As a calculation method based on the Galerkin variation,the numerical manifold method(NMM)adopts a double covering system,which can easily deal with discontinuous deformation problems and has a high calculation accura...As a calculation method based on the Galerkin variation,the numerical manifold method(NMM)adopts a double covering system,which can easily deal with discontinuous deformation problems and has a high calculation accuracy.Aiming at the thermo-mechanical(TM)coupling problem of fractured rock masses,this study uses the NMM to simulate the processes of crack initiation and propagation in a rock mass under the influence of temperature field,deduces related system equations,and proposes a penalty function method to deal with boundary conditions.Numerical examples are employed to confirm the effectiveness and high accuracy of this method.By the thermal stress analysis of a thick-walled cylinder(TWC),the simulation of cracking in the TWC under heating and cooling conditions,and the simulation of thermal cracking of the SwedishÄspöPillar Stability Experiment(APSE)rock column,the thermal stress,and TM coupling are obtained.The numerical simulation results are in good agreement with the test data and other numerical results,thus verifying the effectiveness of the NMM in dealing with thermal stress and crack propagation problems of fractured rock masses.展开更多
Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate change.The Wugongshan area,situated in the southeast coast geothermal belt...Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate change.The Wugongshan area,situated in the southeast coast geothermal belt of China,is a typical geothermal anomaly and contains abundant medium-and low-temperature geothermal resources.This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region,encompassing the recharge origin,water-rock interaction mechanisms,and residence time.The results show that the geothermal water in the western region of Wugongshan is weakly alkaline,with low enthalpy and mineralization levels.The hydrochemistry of geothermal waters is dominated by Na-HCO_(3)and Na-SO_(4),while the hydrochemistry types of cold springs are all Na-HCO_(3).The hydrochemistry types of surface waters and rain waters are NaHCO_(3)or Ca-HCO_(3).The δD and δ^(18)O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m.Molar ratios of maj or solutes and isotopic compositions of^(87)Sr/^(86)Sr underscore the significant role of silicate weathering,dissolution,and cation exchange in controlling geothermal water chemistry.Additionally,geothermal waters experienced varying degrees of mixing with cold water during their ascent.Theδ^(13)C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic.Theδ^(34)S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock.Age dating using 3H and^(14)C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.展开更多
The frequent occurrence of extreme weather events has rendered numerous landslides to a global natural disaster issue.It is crucial to rapidly and accurately determine the boundaries of landslides for geohazards evalu...The frequent occurrence of extreme weather events has rendered numerous landslides to a global natural disaster issue.It is crucial to rapidly and accurately determine the boundaries of landslides for geohazards evaluation and emergency response.Therefore,the Skip Connection DeepLab neural network(SCDnn),a deep learning model based on 770 optical remote sensing images of landslide,is proposed to improve the accuracy of landslide boundary detection.The SCDnn model is optimized for the over-segmentation issue which occurs in conventional deep learning models when there is a significant degree of similarity between topographical geomorphic features.SCDnn exhibits notable improvements in landslide feature extraction and semantic segmentation by combining an enhanced Atrous Spatial Pyramid Convolutional Block(ASPC)with a coding structure that reduces model complexity.The experimental results demonstrate that SCDnn can identify landslide boundaries in 119 images with MIoU values between 0.8and 0.9;while 52 images with MIoU values exceeding 0.9,which exceeds the identification accuracy of existing techniques.This work can offer a novel technique for the automatic extensive identification of landslide boundaries in remote sensing images in addition to establishing the groundwork for future inve stigations and applications in related domains.展开更多
Latewood width(LWW)indices of trees are considered a reliable proxy of summer precipitation in the Northern Hemisphere.However,the strong coupling and high correlation between earlywood width(EWW)and LWW indices often...Latewood width(LWW)indices of trees are considered a reliable proxy of summer precipitation in the Northern Hemisphere.However,the strong coupling and high correlation between earlywood width(EWW)and LWW indices often prevent registration of climate signals of the LWW index.In this study,328-year-long earlywood width and latewood width chronologies were developed from Chinese pine at two sites in the Hasi Mountains,north central China.The climate responses of these chronologies were analyzed and the LWW index used to derive sum-mer precipitation signals.Correlation analyses showed that LWW was particularly influenced by earlywood growth and recorded stronger climate signals of the previous year as EWW,rather than those of the current year with infrequent summer climate signals.However,after removing the effect of earlywood growth using a simple regression model,the adjusted LWW chronology(LWW_(adj))showed a strong relationship with July precipitation in dry years.This suggests that the LWW_(adj) chronology has the potential to be used to investigate long-term variability in summer precipitation in drought-limited regions.展开更多
1.Objective Unlike the North China Plate where Archean and Paleoproterozoic crustal rocks are widely distributed,Early Precambrian basement rocks in the Yangtze Block of South China are locally exposed(Fig.1a),such as...1.Objective Unlike the North China Plate where Archean and Paleoproterozoic crustal rocks are widely distributed,Early Precambrian basement rocks in the Yangtze Block of South China are locally exposed(Fig.1a),such as in the Kongling Complex,the Zhongxiang Complex,and the Douling Complex(Zhao GC and Cawood PA,2012).The Dabie Orogen is the eastward extension of the Qinling Orogen.展开更多
