Skyrmions, with their vortex-like structures and inherent topological protection, play a pivotal role in developing innovative low-power memory and logic devices. The efficient generation and control of skyrmions in g...Skyrmions, with their vortex-like structures and inherent topological protection, play a pivotal role in developing innovative low-power memory and logic devices. The efficient generation and control of skyrmions in geometrically confined systems are crucial for the development of skyrmion-based spintronic devices. In this study, we focus on investigating the non-reciprocal transport behavior of skyrmions and their interactions with boundaries of various shapes. The shape of the notch structure in the nanotrack significantly affects the dynamic behavior of magnetic skyrmions. Through micromagnetic simulation, the non-reciprocal transport properties of skyrmions in nanowires with different notch structures are investigated in this work.展开更多
Objectives This paper aims to investigate the effects of enrollment in the Ethiopian community-based health insurance(CBHI)scheme on household preventive care activities and the timing of treatment-seeking behavior fo...Objectives This paper aims to investigate the effects of enrollment in the Ethiopian community-based health insurance(CBHI)scheme on household preventive care activities and the timing of treatment-seeking behavior for illness symptoms.There is growing concern about the financial sustainability of CBHI schemes in developing countries.However,few empirical studies have identified potential contributors,including ex-ante and ex-post moral hazards.Methods We implement a household fixed-effect panel data regression model,drawing on three rounds of household survey data collected face to face in districts where CBHI scheme is operational and in districts where it is not operational in Ethiopia.Results The findings show that enrolment in CBHI does not significantly influence household behaviour regarding preventive care activities such as water treatment before drinking and handwashing before meals.However,CBHI significantly increases delay in treatment-seeking behaviour for diseases symptoms.Particularly,on average,we estimate about 4-6 h delay for malaria symptoms,a little above 4 h for tetanus,and 10-11 h for tuberculosis among the insured households.Conclusions While there is evidence that CBHI improve the utilization of outpatient or primary care services,our study suggests that insured members may wait longer before visiting health facilities.This delay could be partly due to moral hazard problems,as insured households,particularly those from rural areas,may consider the opportunity costs associated with visiting health facilities for minor symptoms.Overall,it is essential to identify the primary causes of delays in seeking medical services and implement appropriate interventions to encourage insured individuals to seek early medical attention.展开更多
Over the last couple of decades,community question-answering sites(CQAs)have been a topic of much academic interest.Scholars have often leveraged traditional machine learning(ML)and deep learning(DL)to explore the eve...Over the last couple of decades,community question-answering sites(CQAs)have been a topic of much academic interest.Scholars have often leveraged traditional machine learning(ML)and deep learning(DL)to explore the ever-growing volume of content that CQAs engender.To clarify the current state of the CQA literature that has used ML and DL,this paper reports a systematic literature review.The goal is to summarise and synthesise the major themes of CQA research related to(i)questions,(ii)answers and(iii)users.The final review included 133 articles.Dominant research themes include question quality,answer quality,and expert identification.In terms of dataset,some of the most widely studied platforms include Yahoo!Answers,Stack Exchange and Stack Overflow.The scope of most articles was confined to just one platform with few cross-platform investigations.Articles with ML outnumber those with DL.Nonetheless,the use of DL in CQA research is on an upward trajectory.A number of research directions are proposed.展开更多
The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical industries.The selective deoxygenation of natural oils to diesel-range...The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical industries.The selective deoxygenation of natural oils to diesel-ranged hydrocarbons,bio-jet fuels,or fatty alcohols with controllable selectivity is especially attractive in natural oil feedstock biorefineries.This review presents recent progress in catalytic deoxygenation of natural oils or related model compounds(e.g.,fatty acids)to renewable liquid fuels(green diesel and bio-jet fuels)and valuable fatty alcohols(unsaturated and saturated fatty alcohols).Besides,it discusses and compares the existing and potential strategies to control the product selectivity over heterogeneous catalysts.Most research conducted and reviewed has only addressed the production of one category;therefore,a new integrative vision exploring how to direct the process toward fuel and/or chemicals is urgently needed.Thus,work conducted to date addressing the development of new catalysts and studying the influence of the reaction parameters(e.g.,temperature,time and hydrogen pressure)is summarized and critically discussed from a green and sustainable perspective using efficiency indicators(e.g.,yields,selectivity,turnover frequencies and catalysts lifetime).Special attention has been given to the chemical transformations occurring to identify key descriptors to tune the selectivity toward target products by manipulating the reaction conditions and the structures of the catalysts.Finally,the challenges and future research goals to develop novel and holistic natural oil biorefineries are proposed.As a result,this critical review provides the readership with appropriate information to selectively control the transformation of natural oils into either biofuels and/or value-added chemicals.This new flexible vision can help pave the wave to suit the present and future market needs.展开更多
