The“one-stop”student community is an important component of the education system in the new era of universities,and is an important practical base for university students to carry out practical education and moral e...The“one-stop”student community is an important component of the education system in the new era of universities,and is an important practical base for university students to carry out practical education and moral education.However,the construction of student communities still faces practical problems such as insufficient strength and lack of effective support in the current education system.Therefore,building a reasonable“one-stop”student community operation mode and exploring effective practical methods are the key to promoting student growth and development,stimulating learning willingness,and enhancing service awareness.They are also a powerful development and key force for highquality construction of student communities and the effectiveness of university education.展开更多
In permafrost regions with warm frozen soil,subgrade thaw-collapse phenomenon commonly occurs,facing thaw collapse problems of the existed frozen soil subgrade,thus it is difficult to use traditional methods such as a...In permafrost regions with warm frozen soil,subgrade thaw-collapse phenomenon commonly occurs,facing thaw collapse problems of the existed frozen soil subgrade,thus it is difficult to use traditional methods such as active cooling and passive protection technology to stabilize the existed warm frozen soil subgrade.This study derives a novel stabilizer method,a long-short(L-S)cement-mixed batter pile composite foundation to stabilize the existed warm frozen soil subgrade.To solve the thawcollapse problems in warm frozen soil subgrade,high water content and large compressibility characteristics were compared between soft soil and warm frozen soils.Theoretical analysis of heat conduction and numerical simulation of finite element model were used to study the freeze–thaw process and evaluate the stabilized effects of the L-S cement-mixed batter piles on the warm frozen soil foundation of the Qinghai-Tibet Highway.Furthermore,the thaw process and mechanical properties of foundation and piles were analyzed by introducing the hydration heat factor in the thermodynamic control equation.The results indicate that the thawing displacement of the existed warm frozen soil subgrade was reduced owing to the“support”and“grasp”effects of the L-S cement-mixed batter piles on the surrounding soil.The composite ground formed by strengthening the warm frozen ground with batter piles could considerably improve the bearing capacity of the existed warm frozen ground,effectively restrain the deformation of the upper embankment,and improve the strength of the ground.The analysis can provide method for the construction design of cement mixing batter pile foundation in cold regions.展开更多
The study of pore structure requires consideration of important factors including pore throat size,pore radius composition,and pore-throat configuration.As the nuclear magnetic resonance(NMR)experimental results conta...The study of pore structure requires consideration of important factors including pore throat size,pore radius composition,and pore-throat configuration.As the nuclear magnetic resonance(NMR)experimental results contain rich information about pore structures and fluid occurrence states,this study investigated the pore structures of the tight sandstone reservoirs of the Shanxi Formation in the Daning-Jixian area,eastern Ordos Basin.Firstly,by making the inverse cumulative curve of the NMR T2 spectrum coincide with the capillary pressure curves which were obtained by the mercury injection capillary pressure(MICP)technique,this study derived a conversion coefficient that can be used to convert the NMR T2 spectrum into the pore throat radius distribution curves based on the NMR experimental results.Subsequently,we determined the pore radius intervals corresponding to irreducible water distribution using the NMR-derived pore radius distribution curves.Finally,the NMR T2 distribution curves based on the fractal theory were analyzed and the relationships between fractal dimensions and parameters,including permeability,porosity,reservoir quality index(RQI),flow zone indicator(FZI),irreducible water saturation,RT35,and RT50,were also discussed.The NMR-derived pore throat radius distribution curves of the study area are mainly unimodal,with some curves showing slightly bimodal distributions.The irreducible water mainly occurs in small pores with a pore radius less than 100 nm.As the permeability decreases,the contribution rate of small pores to the irreducible water gradually increases.The NMR-based fractal dimensions of pores show a two-segment distribution.Small pores have small fractal dimensions and are evenly distributed,while large pores have large fractal dimensions and complex pore structures.The fractal dimension of large pores(Dmax)is poorly correlated with porosity but strongly correlated with FZI,RQI,RT35,and RT50.These results indicate that large pores are the main pore zones that determine the seepage capacity of the reservoirs.Additionally,there is a certain correlation between Dmax and the irreducible water saturation.展开更多
The flow of fluid through the porous matrix of a reservoir rock applies a seepage force to the solid rock matrix.Although the seepage force exerted by fluid flow through the porous matrix of a reservoir rock has a not...The flow of fluid through the porous matrix of a reservoir rock applies a seepage force to the solid rock matrix.Although the seepage force exerted by fluid flow through the porous matrix of a reservoir rock has a notable influence on rock deformation and failure,its effect on hydraulic fracture(HF)propagation remains ambiguous.Therefore,in this study,we improved a traditional fluid–solid coupling method by incorporating the role of seepage force during the fracturing fluid seepage,using the discrete element method.First,we validated the simulation results of the improved method by comparing them with an analytical solution of the seepage force and published experimental results.Next,we conducted numerical simulations in both homogeneous and heterogeneous sandstone formations to investigate the influence of seepage force on HF propagation.Our results indicate that fluid viscosity has a greater impact on the magnitude and extent of seepage force compared to injection rate,and that lower viscosity and injection rate correspond to shorter hydraulic fracture lengths.Furthermore,seepage force influences the direction of HF propagation,causing HFs to deflect towards the side of the reservoir with weaker cementation and higher permeability.展开更多
Due to the strong unsteadiness of pulse detonation,large flow losses are generated when the detonation wave interacts with the turbine blades,resulting in low turbine efficiency.Considering that the flow losses are di...Due to the strong unsteadiness of pulse detonation,large flow losses are generated when the detonation wave interacts with the turbine blades,resulting in low turbine efficiency.Considering that the flow losses are dissipated into the gas as heat energy,some of them can be recycled during the expansion process in subsequent stages by the reheat effect,which should be helpful to improve the detonationdriven turbine efficiency.Taking this into account,this paper developed a numerical model of the detonation chamber coupled with a two-stage axial turbine,and a stoichiometric hydrogen-air mixture was used.The improvement in turbine efficiency attributable to the reheat effect was calculated by comparing the average efficiency of the stages with the efficiency of the two-stage turbine.The research indicated that the first stage was critical in suppressing the flow unsteadiness caused by pulse detonation,which stabilized the intake condition of the second stage and consequently allowed much of the flow losses from the first stage to be recycled,so that the efficiency of the two-stage turbine was improved.At a 95%confidence level,the efficiency improvement was stable at 4.5%—5.3%,demonstrating that the reheat effect is significant in improving the efficiency of the detonation-driven turbine.展开更多