Deep-water channel systems are important petroleum reservoirs,and many have been discovered worldwide.Understanding deep-water channel sedimentary elements and evolution is helpful for deep-sea petroleum exploration a...Deep-water channel systems are important petroleum reservoirs,and many have been discovered worldwide.Understanding deep-water channel sedimentary elements and evolution is helpful for deep-sea petroleum exploration and development.Based on high-resolution 3D seismic data,the Miocene channel system in the deep-water Taranaki Basin,New Zealand,was analyzed by using seismic interpretation techniques such as interlayer attribute extraction and strata slicing.The channel system was divided into five composite channels(CC-I to CC-V)according to four secondary level channel boundaries,and sedimentary elements such as channels,slump deposits,inner levees,mass transport deposits,and hemipelagic drape deposits were identified in the channel system.The morphological characteristics of several composite channels exhibited stark variances,and the overall morphology of the composite channels changed from relatively straight to highly sinuous to relatively straight.The evolution of the composite channels involved a gradual and repeated process of erosion and filling,and the composite channels could be divided into three evolutionary stages:initial erosion-filling,later erosion-filling(multistage),and channel abandonment.The middle Miocene channel system may have formed as a consequence of combined regional tectonic activity and global climatic change,and its intricate morphological alterations may have been influenced by the channel's ability to self-regulate and gravity flow properties.When studying the sedimentary evolution of a large-scale deep-water channel system in the Taranaki Basin during the Oligocene-Miocene,which transitioned from a passive margin to plate convergence,it can be understood how tectonic activity affected the channel and can also provide a theoretical reference for the evolution of the deepwater channels in areas with similar tectonic conversion environments around the world.展开更多
A comprehensive dataset from 594 fracturing wells throughout the Duvernay Formation near Fox Creek, Alberta, is collected to quantify the influences of geological, geomechanical, and operational features on the distri...A comprehensive dataset from 594 fracturing wells throughout the Duvernay Formation near Fox Creek, Alberta, is collected to quantify the influences of geological, geomechanical, and operational features on the distribution and magnitude of hydraulic fracturing-induced seismicity. An integrated machine learning-based investigation is conducted to systematically evaluate multiple factors that contribute to induced seismicity. Feature importance indicates that a distance to fault, a distance to basement, minimum principal stress, cumulative fluid injection, initial formation pressure, and the number of fracturing stages are among significant model predictors. Our seismicity prediction map matches the observed spatial seismicity, and the prediction model successfully guides the fracturing job size of a new well to reduce seismicity risks. This study can apply to mitigating potential seismicity risks in other seismicity-frequent regions.展开更多
In this paper, we have studied several classes of planar piecewise Hamiltonian systems with three zones separated by two parallel straight lines. Firstly, we give the maximal number of limit cycles in these classes of...In this paper, we have studied several classes of planar piecewise Hamiltonian systems with three zones separated by two parallel straight lines. Firstly, we give the maximal number of limit cycles in these classes of systems with a center in two zones and without equilibrium points in the other zone (or with a center in one zone and without equilibrium points in the other zones). In addition, we also give examples to illustrate that it can reach the maximal number.展开更多
The Tiegelongnan deposit is a newly discovered super-large porphyry-epithermal Cu-(Au) deposit in the western part of the Bangong Co-Nujiang metallogenic belt, Tibet(China). Field geology and geochronology indicat...The Tiegelongnan deposit is a newly discovered super-large porphyry-epithermal Cu-(Au) deposit in the western part of the Bangong Co-Nujiang metallogenic belt, Tibet(China). Field geology and geochronology indicate that the porphyry mineralization was closely related to the Early Cretaceous intermediate-felsic intrusions(ca. 123–120 Ma). Various epithermal ore and gangue mineral types were discovered in the middle-shallow part of the orebody, indicating the presence of epithermal mineralization at Tiegelongnan. Potassic, propylitic, phyllic and advanced argillic alteration zones were identified. 40Ar/39Ar dating of hydrothermal biotite(potassic zone), sericite(phyllic zone), and alunite(advanced argillic zone) in/around the ore-bearing granodiorite porphyry yielded 121.1±0.6 Ma(1σ), 120.8±0.7 Ma(1σ) and 117.9±1.6 Ma(1σ), respectively. Five hydrothermal mineralization stages were identified, of which the Stage IV pyrite was Rb-Sr dated to be 117.5±1.8 Ma(2σ), representing the end of epithermal mineralization. Field geology and geochronology suggest that both the epithermal and porphyry mineralization belong to the same magmatic-hydrothermal system. The Tiegelongnan super-large Cu-(Au) deposit may have undergone a prolonged magmatichydrothermal evolution, with the major mineralization event occurring at ca.120–117Ma.展开更多
Shale fractures are an important factor controlling shale gas enrichment and high-productivity zones in the Longmaxi Formation, Jiaoshiba area in eastern Sichuan. Drilling results have, however, shown that the shale f...Shale fractures are an important factor controlling shale gas enrichment and high-productivity zones in the Longmaxi Formation, Jiaoshiba area in eastern Sichuan. Drilling results have, however, shown that the shale fracture density does not have a straightforward correlation with shale gas productivity. Based on logging data, drilling and seismic data, the relationship between shale fracture and shale gas accumulation is investigated by integrating the results of experiments and geophysical methods. The following conclusions have been drawn:(1) Tracer diffusion tests indicate that zones of fracture act as favorable channels for shale gas migration and high-angle fractures promote gas accumulation.(2) Based on the result of azimuthal anisotropy prediction, a fracture system with anisotropy strength values between 1 and 1.15 represents a moderate development of high-angle fractures, which is considered to be favorable for shale gas accumulation and high productivity, while fracture systems with anisotropy strength values larger than 1.15 indicate over-development of shale fracture, which may result in the destruction of the shale reservoir preservation conditions.展开更多