Research of spin polarization of magnetic CoFeB thin films is of practical importance in spintronic applications.Here,using a direct characterization technique of spin-resolved photoemission spectroscopy,we obtain the...Research of spin polarization of magnetic CoFeB thin films is of practical importance in spintronic applications.Here,using a direct characterization technique of spin-resolved photoemission spectroscopy,we obtain the surface spin polarization of amorphous Co_(40)Fe_(40)B_(20)thin films with different annealing temperatures from 100℃to 500℃prepared by magnetron sputtering.After high annealing temperature,a quasi-semiconductor state is gradually formed at the CoFeB surface due to the boron diffusion.While the global magnetization remains almost constant,the secondary electrons’spin polarization,average valence band spin polarization and the spin polarization at Fermi level from spin-resolved photoemission spectroscopy show a general trend of decreasing with the increasing annealing temperature above 100℃.These distinct surface properties are attributed to the enhanced Fe-B bonding due to the boron segregation upon surface after annealing as confirmed by x-ray photoelectron spectroscopy and scanning transmission electron microscopy with energy dispersive spectroscopy.Our findings provide insight into the surface spin-resolved electronic structure of the CoFeB thin films,which should be important for development of high-performance magnetic random-access memories.展开更多
This study examined and analysed the impact of self-efficacy on the career decisions of 52 viola students enrolled in Chinese universities.According to the findings,the level of self-efficacy influences the learning a...This study examined and analysed the impact of self-efficacy on the career decisions of 52 viola students enrolled in Chinese universities.According to the findings,the level of self-efficacy influences the learning and career decisions of students directly.Higher self-efficacy can positively affect how individuals perceive their past experiences and those of others.Therefore,a high degree of self-efficacy can be advantageous.Self-efficacy is primarily influenced by a person’s prior experiences,alternative experiences,verbal persuasion,and physical and emotional state during work-based learning.Schools may offer courses that foster and improve the development of self-efficacy in order to help viola majors in improving their self-efficacy effectively.展开更多
In an experiment carried out at the Prague Asterix Laser System at laser intensities relevant to shock ignition conditions(I>10^(16) W/cm^(2)),the heating and transport of hot electrons were studied by using severa...In an experiment carried out at the Prague Asterix Laser System at laser intensities relevant to shock ignition conditions(I>10^(16) W/cm^(2)),the heating and transport of hot electrons were studied by using several complementary diagnostics,i.e.,K_(α)time-resolved imaging,hard x-ray filtering(a bremsstrahlung cannon),and electron spectroscopy.Ablators with differing composition from low Z(parylene N)to high Z(nickel)were used in multilayer planar targets to produce plasmas with different coronal temperature and collisionality and modify the conditions of hot-electron generation.The variety of available diagnostics allowed full characterization of the population of hot electrons,retrieving their conversion efficiency,time generation and duration,temperature,and angular divergence.The obtained results are shown to be consistent with those from detailed simulations and similar inertial confinement fusion experiments.Based on the measured data,the advantages,reliability,and complementarity of the experimental diagnostics are discussed.展开更多
China’s traditional national music is an art form formed by the working people and art pioneers to express their emotions during thousands of years of productive labor.National music not only contains emotional stori...China’s traditional national music is an art form formed by the working people and art pioneers to express their emotions during thousands of years of productive labor.National music not only contains emotional stories that are capable of evoking praises and tears,but also has a profound understanding of the lives of sages.In summary,integrating college music education with national music culture can allow students to deeply discover music,thereby stimulating students’enthusiasm for learning music,improving students’learning quality,mastering the core parts of music learning,and helping students to go a long way in music.This article mainly focuses on the characteristics and educational value of national music culture,and its effective integration with music education in colleges and universities.This article can help relevant workers in college music education and promote the sustainable development of music education in colleges and universities in China.展开更多
The standardized hypertension management provided by primary health care workers is an important part of China's recent health care reform efforts. Investigating 5,116 hypertensive patients from a cross-sectional sur...The standardized hypertension management provided by primary health care workers is an important part of China's recent health care reform efforts. Investigating 5,116 hypertensive patients from a cross-sectional survey conducted by the Chinese Center for Disease Control and Prevention in 2012, this study found that adherence to standardized hypertension management is associated with positive effects on hypertension- related knowledge, healthy lifestyle behavior, antihypertensive medical treatments, and blood pressure control. It will be necessary to provide primary health care workers with sufficient training and reasonable incentives to ensure the implementation and effectiveness of hypertension management.展开更多
A comparison between conventional pyrolysis and a novel developed low-temperature microwave-assisted pyrolysis methodology has been performed for the valorisation of a range of biomass feedstocks including waste resid...A comparison between conventional pyrolysis and a novel developed low-temperature microwave-assisted pyrolysis methodology has been performed for the valorisation of a range of biomass feedstocks including waste residues. Microwave pyrolysis was found to efficiently deliver comparable evolution of bio-gases in the system as compared with conventional pyrolysis at significantly reduced temperatures (120-180 ℃vs 250-400 ℃). The gas obtained from microwave-assisted pyrolysis was found to contain CO2, CH4 and CO as major components as well展开更多
