A novel profile modification HPF-Co gel satisfied with fractured low permeability reservoirs in high temperature and high salinity

Conformance control and water plugging are a widely used EOR method in mature oilfields.However,majority of conformance control and water plugging agents are unavoidable dehydrated situation in high-temperature and high-salinity low permeability reservoirs.Consequently,a novel conformance control system HPF-Co gel,based on high-temperature stabilizer(CoCl_(2)·H_(2)O,CCH)is developed.The HPF-Co bulk gel has better performances with high temperature(120℃)and high salinity(1×10^(5)mg/L).According to Sydansk coding system,the gel strength of HPF-Co with CCH is increased to code G.The dehydration rate of HPF-Co gel is 32.0%after aging for 150 d at 120℃,showing excellent thermal stability.The rheological properties of HPF gel and HPF-Co gel are also studied.The results show that the storage modulus(G′)of HPF-Co gel is always greater than that of HPF gel.The effect of CCH on the microstructure of the gel is studied.The results show that the HPF-Co gel with CCH has a denser gel network,and the diameter of the three-dimensional network skeleton is 1.5-3.5μm.After 90 d of aging,HPF-Co gel still has a good three-dimensional structure.Infrared spectroscopy results show that CCH forms coordination bonds with N and O atoms in the gel amide group,which can suppress the vibration of cross-linked sites and improve the stability at high temperature.Fractured core plugging test determines the optimized polymer gel injection strategy and injection velocity with HPF-Co bulk gel system,plugging rate exceeding 98%.Moreover,the results of subsequent waterflooding recovery can be improved by 17%.

Layer thickness dependent plastic deformation mechanism in Ti/TiCu dual-phase nano-laminates

Crystalline/amorphous nanolaminate is an effective strategy to improve the mechanical properties of metallic materials,but the underlying deformation mechanism is still under the way of exploring.Here,the mechanical properties and plastic deformation mechanism of Ti/TiCu dual-phase nanolaminates(DPNLs)with different layer thicknesses are investigated using molecular dynamics simulations.The results indicate that the influence of the layer thickness on the plastic deformation mechanism in crystalline layer is negligible,while it affects the plastic deformation mechanism of amorphous layers distinctly.The crystallization of amorphous TiCu is exhibited in amorphous parts of the Ti/TiCu DPNLs,which is inversely proportional to the layer thickness.It is observed that the crystallization of the amorphous TiCu is a process driven by stress and heat.Young's moduli for the Ti/TiCu DPNLs are higher than those of composite material due to the amorphous/crystalline interfaces.Furthermore,the main plastic deformation mechanism in crystalline part:grain reorientation,transformation from hexagonal-close-packed-Ti to face-centered cubic-Ti and body-centered cubic-Ti,has also been displayed in the present work.The results may provide a guideline for design of high-performance Ti and its alloy.

Some results on derivations of MV-algebras

In this paper, we review some of their related properties of derivations on MValgebras and give some characterizations of additive derivations. Then we prove that the fixed point set of Boolean additive derivations and that of their adjoint derivations are isomorphic.In particular, we prove that every MV-algebra is isomorphic to the direct product of the fixed point set of Boolean additive derivations and that of their adjoint derivations. Finally we show that every Boolean algebra is isomorphic to the algebra of all Boolean additive(implicative)derivations. These results also give the negative answers to two open problems, which were proposed in [Fuzzy Sets and Systems, 303(2016), 97-113] and [Information Sciences, 178(2008),307-316].

The deep spatiotemporal network with dual-flow fusion for video-oriented facial expression recognition

The video-oriented facial expression recognition has always been an important issue in emotion perception.At present,the key challenge in most existing methods is how to effectively extract robust features to characterize facial appearance and geometry changes caused by facial motions.On this basis,the video in this paper is divided into multiple segments,each of which is simultaneously described by optical flow and facial landmark trajectory.To deeply delve the emotional information of these two representations,we propose a Deep Spatiotemporal Network with Dual-flow Fusion(defined as DSN-DF),which highlights the region and strength of expressions by spatiotemporal appearance features and the speed of change by spatiotemporal geometry features.Finally,experiments are implemented on CKþand MMI datasets to demonstrate the superiority of the proposed method.