The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the D...The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I(gray white color with large phenocrysts), granite porphyry II(pink color with small phenocrysts) and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites:(1) They have high SiO2 content(70.93–80.18 wt% and 72.14–72.64 wt%, respectively), total alkali(7.58–8.95 wt% and 9.35–9.68 wt%, respectively), mafic index(0.95–0.98 and 0.93–0.94, respectively) and felsic index(0.79–0.94 and 0.89–0.91, respectively);(2) They are characterized by pronounced negative Eu anomaly, "seagullstyle" chondrite-normalized REE patterns and "tetrad effect" of REE;(3) They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting.展开更多
Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to ...Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to reddish–orange to colorless. The grains are all 100–300 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm-1 and 1333 cm-1, mostly at 1331.51 cm-1 or 1326.96 cm-1. This investigation extends the occurrence of diamond and moissanite to the Bulqiza chromitites in the Eastern Mirdita Ophiolite. Integration of the mineralogical, petrological and geochemical data of the Bulqiza chromitites suggests their multi–stage formation. Magnesiochromite grains and perhaps small bodies of chromitite formed at various depths in the upper mantle, and encapsulated the ultra–high pressure, highly reduced and crustal minerals. Some oceanic crustal slabs containing the magnesiochromite and their inclusion were later trapped in suprasubduction zones, where they were modified by tholeiitic and boninitic arc magmas, thus changing the magnesiochromite compositions and depositing chromitite ores in melt channels.展开更多
Tho Gudui geothermal field records the highest temperature at equivalent borehole depths among the lainland hydrothermal systems in China's Mainland.Located about 150 km southeast of Lhasa City,the capital of Tibe...Tho Gudui geothermal field records the highest temperature at equivalent borehole depths among the lainland hydrothermal systems in China's Mainland.Located about 150 km southeast of Lhasa City,the capital of Tibet,the Gudui geothermal field belongs to the Sangri-Cuona rift belt,also known as the Sangri-Cuona geothermal belt,and is representative of the non-volcanic geothermal systems in the Himalayas.In this study,oxygen-18 and deuterium isotope compositions as well as 87Sr/86Sr ratios of water samples collected from the Gudui geothermal field were characterized to understand the origin and mixing processes of the geothermal fluids at Gudui.Hydrogen and oxygen isotope plots show both,deep and shallow reservoirs in the Gudui geothermal field.Deep geothermal fluids are the mixing product of magmatic and infiltrating snow-melt water.Calculations show that the magma fluid component of the deep geothermal fluids account for about 21.10%-24.04%;magma fluids lay also be a contributing source of lithium.The linear relationship of the 87Sr/86Sr isotopic ratio versus the 1/Sr plot indicates that shallow geothermal fluids form from the mixing of deep geothermal fluids with cold groundwater.Using a binary mixing model with deep geothermal fluid and cold groundwater as two end-members,the nixing ratios of the latter in most surface hot springs samples were calculated to be between 5% and 10%.Combined with basic geological characteristics,hydrogen and oxygen isotope characteristics,strontium concentration,87Sr/(86)Sr ratios,and the binary mixing model,we infer the 6 th-Class Reservoirs Evolution Conceptual Model(6-CRECM) for the Gudui geothermal system.This model represents an idealized summary of the characteristics of the Gudui geothermal field based on our comprehensive understanding of the origin and mixing processes of the geothermal fluid in Gudui.This study may aid in identifying the geothermal and geochemical origin of the Gudui high-temperature hydrothermal systems in remote Tibet of China,whose potential for geothermal development and utilization is enormous and untapped.展开更多
The northeastern Tibetan Plateau is located at the convergence of the Asian winter and summer monsoons and westerlies; thus, this area has witnessed historic climate changes.The Xunhua basin is an intermontane basin o...The northeastern Tibetan Plateau is located at the convergence of the Asian winter and summer monsoons and westerlies; thus, this area has witnessed historic climate changes.The Xunhua basin is an intermontane basin on the northeastern margin of the Tibetan Plateau.The basin contains more than 2000 m of Cenozoic fluvial–lacustrine sediments, recording a long history of climate and environmental changes.We collected the mid-Miocene sediments from the Xunhua basin and used palynological methods to discuss the relationship between aridification in the interior of Asia, global cooling, and uplift of the Tibetan Plateau.Based on the palynological analysis of the Xigou section, Xunhua basin, the palynological diagram is subdivided into three pollen zones and past vegetation and climate are reconstructed.Zone I, Ephedripites–Nitraridites–Chenopodipollis–Quercoidites(14.0–12.5 Ma), represents mixed shrub–steppe vegetation with a dry and cold climate.In zone II, Pinaceae–Betulaepollenites–Ephedripites–Chenopodipollis–Graminidites(12.5–8.0 Ma), the vegetation and climate conditions improved, even though the vegetation was still dominated by shrub–steppe taxa.Zone III, Ephedripites–Nitrariadites–Chenopodipollis(8.0–5.0 Ma), represents desert steppe vegetation with drier and colder climate.The palynological records suggest that shrub–steppe dominated the whole Xigou section and the content gradually increased, implying a protracted aridification process, although there was an obvious climate improvement during 12.5–8.0 Ma.The aridification in the Xunhua basin and surrounding mountains during 14.0–12.5 Ma was probably related to global cooling induced by the rapid expansion of the East Antarctic ice-sheets and the relatively higher evaporation rate.During the 12.5–8.0 Ma period, although topographic changes(uplift of Jishi Shan) decreased precipitation and strengthened aridification in the Xunhua basin on leeward slopes, the improved vegetation and climate conditions were probably controlled by the decrease in evaporation rates as a result of continuous cooling.From 8.0 to 5.0 Ma, the rapid development of the desert steppe can be attributed to global cooling and uplift of the Tibetan Plateau.展开更多