Acute coronary syndromes presenting with ST elevation are usually treated with emergency reperfusion/revascularisation therapy. In contrast current evidence and national guidelines recommend risk stratification for no...Acute coronary syndromes presenting with ST elevation are usually treated with emergency reperfusion/revascularisation therapy. In contrast current evidence and national guidelines recommend risk stratification for non ST segment elevation myocardial infarction(NSTEMI) with the decision on revascularisation dependent on perceived clinical risk. Risk stratification for STEMI has no recommendation. Statistical risk scoring techniques in NSTEMI have been demonstrated to improve outcomes however their uptake has been poor perhaps due to questions over their discrimination and concern for application to individuals who may not have been adequately represented in clinical trials. STEMI is perceived to carry sufficient risk to warrant emergency coronary intervention [by primary percutaneous coronary intervention(PPCI)] even if this results in a delay to reperfusion with immediate thrombolysis. Immediate thrombolysis may be as effective in patients presenting early, or at low risk, but physicians are poor at assessing clinical and procedural risks and currently are not required to consider this. Inadequate data on risk stratification in STEMI inhibits the option of immediate fibrinolysis, which may be cost-effective. Currently the mode of reperfusion for STEMI defaults to emergency angiography and percutaneous coronary intervention ignoring alternative strategies. This review article examines the current risk scores and evidence base for risk stratification for STEMI patients. The requirements for an ideal STEMI risk score are discussed.展开更多
A known species, Physarum melleum, was found fruiting on living leaves of Dendrobium candidum, which was collected in China in 2004. Its morphological characters were revealed by light microscopy (LM), environmental s...A known species, Physarum melleum, was found fruiting on living leaves of Dendrobium candidum, which was collected in China in 2004. Its morphological characters were revealed by light microscopy (LM), environmental scanning elec- tron microscopy (ESEM) and scanning electron microscopy (SEM). Character variations were distinguished by its olive-yellow peridium and its always thinner capillitium containing globulose granular material between the large calcareous nodes. The cal- cium carbonate granules, deposited on stalks, peridium and hypothallus as well as within stalks, were globose and smooth.展开更多
The Autographa californica multiple capsid nucleopolyhedrovirus (AcMNPV) was the first baculovirus for which the complete nucleotide sequence became known. Since then 15 years lapsed and much research has been perform...The Autographa californica multiple capsid nucleopolyhedrovirus (AcMNPV) was the first baculovirus for which the complete nucleotide sequence became known. Since then 15 years lapsed and much research has been performed to elucidate putative functions of the annotated open reading frames of this virus and this endeavour is still ongoing. AcMNPV is the most well-known and well-studied baculovirus species, not in the least for its application as a vector for the high-level expression of foreign genes in insect cells. This article is the first monograph of a single baculovirus and gives a current overview of what is known about the 151 AcMNPV ORFs, including (putative) function and temporal and spatial presence of transcripts and protein. To date 60 ORFs have a proven function, another 19 ORFs have homologs for which functions are known in other baculoviruses and 72 ORFs are still enigmatic. This paper should assist the reader in quickly finding the essentials of AcMNPV.展开更多
In recent years, high-polluting industries have been gradually shifted from the eastern developed regions to the central and western underdeveloped regions in China. Certain environmental regulations have been in plac...In recent years, high-polluting industries have been gradually shifted from the eastern developed regions to the central and western underdeveloped regions in China. Certain environmental regulations have been in place accordingly in various regions, but the pollution in the central and western regions has risen sharply. Based on the data of interprovincial panel in China from 2006 to 2015, this paper calculates high-pollution industry dynamic agglomeration index, environmental pollution agglomeration index and relative environmental regulation intensity index, and uses Generalized Method of Moments to carry out the regression analyses of the whole samples,regional heterogeneity and temporal heterogeneity. The results show that there is an inverted Ushaped relationship between relative environmental regulation and environmental pollution concentration in China. The concentration degrees of industrial wastewater pollution and industrial waste gas pollution are deepened, which are mainly caused by the transfer of highly polluting industries. However, the concentration of industrial solid waste pollution caused by the transfer is not obvious. Furthermore, the deepening of industrialization intensifies the concentration of regional environmental pollution. Environmental Kuznets Curve does exist in China,but it is not significant. The increase of labor cost and quality will reduce the concentration of environmental pollution.展开更多
To lower the difficulty of fault protection,a doubly-fed induction machine based shipboard propulsion system(DFIM-SPS)that is partially power decoupled is presented.In such an intrinsically safe SPS architecture,a syn...To lower the difficulty of fault protection,a doubly-fed induction machine based shipboard propulsion system(DFIM-SPS)that is partially power decoupled is presented.In such an intrinsically safe SPS architecture,a synchronous generator(SG)is employed for power generation,and the accuracy of the parameters of power generation unit(PGU)plays an important role in SPS stable operation.In this paper,the PGU parameter deviations are studied to evaluate the effects on system performance.The models of salient-pole SG,type DC1A excitation system(EXS)and DFIM are illustrated first.Besides,the corresponding control scheme is explained.For the 16 important parameters of PGU,up to 40%of parameter deviations are applied to implement parameter sensitivity analysis.Then,simulation studies are carried out to evaluate the parameter deviation effects on system performance in detail.By defining three parameter deviation effect indicators(PDEIs),the effects on the PGU output variables,which are the terminal voltage and output active power,are studied.Moreover,the increasing rates of PDEIs with different degrees of parameter deviations for the key parameters are analyzed.Furthermore,the overall system performance is investigated for the two most influential PGU parameters.This paper provides some vital clues on SG and EXS parameter identification for DFIM-SPS.展开更多
X-ray absorption spectroscopy is a well-accepted diagnostic for experimental studies of warm dense matter.It requires a short-lived X-ray source of sufficiently high emissivity and without characteristic lines in the ...X-ray absorption spectroscopy is a well-accepted diagnostic for experimental studies of warm dense matter.It requires a short-lived X-ray source of sufficiently high emissivity and without characteristic lines in the spectral range of interest.In the present work,we discuss how to choose an optimum material and thickness to get a bright source in the wavelength range 2A–6A(∼2 keV to 6 keV)by considering relatively low-Z elements.We demonstrate that the highest emissivity of solid aluminum and silicon foil targets irradiated with a 1-ps high-contrast sub-kJ laser pulse is achieved when the target thickness is close to 10μm.An outer plastic layer can increase the emissivity even further.展开更多
