Girth weldability and welding process of Baosteel X80 UOE linepipes

An analysis of the girth weldability of Baosteel X80 UOE （U-ing-O-ing-Expanding） linepipes was conducted using manual shielded metal arc welding （SMAW） and semiautomatic self-shielded flux cored wire arc welding （FCAW）. A technical specification for the optimum quality of a girth welding joint was obtained through a large amount of testing. According to the requirements of America Petroleum Institute（API） standard 1104 and the standards of the 2nd West-East natural gas transmission pipeline project,the mechanical properties of a girth welding joint were estimated. In addition,the effect of the girth welding procedure specifications and the consumable＇ s suitability on the impact toughness of the girth welding joint was discussed.

Methods for assessing the grooving corrosion of high-frequency electric resistance welded pipes

Grooving corrosion is a major form of corrosion and is prone to occur when high-frequency electric resistance welded （HFW） pipes are being used. Therefore,grooving corrosion is one of the performance indexes of HFW products. Grooving corrosion usually occurs along the welding fusion line, resulting in one or more corrosion grooves. The main factors affecting grooving corrosion include the contents of alloying elements and impurities （especially sulphur） in the steel,the microstructure of the welds and the steel substrate, welding parameters and the service environment as well. In this study, the existing methods for assessing grooving corrosion were systematically reviewed, improvements and new methods were proposed and developed to overcome the shortcomings of the existing methods, such as inaccuracy and excessive research time. By comparison with the existing methods, the operational procedures and the characteristics of the new methods are introduced, and issues regarding the behavior of grooving corrosion and their assessment methods, which both need further research,are discussed in this study.

Study on the microstructure of 12%chromium low carbon stainless steel in a high temperature heat-affected zone

Coarsening, embrittlement and corrosion sensitization in a high temperature heat-affected zone （HTHAZ） are the major problems when 12% chromium low carbon stainless steel is being welded, which induce the deterioration of the impact toughness at a low temperature and intergranular corrosion resistance property. This study investigates the corresponding microstructures in HTHAZ with different chemical compositions and heat inputs through thermal simulation tests. The results show that the martensite content increases with the descending of ferrite factor （FF） when FF is below 9.0 and heat input influences the microstructure of high FF steel in HTHAZ. Martensite of 12% Cr stainless steel in HTHAZ with only Nb stabilization reticularly distributes at ferrite grain boundaries.

Rusting behavior and preventative measures of hot-rolled steel plates for automobile applications

As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufacturing, transportation and/or storage of the plates. General corrosion often takes place on the surface of a plate in the exterior part of a package, and only reduces the thickness of the plate and slightly increases the roughness of the surface; however, localized corrosion on the surface of a plate inside the package is likely to result in the formation of pit-like defects on the substrate of the plate, which cannot be removed thoroughly by normal acid pickling or sand blasting, and affects the application of the plate. This research report analyzes the phenomena and characteristics of the rusting behavior of hot- rolled steel plates for automobile applications, and the influencing factors are summaried. The corresponding preventative measures are proposed.

Study on the formation of intermetallic phases in the new type of Zn-Mg coatings on steel sheets

Zn-Mg alloy coatings were obtained by physical vapor deposition （PVD） on electroplated steel sheets. Study on the formation of intermetallic phases in the coatings was conducted through the use of X-ray diffraction （XRD） ,scanning electron microscope （SEM） and glow discharge optical emission spectrometry （GDOES）. It is found that MgZn2 is the main Zn-Mg alloy phase formed after heat treatment. The formation of Mg-Zn intermetallic phases is controlled not only by thermodynamics, but also by kinetics. MgZn2 has different morphologies, such as laminar structure,porous structure and floc-like structure,which are mainly determined by the annealing temperature. Obvious diffusion of Mg starts at 350 ℃, and the diffusion of iron increases significantly when the temperature is elevated to 380℃.

The corrosive behaviors of GI and IF steel sheets in salt water drops

The corrosive behaviors of hot-dip galvanized steel （G I） sheets and the corresponding interstitial free （IF） steel base sheets for use in automobiles were investigated by the classical salt water drop （SWD） test at room temperature. The corrosive processes and products were observed and analyzed through morphological observation, a scanning electronic microscope （SEM） and an energy dispersive spectrum （EDS）. The results show that the anodic and cathode sites can be distinguished clearly during and after the test. The propagation of rusting, and the color, distribution and composition of the final corrosive products of the two kinds of materials are quite different. The SWD corrosive mechanisms of steel with and without galvanized coating are both discussed in this paper.

Corrosion characteristics and mechanism of the S135 drill pipes in slurry

The corrosion mechanism of the S135 drill pipes was investigated through observation of the corrosion morphology and analysis of the corrosion products by scanning electronic microscope （ SEM）, energy dispersive spectrum （EDS） and X-ray diffraction （XRD）. The results show that the localized corrosion on the outer surface of the drill pipes was caused by oxygen corrosion due to the action of retained slurry. Cl - contained in slurry accelerated the corrosion and promoted the development of corrosion pits. Suggestions for mitigating or preventing such corrosion of the drill pipes are proposed based on the research results.

Mill scale structure and damp heat corrosion performance of four 510L hot-rolled strips

In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy （OM） ,scanning electron microscopy （SEM） and X-ray diffraction （XRD）. The corrosion behavior of the steels with and without mill scales were investigated by means of hot-humid corrosion tests under the condition of relative humidity （ RH ） of 95% at 50℃ and 70℃, respectively. The results show that the matrix structures, state, composition and thickness of mill scales vary in the strips. The rusting starting time of the specimens with scales is generally a bit longer than that of the specimens without scales, but their corrosion mass-gain is higher. For these two kinds of specimens ,their corrosion rate increases significantly with the increase of temperature. The rusting behavior of the 510L strips produced by various plants is different due to the variations of hot-rolling processes and designed chemical compositions. Various relevant aspects should be taken into account in the evaluation of the corrosion behavior of hot-rolled strips.

Analysis of point defects in automobile sheet coating

The analysis of the point defects is an important method to solve the problem. Typical point defects distinguished as pinholes or bumps in automobile sheet coating were investigated in the present study. Cross-sectional images of pinholes in prime coating or top coating show that they were caused in the same way by fractures in base steel or a zinc alloyed layer. Furthermore,the formation of the defects is inferred,along with the specific painting process. The analysis also shows that bumps frequently occurred in the e-coating layer were mainly caused by contamination.

A comparison of the pitting corrosion resistances of the 304 and new 200 series of stainless steels by potential dependent critical pitting corrosion temperatures

This study researched the relationship between the applied potential and the critical pitting temperature （CPT） of the 304 and new 200 series of stainless steels. The fluctuation about the potential dependent CPT for the stainless steels was investigated and the CPT range was obtained. The difference between the potential dependent CPTs of the 304 and 200 series of stainless steels with an applied potential of 100 mV （ vs SCE）, were presented, and by this means the pitting corrosion resistances of them were compared.

Low molybdenum ultra-pure ferritic stainless steel for solar water heaters

In order to meet the demands of service life and the synthetical performance/price ratio of stainless steel in the solar water heater industry, the low molybdenum ultra-pure ferritic stainless steel （FSS） B445J1M was developed at Baosteel. In this study, comparative studies were carried out on the mechanical properties, the formability and the corrosion resistance of B445J1M ,304 and 444 ,and the advantages and application fields of B445J1M were summarized.