Climate change has been a matter of discourse for the last several decades. Much research has been conducted regarding the causes and impacts of climate change around the world. The current research contributes to the...Climate change has been a matter of discourse for the last several decades. Much research has been conducted regarding the causes and impacts of climate change around the world. The current research contributes to the knowledge of the influence of climate change on our environment, with emphasis on earthquake occurrences in the region of Indonesia. Using global temperature anomaly as a measure of climate change, and earthquake data in Indonesia for the period 1900-2022, the paper seeks to find a relationship (if any) between the two variables. Statistical methods used include normal distribution analysis, linear regression and correlation test. The results show peculiar patterns in the progression of earthquake occurrences as well as global temperature anomaly occurring in the same time periods. The findings also indicated that the magnitudes of earthquakes remained unaffected by global temperature anomalies over the years. Nonetheless, there appears to be a potential correlation between temperature anomalies and the frequency of earthquake occurrences. As per the results, an increase in temperature anomaly is associated with a higher frequency of earthquakes.展开更多
During subway operation,various factors will cause long-term land subsidence,such as the vibration subsidence of foundation soil caused by train vibration load,incomplete consolidation deformation of foundation soil d...During subway operation,various factors will cause long-term land subsidence,such as the vibration subsidence of foundation soil caused by train vibration load,incomplete consolidation deformation of foundation soil during tunnel construction,dense buildings and structures in the vicinity of the tunnel,and changes in water level in the stratum where the tunnel is located.The monitoring of long-term land subsidence during subway operation in high-density urban areas differs from that in low-density urban construction areas.The former is the gathering point of the entire urban population.There are many complex buildings around the project,busy road traffic,high pedestrian flow,and less vegetation cover.Several existing items requiremonitoring.However,monitoring distance is long,and providing early warning is difficult.This study uses the 2.8 km operation line between Wulin Square station and Ding’an Road station of Hangzhou Subway Line 1 as an example to propose the integrated method of DInSAR-GPS-GIS technology and the key algorithm for long-term land subsidence deformation.Then,it selects multiscene image data to analyze long-termland subsidence of high-density urban areas during subway operation.Results show that long-term land subsidence caused by the operation of Wulin Square station to Ding’an Road station of Hangzhou Subway Line 1 is small,with maximumsubsidence of 30.64 mm,and minimumsubsidence of 11.45 mm,and average subsidence ranging from 19.27 to 21.33 mm.And FLAC3D software was used to verify the monitoring situation,using the geological conditions of the soil in the study area and the tunnel profile to simulate the settlement under vehicle load,and the simulation results tended to be consistent with the monitoring situation.展开更多
To study the dynamic mechanical properties of tuff under different environmental conditions,the tuff from an ancient quarry in Shepan Island was prepared.The impact damage to the rock was tested using a triaxial dynam...To study the dynamic mechanical properties of tuff under different environmental conditions,the tuff from an ancient quarry in Shepan Island was prepared.The impact damage to the rock was tested using a triaxial dynamic impact mechanical testing system(TDIMTS)with different ground stresses,temperatures,and groundwater pressures.The time-strain relationship,dynamic stress-strain relationship,energy dissipation law,energy-peak strain relationship,and the impact damage pattern of the tuff specimens under impact air pressures were investigated.The TDIMTS experiment on ancient underground rock mass under impact loading was also simulated using the finite element analysis software LS-DYNA based on the Holmquist-Johnson-Cook(HJC)material model.The dynamic failure process,failure pattern and peak stress of tuff specimen were calculated.The simulation results obtained using the above methods were in good agreement with the experimental results.The results of the dynamic experiment show that with the same local stress,groundwater pressure,and temperature,the damage to the tuff specimens caused by blasting and quarrying disturbances gradually increases as the impact pressure increases.Under the same local stress,groundwater pressure,and temperature,the energy required to rupture the tuffs in ancient underground caverns is relatively small if the impact pressure is low accordingly,but as the impact pressure increases,the damage to the tuff caused by quarrying disturbance gradually increases.The damage gradually increases and the degree of damage to the tuff and the strain energy exhibit asymptotic growth when the tuff specimens are subjected to the greater strain energy,increasing the degree of rupturing of the tuff.In addition,the average crushing size decreases with increasing strain energy.By comparing the simulation results with the experimental results,it was found that the HJC model reflected the dynamic impact performance of tuff specimen,and the simulation results showed an evident strain rate effect.These results of this study can offer some guidance and theoretical support for the stability evaluation,protection,and safe operation of the ancient underground caverns in future.展开更多
Let C be the familiar class of normalized close-to-convex functions in the unit disk.In[17],Koepf demonstrated that,as to a function■in the class C,■By applying this inequality,it can be proven that‖a3|-|a2‖≤1 fo...Let C be the familiar class of normalized close-to-convex functions in the unit disk.In[17],Koepf demonstrated that,as to a function■in the class C,■By applying this inequality,it can be proven that‖a3|-|a2‖≤1 for close-to-convex functions.Now we generalized the above conclusions to a subclass of close-to-starlike mappings defined on the unit ball of a complex Banach space.展开更多