Background: Canopy structure, defined by leaf area index (LAI), fractional vegetation cover (FCover) and fraction of absorbed photosynthetically active radiation (fAPAR), regulates a wide range of forest functi...Background: Canopy structure, defined by leaf area index (LAI), fractional vegetation cover (FCover) and fraction of absorbed photosynthetically active radiation (fAPAR), regulates a wide range of forest functions and ecosystem services. Spatially consistent field-measurements of canopy structure are however lacking, particularly for the tropics. Methods: Here, we introduce the Global LAI database: a global dataset of field-based canopy structure measurements spanning tropical forests in four continents (Africa, Asia, Australia and the Americas). We use these measurements to test for climate dependencies within and across continents, and to test for the potential of anthropogenic disturbance and forest protection to modulate those dependences. Results: Using data collected from 887 tropical forest plots, we show that maximum water deficit, defined across the most arid months of the year, is an important predictor of canopy structure, with all three canopy attributes declining significantly with increasing water deficit. Canopy attributes also increase with minimum temperature, and with the protection of forests according to both active (within protected areas) and passive measures (through topography). Once protection and continent effects are accounted for, other anthropogenic measures (e.g. human population) do not improve the model. Conclusions: We conclude that canopy structure in the tropics is primarily a consequence of forest adaptation to the maximum water deficits historically experienced within a given region. Climate change, and in particular changes in drought regimes may thus affect forest structure and function, but forest protection may offer some resilience against this effect.展开更多
Reaction dynamics in gases at operating temperatures at the atomic level are the basis of heterogeneous gas-solid catalyst reactions and are crucial to the catalyst function.Supported noble metal nanocatalysts such as...Reaction dynamics in gases at operating temperatures at the atomic level are the basis of heterogeneous gas-solid catalyst reactions and are crucial to the catalyst function.Supported noble metal nanocatalysts such as platinum are of interest in fuel cells and as diesel oxidation catalysts for pollution control,and practical ruthenium nanocatalysts are explored for ammonia synthesis.Graphite and graphitic carbons are of interest as supports for the nanocatalysts.Despite considerable literature on the catalytic processes on graphite and graphitic supports,reaction dynamics of the nanocatalysts on the supports in different reactive gas environments and operating temperatures at the single atom level are not well understood.Here we present real time in-situ observations and analyses of reaction dynamics of Pt in oxidation,and practical Ru nanocatalysts in ammonia synthesis,on graphite and related supports under controlled reaction environments using a novel in-situ environmental(scanning) transmission electron microscope with single atom resolution.By recording snapshots of the reaction dynamics,the behaviour of the catalysts is imaged.The images reveal single metal atoms,clusters of a few atoms on the graphitic supports and the support function.These all play key roles in the mobility,sintering and growth of the catalysts.The experimental findings provide new structural insights into atomic scale reaction dynamics,morphology and stability of the nanocatalysts.展开更多
Due to the characteristics of chaotic systems,different cryptosystems based on chaos have been proposed to satisfy the security of multimedia data.A plain image-related chaotic algorithm is proposed by Luo et al.with ...Due to the characteristics of chaotic systems,different cryptosystems based on chaos have been proposed to satisfy the security of multimedia data.A plain image-related chaotic algorithm is proposed by Luo et al.with high speed and efficiency.Security weaknesses of the cryptosystem are studied in this paper.It is found that the important secret key information is leaked because an important parameter can be obtained after an inverse operation in the last step of the cryptosystems without secret key.Meanwhile,the value zero is processed improperly in quantification algorithm.Based on the weaknesses,chosen plaintext attack on the cryptosystem is proposed,by which,an important parameter,equivalent to secret key,can be calculated with a specific chosen plain image.With the obtained parameter,the plain image of any ciphered image,encrypted by the cryptosystem,can be recovered.Then,an improvement is proposed to solve the problems after modifying the quantification algorithm.It is from the experiments that chosen plaintext attack is valid and improved algorithm possesses better performance.展开更多
基金Project supported by the Key-Area Research and Development Program of Guangdong Province,China(Grant No.2021B0101300003)the Guangdong Basic and Applied Basic Research Foundation,China(Grant Nos.2022A1515110863 and 2023A1515010837)+5 种基金the National Key Research and Development Program of China(Grant No.2016YFA0300803)the National Natural Science Foundation of China(Grant Nos.12304136,61427812,11774160,12241403,51771127,52171188,and 52111530143)the Natural Science Foundation of Jiangsu Province,China(Grant Nos.BK20192006 and BK20200307)the Fundamental Research Funds for the Central Universities,China(Grant No.021014380113)International Exchanges 2020 Cost Share(NSFC),China(Grant No.IECNSFC201296)the Project for Maiden Voyage of Guangzhou Basic and Applied Basic Research Scheme,China(Grant No.2024A04J4186)。
文摘Skyrmions, with their vortex-like structures and inherent topological protection, play a pivotal role in developing innovative low-power memory and logic devices. The efficient generation and control of skyrmions in geometrically confined systems are crucial for the development of skyrmion-based spintronic devices. In this study, we focus on investigating the non-reciprocal transport behavior of skyrmions and their interactions with boundaries of various shapes. The shape of the notch structure in the nanotrack significantly affects the dynamic behavior of magnetic skyrmions. Through micromagnetic simulation, the non-reciprocal transport properties of skyrmions in nanowires with different notch structures are investigated in this work.