A novel triple responsive smart fluid for tight oil fracturing-oil expulsion integration

The traditional multi-process to enhance tight oil recovery based on fracturing and huff-n-puff has obvious deficiencies,such as low recovery efficiency,rapid production decline,high cost,and complexity,etc.Therefore,a new technology,the so-called fracturing-oil expulsion integration,which does not need flowback after fracturing while making full use of the fracturing energy and gel breaking fluids,are needed to enable efficient exploitation of tight oil.A novel triple-responsive smart fluid based on“pseudo-Gemini”zwitterionic viscoelastic surfactant(VES)consisting of N-erucylamidopropyl-N,N-dimethyl-3-ammonio-2-hydroxy-1-propane-sulfonate(EHSB),N,N,N′,N′-tetramethyl-1,3-propanediamine(TMEDA)and sodium p-toluenesulfonate(NaPts),is developed.Then,the rheology of smart fluid is systematically studied at varying conditions(CO_(2),temperature and pressure).Moreover,the mechanism of triple-response is discussed in detail.Finally,a series of fracturing and spontaneous imbibition performances are systematically investigated.The smart fluid shows excellent CO_(2)-,thermal-,and pressure-triple responsive behavior.It can meet the technical requirement of tight oil fracturing construction at 140°C in the presence of 3.5 MPa CO_(2).The gel breaking fluid shows excellent spontaneous imbibition oil expulsion(∼40%),salt resistance(1.2×104 mg/L Na+),temperature resistance(140°C)and aging stability(30 days).

Identification of watered-out zones in carbonate reservoirs using resistivity curve reconstruction based on reservoir classification

The KT-II layer in the Zananor Oilfield,Caspian Basin,Kazakhstan,contains carbonate reservoirs of various types.The complex pore structure of the reservoirs have made it difficult to identify watered-out zones with traditional logging interpretation methods.This study classifies the reservoirs on the basis of core analysis and establishes an identification model for watered-out layers in the field to effectively improve the interpretation accuracy.Thin section analysis shows that there are three types of pores in the reservoirs,i.e.,the matrix pore,fracture and dissolution vug.A triple porosity model is used to calculate the porosities of the reservoirs and the results are combined with core analysis to classify the reservoirs into the fractured,matrix pore,fracture-pore as well as composite types.A classification standard is also proposed.There are differences in resistivity logging responses from the reservoirs of different types before and after watering-out.The preewatering-out resistivities are reconstructed using generalized neural network for different types of reservoirs.The watered-out layers can be effectively identified according to the difference in resistivity curves before and after watering-out.The results show that the watered-out layers identified with the method are consistent with measured data,thus serving as a reference for the evaluation of watered-out layers in the study area.

Comparison between BCR sequential extraction and geo-accumulation method to evaluate metal mobility in sediments of Dongting Lake, Central China

The form in which a metal exists strongly influences its mobility and thus, the effects on the environment. Operational methods of speciation analysis, such as the use of sequential extraction procedures, are commonly applied. The Dongting Lake, the second largest fresh-water lake in China, contains three China wetlands of international importance, the East Dongting Lake, South Dongting Lake, and West Dongting Lake. In this work, an optimized BCR sequential extraction procedure was used to assess the environmental risk of Cd, Cr, Cu, Ni, Pb and Zn in contaminated sediment of the Dongting Lake. The procedure was evaluated by using a certified reference material, BCR701. The results of the partitioning study indicated that in the lake sediments, more easily mobilized forms (acid exchangeable) were predominant for Cd, particularly in the samples from the East Dongting Lake. In contrast, the largest amount of Pb was associated with the iron and manganese oxide fractions and Cu, Zn, Cr, and Ni analyzed were mainly distributed in residual phase at an average percentage greater than 60% of the total metals. The potential risk to the lake's water contamination was highest in the East Dongting Lake based on the calculated contamination factors. On the other hand, the total metal content was determined as well by inductively coupled plasma and mass spectrometry (ICP-MS) and assessed by using geo-accumulation index. The assessment results using geo-accumulation index were compared with the information on metal speciation. Both were correspondent with each other.