In this paper,the authors consider theω-type Calder´on-Zygmund operator T_(ω)and the commutator[b,T_(ω)]generated by a symbol function b on the Lorentz space L^(p,r)(X)over the homogeneous space(X,d,μ).The bo...In this paper,the authors consider theω-type Calder´on-Zygmund operator T_(ω)and the commutator[b,T_(ω)]generated by a symbol function b on the Lorentz space L^(p,r)(X)over the homogeneous space(X,d,μ).The boundedness and the compactness of the commutator[b,T_(ω)]on Lorentz space L^(p,r)(X)are founded for any p∈(1,∞)and r∈[1,∞).展开更多
We focus on the effect of ionic radius of lanthanides and the number of electrons in 4f orbitals on the superconducting temperature in 12442-type iron-based superconductors RbLn_(2)Fe_(4)As_(4)O_(2)(Ln=Sm and Ho).Elec...We focus on the effect of ionic radius of lanthanides and the number of electrons in 4f orbitals on the superconducting temperature in 12442-type iron-based superconductors RbLn_(2)Fe_(4)As_(4)O_(2)(Ln=Sm and Ho).Electronic properties of RbSm_(2)Fe_(4)As_(4)O_(2) and RbHo2Fe4As4O2with the largest differences of ionic radii and numbers of electrons in 4f orbital,and the largest difference of superconducting temperatures by using firstprinciples calculations.We predict that the ground state of RbLn_(2)Fe_(4)As_(4)O_(2) is spin-density-wave-type in-plane striped antiferromagnet,and the magnetic moment around each Fe atom is about 2μB.RbSm_(2)Fe_(4)As_(4)O_(2)has a great influence on the energy band near theΓpoint,and a Dirac-like dispersion energy band appears.This band is mainly contributed by the dz2orbital of Fe,which proves that RbSm_(2)Fe_(4)As_(4)O_(2)has a stronger threedimensionality.At the same time,this extra Fermi surface appears at theΓpoint,which also shows that Sm can effectively enhance the coupling strength within Fe2As2bilayers.This is also confirmed by the charge density differenceρ(RbHo_(2)Fe_(4)As_(4)O_(2))-ρ(RbSm_(2)Fe_(4)As_(4)O_(2)).It increases the internal coupling strength of the bilayer Fe_(2)As2layers,which in turn leads to a higher Tcof RbSm_(2)Fe_(4)As_(4)O_(2)than RbHo_(2)Fe_(4)As_(4)O_(2).Determining the details of their electronic structure,which may be closely related to superconductivity,is crucial to understanding the underlying mechanism.Such microscopic studies provide useful clues for our further research of other hightemperature superconductors.展开更多
Amine transaminases(ATAs)catalyze the asymmetric amination of prochiral ketones or aldehydes to their corresponding chiral amines.However,the trade-off between activity and stability in enzyme engineering represents a...Amine transaminases(ATAs)catalyze the asymmetric amination of prochiral ketones or aldehydes to their corresponding chiral amines.However,the trade-off between activity and stability in enzyme engineering represents a major obstacle to the practical application of ATAs.Overcoming this trade-off is important for developing robustly engineered enzymes and a universal approach for ATAs.Herein,we modified the binding pocket of co-ATA from Aspergillus terreus(AtATA)to identify the key amino acid residues controlling the activity and stability of AtATA toward 1-acetonaphthone.We discovered a structural switch comprising four key amino acid sites(R128,V149,L182,and L187),as well as the"best"mutant(AtATAD224K/V149A/L182 F/L187F;termed M4).Compared to the parent enzyme AtATAD224K(AtATAPa),M4 increased the catalytic efficiency(k_(cat)/K_(m)^(1-acetonaphthone),where kcatis the constant of catalytic activities and is 10.1 min^(-1),K_(m)^(1-acetonaphthoneis) Michaelis-Menten constant and is 1.7 mmol·L^(-1))and half-life(t1/2)by 59-fold to 5.9 L·min^(-1)·mmol-1and by 1.6-fold to 46.9 min,respectively.Moreover,using M4 as the biocatalyst,we converted a 20 mmol·L^(-1)aliquot of 1-acetonaphthone in a 50 mL scaled-up system to the desired product,(R)-(+)-1(1-naphthyl)ethylamine((R)-NEA),with 78%yield and high enantiomeric purity(R>99.5%)within 10 h.M4 also displayed significantly enhanced activity toward various 1-acetonaphthone analogs.The related structural properties derived by analyzing structure and sequence information of robust ATAs illustrated their enhanced activity and thermostability.Strengthening of intramolecular interactions and expansion of the angle between the substratebinding pocket and the pyridoxal 5’-phosphate(PLP)-binding pocket contributed to synchronous enhancement of ATA thermostability and activity.Moreover,this pocket engineering strategy successfully transferred enhanced activity and thermostability to three other ATAs,which exhibited 8%-22%sequence similarity with AtATA.This research has important implications for overcoming the trade-off between ATA activity and thermostability.展开更多
Calcium silicate hydrate(C-S-H)is the mainly strength source of cement-based materials,but there is little basic research.In this paper,molecular dynamics method is applied to analyze the multi-scale tensile strength ...Calcium silicate hydrate(C-S-H)is the mainly strength source of cement-based materials,but there is little basic research.In this paper,molecular dynamics method is applied to analyze the multi-scale tensile strength and tensile strain of C-S-H layered materials under the condition of external physical fields(temperature and strain rate).The results show that the tensile strength and strain of C-S-H model decrease with temperature raises.The temperature(from 1 K to 600 K)has obvious influence on the tensile strain and strength of C-S-H layered materials.In addition,at(0.00025 ps^(-1)-0.001 ps^(-1)),the tensile strain and strength of C-S-H layered materials are less sensitive to strain rate.The whole model is closer to a 3-dimensional deformation.However,at(0.001 ps^(-1)-0.005 ps^(-1)),the dynamic load effect begins to increase,and the work done by the load per unit time increased.The tensile strain and strength of C-S-H layered materials indicates intensified by the change of strain rate.The energies are randomly distributed in the system,not concentrated in a certain area.展开更多