基金The authors acknowledge the financial support of the Dutch Research Council(NWO-WOTRO)(Grant No.W07.45.103.00)and the support of D.P.Hoijer Fonds,Erasmus Trustfonds,Erasmus University Rotterdam.
文摘Objectives This paper aims to investigate the effects of enrollment in the Ethiopian community-based health insurance(CBHI)scheme on household preventive care activities and the timing of treatment-seeking behavior for illness symptoms.There is growing concern about the financial sustainability of CBHI schemes in developing countries.However,few empirical studies have identified potential contributors,including ex-ante and ex-post moral hazards.Methods We implement a household fixed-effect panel data regression model,drawing on three rounds of household survey data collected face to face in districts where CBHI scheme is operational and in districts where it is not operational in Ethiopia.Results The findings show that enrolment in CBHI does not significantly influence household behaviour regarding preventive care activities such as water treatment before drinking and handwashing before meals.However,CBHI significantly increases delay in treatment-seeking behaviour for diseases symptoms.Particularly,on average,we estimate about 4-6 h delay for malaria symptoms,a little above 4 h for tetanus,and 10-11 h for tuberculosis among the insured households.Conclusions While there is evidence that CBHI improve the utilization of outpatient or primary care services,our study suggests that insured members may wait longer before visiting health facilities.This delay could be partly due to moral hazard problems,as insured households,particularly those from rural areas,may consider the opportunity costs associated with visiting health facilities for minor symptoms.Overall,it is essential to identify the primary causes of delays in seeking medical services and implement appropriate interventions to encourage insured individuals to seek early medical attention.
文摘Over the last couple of decades,community question-answering sites(CQAs)have been a topic of much academic interest.Scholars have often leveraged traditional machine learning(ML)and deep learning(DL)to explore the ever-growing volume of content that CQAs engender.To clarify the current state of the CQA literature that has used ML and DL,this paper reports a systematic literature review.The goal is to summarise and synthesise the major themes of CQA research related to(i)questions,(ii)answers and(iii)users.The final review included 133 articles.Dominant research themes include question quality,answer quality,and expert identification.In terms of dataset,some of the most widely studied platforms include Yahoo!Answers,Stack Exchange and Stack Overflow.The scope of most articles was confined to just one platform with few cross-platform investigations.Articles with ML outnumber those with DL.Nonetheless,the use of DL in CQA research is on an upward trajectory.A number of research directions are proposed.
基金financially supported by the National Natural Science Foundation of China (No.21536007)the 111 Project (B17030)+1 种基金support from China Scholarship Council (CSC No.202006240156)the Spanish Ministry of Science,Innovation and Universities for the Juan de la Cierva (JdC)fellowships (Grant Numbers FJCI-2016-30847 and IJC2018-037110-I)awarded.
文摘The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical industries.The selective deoxygenation of natural oils to diesel-ranged hydrocarbons,bio-jet fuels,or fatty alcohols with controllable selectivity is especially attractive in natural oil feedstock biorefineries.This review presents recent progress in catalytic deoxygenation of natural oils or related model compounds(e.g.,fatty acids)to renewable liquid fuels(green diesel and bio-jet fuels)and valuable fatty alcohols(unsaturated and saturated fatty alcohols).Besides,it discusses and compares the existing and potential strategies to control the product selectivity over heterogeneous catalysts.Most research conducted and reviewed has only addressed the production of one category;therefore,a new integrative vision exploring how to direct the process toward fuel and/or chemicals is urgently needed.Thus,work conducted to date addressing the development of new catalysts and studying the influence of the reaction parameters(e.g.,temperature,time and hydrogen pressure)is summarized and critically discussed from a green and sustainable perspective using efficiency indicators(e.g.,yields,selectivity,turnover frequencies and catalysts lifetime).Special attention has been given to the chemical transformations occurring to identify key descriptors to tune the selectivity toward target products by manipulating the reaction conditions and the structures of the catalysts.Finally,the challenges and future research goals to develop novel and holistic natural oil biorefineries are proposed.As a result,this critical review provides the readership with appropriate information to selectively control the transformation of natural oils into either biofuels and/or value-added chemicals.This new flexible vision can help pave the wave to suit the present and future market needs.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFB3601600)the National Natural Science Foundation of China(Grant Nos.12104216,61427812,11774160,51971109,51871236,51771053,U1806219)+1 种基金the Natural Science Foundation of Jiangsu Province of China(Grant Nos.BK20200307,BK20192006,BK20180056)the Fundamental Research Funds for the Central Universities(Grant No.21014380113)。
文摘Research of spin polarization of magnetic CoFeB thin films is of practical importance in spintronic applications.Here,using a direct characterization technique of spin-resolved photoemission spectroscopy,we obtain the surface spin polarization of amorphous Co_(40)Fe_(40)B_(20)thin films with different annealing temperatures from 100℃to 500℃prepared by magnetron sputtering.After high annealing temperature,a quasi-semiconductor state is gradually formed at the CoFeB surface due to the boron diffusion.While the global magnetization remains almost constant,the secondary electrons’spin polarization,average valence band spin polarization and the spin polarization at Fermi level from spin-resolved photoemission spectroscopy show a general trend of decreasing with the increasing annealing temperature above 100℃.These distinct surface properties are attributed to the enhanced Fe-B bonding due to the boron segregation upon surface after annealing as confirmed by x-ray photoelectron spectroscopy and scanning transmission electron microscopy with energy dispersive spectroscopy.Our findings provide insight into the surface spin-resolved electronic structure of the CoFeB thin films,which should be important for development of high-performance magnetic random-access memories.