To support the explosive growth of Information and Communications Technology(ICT),Mobile Edge Comput-ing(MEC)provides users with low latency and high bandwidth service by offloading computational tasks to the network...To support the explosive growth of Information and Communications Technology(ICT),Mobile Edge Comput-ing(MEC)provides users with low latency and high bandwidth service by offloading computational tasks to the network’s edge.However,resource-constrained mobile devices still suffer from a capacity mismatch when faced with latency-sensitive and compute-intensive emerging applications.To address the difficulty of running computationally intensive applications on resource-constrained clients,a model of the computation offloading problem in a network consisting of multiple mobile users and edge cloud servers is studied in this paper.Then a user benefit function EoU(Experience of Users)is proposed jointly considering energy consumption and time delay.The EoU maximization problem is decomposed into two steps,i.e.,resource allocation and offloading decision.The offloading decision is usually given by heuristic algorithms which are often faced with the challenge of slow convergence and poor stability.Thus,a combined offloading algorithm,i.e.,a Gini coefficient-based adaptive genetic algorithm(GCAGA),is proposed to alleviate the dilemma.The proposed algorithm optimizes the offloading decision by maximizing EoU and accelerates the convergence with the Gini coefficient.The simulation compares the proposed algorithm with the genetic algorithm(GA)and adaptive genetic algorithm(AGA).Experiment results show that the Gini coefficient and the adaptive heuristic operators can accelerate the convergence speed,and the proposed algorithm performs better in terms of convergence while obtaining higher EoU.The simulation code of the proposed algorithm is available:https://github.com/Grox888/Mobile_Edge_Computing/tree/GCAGA.展开更多
Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fu...Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fully non-fused ring electron acceptors(NFREAs,medium bandgap,i,e.,1,3-1,8 eV),namely PTR-2Cl and PTR-4Cl are synthesized with only four steps by using intramolecular noncovalent interaction central core,structured alkyl side chain orientation linking units and flanking with different electron-withdrawing end group.Among them,PTR-4C1 exhibits increased average electrostatic potential(ESP)difference with polymer donor,enhanced crystallinity and compactπ-πstacking compared with the control molecule PTR-2CI.As a result,the PTR-4Cl-based OSC achieved an impressive power conversion efficiency(PCE)of 14.72%,with a much higher open-circuit voltage(V_(OC))of 0.953 V and significantly improved fill factor(FF)of 0.758,demonstrating one of the best acceptor material in the top-performing fully NFREA-based OSCs with both high PCE and V_(OC).Notably,PTR-4Cl-based cells maintain a good T_80lifetime of its initial PCE after over 936 h under a continuous thermal annealing treatment and over1300 h T_(80)lifetime without encapsulation.This work provides a cost-effective design strategy for NFREAs on obtaining high V_(OC),efficient exciton dissociation,and ordered molecular packing and thus high-efficiency and stable OSCs.展开更多
Tungstated zirconia(WO_(3)/ZrO_(2))solid acid catalysts with different WO_(3) contents were prepared by a hydrothermal method and then used in the catalytic aquathermolysis of heavy oil from Xinjiang.The WO_(3)/ZrO_(2...Tungstated zirconia(WO_(3)/ZrO_(2))solid acid catalysts with different WO_(3) contents were prepared by a hydrothermal method and then used in the catalytic aquathermolysis of heavy oil from Xinjiang.The WO_(3)/ZrO_(2) solid acid catalyst was characterized by a range of characterization methods,including X-ray diffraction,NH3-temperature programmed desorption,and pyridine infrared spectroscopy.The WO_(3) content of the WO_(3)/ZrO_(2) catalysts had an important impact on the structure and property of the catalysts.When the WO_(3) mass fraction was 20%,it facilitated the formation of tetragonal zirconia,thereby enhancing the creation of robust acidic sites.Acidity is considered to have a strong impact on the catalytic performance of the aquathermolysis of heavy oil.When the catalyst containing 20%WO_(3) was used to catalyze the aquathermolysis of heavy oil under conditions of 14.5 MPa,340℃,and 24 h,the viscosity of heavy oil decreased from 47266 to 5398 mPa·s and the viscosity reduction rate reached 88.6%.The physicochemical properties of heavy oil before and after the aquathermolysis were analyzed using a saturates,aromatics,resins,and asphaltenes analysis,gas chromatography,elemental analysis,densimeter etc.After the aquathermolysis,the saturate and aromatic contents significantly increased from 43.3%to 48.35%and 19.47%to 21.88%,respectively,with large reductions in the content of resin and asphaltene from 28.22%to 25.06%and 5.36%to 2.03%,respectively.The sulfur and nitrogen contents,and the density of the oil were significantly decreased.These factors were likely the main reasons for promoting the viscosity reduction of heavy oil during the aquathermolysis over the WO_(3)/ZrO_(2) solid acid catalysts.展开更多
A three-dimensional reconstruction of rough fracture surfaces of hydraulically fractured rock outcrops is carried out by casting process,a large-scale experimental setup for visualizing rough fractures is built to per...A three-dimensional reconstruction of rough fracture surfaces of hydraulically fractured rock outcrops is carried out by casting process,a large-scale experimental setup for visualizing rough fractures is built to perform proppant transport experiments.The typical characteristics of proppant transport and placement in rough fractures and its intrinsic mechanisms are investigated,and the influences of fracture inclination,fracture width and fracturing fluid viscosity on proppant transport and placement in rough fractures are analyzed.The results show that the rough fractures cause variations in the shape of the flow channel and the fluid flow pattern,resulting in the bridging buildup during proppant transport to form unfilled zone,the emergence of multiple complex flow patterns such as channeling,reverse flow and bypassing of sand-carrying fluid,and the influence on the stability of the sand dune.The proppant has a higher placement rate in inclined rough fractures,with a maximum increase of 22.16 percentage points in the experiments compared to vertical fractures,but exhibits poor stability of the sand dune.Reduced fracture width aggravates the bridging of proppant and induces higher pumping pressure.Increasing the viscosity of the fracturing fluid can weaken the proppant bridging phenomenon caused by the rough fractures.展开更多
A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax depositi...A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax deposition in crude oil pipelines.Aiming at the shortcomings of the ENN prediction model,which easily falls into the local minimum value and weak generalization ability in the implementation process,an optimized ENN prediction model based on the IRSA is proposed.The validity of the new model was confirmed by the accurate prediction of two sets of experimental data on wax deposition in crude oil pipelines.The two groups of crude oil wax deposition rate case prediction results showed that the average absolute percentage errors of IRSA-ENN prediction models is 0.5476% and 0.7831%,respectively.Additionally,it shows a higher prediction accuracy compared to the ENN prediction model.In fact,the new model established by using the IRSA to optimize ENN can optimize the initial weights and thresholds in the prediction process,which can overcome the shortcomings of the ENN prediction model,such as weak generalization ability and tendency to fall into the local minimum value,so that it has the advantages of strong implementation and high prediction accuracy.展开更多