The tangential k-Cauchy-Fueter operator and k-CF functions are counterparts of the tangential Cauchy–Riemann operator and CR functions on the Heisenberg group in the theory of several complex variables,respectively.I...The tangential k-Cauchy-Fueter operator and k-CF functions are counterparts of the tangential Cauchy–Riemann operator and CR functions on the Heisenberg group in the theory of several complex variables,respectively.In this paper,we introduce a Lie group that the Heisenberg group can be imbedded into and call it generalized complex Heisenberg.We investigate quaternionic analysis on the generalized complex Heisenberg.We also give the Penrose integral formula for k-CF functions and construct the tangential k-Cauchy-Fueter complex.展开更多
Understanding the topographic patterns of the seafloor is a very important part of understanding our planet.Although the science involved in bathymetric surveying has advanced much over the decades,less than 20%of the...Understanding the topographic patterns of the seafloor is a very important part of understanding our planet.Although the science involved in bathymetric surveying has advanced much over the decades,less than 20%of the seafloor has been precisely modeled to date,and there is an urgent need to improve the accuracy and reduce the uncertainty of underwater survey data.In this study,we introduce a pretrained visual geometry group network(VGGNet)method based on deep learning.To apply this method,we input gravity anomaly data derived from ship measurements and satellite altimetry into the model and correct the latter,which has a larger spatial coverage,based on the former,which is considered the true value and is more accurate.After obtaining the corrected high-precision gravity model,it is inverted to the corresponding bathymetric model by applying the gravity-depth correlation.We choose four data pairs collected from different environments,i.e.,the Southern Ocean,Pacific Ocean,Atlantic Ocean and Caribbean Sea,to evaluate the topographic correction results of the model.The experiments show that the coefficient of determination(R~2)reaches 0.834 among the results of the four experimental groups,signifying a high correlation.The standard deviation and normalized root mean square error are also evaluated,and the accuracy of their performance improved by up to 24.2%compared with similar research done in recent years.The evaluation of the R^(2) values at different water depths shows that our model can achieve performance results above 0.90 at certain water depths and can also significantly improve results from mid-water depths when compared to previous research.Finally,the bathymetry corrected by our model is able to show an accuracy improvement level of more than 21%within 1%of the total water depths,which is sufficient to prove that the VGGNet-based method has the ability to perform a gravity-bathymetry correction and achieve outstanding results.展开更多
The "Zhejiang spirit" refers to a theoretical summary of the group consciousness, mental state, value orientation and ideological realm, which is, as a motivating power, owned and recognized by all Zhejiang ...The "Zhejiang spirit" refers to a theoretical summary of the group consciousness, mental state, value orientation and ideological realm, which is, as a motivating power, owned and recognized by all Zhejiang people, and carries Zhejiang peculiarities. President Xi Jinping, during his term of office in Zhejiang, launched a number of seminars and activities to seek "a Zhejiang spirit that moves with the times." Forty years of reform and opening-up, the "Zhejiang spirit" has experienced an evolution that can be summarized as three improvements: from spontaneous formation to deliberate cultivation, from something limited to eastern Zhejiang to an integrating force that spans the entire Zhejiang Province, and from a mere existence to a role that functions adequately. The "Zhejiang spirit" is extracted from the humanistic spirits shaped in all corners of Zhejiang province. It is "an instrumental ensemble played across the entire province," and represents a certain judgment and interpretation. The "Zhejiang spirit" not only describes and summarizes the past and present, but will also guide and motivate the future, and support people in their enterprising and industrious practices to move with the times.展开更多
The spatial interaction model is an effective way to explore the geographical disparities inherent in the Belt and Road Initiative(BRI) by simulating spatial flows. The traditional gravity model implies the hypothesis...The spatial interaction model is an effective way to explore the geographical disparities inherent in the Belt and Road Initiative(BRI) by simulating spatial flows. The traditional gravity model implies the hypothesis of equilibrium points without any reference to when or how to achieve it. In this paper, a dynamic gravity model was established based on the Maximum Entropy(MaxEnt) theory to estimate and monitor the interconnection intensity and dynamic characters of bilateral relations. In order to detect the determinants of interconnection intensity, a Geodetector method was applied to identify and evaluate the determinants of spatial networks in five dimensions. The empirical study clearly demonstrates a heterogeneous and non-circular spatial structure. The main driving forces of spatial-temporal evolution are foreign direct investment, tourism and railway infrastructure construction, while determinants in different sub-regions show obvious spatial differentiation. Southeast Asian countries are typically multi-island area where aviation infrastructure plays a more important role. North and Central Asian countries regard oil as a pillar industry where power and port facilities have a greater impact on the interconnection. While Western Asian countries are mostly influenced by the railway infrastructure, Eastern European countries already have relatively robust infrastructure where tariff policies provide a greater impetus.展开更多