文摘This study examined and analysed the impact of self-efficacy on the career decisions of 52 viola students enrolled in Chinese universities.According to the findings,the level of self-efficacy influences the learning and career decisions of students directly.Higher self-efficacy can positively affect how individuals perceive their past experiences and those of others.Therefore,a high degree of self-efficacy can be advantageous.Self-efficacy is primarily influenced by a person’s prior experiences,alternative experiences,verbal persuasion,and physical and emotional state during work-based learning.Schools may offer courses that foster and improve the development of self-efficacy in order to help viola majors in improving their self-efficacy effectively.
基金This work was carried out within the framework of the EUROfusion Consortium,funded by the European Union via the Euratom Research and Training Programme(Grant No.101052200-EUROfusion)Views and opinions expressed are however those of the authors only and do not necessarily reflect those of the European Union or the European Commission.Neither the European Union nor the European Commission can be held responsible for them.The involved teams have operated within the framework of the Enabling Research Project:Grant No.ENR-IFE.01.CEA“Advancing shock ignition for direct-drive inertial fusion.”The work was also supported by the Natural Sciences and Engineering Research Council of Canada(Grant No.RGPIN-2019-05013)+5 种基金The authors acknowledge support of the PALS Infrastructure within the MŠMT(MEYS)project Grant No.LM2023068Staff members of the PALS Research Center appreciate financial support(Grant No.LM2023068)from the Czech Ministry of Education,Youth and Sports facilitating operation of the PALS facilityThe work of JIHT RAS team was supported by the Ministry of Science and Higher Education of the Russian Federation(State Assignment No.075-01129-23-00)The work at NRMU MEPhI was supported by the Ministry of Science and Higher Education of the Russian Federation(Agreement No.075-15-2021-1361)This project has received funding from the CNR funded Italian research Network ELI-Italy(D.M.No.63108.08.2016)This work was funded by United Kingdom EPSRC Grants No.EP/P026796/1 and No.EP/L01663X/1.The results presented in this paper are based on work carried out between September 2018 and December 2021.
文摘In an experiment carried out at the Prague Asterix Laser System at laser intensities relevant to shock ignition conditions(I>10^(16) W/cm^(2)),the heating and transport of hot electrons were studied by using several complementary diagnostics,i.e.,K_(α)time-resolved imaging,hard x-ray filtering(a bremsstrahlung cannon),and electron spectroscopy.Ablators with differing composition from low Z(parylene N)to high Z(nickel)were used in multilayer planar targets to produce plasmas with different coronal temperature and collisionality and modify the conditions of hot-electron generation.The variety of available diagnostics allowed full characterization of the population of hot electrons,retrieving their conversion efficiency,time generation and duration,temperature,and angular divergence.The obtained results are shown to be consistent with those from detailed simulations and similar inertial confinement fusion experiments.Based on the measured data,the advantages,reliability,and complementarity of the experimental diagnostics are discussed.
文摘China’s traditional national music is an art form formed by the working people and art pioneers to express their emotions during thousands of years of productive labor.National music not only contains emotional stories that are capable of evoking praises and tears,but also has a profound understanding of the lives of sages.In summary,integrating college music education with national music culture can allow students to deeply discover music,thereby stimulating students’enthusiasm for learning music,improving students’learning quality,mastering the core parts of music learning,and helping students to go a long way in music.This article mainly focuses on the characteristics and educational value of national music culture,and its effective integration with music education in colleges and universities.This article can help relevant workers in college music education and promote the sustainable development of music education in colleges and universities in China.
文摘The standardized hypertension management provided by primary health care workers is an important part of China's recent health care reform efforts. Investigating 5,116 hypertensive patients from a cross-sectional survey conducted by the Chinese Center for Disease Control and Prevention in 2012, this study found that adherence to standardized hypertension management is associated with positive effects on hypertension- related knowledge, healthy lifestyle behavior, antihypertensive medical treatments, and blood pressure control. It will be necessary to provide primary health care workers with sufficient training and reasonable incentives to ensure the implementation and effectiveness of hypertension management.
基金supported by the Gobierno de Espaa for the Provision of a Ramon y Cajal Contract (RYC-2009-04199),Projects P10 FQM-6711(Consejeria de Ciencia e Innovacion,Junta de Andalucia) and CTQ2011 28954-C02-02 (MICINN)
文摘A comparison between conventional pyrolysis and a novel developed low-temperature microwave-assisted pyrolysis methodology has been performed for the valorisation of a range of biomass feedstocks including waste residues. Microwave pyrolysis was found to efficiently deliver comparable evolution of bio-gases in the system as compared with conventional pyrolysis at significantly reduced temperatures (120-180 ℃vs 250-400 ℃). The gas obtained from microwave-assisted pyrolysis was found to contain CO2, CH4 and CO as major components as well
文摘Acute coronary syndromes presenting with ST elevation are usually treated with emergency reperfusion/revascularisation therapy. In contrast current evidence and national guidelines recommend risk stratification for non ST segment elevation myocardial infarction(NSTEMI) with the decision on revascularisation dependent on perceived clinical risk. Risk stratification for STEMI has no recommendation. Statistical risk scoring techniques in NSTEMI have been demonstrated to improve outcomes however their uptake has been poor perhaps due to questions over their discrimination and concern for application to individuals who may not have been adequately represented in clinical trials. STEMI is perceived to carry sufficient risk to warrant emergency coronary intervention [by primary percutaneous coronary intervention(PPCI)] even if this results in a delay to reperfusion with immediate thrombolysis. Immediate thrombolysis may be as effective in patients presenting early, or at low risk, but physicians are poor at assessing clinical and procedural risks and currently are not required to consider this. Inadequate data on risk stratification in STEMI inhibits the option of immediate fibrinolysis, which may be cost-effective. Currently the mode of reperfusion for STEMI defaults to emergency angiography and percutaneous coronary intervention ignoring alternative strategies. This review article examines the current risk scores and evidence base for risk stratification for STEMI patients. The requirements for an ideal STEMI risk score are discussed.