Horizontal well-stimulation is the key to unconventional resource exploration and development.The development mode of the well plant helps increase the stimulated reservoir volume.Nevertheless,fracture interference be...Horizontal well-stimulation is the key to unconventional resource exploration and development.The development mode of the well plant helps increase the stimulated reservoir volume.Nevertheless,fracture interference between wells reduces the fracturing effect.Here,a 2D hydro-mechanical coupling model describing hydraulic fracture(HF)propagation is established with the extended finite element method,and the effects of several factors on HF propagation during multiple wells fracturing are analyzed.The results show that with an increase in elastic modulus,horizontal principal stress difference and injection fluid displacement,the total fracture area and the reservoir stimulation efficiency are both improved in all three fracturing technologies.After a comparison of the three technologies,the method of improved zipper fracturing is proposed,which avoids mutual interference between HFs,and the reservoir stimulation effect is improved significantly.The study provides guidance for optimizing the fracturing technology of multiple horizontal wells.展开更多
In this paper, the Chang 2 reservoir in Zichang Area of Ordos Basin, the second largest sedimentary basin in China, is classified and evaluated by using logging and core data, thin section identification and electron ...In this paper, the Chang 2 reservoir in Zichang Area of Ordos Basin, the second largest sedimentary basin in China, is classified and evaluated by using logging and core data, thin section identification and electron microscopy. The main sedimentary microfacies of Chang 2<sub>1</sub><sup>3</sup> is braided river delta sedimentary system in geological history, and there are three main sedimentary microfacies types: swamp microfacies, distributary channel microfacies and natural embankment microfacies on land. The heterogeneity in the study area is as follows: Chang 2<sub>1</sub><sup>2</sup> formation has the strongest heterogeneity, followed by Chang 2<sub>1</sub><sup>1</sup> formation with strong heterogeneity, and finally Chang 2<sub>1</sub><sup>3</sup> formation with medium heterogeneity. The reservoirs of Chang 2 member in the study area are dominated by III<sub>a</sub>, II<sub>b</sub> and III<sub>b</sub>, and the reservoirs are mainly composed of ultra-low porosity and low permeability reservoirs and low porosity and low permeability reservoirs.展开更多
Tensile behaviors of Ti/Ni nanolaminate with model-I crack are investigated by molecular dynamics simulations.The Ti/Ni nanolaminates with center crack either in Ti layer or in Ni layer under different loading directi...Tensile behaviors of Ti/Ni nanolaminate with model-I crack are investigated by molecular dynamics simulations.The Ti/Ni nanolaminates with center crack either in Ti layer or in Ni layer under different loading directions are utilized to systematically study the mechanical performance of the cracked material.The results indicate that pre-existing crack dramatically changes the plastic deformation mechanism of the Ti/Ni nanolaminate.Unlike the initial plastic deformation originating from the interface or weak Ti layer of the crack-free samples,the plastic behavior of cracked Ti/Ni nanolaminate first occurs at the crack tip due to the local stress concentration.Subsequent plastic deformation is dominated by the interaction between the crack and interface.The Ti/Ni interface not only impedes the movement of the initial plastic deformation carriers(dislocation,slip band,and deformation twinning)from the crack tip,but also promotes the movement of interfacial dislocations in the tension process.Microstructure evolution analysis further confirms that the plastic deformation mechanism transition is ascribed to the orientation-dependent tensile behavior at the crack tip,which is intrinsically attributed to the anisotropy of the certain crystal structure and loading direction of the cracked Ti/Ni nanolaminate.In addition,by analyzing the effects of different plastic deformation carriers on crack propagation in specific crystal,it can be discovered that the interfacial dislocations moving towards the crack tip can further promote the crack growth.展开更多
With the implementation of the strategy for Chinese international promotion,the diversified social development needs are constantly adjusting the direction of Chinese education promotion,onefold course setting can no ...With the implementation of the strategy for Chinese international promotion,the diversified social development needs are constantly adjusting the direction of Chinese education promotion,onefold course setting can no longer meet the increasingly abundant practical needs of Chinese.In order to make Chinese education and teaching in Cambodia better,it is necessary to analyze and evaluate the setting of Chinese courses in colleges and universities from the perspectives of social-based value orientation,and reform the relevant Chinese curriculum by developing special-purpose Chinese courses,filling in the gaps in cultural courses,and adding courses to cultivate students'innovative thinking and scientific spirit.展开更多
In the novel White Deer Plain,Chen Zhongshi profoundly narrated the tragic fate of the survival of the image of Chinese women,revealed the social status,inner world and character characteristics of women in Chinese tr...In the novel White Deer Plain,Chen Zhongshi profoundly narrated the tragic fate of the survival of the image of Chinese women,revealed the social status,inner world and character characteristics of women in Chinese traditional culture,and explained the tragic root of the survival of Chinese women from the Chinese cultural level.About the description of the characters,Tian Xiao’e was deeper to touch the depths of human nature affection Aaron and reason of conflict,touched the moral self and human self in a culture of conflict,so that the survival of female tragic signs of the novel has a wider significance and general significance.In this article,the author takes Tian Xiao’e as the example,to analyze this typical characteristic from the angle of the female tragedy semiotics in multi-dimensional interpretation of the characters.It is not only has practical significance for gender ethics construction,also has the vital significance to our mind world and the cultural construction today.展开更多