An expansion theory of spherical cavities in strain-softening materials with different moduli of tension and com-pression was presented. For geomaterials,two controlling parameters were introduced to take into account...An expansion theory of spherical cavities in strain-softening materials with different moduli of tension and com-pression was presented. For geomaterials,two controlling parameters were introduced to take into account the different moduli and strain-softening properties. By means of elastic theory with different moduli and stress-softening models,general solutions cal-culating Tresca and Mohr-Coulomb materials' stress and displacement fields of expansion of spherical cavity were derived. The effects caused by different elastic moduli in tensile and compression and strain-softening rates on stress and displacement fields and development of plastic zone of expansion of cavity were analyzed. The results show that the ultimate expansion pressure,stress and displacement fields and development of plastic zone vary with the different elastic moduli and strain-softening prop-erties. If classical elastic theory is adopted and strain-softening properties are neglected,rather large errors may be the result.展开更多
Production of chemicals and fuels from microcrystalline cellulose has inspired scholars’ attention. Deactivation of metallic catalysts including acid leaching and hydrothermal aggregation is still one of the core iss...Production of chemicals and fuels from microcrystalline cellulose has inspired scholars’ attention. Deactivation of metallic catalysts including acid leaching and hydrothermal aggregation is still one of the core issues in these systems. To address these problems, we designed and fabricated a series of Ni-W/SiO2 catalysts, which were decorated by CxNy species using C-and N- sources and applied in cellulose conversion to C2,3 oxygenated compounds. The Ni-W/SiO2@CxNy catalysts, underwent complexing and selfassembling process, exhibited special heterojunctions, accompanying strong interactions mainly among Ni phase and CxNy layers. Catalytic results showed that the heterojunctions and outer CxNy layers extensively enhanced productions of hydroxyacetone(HDA) and ethylene glycol(EG) and promoted the hydrothermal stability through prospering in concentration of Lewis pairs from Ni–N—N structure and immobilizing the metallic nanoclusters. 48.25% of EG was yielded under 5.0 MPa H2 pressurized 240 ℃ water for 2.0 h. The Lewis pair further improved the formation of HDA with 20.92% yield. High hydrothermal stability of NiW/SiO2@CxNy catalyst was proved according to the recycling results and trace leaching concentration of Ni and W. This construction of metallic catalysts exploited a new strategy to manufacture extraordinary durability of metallic nanoclusters for cellulose conversion under harsh reaction conditions.展开更多
In this article, first, we establish the Fekete and Szeg inequality for an interesting subclass of biholomorphic functions in the open unit disk U. Second, we generalize this result to the bounded starlike circular do...In this article, first, we establish the Fekete and Szeg inequality for an interesting subclass of biholomorphic functions in the open unit disk U. Second, we generalize this result to the bounded starlike circular domain in C^n. The proofs of these results use some restrictive assumptions, which in the case of one complex variable are automatically satisfied.展开更多
The Co-based catalysts were prepared with different cobalt acetate solutions. Effects of p H value were studied deeply on Fischer–Tropsch synthesis(FTS) through a semi-batch reactor. Among all impregnation solutions(...The Co-based catalysts were prepared with different cobalt acetate solutions. Effects of p H value were studied deeply on Fischer–Tropsch synthesis(FTS) through a semi-batch reactor. Among all impregnation solutions(water, butanol, amyl alcohol, acetic acid, nitric acid and ammonium nitrate), the catalyst prepared by NH_4NO_3 solution showed the highest catalytic activity due to its small particle size and high reduction degree. However, the catalyst with the smallest particle size derived from water as impregnation solution exhibited low activity as well as high methane selectivity since it was difficult to be reduced and inactive in FTS. According to FT-IR spectra results, the low intensity of absorbed CO on the catalyst prepared from water solution resulted in low FTS activity. Whereas, the high activity of catalysts prepared from NH_4NO_3 solution could be explained by the high intensity of absorbed CO on the catalysts.The cobalt species on the catalysts prepared under lower p H conditions exhibited smaller particle size distribution as well as lower CO conversion than those prepared at higher p H value.展开更多
The initial-boundary value problem for a class of nonlinear hyperbolic equations system in bounded domain is studiedThe existence of global solutions for this problem is proved by constructing a stable set, and obtain...The initial-boundary value problem for a class of nonlinear hyperbolic equations system in bounded domain is studiedThe existence of global solutions for this problem is proved by constructing a stable set, and obtain the asymptotic stability of global solutions by means of a difference inequality.展开更多
文摘Climate change has been a matter of discourse for the last several decades. Much research has been conducted regarding the causes and impacts of climate change around the world. The current research contributes to the knowledge of the influence of climate change on our environment, with emphasis on earthquake occurrences in the region of Indonesia. Using global temperature anomaly as a measure of climate change, and earthquake data in Indonesia for the period 1900-2022, the paper seeks to find a relationship (if any) between the two variables. Statistical methods used include normal distribution analysis, linear regression and correlation test. The results show peculiar patterns in the progression of earthquake occurrences as well as global temperature anomaly occurring in the same time periods. The findings also indicated that the magnitudes of earthquakes remained unaffected by global temperature anomalies over the years. Nonetheless, there appears to be a potential correlation between temperature anomalies and the frequency of earthquake occurrences. As per the results, an increase in temperature anomaly is associated with a higher frequency of earthquakes.
