In this work, we synthesized cubic perovskite ceramics of the whole La_(1–x)Sr_xCoO_3(0 ≤ x ≤ 1) solid solution for the first time. Synthesis was carried out by solid state reaction and conventional sintering to re...In this work, we synthesized cubic perovskite ceramics of the whole La_(1–x)Sr_xCoO_3(0 ≤ x ≤ 1) solid solution for the first time. Synthesis was carried out by solid state reaction and conventional sintering to reach dense ceramics. For x > 0.8, it was necessary to substitute 3% cobalt by silicon to stabilize the cubic perovskite structure. Electrical conductivity increased with Sr content to reach 3×10~5 S·m^(–1) at 330 K for x = 0.3. However, the optimum electrical properties have been found for x = 0.05 at 330 K with PF_(max) = 3.11×10^(–4)W·m^(–1)·K^(–2). Indeed, the Seebeck coefficient was decreasing when x increased to reach values close to 0 for x ≥ 0.3. Thermal conductivity was low at low temperature(≈ 2.5 W×m^(–1)·K^(–1)) and increased up to 6.5 W·m^(–1)·K^(–1) when temperature increased. As the highest power factor was reached at low temperature as well as the lowest thermal conductivity, La_(1–x)Sr_xCoO_3 compounds with low x values appeared as very promising thermoelectric materials around room temperature, on the contrary to layered cobalt oxides. For high x values, Seebeck coefficient values close to zero made these materials unsuitable for thermoelectric applications.展开更多
基金ADEME(Agence de l'Environnement et de la Maitrise de l'Energie),Plan d'Investissment d'Avenir PIA"Tours 2015"for the financial support
文摘In this work, we synthesized cubic perovskite ceramics of the whole La_(1–x)Sr_xCoO_3(0 ≤ x ≤ 1) solid solution for the first time. Synthesis was carried out by solid state reaction and conventional sintering to reach dense ceramics. For x > 0.8, it was necessary to substitute 3% cobalt by silicon to stabilize the cubic perovskite structure. Electrical conductivity increased with Sr content to reach 3×10~5 S·m^(–1) at 330 K for x = 0.3. However, the optimum electrical properties have been found for x = 0.05 at 330 K with PF_(max) = 3.11×10^(–4)W·m^(–1)·K^(–2). Indeed, the Seebeck coefficient was decreasing when x increased to reach values close to 0 for x ≥ 0.3. Thermal conductivity was low at low temperature(≈ 2.5 W×m^(–1)·K^(–1)) and increased up to 6.5 W·m^(–1)·K^(–1) when temperature increased. As the highest power factor was reached at low temperature as well as the lowest thermal conductivity, La_(1–x)Sr_xCoO_3 compounds with low x values appeared as very promising thermoelectric materials around room temperature, on the contrary to layered cobalt oxides. For high x values, Seebeck coefficient values close to zero made these materials unsuitable for thermoelectric applications.
