The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for CaseI system(e.g.vinyl acetate and vinyl chloride)has been studied.The behaviour of monomer soluble inhibitorsis shown t...The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for CaseI system(e.g.vinyl acetate and vinyl chloride)has been studied.The behaviour of monomer soluble inhibitorsis shown to be quite different from that observed in Case Ⅱ emulsion polymerization system.Model predictionsof the effect of these inhibitors on polymer particle nucleation and growth rate are shown to be in satisfactoryagreement with experimental results.展开更多
The paper presents and discusses theoretical bases and methodology of development of two- and three-dimensional analytical and optical isodynes. Atten- tion is given to the theoretical admissibility of the major compo...The paper presents and discusses theoretical bases and methodology of development of two- and three-dimensional analytical and optical isodynes. Atten- tion is given to the theoretical admissibility of the major components of the physical and mathematical models which are taken as the theoretical basis of the isodynes, and of the related analytical and experimental procedures of stress analysis. Efficiency and reliability of the nondestructive isodyne stress analysis are discussed.展开更多
文摘The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for CaseI system(e.g.vinyl acetate and vinyl chloride)has been studied.The behaviour of monomer soluble inhibitorsis shown to be quite different from that observed in Case Ⅱ emulsion polymerization system.Model predictionsof the effect of these inhibitors on polymer particle nucleation and growth rate are shown to be in satisfactoryagreement with experimental results.
文摘The paper presents and discusses theoretical bases and methodology of development of two- and three-dimensional analytical and optical isodynes. Atten- tion is given to the theoretical admissibility of the major components of the physical and mathematical models which are taken as the theoretical basis of the isodynes, and of the related analytical and experimental procedures of stress analysis. Efficiency and reliability of the nondestructive isodyne stress analysis are discussed.