基金financial supports for this research project by the National Natural Science Foundation of China(Nos.41602308,41967037)supported by Zhejiang Provincial Natural Science Foundation of China under Grant No.LY20E080005+1 种基金funded by National Key Research and Development Projects of China(No.2019YFC507502)Guangxi Science and Technology Plan Project(No.RZ2100000161).
文摘During subway operation,various factors will cause long-term land subsidence,such as the vibration subsidence of foundation soil caused by train vibration load,incomplete consolidation deformation of foundation soil during tunnel construction,dense buildings and structures in the vicinity of the tunnel,and changes in water level in the stratum where the tunnel is located.The monitoring of long-term land subsidence during subway operation in high-density urban areas differs from that in low-density urban construction areas.The former is the gathering point of the entire urban population.There are many complex buildings around the project,busy road traffic,high pedestrian flow,and less vegetation cover.Several existing items requiremonitoring.However,monitoring distance is long,and providing early warning is difficult.This study uses the 2.8 km operation line between Wulin Square station and Ding’an Road station of Hangzhou Subway Line 1 as an example to propose the integrated method of DInSAR-GPS-GIS technology and the key algorithm for long-term land subsidence deformation.Then,it selects multiscene image data to analyze long-termland subsidence of high-density urban areas during subway operation.Results show that long-term land subsidence caused by the operation of Wulin Square station to Ding’an Road station of Hangzhou Subway Line 1 is small,with maximumsubsidence of 30.64 mm,and minimumsubsidence of 11.45 mm,and average subsidence ranging from 19.27 to 21.33 mm.And FLAC3D software was used to verify the monitoring situation,using the geological conditions of the soil in the study area and the tunnel profile to simulate the settlement under vehicle load,and the simulation results tended to be consistent with the monitoring situation.
基金financial supports for this research project by the National Natural Science Foundation of China(No.41602308)supported by Zhejiang Provincial Natural Science Foundation of China under Grant No.LY20E080005.
文摘To study the dynamic mechanical properties of tuff under different environmental conditions,the tuff from an ancient quarry in Shepan Island was prepared.The impact damage to the rock was tested using a triaxial dynamic impact mechanical testing system(TDIMTS)with different ground stresses,temperatures,and groundwater pressures.The time-strain relationship,dynamic stress-strain relationship,energy dissipation law,energy-peak strain relationship,and the impact damage pattern of the tuff specimens under impact air pressures were investigated.The TDIMTS experiment on ancient underground rock mass under impact loading was also simulated using the finite element analysis software LS-DYNA based on the Holmquist-Johnson-Cook(HJC)material model.The dynamic failure process,failure pattern and peak stress of tuff specimen were calculated.The simulation results obtained using the above methods were in good agreement with the experimental results.The results of the dynamic experiment show that with the same local stress,groundwater pressure,and temperature,the damage to the tuff specimens caused by blasting and quarrying disturbances gradually increases as the impact pressure increases.Under the same local stress,groundwater pressure,and temperature,the energy required to rupture the tuffs in ancient underground caverns is relatively small if the impact pressure is low accordingly,but as the impact pressure increases,the damage to the tuff caused by quarrying disturbance gradually increases.The damage gradually increases and the degree of damage to the tuff and the strain energy exhibit asymptotic growth when the tuff specimens are subjected to the greater strain energy,increasing the degree of rupturing of the tuff.In addition,the average crushing size decreases with increasing strain energy.By comparing the simulation results with the experimental results,it was found that the HJC model reflected the dynamic impact performance of tuff specimen,and the simulation results showed an evident strain rate effect.These results of this study can offer some guidance and theoretical support for the stability evaluation,protection,and safe operation of the ancient underground caverns in future.
基金Supported by the NNSF of China(11971165)the Natural Science Foundation of Zhejiang Province(LY21A010003)。
文摘Let C be the familiar class of normalized close-to-convex functions in the unit disk.In[17],Koepf demonstrated that,as to a function■in the class C,■By applying this inequality,it can be proven that‖a3|-|a2‖≤1 for close-to-convex functions.Now we generalized the above conclusions to a subclass of close-to-starlike mappings defined on the unit ball of a complex Banach space.
基金supported by the NNSF of China(12271483,11961056)the NSF of Jiangxi Province(20192BAB201004)+1 种基金supported by the“Xin-Miao”Program of Zhejiang Province(2021R415027)the Innovation Fund of ZUST(2020yjskc06).
文摘In this paper,the authors consider theω-type Calder´on-Zygmund operator T_(ω)and the commutator[b,T_(ω)]generated by a symbol function b on the Lorentz space L^(p,r)(X)over the homogeneous space(X,d,μ).The boundedness and the compactness of the commutator[b,T_(ω)]on Lorentz space L^(p,r)(X)are founded for any p∈(1,∞)and r∈[1,∞).