Reconstruction of the desert paleoclimate is important to understand the mechanisms that triggered and/or enhanced climate change.Through optically stimulated luminescence(OSL)dating,grain size,magnetic susceptibility...Reconstruction of the desert paleoclimate is important to understand the mechanisms that triggered and/or enhanced climate change.Through optically stimulated luminescence(OSL)dating,grain size,magnetic susceptibility,X-ray powder diffraction(XRD)and geochemical indicators,we provide a welldated record of a sedimentary outcrop on the southeast margin of the Bardain Jaran Desert,Northwest China,during the last glacial period.Four Qz-OSL ages are obtained,41.0±3.4 ka,54.7±4.4 ka,59.5±5.0 ka and 66.8±5.8 ka,corresponding to the depths of 35 cm,70 cm,150 cm and 200 cm respectively.Indicators like grain size,clay content,magnetic susceptibility,XRD and geochemical index(e.g.Sr,Ba,Sr/Ca)jointly indicate abrupt climate changes at the depth of 35 cm(age,ca.41.0 ka)and200 cm(age,ca.67 ka).Namely,the 280 cm sedimentary outcrop perfectly records a warm wet climate stage,corresponding to the late Marine Isotope Stages(MIS)4 to the early MIS 3.Besides,there is a trend of grain size increase after around 40ka BP,which is most likely a signal of wind strength change.Our research supports that enhancing Siberian High pressure system during the late MIS 3played a key role in NW East Asia climate evolution.展开更多
The main methods of coalbed methane(CBM)development are drainage and depressurization,and a precise prediction of coal reservoir pressure is thus crucial for the evaluation of reservoir potentials and the formulation ...The main methods of coalbed methane(CBM)development are drainage and depressurization,and a precise prediction of coal reservoir pressure is thus crucial for the evaluation of reservoir potentials and the formulation of reasonable development plans.This work established a new reservoir pressure prediction model based on the material balance equation(MBE)of coal reservoir,which considers the self-regulating effects of coal reservoirs and the dynamic change of equivalent drainage area(EDA).According to the proposed model,the reservoir pressure can be predicted based on reservoir condition data and the actual production data of a single well.Compared with traditional reservoir pressure prediction models which regard EDA as a fixed value,the proposed model can better predict the average pressure of reservoirs.Moreover,orthogonal experiments were designed to evaluate the sensitivity of reservoir parameters on the reservoir pressure prediction results of this proposed model.The results show that the saturation of irreducible water is the most sensitive parameter,followed by Langmuir volume and reservoir porosity,and Langmuir pressure is the least sensitive parameter.In addition,the pressure drop of reservoirs is negatively correlated with the saturation of irreducible water and the Langmuir volume,while it is positively correlated with porosity.This work analyzed the reservoir pressure drop characteristics of the CBM wells in the Shizhuangnan Block of the Qinshui Basin,and the results show that the CBM reservoir depressurization can be divided into three types,i.e.,rapidly drop type,medium-term stability type,and slowly drop type.The drainage features of wells were reasonably interpreted based on the comprehensive analysis of the reservoir depressurization type;the latter was coupled to the corresponding permeability dynamic change characteristics,eventually proving the applicability of the proposed model.展开更多
Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloo...Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.展开更多
In order to improve the prediction accuracy of compressive strength of concrete,103 groups of concrete data were collected as the samples.We selected seven kinds of ingredients from the concrete samples, using Grid-SV...In order to improve the prediction accuracy of compressive strength of concrete,103 groups of concrete data were collected as the samples.We selected seven kinds of ingredients from the concrete samples, using Grid-SVM, PSO-SVM, and GA-SVM models to establish the prediction model of cubic meter compressive strength of concrete.The experimental results show that SVM model based on Grid optimization algorithm,SVM model based on Particle swarm optimization algorithm,SVM model based on Genetic optimization algorithm mean square error respectively are 0.001, 0.489 8, and 0.304 2, correlation coefficients are 0.994 8, 0.994 6, and 0.993 0. It is shown that cubic meter compressive strength prediction method based on Grid-SVM model is the best optimization algorithm.展开更多
The Linjiasandaogou gold deposit is located in the Qingchengzi Orefield,North China Craton,China,and has not attracted many studies.We present geochronological,whole-rock geochemical,and Sr–Nd–Hf isotopic data to co...The Linjiasandaogou gold deposit is located in the Qingchengzi Orefield,North China Craton,China,and has not attracted many studies.We present geochronological,whole-rock geochemical,and Sr–Nd–Hf isotopic data to constrain the age and tectonic setting of the mineralization.U–Pb dating of zircon from pre-and post-ore dikes indicates the Linjiasandaogou Au deposit formed at ca.227–226 Ma.The granite porphyry(ca.227 Ma)and quartz diorite porphyry(ca.228 Ma),which are slightly older than the mineralization,have(;Sr/;Sr)i-=0.7127–0.7162,εNd(t)=–13.7 to–17.0,andεHf(t)=–14.6 to–16.9,and display enrichment in light rare earth elements and large ion lithophile elements and depletion in high field strength elements.Two lamprophyres(226 and225 Ma),which are slightly younger than the mineralization,have higher(;Sr/;Sr)i(0.7165–0.7216),negativeεNd(t)(–11.2 to–14.3)andεHf(t)(–15.6 to–18.6)values,and are enriched in light rare earth elements but depleted in high field strength elements(Nb and Ta).The geochemical characteristics of the granitoid and lamprophyres indicate a lower crustal and enriched mantle source,respectively.We infer that the Linjiasandaogou Au deposit formed in a postcollisional tectonic setting,following the collision between the North China,Yangtze craton,and Central Asian Orogeny in Triassic.展开更多
This thesis focuses Arsenic(As) distribution and occurrence in groundwater of Yangtze River Delta economic region, East China. 2019 groundwater samples were collected to analyze 26 chemical compositions, including As....This thesis focuses Arsenic(As) distribution and occurrence in groundwater of Yangtze River Delta economic region, East China. 2019 groundwater samples were collected to analyze 26 chemical compositions, including As. The Principal Component Analysis(PCA) was used to find out As source in groundwater. The results show that average As concentration in groundwater of this study is 9.33 μg/l, and maximum As concentration is up to 510 μg/l. The variation coefficient is 314.34%. High arsenic phreatic water(>10 μg/l) distributes along the Yangtze River and its estuary. Weak hydrodynamic conditions, wide p H value variation range and deteriorating environment are dominating factors, especially in Yangtze River Delta. The PCA suggests that arsenic in phreatic water is mainly of natural origin. Part of arsenic may directly originate from sediment organics and be related to organics decomposition.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.42277165)the Fundamental Research Funds for the Central Universities,China University of Geosciences(Wuhan)(Grant No.CUGCJ1821)the National Overseas Study Fund(Grant No.202106410040).