A long-term frequency-stabilized erbium-fiber-laser-based optical frequency comb with an intra-cavity electro-optic modulator

We demonstrate an optical frequency comb based on an erbium-doped-fiber femtosecond laser with the nonlinear polarization evolution scheme. The repetition rate of the laser is about 209 MHz. By controlling an intra-cavity electro- optic modulator and a piezo-transducer, the repetition rate can be stabilized with a high-bandwidth servo in a frequency range of 3 kHz, enabling long-term repetition rate phase-locking. The in-loop frequency stability of repetition rate is about 1.6× 10-13 in an integration time of 1 s, limited by the measurement system; and it is inversely proportional to integration time in the short term. Furthermore, using a common path f-2f interferometer, the carrier envelope offset frequency of the comb is obtained with a signal-to-noise ratio of 40 dB in a 3-MHz resolution bandwidth. Stabilized cartier envelope offset frequency exhibits a deviation of 0.6 mHz in an integration time of 1 s.

Heavy metal research in lacustrine sediment:a review

Heavy metals are released into environment from a wide range of natural and anthropogenic sources. Aquatic ecosystems are normally at the receiving end and in many cases, with lakes as intermediaries. Lacustrine sediments are important sinks for heavy metals and play a significant role in enrichment and remobilization of heavy metals in aquatic systems. Therefore, characteristics of heavy metal in lacustrine sediments become one of the important issues in environmental sciences. Progress in heavy metal research of lake sediments since late 1980s is reviewed comprehensively in this paper from over 100. The Highlights are placed on the establishment of aquatic sediment quality guidelines, references chemical speciation of heavy metals, heavy metal transport mechanisms in lakes, and high-resolution study of lake borehole cores. Meanwhile, suggestions for heavy metal research in lacustrine sediment in the future are proposed, including such issues as using integrated approaches to assess aquatic ecosystem, modern lake dynamic process, high-resolution evolutionary sequence and spatial differentiation of environments and international lake database, which should be referential to the promotion of research on heavy metal in aquatic system.

The petroleum system:a new classification scheme based on reservoir qualities

A new classification of petroleum systems(PSs) based on reservoir qualities is proposed. We classify PSs into the following three basic types:(1) source-rock petroleum system(SPS);(2) tight-reservoir or tight petroleum system(TPS);and(3) conventional-reservoir or conventional petroleum system(CPS). The CPS is a PS in which hydrocarbons accumulate in conventional reservoirs, and all the essential elements and processes are significant and indispensable. Oil and gas accumulations are geographically discrete and therefore exist as discontinuous accumulations. The TPS is a PS where hydrocarbons accumulate in tight reservoirs and the source rock, reservoir, seal, migration, and trap are also indispensable,but the traps are mostly non-anticlinal and the accumulations are primarily quasi-continuous and secondarily discontinuous. The SPS is a PS where both hydrocarbon generation and accumulation occurred in source rocks and traps and migration are unnecessary or inconsequential; the hydrocarbon distribution is extensive and continuous and has no distinct boundaries. The aforementioned three PSs can be derived from a common hydrocarbon source kitchen and are closely linked in terms of their formation and distribution. Therefore, to maximize the exploration efficiency, a comprehensive study and different strategies are needed by considering the SPS, TPS, and CPS as parts of a greater whole.

