Interaction between subsequent laser and ablated materials in laser processing changes the laser spatiotemporal distribution and has influences on the efficiency and quality of laser processing. The theoretical and ex...Interaction between subsequent laser and ablated materials in laser processing changes the laser spatiotemporal distribution and has influences on the efficiency and quality of laser processing. The theoretical and experimental researches on transportation behaviour of ablated materials are provided. It is shown that the velocity distribution of ablated materials is determined by ablation mechanism. The transportation behaviour of ablated materials is controlled by diffusion mechanism and light field force during laser pulse duration while it is only determined by diffusion mechanism when the laser pulse terminates. In addition, the spatiotemporal distribution of ablated materials is presented.展开更多
Conventional sutures used in surgical procedures often lack the capability to effectively monitor physical and chemical activities or the microbial environment of surgical wounds due to their inadequate mechanical pro...Conventional sutures used in surgical procedures often lack the capability to effectively monitor physical and chemical activities or the microbial environment of surgical wounds due to their inadequate mechanical properties,insufficient electrical accuracy and unstability.Here,we present a straightforward layer-by-layer coating technique that utilizes 3-glycidoxypropyltrimethoxysilane(CA),graphene oxide(GO),and ascorbic acid(AA)to develop conductive silk-based surgical sutures(CA-rGSFS).The CA-rGSFS feature a continuous reduced graphene oxide(rGO)film on their surface,forming robust hydrogen bonds with silk fibroin.The reduction process of rGO is confirmed through Raman analysis,demonstrating an enhanced D peak to G peak ratio.Notably,the CA-rGSFS exhibit exceptional mechanical properties and efficient electron transmission,with a knot-pull tensile strength of 2089.72±1.20 cN and an electrical conductivity of 130.30±11.34 S/m,respectively,meeting the requirements specified by the United States Pharmacopeia(USP)for 2-0 sutures.These novel CA-rGSFS demonstrate the ability to accurately track resistance changes in various fluid environments with rapid response,including saline,intestinal,and gastric fluids.The suture also retains remarkable stretchablility and stability even after enduring 3000 tensile cycles,highlighting their potential for precise surgical site monitoring during the wound healing process.展开更多
The publisher regrets to note that a production error has occurred in the placement of the two entire graphics of Fig.1 and Fig.2.The two entire graphics are wrongly exchanged in their position although the figure cap...The publisher regrets to note that a production error has occurred in the placement of the two entire graphics of Fig.1 and Fig.2.The two entire graphics are wrongly exchanged in their position although the figure captions are in their correct place.The publisher would like toapologiseforany inconveniencecaused.展开更多
Understanding and tuning charge transport over a single molecule is a fundamental topic in molecular electronics.Single-molecule junctions composed of individual molecules attached to two electrodes are the most commo...Understanding and tuning charge transport over a single molecule is a fundamental topic in molecular electronics.Single-molecule junctions composed of individual molecules attached to two electrodes are the most common components built for single-molecule charge transport studies.During the past two decades,rapid technical and theoretical advances in single-molecule junctions have increased our understanding of the conductance properties and functions of molecular devices.In this perspective article,we introduce the basic principles of charge transport in single-molecule junctions,then give an overview of recent progress in modulating single-molecule transport through external stimuli such as electric field and potential,light,mechanical force,heat,and chemical environment.Lastly,we discuss challenges and offer views on future developments in molecular electronics.展开更多
基金Supported by the National Natural Science Foundation of China under Grants No 60778007, the Jiangsu Postdoctoral Foundation of China under Grant No 0601008B, the Research Initial Funding Project of Nanjing University of Posts and Telecommunications for Introduction of Foreign Talent under Grant No NY207023.
文摘Interaction between subsequent laser and ablated materials in laser processing changes the laser spatiotemporal distribution and has influences on the efficiency and quality of laser processing. The theoretical and experimental researches on transportation behaviour of ablated materials are provided. It is shown that the velocity distribution of ablated materials is determined by ablation mechanism. The transportation behaviour of ablated materials is controlled by diffusion mechanism and light field force during laser pulse duration while it is only determined by diffusion mechanism when the laser pulse terminates. In addition, the spatiotemporal distribution of ablated materials is presented.
基金supported by the National Natural Science Foundation of China(Grant No.82374295)the support of the National Key R&D Program of China(Grant No.2021YFE0111100)+2 种基金the Science and Technology Partnership Program by the Ministry of Science and Technology of China(Grant No.KY202201002)Jiangsu Provincial Department of Science and Technology(Grant No.BZ2022017)China National Textile and Apparel Council(Grant No.J202002)。
文摘Conventional sutures used in surgical procedures often lack the capability to effectively monitor physical and chemical activities or the microbial environment of surgical wounds due to their inadequate mechanical properties,insufficient electrical accuracy and unstability.Here,we present a straightforward layer-by-layer coating technique that utilizes 3-glycidoxypropyltrimethoxysilane(CA),graphene oxide(GO),and ascorbic acid(AA)to develop conductive silk-based surgical sutures(CA-rGSFS).The CA-rGSFS feature a continuous reduced graphene oxide(rGO)film on their surface,forming robust hydrogen bonds with silk fibroin.The reduction process of rGO is confirmed through Raman analysis,demonstrating an enhanced D peak to G peak ratio.Notably,the CA-rGSFS exhibit exceptional mechanical properties and efficient electron transmission,with a knot-pull tensile strength of 2089.72±1.20 cN and an electrical conductivity of 130.30±11.34 S/m,respectively,meeting the requirements specified by the United States Pharmacopeia(USP)for 2-0 sutures.These novel CA-rGSFS demonstrate the ability to accurately track resistance changes in various fluid environments with rapid response,including saline,intestinal,and gastric fluids.The suture also retains remarkable stretchablility and stability even after enduring 3000 tensile cycles,highlighting their potential for precise surgical site monitoring during the wound healing process.
文摘The publisher regrets to note that a production error has occurred in the placement of the two entire graphics of Fig.1 and Fig.2.The two entire graphics are wrongly exchanged in their position although the figure captions are in their correct place.The publisher would like toapologiseforany inconveniencecaused.
基金This work was supported by the National Natural Science Foundation of China(21788102,21790361,22175064,22073109,and 92161122)Shanghai Municipal Sci.&Tech.Major Project(2018SHZDZX03)+1 种基金the 111 Project(B16017)the Fundamental Research Funds for the Central Universities.
文摘Understanding and tuning charge transport over a single molecule is a fundamental topic in molecular electronics.Single-molecule junctions composed of individual molecules attached to two electrodes are the most common components built for single-molecule charge transport studies.During the past two decades,rapid technical and theoretical advances in single-molecule junctions have increased our understanding of the conductance properties and functions of molecular devices.In this perspective article,we introduce the basic principles of charge transport in single-molecule junctions,then give an overview of recent progress in modulating single-molecule transport through external stimuli such as electric field and potential,light,mechanical force,heat,and chemical environment.Lastly,we discuss challenges and offer views on future developments in molecular electronics.