文摘As a calculation method based on the Galerkin variation,the numerical manifold method(NMM)adopts a double covering system,which can easily deal with discontinuous deformation problems and has a high calculation accuracy.Aiming at the thermo-mechanical(TM)coupling problem of fractured rock masses,this study uses the NMM to simulate the processes of crack initiation and propagation in a rock mass under the influence of temperature field,deduces related system equations,and proposes a penalty function method to deal with boundary conditions.Numerical examples are employed to confirm the effectiveness and high accuracy of this method.By the thermal stress analysis of a thick-walled cylinder(TWC),the simulation of cracking in the TWC under heating and cooling conditions,and the simulation of thermal cracking of the SwedishÄspöPillar Stability Experiment(APSE)rock column,the thermal stress,and TM coupling are obtained.The numerical simulation results are in good agreement with the test data and other numerical results,thus verifying the effectiveness of the NMM in dealing with thermal stress and crack propagation problems of fractured rock masses.
基金funded by the project of China Geological Survey(Grant No.DD20221677-2)the Central Public-Interest Scientific Institution Basal Research Fund(Grant No.JKYQN202307)。
文摘Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate change.The Wugongshan area,situated in the southeast coast geothermal belt of China,is a typical geothermal anomaly and contains abundant medium-and low-temperature geothermal resources.This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region,encompassing the recharge origin,water-rock interaction mechanisms,and residence time.The results show that the geothermal water in the western region of Wugongshan is weakly alkaline,with low enthalpy and mineralization levels.The hydrochemistry of geothermal waters is dominated by Na-HCO_(3)and Na-SO_(4),while the hydrochemistry types of cold springs are all Na-HCO_(3).The hydrochemistry types of surface waters and rain waters are NaHCO_(3)or Ca-HCO_(3).The δD and δ^(18)O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m.Molar ratios of maj or solutes and isotopic compositions of^(87)Sr/^(86)Sr underscore the significant role of silicate weathering,dissolution,and cation exchange in controlling geothermal water chemistry.Additionally,geothermal waters experienced varying degrees of mixing with cold water during their ascent.Theδ^(13)C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic.Theδ^(34)S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock.Age dating using 3H and^(14)C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.
基金supported by the National Natural Science Foundation of China(Grant Nos.42090054,41931295)the Natural Science Foundation of Hubei Province of China(2022CFA002)。
文摘The frequent occurrence of extreme weather events has rendered numerous landslides to a global natural disaster issue.It is crucial to rapidly and accurately determine the boundaries of landslides for geohazards evaluation and emergency response.Therefore,the Skip Connection DeepLab neural network(SCDnn),a deep learning model based on 770 optical remote sensing images of landslide,is proposed to improve the accuracy of landslide boundary detection.The SCDnn model is optimized for the over-segmentation issue which occurs in conventional deep learning models when there is a significant degree of similarity between topographical geomorphic features.SCDnn exhibits notable improvements in landslide feature extraction and semantic segmentation by combining an enhanced Atrous Spatial Pyramid Convolutional Block(ASPC)with a coding structure that reduces model complexity.The experimental results demonstrate that SCDnn can identify landslide boundaries in 119 images with MIoU values between 0.8and 0.9;while 52 images with MIoU values exceeding 0.9,which exceeds the identification accuracy of existing techniques.This work can offer a novel technique for the automatic extensive identification of landslide boundaries in remote sensing images in addition to establishing the groundwork for future inve stigations and applications in related domains.
基金supportedbytheNational Natural Science Foundation of China (No.U21A2006 and 42001043).
文摘Latewood width(LWW)indices of trees are considered a reliable proxy of summer precipitation in the Northern Hemisphere.However,the strong coupling and high correlation between earlywood width(EWW)and LWW indices often prevent registration of climate signals of the LWW index.In this study,328-year-long earlywood width and latewood width chronologies were developed from Chinese pine at two sites in the Hasi Mountains,north central China.The climate responses of these chronologies were analyzed and the LWW index used to derive sum-mer precipitation signals.Correlation analyses showed that LWW was particularly influenced by earlywood growth and recorded stronger climate signals of the previous year as EWW,rather than those of the current year with infrequent summer climate signals.However,after removing the effect of earlywood growth using a simple regression model,the adjusted LWW chronology(LWW_(adj))showed a strong relationship with July precipitation in dry years.This suggests that the LWW_(adj) chronology has the potential to be used to investigate long-term variability in summer precipitation in drought-limited regions.
基金financially supported by the Open Fund of the Research Center for Petrogenesis and Mineralization of Granitoid Rocks(PMGR202014)the project of the China Geological Survey(DD20190050)。
文摘1.Objective Unlike the North China Plate where Archean and Paleoproterozoic crustal rocks are widely distributed,Early Precambrian basement rocks in the Yangtze Block of South China are locally exposed(Fig.1a),such as in the Kongling Complex,the Zhongxiang Complex,and the Douling Complex(Zhao GC and Cawood PA,2012).The Dabie Orogen is the eastward extension of the Qinling Orogen.
基金The National Natural Science Foundation of China under contract Nos 42077410 and 41872112。
文摘Deep-water channel systems are important petroleum reservoirs,and many have been discovered worldwide.Understanding deep-water channel sedimentary elements and evolution is helpful for deep-sea petroleum exploration and development.Based on high-resolution 3D seismic data,the Miocene channel system in the deep-water Taranaki Basin,New Zealand,was analyzed by using seismic interpretation techniques such as interlayer attribute extraction and strata slicing.The channel system was divided into five composite channels(CC-I to CC-V)according to four secondary level channel boundaries,and sedimentary elements such as channels,slump deposits,inner levees,mass transport deposits,and hemipelagic drape deposits were identified in the channel system.The morphological characteristics of several composite channels exhibited stark variances,and the overall morphology of the composite channels changed from relatively straight to highly sinuous to relatively straight.The evolution of the composite channels involved a gradual and repeated process of erosion and filling,and the composite channels could be divided into three evolutionary stages:initial erosion-filling,later erosion-filling(multistage),and channel abandonment.The middle Miocene channel system may have formed as a consequence of combined regional tectonic activity and global climatic change,and its intricate morphological alterations may have been influenced by the channel's ability to self-regulate and gravity flow properties.When studying the sedimentary evolution of a large-scale deep-water channel system in the Taranaki Basin during the Oligocene-Miocene,which transitioned from a passive margin to plate convergence,it can be understood how tectonic activity affected the channel and can also provide a theoretical reference for the evolution of the deepwater channels in areas with similar tectonic conversion environments around the world.