To obtain high yields of monocyclic aromatic hydrocarbons with methyl side chains,such as toluene and xylene,methane(CH_(4))can be introduced into the hydrocracking of polycyclic aromatic hydrocarbons.CH_(4)can partic...To obtain high yields of monocyclic aromatic hydrocarbons with methyl side chains,such as toluene and xylene,methane(CH_(4))can be introduced into the hydrocracking of polycyclic aromatic hydrocarbons.CH_(4)can participate in the reaction,supply methyl side chains to the product,and improve product distribution.In this study,the hydrogenation reaction of polycyclic aromatic hydrocarbons over a carbonized NiMo/Hβcatalyst in a CH_(4)and hydrogen(H_(2))environment was investigated to study the promotional effect of CH_(4)on the hydrocracking of polycyclic aromatics.Under conditions of 3.5 MPa,380℃,volume air velocity of 4 h^(-1),gas-oil volume ratio of 800,and H_(2):CH_(4)molar ratio of 1:1,the conversion rate of naphthalene was 99.97%,the liquid phase yield was 93.62%,and the selectivity of BTX were 17.76%,25.17%,and 20.47%,respectively.In comparison to the use of a H_(2)atmosphere,the selectivity of benzene was significantly decreased,whereas the selectivity of toluene and xylene were increased.It was shown that CH_(4)can participate in the hydrocracking of naphthalene and improve the selectivity of toluene and xylene in the liquid product.The carbonized NiMo/Hβcatalyst was characterized by a range of analytical methods(such as X-ray diffraction(XRD),ammonia-temperature-programmed desorption(NH3-TPD),hydrogen-temperature-programmed reduction(H_(2)-TPR),and X-ray photoelectron spectroscopy(XPS)).The results indicated that Ni and Mo carbides were the major species in the carbonized NiMo/Hβcatalyst and were considered to be active sites for the activation of CH_(4)and H_(2).After loading the metal components,the catalyst displayed prominent weak acidic sites,which may be suitable locations for cracking,alkylation,and other related reactions.Therefore,the carbonized NiMo/Hβcatalyst displayed multiple functions during the hydrocracking of polycyclic aromatic hydrocarbons in a CH_(4)and H_(2)environment.These results could be used to develop a new way to efficiently utilize polycyclic aromatic hydrocarbons and natural gas resources.展开更多
Mg-Zn-Ca-Mn series alloys are developed as promising candidates of 5G communication devices with excellent thermal conductivities,great ductility,and acceptable strength.In present paper,Mg-x Zn-0.4Ca-0.2Mn(x=2wt%,4wt...Mg-Zn-Ca-Mn series alloys are developed as promising candidates of 5G communication devices with excellent thermal conductivities,great ductility,and acceptable strength.In present paper,Mg-x Zn-0.4Ca-0.2Mn(x=2wt%,4wt%,6wt%)alloys were prepared by a near-solidus extrusion and the effect of Zn content on mechanical and thermal properties were investigated.The results showed that the addition of minor Ca led to the formation of Ca_(2)Mg_(6)Zn_(3) eutectic phase at grain boundaries.A type of bimodal microstructure occurred in the as-extruded alloys,where elongated coarse deformed grains were embedded in refined recrystallized grains matrix.Correspondingly,both yield strength and ductility of the alloys were significantly enhanced after extrusion due to the great grain refinement.Specially,higher Zn content led to the increment in yield strength and a slight reduction in elongation due to the larger fractions of second phase particles.The room temperature thermal conductivity of as-extruded alloys was also improved compared with that of as-cast counterparts.The increment of Zn content decreased the thermal conductivity of both as-cast and as-extruded alloys,which was due to the increased second phase fraction and solution atoms in the matrix,that hindering the motion of electrons.The as-extruded Mg-2Zn-0.4Ca-0.2Mn(wt%)alloy exhibited the highest elongation of 27.7% and thermal conductivity of 139.2 W/(m·K),combined with an acceptable ultimate tensile strength of 244.0 MPa.The present paper provides scientific guidance for the preparation of lightweight materials with high ductility and high thermal conductivity.展开更多
Dissolution mechanism and favorable reservoir distribution prediction are the key problems restricting oil and gas exploration in deep-buried layers.In this paper,the Enping Formation and Zhuhai Formation in Baiyun Sa...Dissolution mechanism and favorable reservoir distribution prediction are the key problems restricting oil and gas exploration in deep-buried layers.In this paper,the Enping Formation and Zhuhai Formation in Baiyun Sag of South China Sea was taken as a target.Based on the thin section,scanning electron microscopy,X-ray diffraction,porosity/permeability measurement,and mercury injection,influencing factors of dissolution were examined,and a dissolution model was established.Further,high-quality reservoirs were predicted temporally and spatially.The results show that dissolved pores constituted the main space of the Paleogene sandstone reservoir.Dissolution primarily occurred in the coarse-and medium-grained sandstones in the subaerial and subaqueous distributary channels,while dissolution was limited in fine-grained sandstones and inequigranular sandstones.The main dissolved minerals were feldspar,tuffaceous matrix,and diagenetic cement.Kaolinization of feldspar and illitization of kaolinite are the main dissolution pathways,but they occur at various depths and temperatures with different geothermal gradients.Dissolution is controlled by four factors,in terms of depositional facies,source rock evolution,overpressure,and fault activities,which co-acted at the period of 23.8–13.8 Ma,and resulted into strong dissolution.Additionally,based on these factors,high-quality reservoirs of the Enping and Zhuhai formations are predicted in the northern slope,southwestern step zone,and Liuhua uplift in the Baiyun Sag.展开更多
Traditional microstructure scale parameters have difficulty describing the structure and distribution of a roughmaterial’s surface morphology comprehensively and quantitatively. This study constructs hydrophilic and ...Traditional microstructure scale parameters have difficulty describing the structure and distribution of a roughmaterial’s surface morphology comprehensively and quantitatively. This study constructs hydrophilic and underwateroleophobic surfaces based on polyvinylidene fluoride (PVDF) using a chemical modification method, and the fractaldimension and multifractal spectrum are used to quantitatively characterize the microscopic morphology. A new contactangle prediction model for underwater oleophobic surfaces is established. The results show that the fractal dimension ofthe PVDF surface first increases and then decreases with the reaction time. The uniformity characterized by the multifractalspectrum was generally consistent with scanning electron microscope observations. The contact angle of water droplets onthe PVDF surface is negatively correlated with the fractal dimension, and oil droplets in water are positively correlated.When the fractal dimension is 2.0975, the new contact angle prediction model has higher prediction accuracy. Themaximum and minimum relative deviations of the contact angle between the theoretical and measured data are 18.20%and 0.72%, respectively. For water ring transportation, the larger the fractal dimension and spectral width of the materialsurface, the smaller the absolute value of the spectral difference, the stronger the hydrophilic and oleophobic properties, andthe better the water ring transportation stability.展开更多
基金2023 Research Project on“Cultivating Virtue and Talents”at Xi'an Shiyou University(LD202312),2023 Excellent Student Work Project of Xi'an Shiyou University(XJYB202303).
文摘The“one-stop”student community is an important component of the education system in the new era of universities,and is an important practical base for university students to carry out practical education and moral education.However,the construction of student communities still faces practical problems such as insufficient strength and lack of effective support in the current education system.Therefore,building a reasonable“one-stop”student community operation mode and exploring effective practical methods are the key to promoting student growth and development,stimulating learning willingness,and enhancing service awareness.They are also a powerful development and key force for highquality construction of student communities and the effectiveness of university education.
基金supported by the National Natural Science Foundation of China(Grant No.41971086)Natural Science Foundation of Shanxi Province(Grant No.2023-JC-QN-0626,2022JQ-467).
