Dysprosium compounds with high magnetic anisotropy are widely studied as single molecule magnets(SMMs).Here the anisotropic magnetocaloric effect in a Dy(Ⅲ)SMM,{[Dy(OSiMe_(3))_(2)(4-Mepy)5(BPh_(4))]0.5 Toluene},was s...Dysprosium compounds with high magnetic anisotropy are widely studied as single molecule magnets(SMMs).Here the anisotropic magnetocaloric effect in a Dy(Ⅲ)SMM,{[Dy(OSiMe_(3))_(2)(4-Mepy)5(BPh_(4))]0.5 Toluene},was studied by single crystals.Angular dependent magnetization can be observed at 300 K because of its high magnetic anisotropy.SMM behavior measured along the easy axis direction is identical to that of the polycrystalline sample.Rotating magnetization from the easy axis to the hard plane gives a maximum magnetic entropy change(-ΔSR)of 3.05 J/(kg·K)at 19 K atΔB=5 T,which enables the Dy(Ⅲ)SMM to be used as a low-temperature rotating magnetic refrigerant.展开更多
基金Project supported by Shenzhen Science and Technology Program(JCYJ20180306170859634)National Natural Science Foundation of China(21620102002,21773130,21871219,21801202,21971203)+3 种基金China Postdoctoral Science Foundation(2019T120891,2019T120892,2018M643615,2018M631138)Postdoctoral Foundation of Shaanxi Province(2018BSHEDZZ100)Natural Science Basic Research Plan in Shaanxi Province(2019JQ-292)Key Laboratory Construction Program of Xi’an Municipal Bureau of Science and Technology(201805056ZD7CG40)。
文摘Dysprosium compounds with high magnetic anisotropy are widely studied as single molecule magnets(SMMs).Here the anisotropic magnetocaloric effect in a Dy(Ⅲ)SMM,{[Dy(OSiMe_(3))_(2)(4-Mepy)5(BPh_(4))]0.5 Toluene},was studied by single crystals.Angular dependent magnetization can be observed at 300 K because of its high magnetic anisotropy.SMM behavior measured along the easy axis direction is identical to that of the polycrystalline sample.Rotating magnetization from the easy axis to the hard plane gives a maximum magnetic entropy change(-ΔSR)of 3.05 J/(kg·K)at 19 K atΔB=5 T,which enables the Dy(Ⅲ)SMM to be used as a low-temperature rotating magnetic refrigerant.