基金supported by the National Natural Science Foundation of China(Grant Nos.11904319 and 11974354)the Zhejiang Provincial Natural Science Foundation of China(Grant No.LQ18A040002)。
文摘We focus on the effect of ionic radius of lanthanides and the number of electrons in 4f orbitals on the superconducting temperature in 12442-type iron-based superconductors RbLn_(2)Fe_(4)As_(4)O_(2)(Ln=Sm and Ho).Electronic properties of RbSm_(2)Fe_(4)As_(4)O_(2) and RbHo2Fe4As4O2with the largest differences of ionic radii and numbers of electrons in 4f orbital,and the largest difference of superconducting temperatures by using firstprinciples calculations.We predict that the ground state of RbLn_(2)Fe_(4)As_(4)O_(2) is spin-density-wave-type in-plane striped antiferromagnet,and the magnetic moment around each Fe atom is about 2μB.RbSm_(2)Fe_(4)As_(4)O_(2)has a great influence on the energy band near theΓpoint,and a Dirac-like dispersion energy band appears.This band is mainly contributed by the dz2orbital of Fe,which proves that RbSm_(2)Fe_(4)As_(4)O_(2)has a stronger threedimensionality.At the same time,this extra Fermi surface appears at theΓpoint,which also shows that Sm can effectively enhance the coupling strength within Fe2As2bilayers.This is also confirmed by the charge density differenceρ(RbHo_(2)Fe_(4)As_(4)O_(2))-ρ(RbSm_(2)Fe_(4)As_(4)O_(2)).It increases the internal coupling strength of the bilayer Fe_(2)As2layers,which in turn leads to a higher Tcof RbSm_(2)Fe_(4)As_(4)O_(2)than RbHo_(2)Fe_(4)As_(4)O_(2).Determining the details of their electronic structure,which may be closely related to superconductivity,is crucial to understanding the underlying mechanism.Such microscopic studies provide useful clues for our further research of other hightemperature superconductors.
基金National Natural Science Foundation of China(32071268 and 31971372)the Ningbo"Scientific and Technological Innovation 2025"Key Project(2020Z080)for financial support。
文摘Amine transaminases(ATAs)catalyze the asymmetric amination of prochiral ketones or aldehydes to their corresponding chiral amines.However,the trade-off between activity and stability in enzyme engineering represents a major obstacle to the practical application of ATAs.Overcoming this trade-off is important for developing robustly engineered enzymes and a universal approach for ATAs.Herein,we modified the binding pocket of co-ATA from Aspergillus terreus(AtATA)to identify the key amino acid residues controlling the activity and stability of AtATA toward 1-acetonaphthone.We discovered a structural switch comprising four key amino acid sites(R128,V149,L182,and L187),as well as the"best"mutant(AtATAD224K/V149A/L182 F/L187F;termed M4).Compared to the parent enzyme AtATAD224K(AtATAPa),M4 increased the catalytic efficiency(k_(cat)/K_(m)^(1-acetonaphthone),where kcatis the constant of catalytic activities and is 10.1 min^(-1),K_(m)^(1-acetonaphthoneis) Michaelis-Menten constant and is 1.7 mmol·L^(-1))and half-life(t1/2)by 59-fold to 5.9 L·min^(-1)·mmol-1and by 1.6-fold to 46.9 min,respectively.Moreover,using M4 as the biocatalyst,we converted a 20 mmol·L^(-1)aliquot of 1-acetonaphthone in a 50 mL scaled-up system to the desired product,(R)-(+)-1(1-naphthyl)ethylamine((R)-NEA),with 78%yield and high enantiomeric purity(R>99.5%)within 10 h.M4 also displayed significantly enhanced activity toward various 1-acetonaphthone analogs.The related structural properties derived by analyzing structure and sequence information of robust ATAs illustrated their enhanced activity and thermostability.Strengthening of intramolecular interactions and expansion of the angle between the substratebinding pocket and the pyridoxal 5’-phosphate(PLP)-binding pocket contributed to synchronous enhancement of ATA thermostability and activity.Moreover,this pocket engineering strategy successfully transferred enhanced activity and thermostability to three other ATAs,which exhibited 8%-22%sequence similarity with AtATA.This research has important implications for overcoming the trade-off between ATA activity and thermostability.
基金This work was supported by a Natural Science Foundation of Zhejiang Province(LQ23E080003)Innovative training program for college students.
文摘Calcium silicate hydrate(C-S-H)is the mainly strength source of cement-based materials,but there is little basic research.In this paper,molecular dynamics method is applied to analyze the multi-scale tensile strength and tensile strain of C-S-H layered materials under the condition of external physical fields(temperature and strain rate).The results show that the tensile strength and strain of C-S-H model decrease with temperature raises.The temperature(from 1 K to 600 K)has obvious influence on the tensile strain and strength of C-S-H layered materials.In addition,at(0.00025 ps^(-1)-0.001 ps^(-1)),the tensile strain and strength of C-S-H layered materials are less sensitive to strain rate.The whole model is closer to a 3-dimensional deformation.However,at(0.001 ps^(-1)-0.005 ps^(-1)),the dynamic load effect begins to increase,and the work done by the load per unit time increased.The tensile strain and strength of C-S-H layered materials indicates intensified by the change of strain rate.The energies are randomly distributed in the system,not concentrated in a certain area.