基金This research has been made possible by contributions from the Natural Sciences and Engineering Research Council(NSERC)/Energi Simulation Industrial Research Chair in Reservoir Simulation and the Alberta Innovates(iCore)Chair in Reservoir ModelingThis research was supported by the Science Foundation of China University of Petroleum,Beijing(No.2462023BJRC001)the National Natural Science Foundation of China Joint Fund Key Support Project(No.U19B6003).
文摘A comprehensive dataset from 594 fracturing wells throughout the Duvernay Formation near Fox Creek, Alberta, is collected to quantify the influences of geological, geomechanical, and operational features on the distribution and magnitude of hydraulic fracturing-induced seismicity. An integrated machine learning-based investigation is conducted to systematically evaluate multiple factors that contribute to induced seismicity. Feature importance indicates that a distance to fault, a distance to basement, minimum principal stress, cumulative fluid injection, initial formation pressure, and the number of fracturing stages are among significant model predictors. Our seismicity prediction map matches the observed spatial seismicity, and the prediction model successfully guides the fracturing job size of a new well to reduce seismicity risks. This study can apply to mitigating potential seismicity risks in other seismicity-frequent regions.
文摘In this paper, we have studied several classes of planar piecewise Hamiltonian systems with three zones separated by two parallel straight lines. Firstly, we give the maximal number of limit cycles in these classes of systems with a center in two zones and without equilibrium points in the other zone (or with a center in one zone and without equilibrium points in the other zones). In addition, we also give examples to illustrate that it can reach the maximal number.
基金jointly sponsored by the Public Science and Technology Research Funds Projects,Ministry of Land Resources of the People’s Republic of China(project No.201511017 and 201511022-02)the Basic Research Fund of the Chinese Academy of Geological Sciences(Grant No.YYWF201608)+3 种基金the National Natural Science Foundation of China(Grant No.41402178)Geological Survey Project of the China Geological Survey(project 1212011405040)Golden Dragon Mining Co.Ltd.(project XZJL-2013-JS03)China Scholarship Council
文摘The Tiegelongnan deposit is a newly discovered super-large porphyry-epithermal Cu-(Au) deposit in the western part of the Bangong Co-Nujiang metallogenic belt, Tibet(China). Field geology and geochronology indicate that the porphyry mineralization was closely related to the Early Cretaceous intermediate-felsic intrusions(ca. 123–120 Ma). Various epithermal ore and gangue mineral types were discovered in the middle-shallow part of the orebody, indicating the presence of epithermal mineralization at Tiegelongnan. Potassic, propylitic, phyllic and advanced argillic alteration zones were identified. 40Ar/39Ar dating of hydrothermal biotite(potassic zone), sericite(phyllic zone), and alunite(advanced argillic zone) in/around the ore-bearing granodiorite porphyry yielded 121.1±0.6 Ma(1σ), 120.8±0.7 Ma(1σ) and 117.9±1.6 Ma(1σ), respectively. Five hydrothermal mineralization stages were identified, of which the Stage IV pyrite was Rb-Sr dated to be 117.5±1.8 Ma(2σ), representing the end of epithermal mineralization. Field geology and geochronology suggest that both the epithermal and porphyry mineralization belong to the same magmatic-hydrothermal system. The Tiegelongnan super-large Cu-(Au) deposit may have undergone a prolonged magmatichydrothermal evolution, with the major mineralization event occurring at ca.120–117Ma.
基金supported by the National Key Basic Research Program of China (973 Program, No. 2014CB239104)National Science and Technology Major Project (No. 2017ZX05049002-005)+1 种基金Sinopec Basic Prospect Project (No. G5800-16-ZS-KJB043)NSFC-Sinopec Joint Key Project (No. U1663207)
文摘Shale fractures are an important factor controlling shale gas enrichment and high-productivity zones in the Longmaxi Formation, Jiaoshiba area in eastern Sichuan. Drilling results have, however, shown that the shale fracture density does not have a straightforward correlation with shale gas productivity. Based on logging data, drilling and seismic data, the relationship between shale fracture and shale gas accumulation is investigated by integrating the results of experiments and geophysical methods. The following conclusions have been drawn:(1) Tracer diffusion tests indicate that zones of fracture act as favorable channels for shale gas migration and high-angle fractures promote gas accumulation.(2) Based on the result of azimuthal anisotropy prediction, a fracture system with anisotropy strength values between 1 and 1.15 represents a moderate development of high-angle fractures, which is considered to be favorable for shale gas accumulation and high productivity, while fracture systems with anisotropy strength values larger than 1.15 indicate over-development of shale fracture, which may result in the destruction of the shale reservoir preservation conditions.
基金financially supported by NSFC project 41203035the National Basic Research Program(2012CB416803)the Chinese Geological Survey Program(DD20160124)
文摘The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I(gray white color with large phenocrysts), granite porphyry II(pink color with small phenocrysts) and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites:(1) They have high SiO2 content(70.93–80.18 wt% and 72.14–72.64 wt%, respectively), total alkali(7.58–8.95 wt% and 9.35–9.68 wt%, respectively), mafic index(0.95–0.98 and 0.93–0.94, respectively) and felsic index(0.79–0.94 and 0.89–0.91, respectively);(2) They are characterized by pronounced negative Eu anomaly, "seagullstyle" chondrite-normalized REE patterns and "tetrad effect" of REE;(3) They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting.
