Magnetic susceptibility of Al2RE （RE=Y, Ce, Sm, Gd, Dy, Ho, Yb） compounds was studied experimentally in wide temperature （T=290–2000 K） and field （B=0.3–1.3 T） intervals. The abnormal increase in susceptibilit...Magnetic susceptibility of Al2RE （RE=Y, Ce, Sm, Gd, Dy, Ho, Yb） compounds was studied experimentally in wide temperature （T=290–2000 K） and field （B=0.3–1.3 T） intervals. The abnormal increase in susceptibility beginning above the melting point was fixed for all the compositions. The values for the effective magnetic moments per RE atoms in these compounds were found to be smaller than the values typical for free ions RE3＋. The results were discussed in supposition of the directed bonds between aluminum and rare-earth atoms.展开更多
The method of crucible rotating oscillation damping was employed to measure the kinematic viscosity of aluminum melt,and the curve of viscosity v versus temperature T from 935 to 1383 K was obtained.Besides,based on t...The method of crucible rotating oscillation damping was employed to measure the kinematic viscosity of aluminum melt,and the curve of viscosity v versus temperature T from 935 to 1383 K was obtained.Besides,based on the calculation model of the evolution behavior of atomic clusters in liquid structure,the curve of atomic clusters size d versus temperature was obtained,and the calculated results are in good agreement with the experimental values.By analyzing experimental data,it was found that both the viscosity and the size of atomic clusters of aluminum melt are monodrome functions of temperature,and the relation between v(T) and d(T) is a linear function,i.e.,v = v 0 + K·d(T).This relation indirectly verifies the calculation model of the structural information of metal melt,which is of great significance for studying the relation between melt microstructure and macro-physical properties.展开更多
基金Project supported by RFBR (Grant N N 09-03-90450-Ukr)FTP (NK-255P/1, NK-16P/1)
文摘Magnetic susceptibility of Al2RE （RE=Y, Ce, Sm, Gd, Dy, Ho, Yb） compounds was studied experimentally in wide temperature （T=290–2000 K） and field （B=0.3–1.3 T） intervals. The abnormal increase in susceptibility beginning above the melting point was fixed for all the compositions. The values for the effective magnetic moments per RE atoms in these compounds were found to be smaller than the values typical for free ions RE3＋. The results were discussed in supposition of the directed bonds between aluminum and rare-earth atoms.
基金supported by the National Basic Research Program of China (Grant No.2007CB613702)International Cooperation Program in Science and Technology (Grant No.2007DFC50090)
文摘The method of crucible rotating oscillation damping was employed to measure the kinematic viscosity of aluminum melt,and the curve of viscosity v versus temperature T from 935 to 1383 K was obtained.Besides,based on the calculation model of the evolution behavior of atomic clusters in liquid structure,the curve of atomic clusters size d versus temperature was obtained,and the calculated results are in good agreement with the experimental values.By analyzing experimental data,it was found that both the viscosity and the size of atomic clusters of aluminum melt are monodrome functions of temperature,and the relation between v(T) and d(T) is a linear function,i.e.,v = v 0 + K·d(T).This relation indirectly verifies the calculation model of the structural information of metal melt,which is of great significance for studying the relation between melt microstructure and macro-physical properties.