文摘In permafrost regions with warm frozen soil,subgrade thaw-collapse phenomenon commonly occurs,facing thaw collapse problems of the existed frozen soil subgrade,thus it is difficult to use traditional methods such as active cooling and passive protection technology to stabilize the existed warm frozen soil subgrade.This study derives a novel stabilizer method,a long-short(L-S)cement-mixed batter pile composite foundation to stabilize the existed warm frozen soil subgrade.To solve the thawcollapse problems in warm frozen soil subgrade,high water content and large compressibility characteristics were compared between soft soil and warm frozen soils.Theoretical analysis of heat conduction and numerical simulation of finite element model were used to study the freeze–thaw process and evaluate the stabilized effects of the L-S cement-mixed batter piles on the warm frozen soil foundation of the Qinghai-Tibet Highway.Furthermore,the thaw process and mechanical properties of foundation and piles were analyzed by introducing the hydration heat factor in the thermodynamic control equation.The results indicate that the thawing displacement of the existed warm frozen soil subgrade was reduced owing to the“support”and“grasp”effects of the L-S cement-mixed batter piles on the surrounding soil.The composite ground formed by strengthening the warm frozen ground with batter piles could considerably improve the bearing capacity of the existed warm frozen ground,effectively restrain the deformation of the upper embankment,and improve the strength of the ground.The analysis can provide method for the construction design of cement mixing batter pile foundation in cold regions.
基金supported by the National Natural Science Foundation of China(41702132).
文摘The study of pore structure requires consideration of important factors including pore throat size,pore radius composition,and pore-throat configuration.As the nuclear magnetic resonance(NMR)experimental results contain rich information about pore structures and fluid occurrence states,this study investigated the pore structures of the tight sandstone reservoirs of the Shanxi Formation in the Daning-Jixian area,eastern Ordos Basin.Firstly,by making the inverse cumulative curve of the NMR T2 spectrum coincide with the capillary pressure curves which were obtained by the mercury injection capillary pressure(MICP)technique,this study derived a conversion coefficient that can be used to convert the NMR T2 spectrum into the pore throat radius distribution curves based on the NMR experimental results.Subsequently,we determined the pore radius intervals corresponding to irreducible water distribution using the NMR-derived pore radius distribution curves.Finally,the NMR T2 distribution curves based on the fractal theory were analyzed and the relationships between fractal dimensions and parameters,including permeability,porosity,reservoir quality index(RQI),flow zone indicator(FZI),irreducible water saturation,RT35,and RT50,were also discussed.The NMR-derived pore throat radius distribution curves of the study area are mainly unimodal,with some curves showing slightly bimodal distributions.The irreducible water mainly occurs in small pores with a pore radius less than 100 nm.As the permeability decreases,the contribution rate of small pores to the irreducible water gradually increases.The NMR-based fractal dimensions of pores show a two-segment distribution.Small pores have small fractal dimensions and are evenly distributed,while large pores have large fractal dimensions and complex pore structures.The fractal dimension of large pores(Dmax)is poorly correlated with porosity but strongly correlated with FZI,RQI,RT35,and RT50.These results indicate that large pores are the main pore zones that determine the seepage capacity of the reservoirs.Additionally,there is a certain correlation between Dmax and the irreducible water saturation.
基金National Natural Science Foundation of China(51934005,U23B2089)Shaanxi Provincial Natural Science Basic Research Program Project(2024JC-YBQN-0554).
文摘The flow of fluid through the porous matrix of a reservoir rock applies a seepage force to the solid rock matrix.Although the seepage force exerted by fluid flow through the porous matrix of a reservoir rock has a notable influence on rock deformation and failure,its effect on hydraulic fracture(HF)propagation remains ambiguous.Therefore,in this study,we improved a traditional fluid–solid coupling method by incorporating the role of seepage force during the fracturing fluid seepage,using the discrete element method.First,we validated the simulation results of the improved method by comparing them with an analytical solution of the seepage force and published experimental results.Next,we conducted numerical simulations in both homogeneous and heterogeneous sandstone formations to investigate the influence of seepage force on HF propagation.Our results indicate that fluid viscosity has a greater impact on the magnitude and extent of seepage force compared to injection rate,and that lower viscosity and injection rate correspond to shorter hydraulic fracture lengths.Furthermore,seepage force influences the direction of HF propagation,causing HFs to deflect towards the side of the reservoir with weaker cementation and higher permeability.
基金financially supported by the National Natural Science Foundation of China through Grant Nos.12372338 and U2241272the Natural Science Foundation of Shaanxi Province of China through Grant Nos.2023-JC-YB-352 and 2022JZ-20+1 种基金the Guangdong Basic and Applied Basic Research Foundation through Grant No.2023A1515011663the Practice and Innovation Funds for Graduate Students of Northwestern Polytechnical University through Grant No.PF2023010。
文摘Due to the strong unsteadiness of pulse detonation,large flow losses are generated when the detonation wave interacts with the turbine blades,resulting in low turbine efficiency.Considering that the flow losses are dissipated into the gas as heat energy,some of them can be recycled during the expansion process in subsequent stages by the reheat effect,which should be helpful to improve the detonationdriven turbine efficiency.Taking this into account,this paper developed a numerical model of the detonation chamber coupled with a two-stage axial turbine,and a stoichiometric hydrogen-air mixture was used.The improvement in turbine efficiency attributable to the reheat effect was calculated by comparing the average efficiency of the stages with the efficiency of the two-stage turbine.The research indicated that the first stage was critical in suppressing the flow unsteadiness caused by pulse detonation,which stabilized the intake condition of the second stage and consequently allowed much of the flow losses from the first stage to be recycled,so that the efficiency of the two-stage turbine was improved.At a 95%confidence level,the efficiency improvement was stable at 4.5%—5.3%,demonstrating that the reheat effect is significant in improving the efficiency of the detonation-driven turbine.
文摘To support the explosive growth of Information and Communications Technology(ICT),Mobile Edge Comput-ing(MEC)provides users with low latency and high bandwidth service by offloading computational tasks to the network’s edge.However,resource-constrained mobile devices still suffer from a capacity mismatch when faced with latency-sensitive and compute-intensive emerging applications.To address the difficulty of running computationally intensive applications on resource-constrained clients,a model of the computation offloading problem in a network consisting of multiple mobile users and edge cloud servers is studied in this paper.Then a user benefit function EoU(Experience of Users)is proposed jointly considering energy consumption and time delay.The EoU maximization problem is decomposed into two steps,i.e.,resource allocation and offloading decision.The offloading decision is usually given by heuristic algorithms which are often faced with the challenge of slow convergence and poor stability.Thus,a combined offloading algorithm,i.e.,a Gini coefficient-based adaptive genetic algorithm(GCAGA),is proposed to alleviate the dilemma.The proposed algorithm optimizes the offloading decision by maximizing EoU and accelerates the convergence with the Gini coefficient.The simulation compares the proposed algorithm with the genetic algorithm(GA)and adaptive genetic algorithm(AGA).Experiment results show that the Gini coefficient and the adaptive heuristic operators can accelerate the convergence speed,and the proposed algorithm performs better in terms of convergence while obtaining higher EoU.The simulation code of the proposed algorithm is available:https://github.com/Grox888/Mobile_Edge_Computing/tree/GCAGA.