基金funded by grants from the NSF China(Nos.41502062,41672046,41541017,41641015)the China Geological Survey(Nos.DD20160023-01,201511022)+2 种基金National Key Research and Development Project of China(2016YFC0600310)from the Institute of Geology,Chinese Academy of Geological Sciences(J1526)IGCP–649
文摘Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to reddish–orange to colorless. The grains are all 100–300 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm-1 and 1333 cm-1, mostly at 1331.51 cm-1 or 1326.96 cm-1. This investigation extends the occurrence of diamond and moissanite to the Bulqiza chromitites in the Eastern Mirdita Ophiolite. Integration of the mineralogical, petrological and geochemical data of the Bulqiza chromitites suggests their multi–stage formation. Magnesiochromite grains and perhaps small bodies of chromitite formed at various depths in the upper mantle, and encapsulated the ultra–high pressure, highly reduced and crustal minerals. Some oceanic crustal slabs containing the magnesiochromite and their inclusion were later trapped in suprasubduction zones, where they were modified by tholeiitic and boninitic arc magmas, thus changing the magnesiochromite compositions and depositing chromitite ores in melt channels.
基金This work was financially supported by the China Geological Survey(Grant No.DD20160054)the National Natural Science Foundation of China(Grant No.U1407207)the National Key Research and Development Program of China(Grant No.2017YFC0602802).
文摘Tho Gudui geothermal field records the highest temperature at equivalent borehole depths among the lainland hydrothermal systems in China's Mainland.Located about 150 km southeast of Lhasa City,the capital of Tibet,the Gudui geothermal field belongs to the Sangri-Cuona rift belt,also known as the Sangri-Cuona geothermal belt,and is representative of the non-volcanic geothermal systems in the Himalayas.In this study,oxygen-18 and deuterium isotope compositions as well as 87Sr/86Sr ratios of water samples collected from the Gudui geothermal field were characterized to understand the origin and mixing processes of the geothermal fluids at Gudui.Hydrogen and oxygen isotope plots show both,deep and shallow reservoirs in the Gudui geothermal field.Deep geothermal fluids are the mixing product of magmatic and infiltrating snow-melt water.Calculations show that the magma fluid component of the deep geothermal fluids account for about 21.10%-24.04%;magma fluids lay also be a contributing source of lithium.The linear relationship of the 87Sr/86Sr isotopic ratio versus the 1/Sr plot indicates that shallow geothermal fluids form from the mixing of deep geothermal fluids with cold groundwater.Using a binary mixing model with deep geothermal fluid and cold groundwater as two end-members,the nixing ratios of the latter in most surface hot springs samples were calculated to be between 5% and 10%.Combined with basic geological characteristics,hydrogen and oxygen isotope characteristics,strontium concentration,87Sr/(86)Sr ratios,and the binary mixing model,we infer the 6 th-Class Reservoirs Evolution Conceptual Model(6-CRECM) for the Gudui geothermal system.This model represents an idealized summary of the characteristics of the Gudui geothermal field based on our comprehensive understanding of the origin and mixing processes of the geothermal fluid in Gudui.This study may aid in identifying the geothermal and geochemical origin of the Gudui high-temperature hydrothermal systems in remote Tibet of China,whose potential for geothermal development and utilization is enormous and untapped.
基金supported by Foundation of Geological Survey of China (no.1212011121261)the National Natural Science Foundation (no.40902049)the State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences (no.GBL11307)
文摘The northeastern Tibetan Plateau is located at the convergence of the Asian winter and summer monsoons and westerlies; thus, this area has witnessed historic climate changes.The Xunhua basin is an intermontane basin on the northeastern margin of the Tibetan Plateau.The basin contains more than 2000 m of Cenozoic fluvial–lacustrine sediments, recording a long history of climate and environmental changes.We collected the mid-Miocene sediments from the Xunhua basin and used palynological methods to discuss the relationship between aridification in the interior of Asia, global cooling, and uplift of the Tibetan Plateau.Based on the palynological analysis of the Xigou section, Xunhua basin, the palynological diagram is subdivided into three pollen zones and past vegetation and climate are reconstructed.Zone I, Ephedripites–Nitraridites–Chenopodipollis–Quercoidites(14.0–12.5 Ma), represents mixed shrub–steppe vegetation with a dry and cold climate.In zone II, Pinaceae–Betulaepollenites–Ephedripites–Chenopodipollis–Graminidites(12.5–8.0 Ma), the vegetation and climate conditions improved, even though the vegetation was still dominated by shrub–steppe taxa.Zone III, Ephedripites–Nitrariadites–Chenopodipollis(8.0–5.0 Ma), represents desert steppe vegetation with drier and colder climate.The palynological records suggest that shrub–steppe dominated the whole Xigou section and the content gradually increased, implying a protracted aridification process, although there was an obvious climate improvement during 12.5–8.0 Ma.The aridification in the Xunhua basin and surrounding mountains during 14.0–12.5 Ma was probably related to global cooling induced by the rapid expansion of the East Antarctic ice-sheets and the relatively higher evaporation rate.During the 12.5–8.0 Ma period, although topographic changes(uplift of Jishi Shan) decreased precipitation and strengthened aridification in the Xunhua basin on leeward slopes, the improved vegetation and climate conditions were probably controlled by the decrease in evaporation rates as a result of continuous cooling.From 8.0 to 5.0 Ma, the rapid development of the desert steppe can be attributed to global cooling and uplift of the Tibetan Plateau.
基金financial support from China University of Geosciences, Beijingsupported by the Project of National Nature Science Foundation of China (Grant No. 41572094)+2 种基金the Ph. D Research Start-up Fund of Fuyang Normal University (Grant No. 2016kyqd0004)the Scientific Research Project of Fuyang Normal University (Grant No. 2018FSKJ08ZD)the Key Project of Youth Science Funds of Fuyang Normal University (Gran No. rcxm201907)
文摘Reconstruction of the desert paleoclimate is important to understand the mechanisms that triggered and/or enhanced climate change.Through optically stimulated luminescence(OSL)dating,grain size,magnetic susceptibility,X-ray powder diffraction(XRD)and geochemical indicators,we provide a welldated record of a sedimentary outcrop on the southeast margin of the Bardain Jaran Desert,Northwest China,during the last glacial period.Four Qz-OSL ages are obtained,41.0±3.4 ka,54.7±4.4 ka,59.5±5.0 ka and 66.8±5.8 ka,corresponding to the depths of 35 cm,70 cm,150 cm and 200 cm respectively.Indicators like grain size,clay content,magnetic susceptibility,XRD and geochemical index(e.g.Sr,Ba,Sr/Ca)jointly indicate abrupt climate changes at the depth of 35 cm(age,ca.41.0 ka)and200 cm(age,ca.67 ka).Namely,the 280 cm sedimentary outcrop perfectly records a warm wet climate stage,corresponding to the late Marine Isotope Stages(MIS)4 to the early MIS 3.Besides,there is a trend of grain size increase after around 40ka BP,which is most likely a signal of wind strength change.Our research supports that enhancing Siberian High pressure system during the late MIS 3played a key role in NW East Asia climate evolution.