基金Supported by National Nature Science Foundation in China(12101564,11971425,11801508)Nature Science Foundation of Zhejiang province(LY22A010013)Domestic Visiting Scholar Teacher Professional Development Project(FX2021042)。
文摘The tangential k-Cauchy-Fueter operator and k-CF functions are counterparts of the tangential Cauchy–Riemann operator and CR functions on the Heisenberg group in the theory of several complex variables,respectively.In this paper,we introduce a Lie group that the Heisenberg group can be imbedded into and call it generalized complex Heisenberg.We investigate quaternionic analysis on the generalized complex Heisenberg.We also give the Penrose integral formula for k-CF functions and construct the tangential k-Cauchy-Fueter complex.
基金The National Key R&D Program of China under contract Nos 2022YFC3003800,2020YFC1521700 and 2020YFC1521705the National Natural Science Foundation of China under contract No.41830540+3 种基金the Open Fund of the East China Coastal Field Scientific Observation and Research Station of the Ministry of Natural Resources under contract No.OR-SECCZ2022104the Deep Blue Project of Shanghai Jiao Tong University under contract No.SL2020ZD204the Special Funding Project for the Basic Scientific Research Operation Expenses of the Central Government-Level Research Institutes of Public Interest of China under contract No.SZ2102the Zhejiang Provincial Project under contract No.330000210130313013006。
文摘Understanding the topographic patterns of the seafloor is a very important part of understanding our planet.Although the science involved in bathymetric surveying has advanced much over the decades,less than 20%of the seafloor has been precisely modeled to date,and there is an urgent need to improve the accuracy and reduce the uncertainty of underwater survey data.In this study,we introduce a pretrained visual geometry group network(VGGNet)method based on deep learning.To apply this method,we input gravity anomaly data derived from ship measurements and satellite altimetry into the model and correct the latter,which has a larger spatial coverage,based on the former,which is considered the true value and is more accurate.After obtaining the corrected high-precision gravity model,it is inverted to the corresponding bathymetric model by applying the gravity-depth correlation.We choose four data pairs collected from different environments,i.e.,the Southern Ocean,Pacific Ocean,Atlantic Ocean and Caribbean Sea,to evaluate the topographic correction results of the model.The experiments show that the coefficient of determination(R~2)reaches 0.834 among the results of the four experimental groups,signifying a high correlation.The standard deviation and normalized root mean square error are also evaluated,and the accuracy of their performance improved by up to 24.2%compared with similar research done in recent years.The evaluation of the R^(2) values at different water depths shows that our model can achieve performance results above 0.90 at certain water depths and can also significantly improve results from mid-water depths when compared to previous research.Finally,the bathymetry corrected by our model is able to show an accuracy improvement level of more than 21%within 1%of the total water depths,which is sufficient to prove that the VGGNet-based method has the ability to perform a gravity-bathymetry correction and achieve outstanding results.
基金a milestone achievement of the Philosophy and Social Science Planning Project of Zhejiang Province(13JDZT02YB)
文摘The "Zhejiang spirit" refers to a theoretical summary of the group consciousness, mental state, value orientation and ideological realm, which is, as a motivating power, owned and recognized by all Zhejiang people, and carries Zhejiang peculiarities. President Xi Jinping, during his term of office in Zhejiang, launched a number of seminars and activities to seek "a Zhejiang spirit that moves with the times." Forty years of reform and opening-up, the "Zhejiang spirit" has experienced an evolution that can be summarized as three improvements: from spontaneous formation to deliberate cultivation, from something limited to eastern Zhejiang to an integrating force that spans the entire Zhejiang Province, and from a mere existence to a role that functions adequately. The "Zhejiang spirit" is extracted from the humanistic spirits shaped in all corners of Zhejiang province. It is "an instrumental ensemble played across the entire province," and represents a certain judgment and interpretation. The "Zhejiang spirit" not only describes and summarizes the past and present, but will also guide and motivate the future, and support people in their enterprising and industrious practices to move with the times.
基金This project is supported by Provincial Basic Science Research Foundation of Hunan, China(No.02-jxz3011)Research Foundation of Railway Department, China(No.J98Z102).
基金Supported by the National'Naturai Science Foundation of China (30970638, 21176220 and 31240054), Zhejiang Provincial Natural Science Foundation (Z13B06008) and the National Basic Research Program of China (2007CB714305).