基金the financial support by Hong Kong Scholar program(XJ2021-038)Young Talent Fund of Xi’an Association for Science and Technology(959202313080)+6 种基金the Natural Science Foundation Research Project of Shaanxi Province(2022JM-269)the Postgraduate Innovation and Practical Ability Training Program of Xi’an Shiyou University(YCS21212144)the National Natural Science Foundation of China(52103221,52172048,12175298)the Shandong Provincial Natural Science Foundation(ZR2021QB179,ZR2021QB024,ZR2021ZD06)the Guangdong Natural Science Foundation of China(2023A1515012323,2023A1515010943)the National Key Research and Development Program of China(2022YFB4200400)funded by MOSTthe Fundamental Research Funds of Shandong University。
文摘Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fully non-fused ring electron acceptors(NFREAs,medium bandgap,i,e.,1,3-1,8 eV),namely PTR-2Cl and PTR-4Cl are synthesized with only four steps by using intramolecular noncovalent interaction central core,structured alkyl side chain orientation linking units and flanking with different electron-withdrawing end group.Among them,PTR-4C1 exhibits increased average electrostatic potential(ESP)difference with polymer donor,enhanced crystallinity and compactπ-πstacking compared with the control molecule PTR-2CI.As a result,the PTR-4Cl-based OSC achieved an impressive power conversion efficiency(PCE)of 14.72%,with a much higher open-circuit voltage(V_(OC))of 0.953 V and significantly improved fill factor(FF)of 0.758,demonstrating one of the best acceptor material in the top-performing fully NFREA-based OSCs with both high PCE and V_(OC).Notably,PTR-4Cl-based cells maintain a good T_80lifetime of its initial PCE after over 936 h under a continuous thermal annealing treatment and over1300 h T_(80)lifetime without encapsulation.This work provides a cost-effective design strategy for NFREAs on obtaining high V_(OC),efficient exciton dissociation,and ordered molecular packing and thus high-efficiency and stable OSCs.
基金the financial support from the Open Fund Project of the National Oil Shale Exploitation Research and Development Center,China(No.33550000-22-ZC0613-0255)the Graduate Student Innovation and Practical Ability Training Program of Xi’an Shiyou University(No.YCS23213098)+3 种基金the National Natural Science Foundation of China(No.52274039)the Natural Science Basic Research Plan in Shaanxi Province of China(Program No.2024JC-YBMS-085)the CNPC Innovation Found(No.2022DQ02-0402)The authors also thank the Modern Analysis and Test Center of Xi’an Shiyou University for their help with the characterization of catalysts and analysis of products.
文摘Tungstated zirconia(WO_(3)/ZrO_(2))solid acid catalysts with different WO_(3) contents were prepared by a hydrothermal method and then used in the catalytic aquathermolysis of heavy oil from Xinjiang.The WO_(3)/ZrO_(2) solid acid catalyst was characterized by a range of characterization methods,including X-ray diffraction,NH3-temperature programmed desorption,and pyridine infrared spectroscopy.The WO_(3) content of the WO_(3)/ZrO_(2) catalysts had an important impact on the structure and property of the catalysts.When the WO_(3) mass fraction was 20%,it facilitated the formation of tetragonal zirconia,thereby enhancing the creation of robust acidic sites.Acidity is considered to have a strong impact on the catalytic performance of the aquathermolysis of heavy oil.When the catalyst containing 20%WO_(3) was used to catalyze the aquathermolysis of heavy oil under conditions of 14.5 MPa,340℃,and 24 h,the viscosity of heavy oil decreased from 47266 to 5398 mPa·s and the viscosity reduction rate reached 88.6%.The physicochemical properties of heavy oil before and after the aquathermolysis were analyzed using a saturates,aromatics,resins,and asphaltenes analysis,gas chromatography,elemental analysis,densimeter etc.After the aquathermolysis,the saturate and aromatic contents significantly increased from 43.3%to 48.35%and 19.47%to 21.88%,respectively,with large reductions in the content of resin and asphaltene from 28.22%to 25.06%and 5.36%to 2.03%,respectively.The sulfur and nitrogen contents,and the density of the oil were significantly decreased.These factors were likely the main reasons for promoting the viscosity reduction of heavy oil during the aquathermolysis over the WO_(3)/ZrO_(2) solid acid catalysts.
基金Supported by National Key Research and Development Program of China(2022YFE0137200)Outstanding Youth Natural Science Fund of Shaanxi Province(2022JC-37)+2 种基金Innovation Capability Support Program of Shaanxi(2023-CX-TD-31)Natural Science Basic Research Project of Shaanxi Province(2024JC-YBQN-0381)National Natural Science Foundation of China(51874240,52204021)。
文摘A three-dimensional reconstruction of rough fracture surfaces of hydraulically fractured rock outcrops is carried out by casting process,a large-scale experimental setup for visualizing rough fractures is built to perform proppant transport experiments.The typical characteristics of proppant transport and placement in rough fractures and its intrinsic mechanisms are investigated,and the influences of fracture inclination,fracture width and fracturing fluid viscosity on proppant transport and placement in rough fractures are analyzed.The results show that the rough fractures cause variations in the shape of the flow channel and the fluid flow pattern,resulting in the bridging buildup during proppant transport to form unfilled zone,the emergence of multiple complex flow patterns such as channeling,reverse flow and bypassing of sand-carrying fluid,and the influence on the stability of the sand dune.The proppant has a higher placement rate in inclined rough fractures,with a maximum increase of 22.16 percentage points in the experiments compared to vertical fractures,but exhibits poor stability of the sand dune.Reduced fracture width aggravates the bridging of proppant and induces higher pumping pressure.Increasing the viscosity of the fracturing fluid can weaken the proppant bridging phenomenon caused by the rough fractures.
文摘A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax deposition in crude oil pipelines.Aiming at the shortcomings of the ENN prediction model,which easily falls into the local minimum value and weak generalization ability in the implementation process,an optimized ENN prediction model based on the IRSA is proposed.The validity of the new model was confirmed by the accurate prediction of two sets of experimental data on wax deposition in crude oil pipelines.The two groups of crude oil wax deposition rate case prediction results showed that the average absolute percentage errors of IRSA-ENN prediction models is 0.5476% and 0.7831%,respectively.Additionally,it shows a higher prediction accuracy compared to the ENN prediction model.In fact,the new model established by using the IRSA to optimize ENN can optimize the initial weights and thresholds in the prediction process,which can overcome the shortcomings of the ENN prediction model,such as weak generalization ability and tendency to fall into the local minimum value,so that it has the advantages of strong implementation and high prediction accuracy.