基金financially supported by the National Natural Science Foundation of China (grants No. 41772159/D0208, No. 41872178)the National Science and Technology Major Project of China (grant No. 2017ZX05064003)
文摘The main methods of coalbed methane(CBM)development are drainage and depressurization,and a precise prediction of coal reservoir pressure is thus crucial for the evaluation of reservoir potentials and the formulation of reasonable development plans.This work established a new reservoir pressure prediction model based on the material balance equation(MBE)of coal reservoir,which considers the self-regulating effects of coal reservoirs and the dynamic change of equivalent drainage area(EDA).According to the proposed model,the reservoir pressure can be predicted based on reservoir condition data and the actual production data of a single well.Compared with traditional reservoir pressure prediction models which regard EDA as a fixed value,the proposed model can better predict the average pressure of reservoirs.Moreover,orthogonal experiments were designed to evaluate the sensitivity of reservoir parameters on the reservoir pressure prediction results of this proposed model.The results show that the saturation of irreducible water is the most sensitive parameter,followed by Langmuir volume and reservoir porosity,and Langmuir pressure is the least sensitive parameter.In addition,the pressure drop of reservoirs is negatively correlated with the saturation of irreducible water and the Langmuir volume,while it is positively correlated with porosity.This work analyzed the reservoir pressure drop characteristics of the CBM wells in the Shizhuangnan Block of the Qinshui Basin,and the results show that the CBM reservoir depressurization can be divided into three types,i.e.,rapidly drop type,medium-term stability type,and slowly drop type.The drainage features of wells were reasonably interpreted based on the comprehensive analysis of the reservoir depressurization type;the latter was coupled to the corresponding permeability dynamic change characteristics,eventually proving the applicability of the proposed model.
基金funded by the National Natural Science Foundation of China(grants No.41406080,41273066 and 41106060)
文摘Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.
基金Funded by Natioanl Natural Science Foundation of Chin a(Nos.2012BAJ11B00,41301588,41471339,41571514)the Center for Materials Research and Analysis,Wuhan University of Technology
文摘In order to improve the prediction accuracy of compressive strength of concrete,103 groups of concrete data were collected as the samples.We selected seven kinds of ingredients from the concrete samples, using Grid-SVM, PSO-SVM, and GA-SVM models to establish the prediction model of cubic meter compressive strength of concrete.The experimental results show that SVM model based on Grid optimization algorithm,SVM model based on Particle swarm optimization algorithm,SVM model based on Genetic optimization algorithm mean square error respectively are 0.001, 0.489 8, and 0.304 2, correlation coefficients are 0.994 8, 0.994 6, and 0.993 0. It is shown that cubic meter compressive strength prediction method based on Grid-SVM model is the best optimization algorithm.
基金jointly the National Key Research and Development Program of China(Grant Nos.2018YFC0603806 and 2017YFC0601506)the National Natural Science Foundation of China(Grant No.41902101)the Geological Survey Program of China(Grant No.DD20190166)。
文摘The Linjiasandaogou gold deposit is located in the Qingchengzi Orefield,North China Craton,China,and has not attracted many studies.We present geochronological,whole-rock geochemical,and Sr–Nd–Hf isotopic data to constrain the age and tectonic setting of the mineralization.U–Pb dating of zircon from pre-and post-ore dikes indicates the Linjiasandaogou Au deposit formed at ca.227–226 Ma.The granite porphyry(ca.227 Ma)and quartz diorite porphyry(ca.228 Ma),which are slightly older than the mineralization,have(;Sr/;Sr)i-=0.7127–0.7162,εNd(t)=–13.7 to–17.0,andεHf(t)=–14.6 to–16.9,and display enrichment in light rare earth elements and large ion lithophile elements and depletion in high field strength elements.Two lamprophyres(226 and225 Ma),which are slightly younger than the mineralization,have higher(;Sr/;Sr)i(0.7165–0.7216),negativeεNd(t)(–11.2 to–14.3)andεHf(t)(–15.6 to–18.6)values,and are enriched in light rare earth elements but depleted in high field strength elements(Nb and Ta).The geochemical characteristics of the granitoid and lamprophyres indicate a lower crustal and enriched mantle source,respectively.We infer that the Linjiasandaogou Au deposit formed in a postcollisional tectonic setting,following the collision between the North China,Yangtze craton,and Central Asian Orogeny in Triassic.
基金supported by the National Natural Science Foundation of China (Grant No. 41302209)the National groundwater investigation project (Grant No.1212011121169)
文摘This thesis focuses Arsenic(As) distribution and occurrence in groundwater of Yangtze River Delta economic region, East China. 2019 groundwater samples were collected to analyze 26 chemical compositions, including As. The Principal Component Analysis(PCA) was used to find out As source in groundwater. The results show that average As concentration in groundwater of this study is 9.33 μg/l, and maximum As concentration is up to 510 μg/l. The variation coefficient is 314.34%. High arsenic phreatic water(>10 μg/l) distributes along the Yangtze River and its estuary. Weak hydrodynamic conditions, wide p H value variation range and deteriorating environment are dominating factors, especially in Yangtze River Delta. The PCA suggests that arsenic in phreatic water is mainly of natural origin. Part of arsenic may directly originate from sediment organics and be related to organics decomposition.