Hydroxy-5-methyl-5, 10- dihydrophenophosphazine 10-oxide (1) was prepared by a new technique of treating 10-methoxy-5,10-dihydrophenophosphazine 10-oxide (2) with an equivalent of NaH in anhydrous DMF, and then at 120...Hydroxy-5-methyl-5, 10- dihydrophenophosphazine 10-oxide (1) was prepared by a new technique of treating 10-methoxy-5,10-dihydrophenophosphazine 10-oxide (2) with an equivalent of NaH in anhydrous DMF, and then at 120C for 3~4 h, which not only avoided poisonous and expensive methyl iodide used in literature, but made the consumption of NaH greatly decrease as well. The possible reaction mechanism was also described. The chemical structure of 1 was confirmed by IR, NMR, and mass spectroscopy.展开更多
A novel stochastic resonance algorithm was employed to enhance the signal-to-noise ratio (SNR) of signals of analytical chemistry. By using a gas chromatographic data set, it was proven that the SNR was greatly impro...A novel stochastic resonance algorithm was employed to enhance the signal-to-noise ratio (SNR) of signals of analytical chemistry. By using a gas chromatographic data set, it was proven that the SNR was greatly improved and the quantitative relationship between concentrations and chromatographic responses remained simultaneously. The linear range was extended beyond the instrumental detection limit.展开更多
In this paper,the Jacobson radical of (R[G])^G, the fixed point subring of a group ring (R[G]) is studied. Some related properties of (R[G])^G are discussed.
基金The authors would like to acknowledge support from the National Natural Science Foundation of China(29972006) especially to express the deep appreciation to Professor Q. J. Peng and Miss K. Jin from our laboratory for their assistance in performing str
文摘Hydroxy-5-methyl-5, 10- dihydrophenophosphazine 10-oxide (1) was prepared by a new technique of treating 10-methoxy-5,10-dihydrophenophosphazine 10-oxide (2) with an equivalent of NaH in anhydrous DMF, and then at 120C for 3~4 h, which not only avoided poisonous and expensive methyl iodide used in literature, but made the consumption of NaH greatly decrease as well. The possible reaction mechanism was also described. The chemical structure of 1 was confirmed by IR, NMR, and mass spectroscopy.
基金supported by the National Natural Science Foundation of China (No.20075024).
文摘A novel stochastic resonance algorithm was employed to enhance the signal-to-noise ratio (SNR) of signals of analytical chemistry. By using a gas chromatographic data set, it was proven that the SNR was greatly improved and the quantitative relationship between concentrations and chromatographic responses remained simultaneously. The linear range was extended beyond the instrumental detection limit.
基金Supported by the NSF of Educational Department of Henan Province(20025100003)
文摘In this paper,the Jacobson radical of (R[G])^G, the fixed point subring of a group ring (R[G]) is studied. Some related properties of (R[G])^G are discussed.