基金funded by Shaanxi Natural Science Basic Research Program Project Study on Liquid Propellant High Energy Gas Fracturing Mechanism in Radial Well Based on Phase Field Method(No.2019JQ-824)NSFC Projects Evolution Mechanism and Effectiveness Evaluation of Fracture Network Produced by Volume Fracturing with Tighter Clusters in Continental Shale Oil Reservoir(No.52274040)+1 种基金Study on Thermal Secondary Pore Evolution and Salt Precipitation Regulation Mechanism in Fire Flooding Reservoirs Based on Multi-field Coupling of Thermal-Flow-Solid-Chemical(No.52274039)Xi’an Shiyou University Youth Scientific Research and Innovation Team Operation Funds in 2018 Flow Mechanism of Complex Reservoirs and High Efficiency Development and Oil Production Technology(No.115080020).
文摘Horizontal well-stimulation is the key to unconventional resource exploration and development.The development mode of the well plant helps increase the stimulated reservoir volume.Nevertheless,fracture interference between wells reduces the fracturing effect.Here,a 2D hydro-mechanical coupling model describing hydraulic fracture(HF)propagation is established with the extended finite element method,and the effects of several factors on HF propagation during multiple wells fracturing are analyzed.The results show that with an increase in elastic modulus,horizontal principal stress difference and injection fluid displacement,the total fracture area and the reservoir stimulation efficiency are both improved in all three fracturing technologies.After a comparison of the three technologies,the method of improved zipper fracturing is proposed,which avoids mutual interference between HFs,and the reservoir stimulation effect is improved significantly.The study provides guidance for optimizing the fracturing technology of multiple horizontal wells.
文摘In this paper, the Chang 2 reservoir in Zichang Area of Ordos Basin, the second largest sedimentary basin in China, is classified and evaluated by using logging and core data, thin section identification and electron microscopy. The main sedimentary microfacies of Chang 2<sub>1</sub><sup>3</sup> is braided river delta sedimentary system in geological history, and there are three main sedimentary microfacies types: swamp microfacies, distributary channel microfacies and natural embankment microfacies on land. The heterogeneity in the study area is as follows: Chang 2<sub>1</sub><sup>2</sup> formation has the strongest heterogeneity, followed by Chang 2<sub>1</sub><sup>1</sup> formation with strong heterogeneity, and finally Chang 2<sub>1</sub><sup>3</sup> formation with medium heterogeneity. The reservoirs of Chang 2 member in the study area are dominated by III<sub>a</sub>, II<sub>b</sub> and III<sub>b</sub>, and the reservoirs are mainly composed of ultra-low porosity and low permeability reservoirs and low porosity and low permeability reservoirs.
基金Project supported by the National Natural Science Foundation of China(Grant No.11572259)the Program for International Cooperation and Exchanges of Shaanxi Province,China(Grant No.2016KW-049)+1 种基金the Natural Science Foundation of Shaanxi Province,China(Grant No.2019JQ-827)the Scientific Research Program Funded by Shaanxi Provincial Education Department,China(Grant No.19JK0672).
文摘Tensile behaviors of Ti/Ni nanolaminate with model-I crack are investigated by molecular dynamics simulations.The Ti/Ni nanolaminates with center crack either in Ti layer or in Ni layer under different loading directions are utilized to systematically study the mechanical performance of the cracked material.The results indicate that pre-existing crack dramatically changes the plastic deformation mechanism of the Ti/Ni nanolaminate.Unlike the initial plastic deformation originating from the interface or weak Ti layer of the crack-free samples,the plastic behavior of cracked Ti/Ni nanolaminate first occurs at the crack tip due to the local stress concentration.Subsequent plastic deformation is dominated by the interaction between the crack and interface.The Ti/Ni interface not only impedes the movement of the initial plastic deformation carriers(dislocation,slip band,and deformation twinning)from the crack tip,but also promotes the movement of interfacial dislocations in the tension process.Microstructure evolution analysis further confirms that the plastic deformation mechanism transition is ascribed to the orientation-dependent tensile behavior at the crack tip,which is intrinsically attributed to the anisotropy of the certain crystal structure and loading direction of the cracked Ti/Ni nanolaminate.In addition,by analyzing the effects of different plastic deformation carriers on crack propagation in specific crystal,it can be discovered that the interfacial dislocations moving towards the crack tip can further promote the crack growth.
文摘With the implementation of the strategy for Chinese international promotion,the diversified social development needs are constantly adjusting the direction of Chinese education promotion,onefold course setting can no longer meet the increasingly abundant practical needs of Chinese.In order to make Chinese education and teaching in Cambodia better,it is necessary to analyze and evaluate the setting of Chinese courses in colleges and universities from the perspectives of social-based value orientation,and reform the relevant Chinese curriculum by developing special-purpose Chinese courses,filling in the gaps in cultural courses,and adding courses to cultivate students'innovative thinking and scientific spirit.
文摘In the novel White Deer Plain,Chen Zhongshi profoundly narrated the tragic fate of the survival of the image of Chinese women,revealed the social status,inner world and character characteristics of women in Chinese traditional culture,and explained the tragic root of the survival of Chinese women from the Chinese cultural level.About the description of the characters,Tian Xiao’e was deeper to touch the depths of human nature affection Aaron and reason of conflict,touched the moral self and human self in a culture of conflict,so that the survival of female tragic signs of the novel has a wider significance and general significance.In this article,the author takes Tian Xiao’e as the example,to analyze this typical characteristic from the angle of the female tragedy semiotics in multi-dimensional interpretation of the characters.It is not only has practical significance for gender ethics construction,also has the vital significance to our mind world and the cultural construction today.