基金the auspices of A Category of Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA20010101)。
文摘The spatial interaction model is an effective way to explore the geographical disparities inherent in the Belt and Road Initiative(BRI) by simulating spatial flows. The traditional gravity model implies the hypothesis of equilibrium points without any reference to when or how to achieve it. In this paper, a dynamic gravity model was established based on the Maximum Entropy(MaxEnt) theory to estimate and monitor the interconnection intensity and dynamic characters of bilateral relations. In order to detect the determinants of interconnection intensity, a Geodetector method was applied to identify and evaluate the determinants of spatial networks in five dimensions. The empirical study clearly demonstrates a heterogeneous and non-circular spatial structure. The main driving forces of spatial-temporal evolution are foreign direct investment, tourism and railway infrastructure construction, while determinants in different sub-regions show obvious spatial differentiation. Southeast Asian countries are typically multi-island area where aviation infrastructure plays a more important role. North and Central Asian countries regard oil as a pillar industry where power and port facilities have a greater impact on the interconnection. While Western Asian countries are mostly influenced by the railway infrastructure, Eastern European countries already have relatively robust infrastructure where tariff policies provide a greater impetus.
基金Project supported by the National Postdoctoral Science Foundation of China (No.20060400317)the Education Foundation of Zhejiang Province (No.20061459)the Young Foundation of Zhejiang Province (No.0202303005),China
文摘An expansion theory of spherical cavities in strain-softening materials with different moduli of tension and com-pression was presented. For geomaterials,two controlling parameters were introduced to take into account the different moduli and strain-softening properties. By means of elastic theory with different moduli and stress-softening models,general solutions cal-culating Tresca and Mohr-Coulomb materials' stress and displacement fields of expansion of spherical cavity were derived. The effects caused by different elastic moduli in tensile and compression and strain-softening rates on stress and displacement fields and development of plastic zone of expansion of cavity were analyzed. The results show that the ultimate expansion pressure,stress and displacement fields and development of plastic zone vary with the different elastic moduli and strain-softening prop-erties. If classical elastic theory is adopted and strain-softening properties are neglected,rather large errors may be the result.
基金financially supported by the Natural Science Foundation of Zhejiang Province of China(No.LY19B060002)the Enterprise Research Programme by Huzhou City of Zhejiang Province(China)founded by Huzhou Municipal Government(20190040)。
文摘Production of chemicals and fuels from microcrystalline cellulose has inspired scholars’ attention. Deactivation of metallic catalysts including acid leaching and hydrothermal aggregation is still one of the core issues in these systems. To address these problems, we designed and fabricated a series of Ni-W/SiO2 catalysts, which were decorated by CxNy species using C-and N- sources and applied in cellulose conversion to C2,3 oxygenated compounds. The Ni-W/SiO2@CxNy catalysts, underwent complexing and selfassembling process, exhibited special heterojunctions, accompanying strong interactions mainly among Ni phase and CxNy layers. Catalytic results showed that the heterojunctions and outer CxNy layers extensively enhanced productions of hydroxyacetone(HDA) and ethylene glycol(EG) and promoted the hydrothermal stability through prospering in concentration of Lewis pairs from Ni–N—N structure and immobilizing the metallic nanoclusters. 48.25% of EG was yielded under 5.0 MPa H2 pressurized 240 ℃ water for 2.0 h. The Lewis pair further improved the formation of HDA with 20.92% yield. High hydrothermal stability of NiW/SiO2@CxNy catalyst was proved according to the recycling results and trace leaching concentration of Ni and W. This construction of metallic catalysts exploited a new strategy to manufacture extraordinary durability of metallic nanoclusters for cellulose conversion under harsh reaction conditions.
基金supported by NNSF of China(11471111,11561030 and 11261022)the Jiangxi Provincial Natural Science Foundation of China(20152ACB20002,20161BAB201019)Natural Science Foundation of Department of Education of Jiangxi Province,China(GJJ150301)
文摘In this article, first, we establish the Fekete and Szeg inequality for an interesting subclass of biholomorphic functions in the open unit disk U. Second, we generalize this result to the bounded starlike circular domain in C^n. The proofs of these results use some restrictive assumptions, which in the case of one complex variable are automatically satisfied.
基金financial support from the National Natural Science Foundation of China (21528302)Zhejiang Province Natural Science Foundation (LQ15B060004)
文摘The Co-based catalysts were prepared with different cobalt acetate solutions. Effects of p H value were studied deeply on Fischer–Tropsch synthesis(FTS) through a semi-batch reactor. Among all impregnation solutions(water, butanol, amyl alcohol, acetic acid, nitric acid and ammonium nitrate), the catalyst prepared by NH_4NO_3 solution showed the highest catalytic activity due to its small particle size and high reduction degree. However, the catalyst with the smallest particle size derived from water as impregnation solution exhibited low activity as well as high methane selectivity since it was difficult to be reduced and inactive in FTS. According to FT-IR spectra results, the low intensity of absorbed CO on the catalyst prepared from water solution resulted in low FTS activity. Whereas, the high activity of catalysts prepared from NH_4NO_3 solution could be explained by the high intensity of absorbed CO on the catalysts.The cobalt species on the catalysts prepared under lower p H conditions exhibited smaller particle size distribution as well as lower CO conversion than those prepared at higher p H value.
基金supported by National Natural Science Foundation of China(61273016)The Natural Science Foundation of Zhejiang Province(Y6100016)The Public Welfare Technology Application Research Project of Zhejiang Province Science and Technology Department(2015C33088)
文摘The initial-boundary value problem for a class of nonlinear hyperbolic equations system in bounded domain is studiedThe existence of global solutions for this problem is proved by constructing a stable set, and obtain the asymptotic stability of global solutions by means of a difference inequality.