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氧化锰对金(Ⅰ)和金(Ⅲ)络和物的吸附 被引量:4
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作者 冉勇 傅家谟 +1 位作者 R.J.Gilkes R.W.Rate 《中国科学(D辑)》 CSCD 1998年第6期523-531,共9页
对 pH 2~ 1 1 .6和 0 .0 1 mol/L或 0 .1mol/LNaNO3 溶液中 ,δ MnO2 对Au Cl4-,AuCl2 -和Au(S2 O3 ) 2 3 -表现出不同程度的吸附 .在pH 4和两种电解质条件下δ MnO2 吸附AuCl4-和Au(S2 O3 ) 2 3 -后表面金的最大吸附密度分别为 0 .1 8... 对 pH 2~ 1 1 .6和 0 .0 1 mol/L或 0 .1mol/LNaNO3 溶液中 ,δ MnO2 对Au Cl4-,AuCl2 -和Au(S2 O3 ) 2 3 -表现出不同程度的吸附 .在pH 4和两种电解质条件下δ MnO2 吸附AuCl4-和Au(S2 O3 ) 2 3 -后表面金的最大吸附密度分别为 0 .1 8~ 0 .2 1和 0 .2 8μmol/m2 ,金的表面覆盖率约等于或低于 1 % . 3种金络合物的吸附均表现为随pH上升而减少 ,符合阴离子的吸附规律 ;其吸附大小次序为 :Au(S2 O3 ) 2 3 ->AuCl4->AuCl2 -;3种金的本征平衡常数logKint为 1 .1 7~ 2 .71 ,均大大地高于铜和镉的本征吸附常数 ;δ MnO2 优先吸附AuCl4-的水解混合配体络合物 ,并形成内圈表面络合物 . 展开更多
关键词 富集 络合物 氧化锰 地球化学 金络合物 吸附
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NUMERICAL INVESTIGATION OF THREE-DIMENSIONAL FLOW AND BED SHEAR STRESS DISTRIBUTION AROUND THE SPAN SHOULDER OF PIPELINE 被引量:3
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作者 CHENBing CHENGLiang 《Journal of Hydrodynamics》 SCIE EI CSCD 2004年第6期687-694,共8页
Three-dimensional flow around a pipeline span shoulder is simulated using afractional step finite element method. The Reynolds number, based on the pipe-diameter and theapproaching flow velocity, is set at 500 and 5 x... Three-dimensional flow around a pipeline span shoulder is simulated using afractional step finite element method. The Reynolds number, based on the pipe-diameter and theapproaching flow velocity, is set at 500 and 5 x 10~5 to simulate both laminar and turbulent flow.In high Reynolds number case, Smagorinsky SGS closure is used to model the turbulent flows. The flowfield visualization by vorticity iso-surfaces shows that a spiral vortex tube is formed around thespan shoulder and extends around the span shoulder. The vortex cores defined by the eigenvalues ofthe symmetric tensor S^2 + Ω~2 (S and Ω are respectively the symmetric and antisymmetric parts ofthe velocity gradient tensor) gives more details of the flow field. It is also found that there aresignificant bed shear stress concentrations in the span shoulder area. The reasons for the shearstress concentration are discussed. 展开更多
关键词 three-dimensional numerical model SCOUR span shoulder PIPELINE bed shearstress
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