Discovery of Kilometer-Scale Uplift and Exhumation Related to the Late Indosinian Movement in the Northern Ordos Basin, North China

The tectonic response of the Ordos Basin to Indosinian movement mainly occurred in the southwestern part of the basin due to the Late Triassic collisional Qinling orogeny to the south.The orogeny resulted in intense uplift and exhumation of the southwestern section of the Ordos Basin,where the upper and middle parts of the Upper Triassic Yanchang Formation were exhumated and the magnitude of exhumation progressively decreased to the northeast(Liu Chiyang et al.,2008).However,little attention has been paid to the influence of Indosinian movement to the northern Ordos Basin.In this study,stratigraphic observations and new apatite fission track(AFT)data are integrated to characterize the effect of Indosinian movement in the northern Ordos Basin.

Mineralogy and fracture development characteristics of marine shale-gas reservoirs: A case study of Lower Silurian strata in southeastern margin of Sichuan Basin, China

Mineral contents and fractures of shale from well Yuye-1 and outcrops were examined mainly based on systematic description of the cores and outcrops, and data from experimental analyses. The data enabled us to thoroughly explore the mineralogy and developmental features of shale of the Lower Silurian Longmaxi Formation in the study area. The results show that,the Lower Silurian Longmaxi Shale(SLS) in the southeastern margin of Sichuan Basin, China, is primarily characterized by a high content of brittle minerals and a relatively low content of clay minerals. The total content of brittle minerals is approximately 57%,including 27% quartz, 12.2% feldspar, 11.2% carbonate and 2.4% pyrite. The total content of clay minerals reaches 41.6%,composed of illite(23.8%), mixed-layer of illite and smectite(I/S)(10.8%) and chlorite(7.0%). The SLS accommodates the widespread development of various types of fractures, including tectonic fractures, diagenetic fractures, inter-layer fractures and slip fractures. The developmental level of the fracture in the SLS is mainly influenced by faults, lithology, mineral contents and total organic carbon content(TOC) in study area.

Simulated annealing spectral clustering algorithm for image segmentation

The similarity measure is crucial to the performance of spectral clustering. The Gaussian kernel function based on the Euclidean distance is usual y adopted as the similarity measure. However, the Euclidean distance measure cannot ful y reveal the complex distribution data, and the result of spectral clustering is very sensitive to the scaling parameter. To solve these problems, a new manifold distance measure and a novel simulated anneal-ing spectral clustering （SASC） algorithm based on the manifold distance measure are proposed. The simulated annealing based on genetic algorithm （SAGA）, characterized by its rapid convergence to the global optimum, is used to cluster the sample points in the spectral mapping space. The proposed algorithm can not only reflect local and global consistency better, but also reduce the sensitivity of spectral clustering to the kernel parameter, which improves the algorithm’s clustering performance. To efficiently apply the algorithm to image segmentation, the Nystrom method is used to reduce the computation complexity. Experimental results show that compared with traditional clustering algorithms and those popular spectral clustering algorithms, the proposed algorithm can achieve better clustering performances on several synthetic datasets, texture images and real images.

Surface wettability and flow properties of non-metallic pipes in laminar flow

In this paper,three liquids flowing in five pipes with the same inner diameter of 14 mm were studied to determine the relationship between the surface wettability and flow properties in laminar flow(Re b 2000).This was motivated by oilfield observations of increased pressure drops in non-metallic pipes compared to those in metal pipes,which was contrary to expectations.A new expression for the frictional coefficient that considers the Reynolds number and contact angleθin laminar flow for non-metallic pipes was proposed based on the experimental results of single-phase flow using dimension and regression analyses.The solutions of the anomalous phenomenon were proposed from the perspectives of the pipe diameter,contact-angle difference,and the compatibility between flexible composite pipe and JLHW105 oil according to the new formula.The surprising finding was that the surface wettability could control the frictional resistance by the critical contact angle(39.9°)obtained at the same Reynolds number.If 0°bθ≤39.9°,the frictional coefficient increased as the contact angle increased.In contrast,if 39.9°bθb 180°,the frictional coefficient decreased with increasing contact angle.The influences of the pipe diameter and contactangle difference on the pressure drop difference of JLHW105 oil showed an inversely proportional relation.A series of materials and liquids were tested.The selection of pipe material for transporting a given fluid can be based on the contact angle,surface tension,and critical limit of the contact angle obtained.The research results are expected to provide some guidelines for the selection of the appropriate pipe material for a given set of fluids.