基金Project (No. 2001BA744C) supported by the 10th Five-year National Key Technologies R & D Program, China
文摘A known species, Physarum melleum, was found fruiting on living leaves of Dendrobium candidum, which was collected in China in 2004. Its morphological characters were revealed by light microscopy (LM), environmental scanning elec- tron microscopy (ESEM) and scanning electron microscopy (SEM). Character variations were distinguished by its olive-yellow peridium and its always thinner capillitium containing globulose granular material between the large calcareous nodes. The cal- cium carbonate granules, deposited on stalks, peridium and hypothallus as well as within stalks, were globose and smooth.
基金The project BACULOGENES of the European Union (LSHB-CT-2006-037541)The Netherlands Scientific Organisation (NWO) MEERVOUD program
文摘The Autographa californica multiple capsid nucleopolyhedrovirus (AcMNPV) was the first baculovirus for which the complete nucleotide sequence became known. Since then 15 years lapsed and much research has been performed to elucidate putative functions of the annotated open reading frames of this virus and this endeavour is still ongoing. AcMNPV is the most well-known and well-studied baculovirus species, not in the least for its application as a vector for the high-level expression of foreign genes in insect cells. This article is the first monograph of a single baculovirus and gives a current overview of what is known about the 151 AcMNPV ORFs, including (putative) function and temporal and spatial presence of transcripts and protein. To date 60 ORFs have a proven function, another 19 ORFs have homologs for which functions are known in other baculoviruses and 72 ORFs are still enigmatic. This paper should assist the reader in quickly finding the essentials of AcMNPV.
基金supported by the key program of National Social Science Fund Major Project"Study on the Mechanism of Transformation of Haze Management and Economic Development Mode"[Grant number:14ZDB144]Ministry of Education Humanities and Social Sciences Youth Fund Project"Energy Efficiency Improvement and Energy Saving Technology Progress at China's Prefectural Level:Research Based on Frontier Theory and Spatial Measurement Methods"[Grant number:16YJC790083]Shanghai Institute of Technology Humanities and Social Sciences Climbing Plan Project"Research on China's Total Factor Energy Productivity Improvement and Regional Synergy Mechanism"[Grant number:SK17PB03]
文摘In recent years, high-polluting industries have been gradually shifted from the eastern developed regions to the central and western underdeveloped regions in China. Certain environmental regulations have been in place accordingly in various regions, but the pollution in the central and western regions has risen sharply. Based on the data of interprovincial panel in China from 2006 to 2015, this paper calculates high-pollution industry dynamic agglomeration index, environmental pollution agglomeration index and relative environmental regulation intensity index, and uses Generalized Method of Moments to carry out the regression analyses of the whole samples,regional heterogeneity and temporal heterogeneity. The results show that there is an inverted Ushaped relationship between relative environmental regulation and environmental pollution concentration in China. The concentration degrees of industrial wastewater pollution and industrial waste gas pollution are deepened, which are mainly caused by the transfer of highly polluting industries. However, the concentration of industrial solid waste pollution caused by the transfer is not obvious. Furthermore, the deepening of industrialization intensifies the concentration of regional environmental pollution. Environmental Kuznets Curve does exist in China,but it is not significant. The increase of labor cost and quality will reduce the concentration of environmental pollution.
基金the National Natural Science Foundation of China under Grant 52007071 and 51907073the China Postdoctoral Science Foundation under Grant 3004131154 and 2020M672355the Applied Basic Frontier Program of Wuhan under Grant 2020010601012207。
文摘To lower the difficulty of fault protection,a doubly-fed induction machine based shipboard propulsion system(DFIM-SPS)that is partially power decoupled is presented.In such an intrinsically safe SPS architecture,a synchronous generator(SG)is employed for power generation,and the accuracy of the parameters of power generation unit(PGU)plays an important role in SPS stable operation.In this paper,the PGU parameter deviations are studied to evaluate the effects on system performance.The models of salient-pole SG,type DC1A excitation system(EXS)and DFIM are illustrated first.Besides,the corresponding control scheme is explained.For the 16 important parameters of PGU,up to 40%of parameter deviations are applied to implement parameter sensitivity analysis.Then,simulation studies are carried out to evaluate the parameter deviation effects on system performance in detail.By defining three parameter deviation effect indicators(PDEIs),the effects on the PGU output variables,which are the terminal voltage and output active power,are studied.Moreover,the increasing rates of PDEIs with different degrees of parameter deviations for the key parameters are analyzed.Furthermore,the overall system performance is investigated for the two most influential PGU parameters.This paper provides some vital clues on SG and EXS parameter identification for DFIM-SPS.