基金the financial support from the Graduate Student Innovation and Practical Ability Training Program of Xi’an Shiyou University (No. YCS21212111)Open Fund Project of the State Key Laboratory of Heavy Oil, China (SKLHOP201703)+3 种基金National Natural Science Foundation of China (No. 52274039)Natural Science Foundation of Shaanxi Provincial Department of Education (Grant 2023-JC-YB-414)Natural Science Foundation of Shaanxi Province in China (No. 2022JZ-28)the Open Fund Project of the National Oil Shale Exploitation Research and Development Center, China (No. 33550022-ZC0613-0255)
文摘To obtain high yields of monocyclic aromatic hydrocarbons with methyl side chains,such as toluene and xylene,methane(CH_(4))can be introduced into the hydrocracking of polycyclic aromatic hydrocarbons.CH_(4)can participate in the reaction,supply methyl side chains to the product,and improve product distribution.In this study,the hydrogenation reaction of polycyclic aromatic hydrocarbons over a carbonized NiMo/Hβcatalyst in a CH_(4)and hydrogen(H_(2))environment was investigated to study the promotional effect of CH_(4)on the hydrocracking of polycyclic aromatics.Under conditions of 3.5 MPa,380℃,volume air velocity of 4 h^(-1),gas-oil volume ratio of 800,and H_(2):CH_(4)molar ratio of 1:1,the conversion rate of naphthalene was 99.97%,the liquid phase yield was 93.62%,and the selectivity of BTX were 17.76%,25.17%,and 20.47%,respectively.In comparison to the use of a H_(2)atmosphere,the selectivity of benzene was significantly decreased,whereas the selectivity of toluene and xylene were increased.It was shown that CH_(4)can participate in the hydrocracking of naphthalene and improve the selectivity of toluene and xylene in the liquid product.The carbonized NiMo/Hβcatalyst was characterized by a range of analytical methods(such as X-ray diffraction(XRD),ammonia-temperature-programmed desorption(NH3-TPD),hydrogen-temperature-programmed reduction(H_(2)-TPR),and X-ray photoelectron spectroscopy(XPS)).The results indicated that Ni and Mo carbides were the major species in the carbonized NiMo/Hβcatalyst and were considered to be active sites for the activation of CH_(4)and H_(2).After loading the metal components,the catalyst displayed prominent weak acidic sites,which may be suitable locations for cracking,alkylation,and other related reactions.Therefore,the carbonized NiMo/Hβcatalyst displayed multiple functions during the hydrocracking of polycyclic aromatic hydrocarbons in a CH_(4)and H_(2)environment.These results could be used to develop a new way to efficiently utilize polycyclic aromatic hydrocarbons and natural gas resources.
基金supported by the Natural Science Basic Research Program of Shaanxi,China(Nos.2022JQ-305 and2022JQ-326)the Qin Chuang Yuan Platform High-Level Talent Project of Innovation and Entrepreneurship(No.QCYRCXM-2023-020)。
文摘Mg-Zn-Ca-Mn series alloys are developed as promising candidates of 5G communication devices with excellent thermal conductivities,great ductility,and acceptable strength.In present paper,Mg-x Zn-0.4Ca-0.2Mn(x=2wt%,4wt%,6wt%)alloys were prepared by a near-solidus extrusion and the effect of Zn content on mechanical and thermal properties were investigated.The results showed that the addition of minor Ca led to the formation of Ca_(2)Mg_(6)Zn_(3) eutectic phase at grain boundaries.A type of bimodal microstructure occurred in the as-extruded alloys,where elongated coarse deformed grains were embedded in refined recrystallized grains matrix.Correspondingly,both yield strength and ductility of the alloys were significantly enhanced after extrusion due to the great grain refinement.Specially,higher Zn content led to the increment in yield strength and a slight reduction in elongation due to the larger fractions of second phase particles.The room temperature thermal conductivity of as-extruded alloys was also improved compared with that of as-cast counterparts.The increment of Zn content decreased the thermal conductivity of both as-cast and as-extruded alloys,which was due to the increased second phase fraction and solution atoms in the matrix,that hindering the motion of electrons.The as-extruded Mg-2Zn-0.4Ca-0.2Mn(wt%)alloy exhibited the highest elongation of 27.7% and thermal conductivity of 139.2 W/(m·K),combined with an acceptable ultimate tensile strength of 244.0 MPa.The present paper provides scientific guidance for the preparation of lightweight materials with high ductility and high thermal conductivity.
基金The National Natural Science Foundation of China under contract No.42202157the China National Offshore Oil Corporation Co.,Ltd.Major Production and Scientific Research Program under contract No.2019KT-SC-22。
文摘Dissolution mechanism and favorable reservoir distribution prediction are the key problems restricting oil and gas exploration in deep-buried layers.In this paper,the Enping Formation and Zhuhai Formation in Baiyun Sag of South China Sea was taken as a target.Based on the thin section,scanning electron microscopy,X-ray diffraction,porosity/permeability measurement,and mercury injection,influencing factors of dissolution were examined,and a dissolution model was established.Further,high-quality reservoirs were predicted temporally and spatially.The results show that dissolved pores constituted the main space of the Paleogene sandstone reservoir.Dissolution primarily occurred in the coarse-and medium-grained sandstones in the subaerial and subaqueous distributary channels,while dissolution was limited in fine-grained sandstones and inequigranular sandstones.The main dissolved minerals were feldspar,tuffaceous matrix,and diagenetic cement.Kaolinization of feldspar and illitization of kaolinite are the main dissolution pathways,but they occur at various depths and temperatures with different geothermal gradients.Dissolution is controlled by four factors,in terms of depositional facies,source rock evolution,overpressure,and fault activities,which co-acted at the period of 23.8–13.8 Ma,and resulted into strong dissolution.Additionally,based on these factors,high-quality reservoirs of the Enping and Zhuhai formations are predicted in the northern slope,southwestern step zone,and Liuhua uplift in the Baiyun Sag.
基金the Natural Science Basic Research Program of Shaanxi(Program No.2023-JC-YB-351)the Scientific Research Program Funded by the Shaanxi Provincial Education Department(Program No.20JS118)the Xi’an Shiyou University Graduate Innovation and Practice Ability Training Plan(YCS21212097,YCS21212092).
文摘Traditional microstructure scale parameters have difficulty describing the structure and distribution of a roughmaterial’s surface morphology comprehensively and quantitatively. This study constructs hydrophilic and underwateroleophobic surfaces based on polyvinylidene fluoride (PVDF) using a chemical modification method, and the fractaldimension and multifractal spectrum are used to quantitatively characterize the microscopic morphology. A new contactangle prediction model for underwater oleophobic surfaces is established. The results show that the fractal dimension ofthe PVDF surface first increases and then decreases with the reaction time. The uniformity characterized by the multifractalspectrum was generally consistent with scanning electron microscope observations. The contact angle of water droplets onthe PVDF surface is negatively correlated with the fractal dimension, and oil droplets in water are positively correlated.When the fractal dimension is 2.0975, the new contact angle prediction model has higher prediction accuracy. Themaximum and minimum relative deviations of the contact angle between the theoretical and measured data are 18.20%and 0.72%, respectively. For water ring transportation, the larger the fractal dimension and spectral width of the materialsurface, the smaller the absolute value of the spectral difference, the stronger the hydrophilic and oleophobic properties, andthe better the water ring transportation stability.