鄂尔多斯盆地奥陶系中组合裂缝特征及其成藏意义（英文）

近年来中国海相碳酸盐岩油气勘探发现了一批大型油气田,其中鄂尔多斯盆地奥陶系马家沟组中组合蕴藏着丰富的天然气资源,储集空间类型主要有裂缝、裂缝-孔隙、孔隙和裂缝-孔洞型储层,输导体系由断层、裂缝、溶蚀孔洞和晶间溶孔构成。然而有关奥陶系中组合裂缝特征、裂缝的形成机制、古压力演化及其成藏意义的报道很少。基于钻井岩心观察、镜下微观分析、流体包裹体系统表征、生烃增压数值模拟等研究结果,结合天然气成藏地质背景,厘定了鄂尔多斯盆地奥陶系中组合裂缝特征、形成机制及其成藏意义。研究发现,鄂尔多斯盆地奥陶系中组合碳酸盐岩裂缝主要可分为近垂直缝、斜交缝和水平缝3种类型。基于裂缝类型特征和发育的主控因素,裂缝的成因机制归类为构造-成岩机制和复合成因机制。这些裂缝的形成期次主要有2期:第一期为中-晚侏罗世,第二期为早白垩世,且在早白垩世时期大量发育的裂缝成为研究区奥陶系中组合天然气运聚成藏的优势通道和良好储集空间。重点探讨了超压成藏演化所反映裂缝的形成和天然气运聚成藏过程,明确了多期次构造运动叠合和天然气超压-强超压运移充注构筑的裂缝网络体系与奥陶系中组合优势输导能力和良好储集性能的关系,建立了相应的机制与模式,为下一步有利勘探靶区评价及开发部署提供理论指导和地质依据。

Determination of microscopic waterflooding characteristics and influence factors in ultra-low permeability sandstone reservoir

Actual sandstone micromodel was used in this work to conduct the microscopic waterflooding experiment of ultra-low sandstone reservoir,since the inside seepage characteristics of microscopic waterflooding process of Chang 8 ultra-low permeability sandstone reservoir of Upper Triassic Yanchang formation in Huaqing region of the Ordos Basin,China is difficult to observe directly.Combined with physical property,casting thin sections,constant-rate mercury injection capillary pressure and nuclear magnetic resonance,the influence of reservoir property on the waterflooding characteristics in pores were analyzed and evaluated.Seepage paths of waterflooding characteristics were divided into four types:homogeneous seepage,reticular-homogeneous seepage,finger-reticular seepage and finger-like seepage,the waterflooding efficiency of which decreases in turn.More than 70%of residual oil occurs as flowing-around seepage and oil film.Physical property,pore structure and movable fluid characteristics are all controlled by digenesis and their impacts on waterflooding efficiency are in accordance.Generally,the pore throat radius size and distribution and movable fluid percentage are closely related to waterflooding law.

Discovery of Early Paleozoic Garnet Amphibolite in the Wenquan Complex,Northern Margin of the Yili Block,NW China

Objective High-pressure(HP)and ultrahigh-pressure(UHP)minerals tend to be preserved in mafic and ultramafic metamorphic rocks(e.g.eclogites and garnet amphibolite)rather than felsic rocks.Generally,HP and UHP rocks are thought to be formed as a result of the tectonic burial or subduction of oceanic crust or thicked continental lithosphere to depths corresponding to the eclogite facies metamorphism,followed by fast uplift(Ernst et al.,2007).

