Oxidation behaviors of TA15 titanium alloy and TiBw reinforced TA15 matrix composites prepared by spark plasma sintering

The purpose of this study is to investigate the oxidation behaviors of the TA15 titanium alloy and TiBw/TA15 composite with network microstructure in the temperature range of 873–1073 K.The results show that the oxidation kinetics of the TA15 titanium alloy and TiBw/TA15 composite follows different laws at various oxidation temperatures.Moreover,the effective activation energy Q for oxidation of the TA15 titanium alloy and TiBw/TA15 composite is determined to be 299±19.9 kJ/mol and 339±8.31 kJ/mol at the temperature of 973–1073 K,respectively.The experimental achievements of oxidation kinetics and oxide scales formed in the test temperatures indicate that the TiBw/TA15 composite exhibits a higher oxidation resistance than TA15 titanium alloy.A schematic diagram of oxidation mechanism is established to further reveal the oxidation process for TiBw/TA15 composite at elevated temperatures.

Interfacial characteristics and mechanical properties of additive manufacturing martensite stainless steel on the Cu-Cr alloy substrate by directed energy deposition

Copper/steel is a typical bimetal functional material,combining the excellent electrical and thermal conductivity of copper alloy and the high strength and hardness of stainless steel.There has been recent interest in manufacturing copper/steel bimetal by directed energy deposition(DED)due to its layer-bylayer method.However,cracks tend to form on the copper/steel interface because of the great difference in thermal expansion coefficient and crystal structure between copper and steel.In this work,interfacial characteristics and mechanical properties of the copper/steel bimetal were studied from one layer to multilayers.The laser power has a great influence on the Cu element distribution of the molten pool,affecting the crack formation dramatically on the solidification stage.Cracks tend to form along columnar grain boundaries because of the Cu-rich liquid films and spherical particles in the cracks.Crack-free and good metallurgical bonding copper/steel interface is formed at a scanning velocity of 800 mm/min and the laser power of 3000 W.The ultimate tensile strength(UTS)and the break elongation(EL)of the vertically combined crack-free copper/steel bimetal are 238.2±4.4 MPa and 20.6±0.7%,respectively.The fracture occurs on the copper side instead of the copper/steel interface,indicating that the bonding strength is higher than that of the Cu-Cr alloy.The UTS of the horizontally combined crack-free copper/steel bimetal is 746.7±22.6 MPa,which is 200%higher than that of the Cu-Cr alloy substrate.The microhardness is 398.6±5.4 HV at the steel side and is 235.3±64.1 HV at the interface,which is400%higher than that of the Cu-Cr alloy substrate.This paper advances the understanding of the interfacial characteristics of heterogeneous materials and provides guidance and reference for the fabrication of multi-material components by DED.