruction using long-chain n-alkanols,which showed C_(3)plant expansion during the LGM.The discrepancy during the interglacial period could be attributed to the aerobic degradation of functionalized long-chain n-alkanols in the oxygen-rich bottom water,resulting in poor preservation of terrestrial vegetation signals.On the other hand,the different advantages of functionalized n-alkanols and non-functional n-alkanes to record local and distal vegetation signals,respectively,may offer a potential explanation for the contradiction during the LGM when the SCS was characterized by low-oxygen deep water.Nevertheless,large variations on n-alkyl lipid compositions in C_(3)/C_(4)plants could play a part in modulating sedimentary long-chain n-alkanols and n-alkanes toward different vegetation signals,thereby suggesting that caution must be taken in respect to the terrestrial vegetation reconstruction using long-chain n-alkanes and long-chain n-alkanols.
基金supported by the Programme Blanc de l’Agence National de la Recherche.
文摘Family-based tests of association between a genetic marker and a disease constitute a common design to dissect the genetic architecture of complex traits. The FBAT software is one of the most popular tools to perform such studies. However, researchers are also often interested in the genetic contribution to a more specific manifestation of the phenotype (e.g. severe vs. non-severe form) known as a secondary outcome. Here, what we demonstrate is the limited power of the classical formulation of the FBAT statistic to detect the effect of genetic variants that influence a secondary outcome, in particular when these variants also impact on the onset of the disease, the primary outcome. We prove that this loss of power is driven by an implicit hypothesis, and we propose a derivation of the original FBAT statistic, free from this implicit hypothesis. Finally, we demonstrate analytically that our new statistic is robust and more powerful than FBAT for the detection of association between a genetic variant and a secondary outcome.
基金supported by National Key Research and Development Project of China(No.2022YFE0113800)National Natural Science Foundation of China(Nos.22288101,21972136,21991090 and 21991091)Key Research Program of Frontier Sciences,Chinese Academy of Sciences(No.QYZDB-SSW-JSC040)。
文摘Aluminosilicate small pore zeolites belonging to ABC-6 family play crucially important roles in the high methanol conversion with the high selectivity of light olefins,gas separation and storage,and selective catalytic reduction of NO_(x).In this work,we report a general method,called the epitaxial growth approach,for designing ABC-6 family small pore zeolites.It is mainly realized through the epitaxial growth on the nonporous SOD-type zeolite in the presence of inorganic cations(Na^(+)and K^(+))combined with a variety of organic structure directing agents(OSDAs).In this case,a series of ABC-6 family small pore zeolites such as ERI-,SWY-,LEV-,AFX-,and PTT-type zeolites have been successfully synthesized within a few hours.More importantly,the advanced focused ion beam(FIB)and the low-dose high-resolution transmission electron microscopy(HRTEM)imaging technique have been utilized for unraveling the zeolite heterojunction at the atomic level during the epitaxial growth process.It turns out(222)crystallographic planes of the SOD-type zeolite substrate provide unique pre-building units,which facilitate the growth of targeted ABC-6 family small pore zeolites along its c-axis.Moreover,the morphologies of ERI-type zeolite can also be tuned through the epitaxial growth approach,achieving a longer lifetime in the methanol conversion.
文摘基于植被降水利用效率(rainfall use efficiency,RUE)模型,综合气候、土地利用/覆盖及光学遥感3个维度,分离人为干预(增加/减少)因素,监测生长季RUE时空演变特征,进一步采用地理探测器法探讨其驱动力。结果显示:(1)宝鸡地区经过两轮退耕还林(草)工程,RUE整体上呈提高趋势,尤其是第一轮后(2009—2013年)呈显著提高趋势的像元面积占比最高,达65.69%。全区由第一轮工程实施下(2001—2008年)的以人为干预增加区域为主转变为以人为干预减少为主;(2)夏季降水量最为充裕,春季雨量较差,表现为夏季RUE的提高速率[0.07·(10a)-1]和春季RUE的降低速率[-0.06·(10a)-1]均最为显著。年际、夏秋季,林地的RUE值最高,春季城乡用地的RUE值最高;(3)植被覆盖率、相对湿度、日照时数、粮食总产量、最大风速、降水量、气温、人口密度、造林面积对RUE的相关性依次递减(置信水平95%),植被类型、坡度、坡向对RUE的相关性不显著。交互作用下RUE空间分布的相关性表现为:气候环境因素>自然资源因素>人类活动因素>地理环境因素。随着坡度的增加,RUE呈先增加后减少的变化趋势,在坡度26°~31°出现拐点;造林面积与RUE具有同步增减的变化趋势;植被对RUE的促进作用显著,人口密度对RUE的胁迫作用显著。此外,665.51~679.80 mm的降水量提高RUE的风险最高,集中于陈仓区东-西水平线区域上。
基金the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB15010103)the National Key Research and Development Program of China(No.2017YFD0200604)+1 种基金the National Natural Science Foundation of China(No.41771284)the Chinese Biodiversity Monitoring and Research Network(Sino BON).
文摘Denitrification is one of the major processes causing nitrogen loss from arable soils.This study aimed to investigate the responses of nir S-type denitrifier communities to different chronic fertilization regimes across the black soil region of Northeast China.Soil samples were collected from sites located in the north(NB),middle(MB),and south(SB)of the black soil region of Northeast China,each with four chronic fertilization regimes:no fertilizer(No F),chemical fertilizer(CF),manure(M),and chemical fertilizer plus manure(CFM).Methods of quantitative polymerase chain reaction(q PCR)and Illumina Mi Seq sequencing were applied to assess the abundance and composition of denitrifier communities by targeting the nir S gene.The results showed that the M and CFM regimes significantly increased the abundances of nir S-type denitrifiers compared with No F at the three locations.The majority of nir S sequences were grouped as unclassified denitrifiers,and the different fertilizers induced little variation in the relative abundance of known nir S-type denitrifier taxa.Over 90%of the sequences were shared among the four fertilization regimes at each location,but none of the abundant operational taxonomic units(OTUs)were shared among the three locations.Principal coordinate analysis(PCo A)revealed that the communities of nir S-type denitrifier were separated into three groups that corresponded with their locations.Although similar fertilization regimes did not induce consistent changes in the nir S-type denitrifier communities,soil p H and NO-3-N content simultaneously and significantly influenced the structure of nir S-type denitrifier communities at the three locations.Our results highlight that geographical separation rather than chronic fertilization was the dominant factor determining the nir S-type denitrifier community structures,and similar chronic fertilization regimes did not induce consistent shifts of nir S-type denitrifier communities in the black soils.