Petrogenesis of Early Carboniferous Alkaline Basalt from the Wusun Mountain:Implications for Tectonic Evolution of the Western Yining Block,NW China

Late Paleozoic volcanic rocks are well exposed in the Yining Block,NW China,and are predominately composed of andesites,rhyolites and volcaniclastics as well as minor basalts.Study of the petrology,whole-rock geochemistry and zircon U-Pb dating for the Early Carboniferous alkaline basalts from Wusun Mountain,western Yining Block,constrains their petrogenesis and tectonic evolution.The alkaline basalts consist mainly of plagioclases,mostly albite and labradorite,as well as clinopyroxenes and olivines;zircon U-Pb dating indicates their formation at ca.350 Ma.Geochemically,the basaltic samples have low SiO_(2)contents,and high TiO_(2),Al_(2)O_(3)and alkaline contents,coupled with high Na_(2)O/K_(2)O ratios,displaying an alkaline basalt affinity.They show remarkable LILE enrichment and HFSE depletion.Meantime,these samples have relatively high TFe_(2)O_(3),MgO,and Mg#values as well as Ni and Cr,relatively high Sm/Yb and U/Th,suggesting origination from a mantle source metasomatized by slab fluids.They formed in a transitional tectonic setting from arc to intraplate,showing a typical affinity of back-arc basin basalts.The alkaline basalts were likely generated in a nascent back-arc extension setting resulting from slab rollback of the southern Tianshan oceanic lithosphere.A bidirectional subduction model seems more reasonable for the evolution of the southern Tianshan Ocean.These new data will provide a new tectonic model for Late Paleozoic tectonic evolution of the western Yining Block.

Effect of twin boundary on nanoimprint process of bicrystal Al thin film studied by molecular dynamics simulation

The effects of a twin boundary（TB） on the mechanical properties of two types of bicrystal Al thin films during the nanoimprint process are investigated by using molecular dynamics simulations.The results indicate that for the TB direction parallel to the imprinting direction,the yield stress reaches the maximum for the initial dislocation nucleation when the mould directly imprints to the TB,and the yield stress first decreases with the increase of the marker interval and then increases.However,for the TB direction perpendicular to the imprinting direction,the effect of the TB location to the imprinting forces is very small,and the yield stress is greater than that with the TB direction parallel to the imprinting direction.The results also demonstrate that the direction of the slip dislocations and the deformation of the thin film caused by spring-back are different due to various positions and directions of the TB.

Characteristics,origin and controlling effects on hydrocarbon accumulation of overpressure in foreland thrust belt of southern margin of Junggar Basin,NW China

Aiming at the differential distribution of overpressure in vertical and lateral directions in the foreland thrust belt in the southern margin of Junggar Basin,the study on overpressure origin identification and overpressure evolution simulation is carried out.Based on the measured formation pressure,drilling fluid density and well logging data,overpressure origin identification and overpressure evolution simulation techniques are used to analyze the vertical and lateral distribution patterns of overpressure,genetic mechanisms of overpressure in different structural belts and causes of the differential distribution of overpressure,and the controlling effects of overpressure development and evolution on the formation and distribution of oil and gas reservoirs.The research shows that overpressure occurs in multiple formations vertically in the southern Junggar foreland thrust belt,the deeper the formation,the bigger the scale of the overpressure is.Laterally,overpressure is least developed in the mountain front belt,most developed in the fold anticline belt,and relatively developed in the slope belt.The differential distribution of overpressure is mainly controlled by the differences in disequilibrium compaction and tectonic compression strengths of different belts.The vertical overpressure transmission caused by faults connecting the deep overpressured system has an important contribution to the further increase of the overpressure strength in this area.The controlling effect of overpressure development and evolution on hydrocarbon accumulation and distribution shows in the following aspects:When the strong overpressure was formed before reservoir becoming tight overpressure maintains the physical properties of deep reservoirs to some extent,expanding the exploration depth of deep reservoirs;reservoirs below the overpressured mudstone cap rocks of the Paleogene Anjihaihe Formation and Lower Cretaceous Tugulu Group are main sites for oil and gas accumulation;under the background of overall overpressure,both overpressure strength too high or too low are not conducive to hydrocarbon enrichment and preservation,and the pressure coefficient between 1.6 and 2.1 is the best.