基金The study was supported financially by the Russian Foundation for Basic Research(Grant No.20-02-00790)the Joint Institute for High Temperatures of the Russian Academy of Sciences(Topic Grant No.01201357846)The UK team received financial support from the Engineering and Physical Sciences Research Council(Grant Nos.EP/L01663X/1 and EP/H012605/1).
文摘X-ray absorption spectroscopy is a well-accepted diagnostic for experimental studies of warm dense matter.It requires a short-lived X-ray source of sufficiently high emissivity and without characteristic lines in the spectral range of interest.In the present work,we discuss how to choose an optimum material and thickness to get a bright source in the wavelength range 2A–6A(∼2 keV to 6 keV)by considering relatively low-Z elements.We demonstrate that the highest emissivity of solid aluminum and silicon foil targets irradiated with a 1-ps high-contrast sub-kJ laser pulse is achieved when the target thickness is close to 10μm.An outer plastic layer can increase the emissivity even further.
基金supported by the‘Uncovering the variable roles of fire in savannah ecosystems’project,funded by Leverhulme Trust under grant IN-2014-022 and‘Resilience in East African Landscapes’project funded by European Commission Marie Curie Initial Training Network(FP7-PEOPLE-2013-ITN project number606879)funding from Australian Research Council,IUCN Sustain/African Wildlife Foundation and University of York Research Pump Priming Fund+1 种基金funding through the European Research Council ERC-2011-St G_20101109(project number 281986)and the British Ecological Society-Ecologists in Africa programmesupport through the‘Climate Change Impacts on Ecosystem Services and Food Security in Eastern Africa(CHIESA)’project(2011–2015),which was funded by the Ministry for Foreign Affairs of Finland,and coordinated by the International Centre of Insect Physiology and Ecology(icipe)in Nairobi,Kenya
文摘Background: Canopy structure, defined by leaf area index (LAI), fractional vegetation cover (FCover) and fraction of absorbed photosynthetically active radiation (fAPAR), regulates a wide range of forest functions and ecosystem services. Spatially consistent field-measurements of canopy structure are however lacking, particularly for the tropics. Methods: Here, we introduce the Global LAI database: a global dataset of field-based canopy structure measurements spanning tropical forests in four continents (Africa, Asia, Australia and the Americas). We use these measurements to test for climate dependencies within and across continents, and to test for the potential of anthropogenic disturbance and forest protection to modulate those dependences. Results: Using data collected from 887 tropical forest plots, we show that maximum water deficit, defined across the most arid months of the year, is an important predictor of canopy structure, with all three canopy attributes declining significantly with increasing water deficit. Canopy attributes also increase with minimum temperature, and with the protection of forests according to both active (within protected areas) and passive measures (through topography). Once protection and continent effects are accounted for, other anthropogenic measures (e.g. human population) do not improve the model. Conclusions: We conclude that canopy structure in the tropics is primarily a consequence of forest adaptation to the maximum water deficits historically experienced within a given region. Climate change, and in particular changes in drought regimes may thus affect forest structure and function, but forest protection may offer some resilience against this effect.
基金the Engineering and Physical Science Research Council(EPSRC),U.K.for the award of a research grant EP/J0118058/1 and postdoctoral research assistantships(PDRAs) to M.R.W.and R.W.M.from the grant。
文摘Reaction dynamics in gases at operating temperatures at the atomic level are the basis of heterogeneous gas-solid catalyst reactions and are crucial to the catalyst function.Supported noble metal nanocatalysts such as platinum are of interest in fuel cells and as diesel oxidation catalysts for pollution control,and practical ruthenium nanocatalysts are explored for ammonia synthesis.Graphite and graphitic carbons are of interest as supports for the nanocatalysts.Despite considerable literature on the catalytic processes on graphite and graphitic supports,reaction dynamics of the nanocatalysts on the supports in different reactive gas environments and operating temperatures at the single atom level are not well understood.Here we present real time in-situ observations and analyses of reaction dynamics of Pt in oxidation,and practical Ru nanocatalysts in ammonia synthesis,on graphite and related supports under controlled reaction environments using a novel in-situ environmental(scanning) transmission electron microscope with single atom resolution.By recording snapshots of the reaction dynamics,the behaviour of the catalysts is imaged.The images reveal single metal atoms,clusters of a few atoms on the graphitic supports and the support function.These all play key roles in the mobility,sintering and growth of the catalysts.The experimental findings provide new structural insights into atomic scale reaction dynamics,morphology and stability of the nanocatalysts.
基金this paper was partially supported by the National Natural Science Foundation of China(Grant No.61601517)basic and advanced technology research project of Henan Province,China(Grant No.2014302703).
文摘Due to the characteristics of chaotic systems,different cryptosystems based on chaos have been proposed to satisfy the security of multimedia data.A plain image-related chaotic algorithm is proposed by Luo et al.with high speed and efficiency.Security weaknesses of the cryptosystem are studied in this paper.It is found that the important secret key information is leaked because an important parameter can be obtained after an inverse operation in the last step of the cryptosystems without secret key.Meanwhile,the value zero is processed improperly in quantification algorithm.Based on the weaknesses,chosen plaintext attack on the cryptosystem is proposed,by which,an important parameter,equivalent to secret key,can be calculated with a specific chosen plain image.With the obtained parameter,the plain image of any ciphered image,encrypted by the cryptosystem,can be recovered.Then,an improvement is proposed to solve the problems after modifying the quantification algorithm.It is from the experiments that chosen plaintext attack is valid and improved algorithm possesses better performance.